arXiv subjects

Gary P. Centers

Publications and source records attributed to Gary P. Centers.

8 recordsLinked to original sources

arXiv2025

Nuclear spin relaxation in zero- to ultralow-field magnetic resonance spectroscopy

Nuclear-magnetic-resonance experiments can interrogate a broad spectrum of molecular-tumbling regimes and can accurately measure interatomic distances in solution with sub-nanometer resolution. In the zero- to ultralow-field (ZULF) regime, population and coherence decay reveal nontrivial behavior due to strong coupling between nuclear spins. We note, in particular, the surprising effects that different resonances show different relaxation rates, depending on (i) the (pre)polarizing magnet field and the shuttling trajectory to the detection region at nano- and microtesla fields, (ii) the strength of the measurement field, (iii) the detection method (single-channel or quadrature), and even (iv) the nutation angle induced by the excitation pulse. We describe herein experimental data of relaxation rates measured for a 13C-labeled formic acid sample, with an atomic-magnetometer-based ZULF setup, and develop a theoretical framework to explain the detected effects and extract molecular properties. The observed effects could be used for spectral assignment, for the establishment of specific motional regimes, for image contrast, and for the characterization of relaxation processes at nano- to microtesla magnetic fields.

physics.chem-ph↗

arXiv2023

Intensity interferometry for ultralight bosonic dark matter detection

Ultralight bosonic dark matter (UBDM) can be described by a classical wave-like field oscillating near the Compton frequency of the bosons. If a measurement scheme for the direct detection of UBDM interactions is sensitive to a signature quadratic in the field, then there is a near-zero-frequency (dc) component of the signal. Thus, a detector with a given finite bandwidth can be used to search for bosons with Compton frequencies many orders of magnitude larger than its bandwidth. This opens the possibility of a detection scheme analogous to Hanbury Brown and Twiss intensity interferometry. Assuming that the UBDM is virialized in the galactic gravitational potential, the random velocities produce slight deviations from the Compton frequency. These result in stochastic fluctuations of the intensity on a time scale determined by the spread in kinetic energies. In order to mitigate ubiquitous local low-frequency noise, a network of sensors can be used to search for the stochastic intensity fluctuations by measuring cross-correlation between the sensors. This method is inherently broadband, since a large range of Compton frequencies will yield near-zero-frequency components within the sensor bandwidth that can be searched for simultaneously. Measurements with existing sensor networks have sufficient sensitivity to search experimentally unexplored parameter space.

hep-ph↗

arXiv2022

Spectral signatures of axionlike dark matter

We derive spectral line shapes of the expected signal for a haloscope experiment searching for axionlike dark matter. The knowledge of these line shapes is needed to optimize an experimental design and data analysis procedure. We extend the previously known results for the axion-photon and axion-gluon couplings to the case of gradient (axion-fermion) coupling. A unique feature of the gradient interaction is its dependence not only on magnitudes but also on directions of velocities of galactic halo particles, which leads to the directional sensitivity of the corresponding haloscope. We also discuss the daily and annual modulations of the gradient signal caused by the Earth's rotational and orbital motions. In the case of detection, these periodic modulations will be an important confirmation that the signal is sourced by axionlike particles in the halo of our Galaxy.

hep-ph↗

arXiv2021

Search for axion-like dark matter using solid-state nuclear magnetic resonance

We report the results of an experimental search for ultralight axion-like dark matter in the mass range 162 neV to 166 neV. The detection scheme of our Cosmic Axion Spin Precession Experiment (CASPEr) is based on a precision measurement of $^{207}$Pb solid-state nuclear magnetic resonance in a polarized ferroelectric crystal. Axion-like dark matter can exert an oscillating torque on $^{207}$Pb nuclear spins via the electric-dipole moment coupling $g_d$, or via the gradient coupling $g_{\text{aNN}}$. We calibrated the detector and characterized the excitation spectrum and relaxation parameters of the nuclear spin ensemble with pulsed magnetic resonance measurements in a 4.4 T magnetic field. We swept the magnetic field near this value and searched for axion-like dark matter with Compton frequency within a 1 MHz band centered at 39.65 MHz. Our measurements place the upper bounds $|g_d|<9.5\times10^{-4}\,\text{GeV}^{-2}$ and $|g_{\text{aNN}}|<2.8\times10^{-1}\,\text{GeV}^{-1}$ (95% confidence level) in this frequency range. The constraint on $g_d$ corresponds to an upper bound of $1.0\times 10^{-21}\,\text{e}\cdot\text{cm}$ on the amplitude of oscillations of the neutron electric dipole moment, and $4.3\times 10^{-6}$ on the amplitude of oscillations of CP-violating $θ$ parameter of quantum chromodynamics. Our results demonstrate the feasibility of using solid-state nuclear magnetic resonance to search for axion-like dark matter in the nano-electronvolt mass range.

hep-ex↗

arXiv2021

Quantum sensitivity limits of nuclear magnetic resonance experiments searching for new fundamental physics

Nuclear magnetic resonance is a promising experimental approach to search for ultra-light axion-like dark matter. Searches such as the cosmic axion spin-precession experiments (CASPEr) are ultimately limited by quantum-mechanical noise sources, in particular, spin-projection noise. We discuss how such fundamental limits can potentially be reached. We consider a circuit model of a magnetic resonance experiment and quantify three noise sources: spin-projection noise, thermal noise, and amplifier noise. Calculation of the total noise spectrum takes into account the modification of the circuit impedance by the presence of nuclear spins, as well as the circuit back-action on the spin ensemble. Suppression of the circuit back-action is especially important in order for the spin-projection noise limits of searches for axion-like dark matter to reach the quantum chromodynamic axion sensitivity.

quant-ph↗

arXiv2020

Stochastic fluctuations of bosonic dark matter

Numerous theories extending beyond the standard model of particle physics predict the existence of bosons that could constitute the dark matter (DM) permeating the universe. In the standard halo model (SHM) of galactic dark matter the velocity distribution of the bosonic DM field defines a characteristic coherence time $τ_c$. Until recently, laboratory experiments searching for bosonic DM fields have been in the regime where the measurement time $T$ significantly exceeds $τ_c$, so null results have been interpreted as constraints on the coupling of bosonic DM to standard model particles with a bosonic DM field amplitude $Φ_0$ fixed by the average local DM density. However, motivated by new theoretical developments, a number of recent searches probe the regime where $T\llτ_c$. Here we show that experiments operating in this regime do not sample the full distribution of bosonic DM field amplitudes and therefore it is incorrect to assume a fixed value of $Φ_0$ when inferring constraints on the coupling strength of bosonic DM to standard model particles. Instead, in order to interpret laboratory measurements (even in the event of a discovery), it is necessary to account for the stochastic nature of such a virialized ultralight field (VULF). The constraints inferred from several previous null experiments searching for ultralight bosonic DM were overestimated by factors ranging from 3 to 10 depending on experimental details, model assumptions, and choice of inference framework.

astro-ph.CO↗

arXiv2019

Constraints on bosonic dark matter from ultralow-field nuclear magnetic resonance

The nature of dark matter, the invisible substance making up over $80\%$ of the matter in the Universe, is one of the most fundamental mysteries of modern physics. Ultralight bosons such as axions, axion-like particles or dark photons could make up most of the dark matter. Couplings between such bosons and nuclear spins may enable their direct detection via nuclear magnetic resonance (NMR) spectroscopy: as nuclear spins move through the galactic dark-matter halo, they couple to dark-matter and behave as if they were in an oscillating magnetic field, generating a dark-matter-driven NMR signal. As part of the Cosmic Axion Spin Precession Experiment (CASPEr), an NMR-based dark-matter search, we use ultralow-field NMR to probe the axion-fermion "wind" coupling and dark-photon couplings to nuclear spins. No dark matter signal was detected above background, establishing new experimental bounds for dark-matter bosons with masses ranging from $1.8\times 10^{-16}$ to $7.8\times 10^{-14}$ eV.

hep-ex↗

arXiv2019

Search for axionlike dark matter with a liquid-state nuclear spin comagnetometer

We report the results of a search for axionlike dark matter using nuclear magnetic resonance (NMR) techniques. This search is part of the multi-faceted Cosmic Axion Spin Precession Experiment (CASPEr) program. In order to distinguish axionlike dark matter from magnetic fields, we employ a comagnetometry scheme measuring ultralow-field NMR signals involving two different nuclei ($^{13}$C and $^{1}$H) in a liquid-state sample of acetonitrile-2-$^{13}$C ($^{13}$CH$_{3}$CN). No axionlike dark matter signal was detected above background. This result constrains the parameter space describing the coupling of the gradient of the axionlike dark matter field to nucleons to be $g_{aNN}<6\times 10^{-5}$ GeV$^{-1}$ (95$\%$ confidence level) for particle masses ranging from $10^{-22}$ eV to $1.3\times10^{-17}$ eV, improving over previous laboratory limits for masses below $10^{-21}$ eV. The result also constrains the coupling of nuclear spins to the gradient of the square of the axionlike dark matter field, improving over astrophysical limits by orders of magnitude over the entire range of particle masses probed.

hep-ex↗