Superconductivity and Magnetism in Bi-Ni System: From Bulk to Heterostructures
Unconventional superconductivity with ingredients of magnetism such as time reversal breaking, triplet pairing and proximity effects has been a long time pursued topic in physics and material science as a new source of innovative phenomena and effects to drive further scientific advances and technologies. The Bi-Ni system has emerged as a convenient candidate for the investigation of such phenomenology. Strictly speaking, the term Bi-Ni system refers to two different schemes, first to the NiBi$_{3}$ intermetallic compound, a 4 K superconductor in which a complex magnetism seems to govern electrical properties in the normal phase, but without implication in the superconducting properties. The second Bi-Ni system is not quite a material but a heterostructure formed by a bilayer of Bi and Ni. Here the superconducting phase has to steal the spotlight by showing strong evidence of time-reversal breaking and triplet pairing featuring a complex unconventional state. The ease of preparing the samples, compared to other candidates for such unconventionality, usually Uranium-based compounds, has accelerated the research in this system. Here, we went through a detailed review of the main results about the electronic properties of these two systems as well as a discussion of the main open questions to be solved in order to reach the complete understanding in this topic.