Bounds on scattering amplitudes of non-identical scalar particles in 4d
We initiate the study of two-to-two scattering amplitudes involving two distinct scalar particles in $d = 4$ spacetime dimensions using the primal S-matrix bootstrap. We impose a $\mathbb{Z}_2 \times \mathbb{Z}_2$ global symmetry under which the two particles are the lightest ones carrying charges $(-,+)$ and $(+,-)$, guaranteeing their absolute stability and absence of triangular anomalous thresholds. For unequal masses, the presence of a pseudo-physical cut whose discontinuity is not directly constrained by physical unitarity qualitatively changes the bootstrap problem. We find several observables to be unbounded, while others obey non-trivial one-sided bounds or become bounded once another observable is fixed. In the equal-mass limit, where the pseudo-physical region disappears, two-sided bounds are recovered. As a proof of concept, we show that supplying information about the pseudo-physical discontinuity through an Omn\`es parametrisation also restores boundedness. Our results provide a starting point for future studies of physical processes such as pion-kaon and pion-nucleon scattering.