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G. van der Laan

Publications and source records attributed to G. van der Laan.

At least 19 recordsLinked to original sources

Quasi-1D Spin Textures: From Chiral Soliton Lattice to Fan State

In most helimagnets, an applied magnetic field aligns the propagation direction of a helical spin texture with the field, resulting in a conical state and obscuring the unwinding process. Here, we access a complementary regime in the anisotropic chiral magnet Mn$_{1.4}$PtSn, where crystal symmetry constrains the propagation direction of the spin modulation. Using resonant elastic X-ray scattering in a vector magnet, we track the evolution of quasi-one-dimensional spin textures that propagate along a chiral crystallographic axis while the magnetic field is applied perpendicular to this direction. Together with micromagnetic simulations, our measurements reveal a transformation from the zero-field $π$-chiral soliton lattice into a fan-like state. In this state, the propagation direction remains transverse to the applied field, while the spins oscillate about the field direction. During magnetization, the modulation length decreases continuously with the field and approaches the field-polarized state. Simulations indicate that magnetostatic interactions in finite samples play a key role in stabilizing this behavior. Our results provide evidence for a fan-like regime in a chiral magnet and highlight how field orientation can be used to control one-dimensional spin textures.

cond-mat.mtrl-sci↗

Field-induced condensation of $π$ to 2$π$ soliton lattices in chiral magnets

Chiral soliton lattices (CSLs) are nontrivial spin textures that emerge from the competition between Dzyaloshinskii-Moriya interaction, anisotropy, and magnetic fields. While well established in monoaxial helimagnets, their role in materials with anisotropic, direction-dependent chirality remains poorly understood. Here, we report the direct observation of a tunable transition from $π$ to 2$π$ soliton lattices in the non-centrosymmetric Heusler compound Mn1.4PtSn. Using Lorentz transmission electron microscopy, resonant elastic X-ray scattering, and micromagnetic simulations, we identify a $π$-CSL as the magnetic ground state, in contrast to the expected helical phase, which evolves into a classical 2$π$-CSL under increasing out-of-plane magnetic fields. This transition is governed by a delicate interplay between uniaxial magnetocrystalline anisotropy and magnetostatic interactions, as captured by a double sine-Gordon model. Our analysis not only reveals the microscopic mechanisms stabilizing these soliton lattices but also demonstrates their general relevance to materials with D2d, S4, Cnv, or Cn symmetries. The results establish a broadly applicable framework for understanding magnetic phase diagrams in chiral systems, with implications for soliton-based spintronic devices and topological transport phenomena.

cond-mat.mtrl-sci↗

Microscopic Observation of Non-Ergodic States in Two-Dimensional Non-Topological Bubble Lattices

Disordered 2D lattices, including hexatic and various glassy states, are observed in a wide range of 2D systems including colloidal nanoparticle assemblies and fluxon lattices. Their disordered nature determines the stability and mobility of these systems, as well as their response to the external stimuli. Here we report on the controlled creation and characterization of a disordered 2D lattice of non-topological magnetic bubbles in the non-centrosymmetric ferrimagnetic alloy Mn$_{1.4}$PtSn. By analyzing the type and frequency of fundamental lattice defects, such as dislocations, the orientational correlation, as well as the induced motion of the lattice in an external field, a non-ergodic glassy state, stabilized by directional application of an external field, is revealed.

cond-mat.mtrl-sci↗

Discovery of an Antiferromagnetic Topological Nodal-line Kondo Semimetal

The symbiosis of strong interactions, flat bands, topology and symmetry has led to the discovery of exotic phases of matter, including fractional Chern insulators, correlated moiré topological superconductors, and Dirac and Weyl semimetals. Correlated metals, such as those present in Kondo lattices, rely on the screening of local moments by a sea of non-magnetic conduction electrons. Here, we report on a unique topological Kondo lattice compound, CeCo2P2, where the Kondo effect - whose existence under the magnetic Co phase is protected by PT symmetry - coexists with antiferromagnetic order emerging from the flat bands associated with the Co atoms. Remarkably, this is the only known Kondo lattice compound where magnetic order occurs in non-heavy electrons, and puzzlingly, at a temperature significantly higher than that of the Kondo effect. Furthermore, at low temperatures, the emergence of the Kondo effect, in conjunction with a glide-mirror-z symmetry, results in a nodal line protected by bulk topology near the Fermi energy. These unusual properties, arising from the interplay between itinerant and correlated electrons from different constituent elements, lead to novel quantum phases beyond the celebrated topological Kondo insulators and Weyl Kondo semimetals. CeCo2P2 thus provides an ideal platform for investigating narrow bands, topology, magnetism, and the Kondo effect in strongly correlated electron systems.

cond-mat.str-el↗

A case for Bragg diffraction by a noncollinear (PT)-symmetric antiferromagnet Cu$_2$(MoO$_4$)(SeO$_3$)

Antiferromagnetic compounds chromium sesquioxide (Cr$_2$O$_3$) and dioxomolybdenum selenite present linear magnetoelectric effects. Anti-inversion symmetry in the corresponding magnetic crystal classes dictate the makeup of magnetic Bragg diffraction patterns. Copper axial and polar magnetic multipoles contribute to resonant x-ray and magnetic neutron amplitudes in a symmetry informed analysis of monoclinic Cu$_2$(MoO$_4$)(SeO$_3$) presented with a view to steering future diffraction experiments. The compound might be viewed as a low-dimensional quantum magnet on account of its crystal structure and extreme Cu spin (S = 1/2).

cond-mat.str-el↗

Depth-dependent magnetic crossover in a room-temperature skyrmion-hosting multilayer

Skyrmion-hosting multilayer stacks are promising avenues for applications, although little is known about the depth dependence of the magnetism. We address this by reporting the results of circular dichroic resonant elastic x-ray scattering (CD-REXS), micromagnetic simulations, and low-energy muon-spin rotation (LE-$μ^+$SR) measurements on a stack comprising [Ta/CoFeB/MgO]$_{16}$/Ta on a Si substrate. Energy-dependent CD-REXS shows a continuous, monotonic evolution of the domain-wall helicity angle with incident energy, consistent with a three-dimensional hybrid domain-wall-like structure that changes from Néel-like near the surface to Bloch-like deeper within the sample. LE-$μ^+$SR reveals that the magnetic field distribution in the trilayers near the surface of the stack is distinct from that in trilayers deeper within the sample. Our micromagnetic simulations support a quantitative analysis of the $μ^+$SR results. By increasing the applied magnetic field, we find a reduction in the volume occupied by domain walls at all depths, consistent with a crossover into a region dominated by skyrmions above approximately 180 mT.

cond-mat.str-el↗

Evidence of temperature-dependent interplay between spin and orbital moment in van der Waals ferromagnet VI3

Van der Waals materials provide a versatile toolbox for the emergence of new quantum phenomena and the fabrication of functional heterostructures. Among them, the trihalide VI3 stands out for its unique magnetic and structural landscape. Here we investigate the spin and orbital magnetic degrees of freedom in the layered ferromagnet VI3 by means of temperature-dependent x-ray absorption spectroscopy and x-ray magnetic circular and linear dichroism. We detect localized electronic states and reduced magnetic dimensionality, due to electronic correlations. We furthermore provide experimental evidence of (a) an unquenched orbital magnetic moment (up to 0.66(7)) in the ferromagnetic state, and (b) an instability of the orbital moment in proximity of the spin reorientation transition. Our results support a coherent picture where electronic correlations give rise to a strong magnetic anisotropy and a large orbital moment, and establish VI3 as a prime candidate for the study of orbital quantum effects.

cond-mat.mtrl-sci↗

Templates for magnetic symmetry and altermagnetism in hexagonal MnTe

The symmetry of long-range magnetic order in manganese telluride (alpha-MnTe) is unknown. Likewise, its standing as an altermagnet. To improve the situation, we present symmetry informed Bragg diffraction patterns based on a primary magnetic order parameter for antiferromagnetic alignment between Mn dipoles. It does not break translation symmetry in a centrosymmetric structure, in keeping with an accepted definition of altermagnetism. Our templates serve x-ray diffraction that benefits from signal enhancement using a Mn atomic resonance, and neutron scattering. Even rank multipoles in magnetic neutron diffraction reflect a core requirement of altermagnetism, because they are zero for strong spin-orbit coupling. Symmetry in the templates demands that nuclear and magnetic contributions possess the same phase, which enables standard neutron polarization analysis on Bragg spots with overlapping contributions. However, three of the four templates generate Bragg spots that do not appear in the lattice (nuclear) diffraction pattern, i.e., Bragg spots that are basis-forbidden and purely magnetic in origin. On the other hand, identical symmetry demands a 90 deg phase shift between magnetic (time-odd) and charge-like (time-even, Templeton-Templeton) contributions to x-ray scattering amplitudes. Consequently, circular polarization in the primary beam of x-rays is rotated. The difference in the intensities of a Bragg spot measured with right- and left-handed circular primary polarization defines a chiral signature. Further tests include predictions in three out four templates of zero intensity in a specified channel of x-ray polarization. Diffraction properties of a template are radically different from those of a parity-time (PT)-symmetric antiferromagnet, for its symmetry allows a linear ME effect and prohibits both a PM effect and a chiral signature.

cond-mat.str-el↗

A magnetic structure of ruthenium dioxide (RuO2) and altermagnetism

The magnetic structure of RuO2 and the Ru atomic configuration are unknown. A magnetic structure is inferred by confronting measured and calculated Bragg diffraction patterns and adjusting the latter to achieve satisfactory agreement. An accepted pattern, a magnetic symmetry, includes symmetry of sites occupied by the magnetic ions. As a realistic starting point, we provide diffraction patterns for a magnetic symmetry of RuO2, a descendent of the tetragonal parent structure, which accommodates a departure of Ru axial dipoles from the crystal c axis. A chiral signal and piezomagnetic effect are permitted, and a linear magnetoelectric effect forbidden. Features of the neutron diffraction pattern test the non-relativistic requirement of altermagnetism, and we scrutinize published room-temperature data. Specifically, one Bragg point is consistent with Ru orbital angular momentum and magnetic quadrupole both zero, and the latter result is not expected from non-relativistic altermagnetism. Azimuthal angle scans in resonant x-ray diffraction are sensitive to the Ru site symmetry and the atomic configuration. Acid tests of the studied magnetic symmetry include a chiral signature and null intensity for unrotated photon polarization.

cond-mat.str-el↗

Anisotropic hybridization probed by polarization dependent x-ray absorption spectroscopy in VI3 van der Waals Mott ferromagnet

Polarization dependent x-ray absorption spectroscopy was used to study the magnetic ground state and the orbital occupation in bulk-phase VI$_3$ van der Waals crystals below and above the ferromagnetic and structural transitions. X-ray natural linear dichroism and X-ray magnetic circular dichroism spectra acquired at the V $L_{2,3}$ edges are compared against multiplet cluster calculations within the frame of the ligand field theory to quantify the intra-atomic electronic interactions at play and evaluate the effects of symmetry reduction occurring in a trigonally distorted VI$_6$ unit. We observed a non zero linear dichroism proving the presence of an anisotropic charge density distribution around the V$^{3+}$ ion due to the unbalanced hybridization between the Vanadium and the ligand states. Such hybridization acts as an effective trigonal crystal field, slightly lifting the degeneracy of the $t_{2g}^2$ ground state. However, the energy splitting associated to the distortion underestimates the experimental band gap, suggesting that the insulating ground state is stabilized by Mott correlation effects rather than via a Jahn-Teller mechanism. Our results clarify the role of the distortion in VI$_3$ and establish a benchmark for the study of the spectroscopic properties of other van der Waals halides, including emerging 2D materials with mono and few-layers thickness, whose fundamental properties might be altered by reduced dimensions and interface proximity.

cond-mat.str-el↗

Synchrotron Radiation Techniques and their Application to Actinide Materials

Research on actinide materials, both basic and applied, has been greatly advanced by the general techniques available from high-intensity photon beams from x-ray synchrotron sources. The most important single reason is that such x-ray sources can work with minute (e.g., microgram) samples, and at this level, the radioactive hazards of actinides are much reduced. We start by discussing the form and encapsulation procedures used for different techniques, then discuss the basic theory for interpreting the results. By reviewing a selection of x-ray diffraction (XRD), resonant elastic x-ray scattering (REXS), x-ray magnetic circular dichroism (XMCD), resonant and non-resonant inelastic scattering (RIXS, NIXS), dispersive inelastic x-ray scattering (IXS), and conventional and resonant photoemission experiments, we demonstrate the potential of synchrotron radiation techniques in studying lattice and electronic structure, hybridization effects, multipolar order, and lattice dynamics in actinide materials.

cond-mat.mtrl-sci↗

Robust Kagome Electronic Structure in Topological Quantum Magnets XMn6Sn6 (X = Dy, Tb, Gd, Y)

Crystal geometry can greatly influence the emergent properties of quantum materials. As an example, the kagome lattice is an ideal platform to study the rich interplay between topology, magnetism, and electronic correlation. In this work, combining high-resolution angle-resolved photoemission spectroscopy and ab-initio calculation, we systematically investigate the electronic structure of XMn6Sn6 (X = Dy, Tb, Gd, Y) family compounds. We observe the Dirac fermion and the flat band arising from the magnetic kagome lattice of Mn atoms. Interestingly, the flat band locates in the same energy region in all compounds studied, regardless of their different magnetic ground states and 4f electronic configurations. These observations suggest a robust Mn magnetic kagome lattice across the XMn6Sn6 family, thus providing an ideal platform for the search and investigation on new emergent phenomena in magnetic topological materials.

cond-mat.str-el↗

Ligand-metal covalency effects in resonance enhanced x-ray Bragg diffraction

Chlorine covalently bonded to an open shell metal is present in many materials with desirable or intriguing physical properties. Materials include highly luminescent nontoxic alternatives to lead halide perovskites for optoelectronic applications K2CuCl3 and Rb2CuCl3, enantiomorphic CsCuCl3 that presents magneto-chiral dichroism at a low temperature, and cubic K2RuCl6 that possesses a singlet ground state generated by antiparallel spin and orbital angular momenta. Structural chirality of CsCuCl3 has been confirmed by resonant x-ray Bragg diffraction. We explore likely benefits of the technique at the chlorine K-edge using a symmetry inspired method of calculation applied to chlorine multipoles. Already, a low energy feature in corresponding x-ray absorption spectra of many compounds has been related to the chlorine-metal bond. Bragg diffraction from chlorine in cubic K2RuCl6 is treated in detail. Diffraction patterns for rhombohedral compounds that present space-group forbidden Bragg spots are found to be relatively simple.

cond-mat.str-el↗

Magnetic properties of ruthenium dioxide (RuO2) and charge-magnetic interference in Bragg diffraction of circularly polarized x-rays

Rutile-type RuO2 likely supports a simple antiferromagnetic structure which can be verified by x-ray Bragg diffraction. Three magnetic motifs that do not break translation symmetry are explored in calculations of amplitudes suitable for diffraction enhanced by tuning the primary x-ray energy to a ruthenium atomic resonance. Coupling to x-ray helicity through a charge-magnetic interference is common to all motifs, together with magnetic and charge intensities in quadrature in the rotated channel of polarization. Necessary conditions for these diffraction phenomena are a centrosymmetric crystal structure, null magnetic propagation vector, and absence of a linear magnetoelectric effect. Published x-ray diffraction data for RuO2 was analysed by the authors against a magnetic motif that does not satisfy the conditions. A polarized neutron study of antiferromagnetic domains can be achieved with a sample that meets the stated crystal and magnetic symmetries.

cond-mat.str-el↗

Spin-current mediated exchange coupling in MgO-based magnetic tunnel junctions

Heterostructures composed of ferromagnetic layers that are mutually interacting through a nonmagnetic spacer are at the core of magnetic sensor and memory devices. In the present study, layer-resolved ferromagnetic resonance was used to investigate the coupling between the magnetic layers of a Co/MgO/Permalloy magnetic tunnel junction. Two magnetic resonance peaks were observed for both magnetic layers, as probed at the Co and Ni L3 x-ray absorption edges, showing a strong interlayer interaction through the insulating MgO barrier. A theoretical model based on the Landau-Lifshitz-Gilbert-Slonczewski equation was developed, including exchange coupling and spin pumping between the magnetic layers. Fits to the experimental data were carried out, both with and without a spin pumping term, and the goodness of the fit was compared using a likelihood ratio test. This rigorous statistical approach provides an unambiguous proof of the existence of interlayer coupling mediated by spin pumping.

cond-mat.mtrl-sci↗

Absence of magnetic-proximity effect at the interface of Bi$_2$Se$_3$ and (Bi,Sb)$_2$Te$_3$ with EuS

We performed x-ray magnetic circular dichroism (XMCD) measurements on heterostructures comprising topological insulators (TIs) of the (Bi,Sb)$_2$(Se,Te)$_3$ family and the magnetic insulator EuS. XMCD measurements allow us to investigate element-selective magnetic proximity effects at the very TI/EuS interface. A systematic analysis reveals that there is neither significant induced magnetism within the TI nor an enhancement of the Eu magnetic moment at such interface. The induced magnetic moments in Bi, Sb, Te, and Se sites are lower than the estimated detection limit of the XMCD measurements of $\sim\!10^{-3}$ $μ_\mathrm{B}$/at.

cond-mat.mes-hall↗

Electronic multipoles in second harmonic generation and neutron scattering

Nonlinear optics, and particularly second harmonic generation (SHG), is increasingly used in many modern disciplines from material characterization in physical sciences to bio-imaging in medicine and optical signal processing in information technology. We present a theoretical analysis providing a strong estimate for the energy-integrated SHG response. Requirements of symmetry in time and space are fully respected in the calculation, and estimates of natural and magnetic circular dichroic signals are superior to previous ones. Like symmetry requirements are traced in the amplitude for magnetic neutron scattering, which includes all axial and polar (Dirac) contributions. Our method of working, in terms of spherical multipoles and implementation of symmetry, could be of use in a variety of other probes of electronic properties.

cond-mat.str-el↗

Diffraction by multipoles in a 5d2 rhenium double perovskite

A recent polarized neutron diffraction experiment on the 5d2 rhenium double perovskite Ba2YReO6 held at a low temperature uncovered weak magnetic diffraction peaks. Data analysis inferred a significantly reduced Re dipole moment, and long-range order compatible with an antiferromagnet, non-collinear motif. To interpret the experimental findings, we present a model wavefunction for Re ions derived from the crystal field potential, Coulomb interaction, and spin-orbit coupling that fully respects the symmetry of the low-temperature ordered state. It is used to calculate in analytic form all multipole moments visible in neutron and resonance enhanced x-ray diffraction. A minimal model consistent with available neutron diffraction data predicts significant multipolar moments up to the hexadecapole, and, in particular, a dominant charge-like quadrupole moment. Calculated diffraction patterns embrace single crystal x-ray diffraction at the Re L-edge, and renewed neutron diffraction, to probe the presumed underlying multipolar order.

cond-mat.str-el↗