arXiv subjects

Geoffrey A. Blake

Publications and source records attributed to Geoffrey A. Blake.

At least 19 recordsLinked to original sources

arXiv2026

A Sulfur-Rich Atmosphere for the Young Jupiter Analog AF Lep b Reveals Significant Solid Accretion

AF Lep b is one of the closest analogs to Jupiter in terms of mass ($3-4~M_{\rm{Jup}}$) and semi-major axis ($9$ AU) amenable to spectroscopic characterization. We present JWST/NIRSpec high-contrast spectroscopy of the planet from $2.85-5.3~\mu$m at $R\sim3000$, which provide detections of CO$_2$, H$_2$S, CH$_4$, $^{12}$CO (and $^{13}$CO), and H$_2$O, as well as complementary JWST/NIRCam imaging that captures the planet's continuum flux from $4.0-4.7~\mu$m. Combining the JWST observations with spectra from VLTI/GRAVITY and VLT/SPHERE ($1.0-2.5~\mu$m), we carry out atmospheric retrievals that include the effects of clouds and disequilibrium chemistry while allowing the C, O, and S abundances to vary independently. AF Lep b exhibits metal enrichment across C, O, and S with $\rm C/H=2.9\pm0.5$, $\rm O/H=3.7\pm0.6$, and $\rm S/H=4.7\pm0.7~\times$ solar (and stellar). The planet's slightly sub-solar C/O and C/S are consistent with formation near its observed location, and disfavor formation beyond the CO snowline. The sulfur enrichment in AF Lep b implies significant accretion of disk solids during formation, and we estimate the planet contains $56\pm7~M_{\oplus}$ of solids. The C, O, and S enrichment levels of AF Lep b are similar to those of Jupiter, and other super-Jupiters like HR 8799 bcde. We also show that the degree of atmospheric metal enrichment of these imaged planets is similar to the bulk metal enrichment of transiting gas giants with masses greater than $\sim1~M_{\rm{Jup}}$, suggesting that the process and efficiency of metal accretion for gas giants may not be strongly dependent on orbital distance or planet mass.

astro-ph.EP↗

arXiv2026

The JDISC Survey: Inner Disk Chemistry of Class I/FS Disks and Tentative Evidence for Early Pebble Drift

We present the first chemical survey of Class I and Flat-Spectrum (I/FS) disks using JWST MIRI/MRS, targeting sixteen sources in the Ophiuchus star-forming region. Through empirical line luminosity measurements and multi-component slab modeling, we characterize the molecular reservoir of these young systems and compare them to twelve Class II disks of similar stellar mass. Water, HCN, C$_2$H$_2$, and CO$_2$ are frequently detected in I/FS sources with inclinations $i < 70^{\circ}$, whereas edge-on systems show significantly suppressed emission. Compared to Class II disks, I/FS sources show suggestive---though not yet statistically significant---evidence for elevated cold water ($\sim$200\,K) mass and lower CO$_2$ excitation temperatures. Statistical analyses identify accretion luminosity as the primary correlate of molecular mass across both evolutionary stages. Once this dependence is removed, cold water and CO$_2$ masses anti-correlate with mm-dust disk radius, while hot water remains insensitive to disk size. These patterns are qualitatively consistent with pebble drift models that predict early water enrichment followed by delayed CO$_2$ delivery, suggesting an evolutionary progression from molecular-poor Class 0 sources, through water-rich Class I/FS disks, to Class II disks with reduced cold water excess. This work provides an initial evolutionary framework for disk chemistry that requires larger, multi-region samples to confirm.

astro-ph.EP↗

arXiv2026

Atmospheric characterization of six ultra-hot Jupiters from $K$-band high-resolution spectroscopy

We present new Keck/KPIC high-resolution spectroscopic detections of three ultra-hot Jupiters (UHJs) in the $K$ band: WASP-189b ($\rm SNR = 7.2$), MASCARA-1b ($\rm SNR = 8.6$), and TOI-1518b ($\rm SNR = 7.1$), as well as a tentative detection of KELT-9b ($\rm SNR = 5.0$). We perform a uniform set of atmospheric retrieval analysis on these objects, as well as previously reported KPIC observations of WASP-33b ($\rm SNR = 11.2$) and KELT-20b ($\rm SNR = 10.5$), We perform atmospheric retrievals for the pressure-temperature ($P-T$) profile, orbital velocity parameters, $v\sin i$, and abundances of CO, H$_2$O, OH, and Fe, with parameterized mixing profiles to account for the expected vertical abundance variations of H$_2$O and OH. We also perform a set of retrievals assuming chemical equilibrium, which are generally in good agreement with the free retrievals. Except for \knb, the retrieved spectra are dominated by CO emission features, with additional weak H$_2$O or OH features consistent with thermal dissociation of H$_2$O. \knb, which is significantly hotter, appears to have very weak molecular features. Dissociation limits our ability to reliably constrain H$_2$O or OH abundances from $K$ band data alone, resulting in poor constraints on the C/O ratio. For all objects, the atmospheric abundances from detected carbon and oxygen species are $1-10\times$ solar. These results highlight the importance of wide spectral coverage for high-resolution retrievals. Additional observations to expand phase and wavelength coverage are needed to better constrain oxygen species and possible spatial inhomogeneities from dissociation.

astro-ph.EP↗

arXiv2026

Chemical Divergence and Water Depletion: Gas Properties of Evolved Upper Scorpius Disks Revealed by JWST/MIRI

Tracing the chemical evolution of protoplanetary disks over time requires observations of disks at different ages. However, most JWST/MIRI surveys published to date have targeted younger ($\sim$1-3 Myr) rather than older systems. We present the results of a JWST/MIRI MRS survey of the inner regions of 10 protoplanetary disks (ages $\sim$2-6 Myr, spectral types M0-M4.5) in the Upper Scorpius region previously characterized by the ALMA AGE-PRO large program. Using MCMC slab modeling, we fit to a wide variety of detected molecules, including H$_2$O, CO, C$_2$H$_2$, $^{13}$CCH$_2$, HCN, HC$_3$N, CO$_2$, $^{13}$CO$_2$, C$_2$H$_6$, C$_4$H$_2$, and OH, as well as C$_6$H$_6$, CH$_3$, and H$_2$ visually. We classify each disk along two independent axes-a Water Classification based on H$_2$O line luminosity (Water-Rich, Water-Poor, or Water-Absent) and a Chemotype based on the dominant non-water chemistry (Organic-Rich, CO$_2$-Dominated, or Molecule-Absent)-and find an unexpectedly high diversity of distinct chemical compositions within our population. We leverage the heterogeneity of detected molecules in our sample to present new characteristic "diagnostic" wavelength regions for most species. We find that carbon-based molecules consistently exhibit markedly lower excitation temperatures ($\lesssim$300 K) compared to younger ($\sim$1-3 Myr) star-forming regions ($\sim$600-1000 K), hinting at relatively colder molecular reservoirs. We also determine that Upper Scorpius disks show systematically lower water luminosities by factors of 10-1000. In particular, disks with strong carbon-based molecular features but no observed H$_2$O defy expectations of an inner-disk dust cavity or a low ($\lesssim3$) $R_{\rm gas}/R_{\rm dust}$ ratio, instead suggesting that the presence of a strong outer-disk dust trap largely controls the chemical outcome of the terrestrial planet-forming region.

astro-ph.EP↗

arXiv2026

From Young to Older Disks: JWST/MIRI Evidence for Fading Molecular Emission and Hints for Elevated C/O in Upper Scorpius

We present JWST/MIRI spectroscopy of 14 disks in the older (~5-10 Myr) Upper Scorpius (USco) association and use slab of gas in local thermal equilibrium to infer basic gas properties. We find that half of these disks are molecular rich, with detections of H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and H$_2$, while the other half are molecular poor, showing no molecular emission other than H$_2$. We further combine this sample with 10 other USco disks from the AGE-PRO program and compare the combined older sample to young (~1-3 Myr) JDISCS Cycle~1 systems, which are analyzed in a similar manner. We find that USco disks have lower detection rates of major molecular species but a significantly higher detection rate of rarer C-bearing molecules such as C$_4$H$_2$. At a given accretion luminosity, molecular line luminosities are systematically lower in USco than in young disks, and the scaling relations with accretion luminosity differ between the two populations. Moreover, we find that about half of the older disks, preferentially the millimeter faint, and likely more compact disks, have observable mass ratios of C- to O-bearing molecules that are higher than the maximum values in the young sample. These results point to reduced inner-disk molecular gas masses, cooler emitting layers, and higher inner gas C/O ratios in older disks, the latter being consistent with pebble drift. Taken together, our findings provide evidence for chemical evolution of inner disk gas from young to older systems, with important implications for the accretion of primordial planetary atmospheres.

astro-ph.EP↗

arXiv2026

The Dust Mineralogy of Interstellar Comet 3I/ATLAS from JWST/MIRI Observations

We present the first spectroscopic mineralogical analysis of the dust coma of an interstellar object (ISO) from JWST mid-infrared spectroscopy of 3I/ATLAS (3I). 3I exhibits a strong 10-micron emissivity feature commonly seen on asteroids, comets, disks, and the interstellar medium. Characterization of this 10-micron emissivity maximum reveals that 3I's dust composition is dominated by amorphous silicates, and that 3I is unlike Solar System comets, which show significant crystalline silicate dust. Instead, 3I's dust composition is more similar to circumstellar transition disks and the interstellar medium. We suggest 3I may have formed in a distant part of its home system out of interstellar medium-like material, without substantial incorporation of silicates condensed near its host star, unlike the mixing scenarios commonly hypothesized for Solar System comets. Alternatively, 3I's original crystalline silicates may have been amorphized during its Gyr-long journey, although we find this alternative less likely due to 3I's mass loss rate and distinct 10 micron feature as opposed to observed Solar System comets.

astro-ph.EP↗

arXiv2026

Molecular Similarity and Water Diversity in Coeval Binary Disks: JWST/MIRI Observations of Sz 65 and Sz 66

We present JWST/MIRI Medium Resolution Spectrometer spectra of the wide-separation (projected separation $= 980$ au) binary protoplanetary disks Sz 65 (K7; $0.68~M_{\odot}$) and Sz 66 (M3; $0.30~M_{\odot}$), reduced using the uniform pipeline of the JWST Disk Infrared Spectral Chemistry Survey. Both disks show rich molecular emission, including H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and OH. The scaled spectra of the two disks exhibit remarkably similar H$_2$O, CO$_2$, and HCN line emission in the 13--18 $\mu$m region, with the only notable difference being stronger C$_2$H$_2$ emission in the primary (Sz 65). Beyond 18 $\mu$m, the difference in H$_2$O line emission between the two disks increases. Both the flux ratios and the slab-model-derived mass ratios of cold to hot H$_2$O ($\sim$200 K to $\sim$750 K) and warm to hot H$_2$O ($\sim$450 K to $\sim$750 K) are significantly higher in the secondary (Sz 66). Because binary stars share nearly the same age and metallicity, and as both disks appear compact in millimeter emission ($<30$ au), we suggest that the excess cold H$_2$O in the secondary is best explained by its unstructured dust disk, in contrast to the primary, which shows gaps at 6 and 20 au. The enhanced cold water in the secondary is consistent with efficient pebble drift across the water snow line and increased H$_2$O vapor from the sublimation of icy mantles. Our results demonstrate that wide-separation binaries can serve as powerful control samples for isolating the impact of individual disk properties on inner-disk chemistry and evolution.

astro-ph.EP↗

arXiv2026

JWST-DECO: The Impact of Accretion on Mid-Infrared Observable Water in Planet-forming Disks

The inner few au of a protoplanetary disk hosts the majority of observed exoplanets and is the primary planet-forming zone of the disk. The mid-IR spectra of disks, with its rich forest of water lines, provides key insights into the composition of forming planets. One of the strongest trends seen with data from Spitzer and now JWST is a correlation between the increase in water line flux and accretion luminosity of a system. We set out to reproduce and understand this trend by adding an accretion module to the thermo-chemical code DALI, and explore how viscous accretion heating and the addition of accretion luminosity impacts the 2D temperature structure and the observable water reservoir. We reproduce the trend that the observed water mass increases with accretion rate, with hot, warm, and cool water being more to less strongly correlated, respectively. Our model suggests that these trends are due to an increased emitting area with accretion rate, with some of the cool and warm population becoming hidden underneath an optically thick dust surface and being constrained to a smaller disk volume. This trend is driven by the accretion-related increase in central luminosity, while viscous heating centralized to the midplane has no impact on observed water mass.

astro-ph.EP↗

arXiv2026

Characterizing the Extended Molecular Hydrogen Winds in Protoplanetary Disks from the JWST Disk Infrared Spectroscopic Chemistry Survey

We present a comprehensive analysis of extended H$_2$ emission from 34 protoplanetary disks observed with the JWST Disk Infrared Spectroscopic Chemistry Survey (JDISCS), supplemented by archival data. We investigated the morphology, kinematics, excitation conditions, and mass dynamics of H$_2$. Extended emission from pure rotational H$_2$ lines is found to be common, with 16 sources exhibiting clear signatures of disk winds. These include monopolar and bipolar structures in inclined disks and ring-like or bubble-like morphologies in face-on systems features indicative of wide-angle disk winds. Our analysis shows that the H$_2$ is consistent with slow {(4.2$^{+6.7}_{-3.0}$ km s$^{-1}$)} MHD driven winds. For ten disks, we model the wind morphology and find a median half-opening angle of $45\arcdeg^{+5}_{-4}$ and a characteristic power-law index of $α\sim$ 1.6. Excitation analysis yields a median gas temperature of 624 $\pm$ 130 K and a column density of $\log(N_{\mathrm{tot}}\,[\mathrm{cm}^{-2}]) = 18.6 \pm 0.6$. The median wind mass-loss rate, ${\rm log_{10}}(\dot{\rm M}_{\rm wind}^{\rm tot}) = -9_{-0.4}^{+0.8}\,{\rm M_\odot\,yr^{-1}}$, implies that, if molecular winds are the dominant mechanism responsible for disk dispersal, a typical disk with a mass of $2-3\,M_{\rm Jup}$ would dissipate on a $\sim$2-3 Myr timescale, consistent with observed disk lifetimes. The $\dot{\rm M}_{\mathrm{\rm wind}}^{\rm tot}$ span a relatively narrow range ($\sim$2 dex) and do not correlate strongly with accretion rates onto the star, suggesting that the mass loss rate and the accretion rates are probing different timescales. Our findings demonstrate that spatially extended warm H$_2$ emission is a widespread and reliable tracer of molecular disk winds in protoplanetary systems.

astro-ph.SR↗

arXiv2026

JWST/MIRI Hydrocarbon and Water Absorption in the Wind of a Young Disk: Signatures of Pebble Drift and Carbon Grain Sublimation

We present JWST/MIRI-MRS observations of ISO-Oph 37, a highly inclined flat-spectrum ($\lesssim$1 Myr old) source, to investigate the chemical composition and dynamical origin of its inner-disk gas. The spectrum reveals a rich combination of molecular emission and absorption: H$_2$O, CO, and OH are detected in emission, while strong absorption is observed from CO, H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and CH$_4$, with no detectable ice absorption features. LTE slab modeling of the absorption yields excitation temperatures of $T_{\rm ex}\sim400-600$ K and column densities of $\log N/{\rm cm}^{2}\sim16-19$, characteristic of warm gas located within the inner few au. The absorption lines are significantly blueshifted relative to the systemic velocity, with mid-IR lines exhibiting larger shifts than near-IR CO absorption. This velocity structure points to a velocity- and temperature-stratified molecular disk wind. In this framework, the absorption directly samples disk material lifted from the inner disk surface, preserving the chemical imprint of the wind-launching region. Along the line of sight, ISO-Oph 37 is unusually hydrocarbon-rich compared to other known absorption systems (GV Tau N and IRS 46), exhibiting high (C$_2$H$_2$+CH$_4$)/HCN, (C$_2$H$_2$+CH$_4$)/CO and H$_2$O/CO column density ratios, while the CO and HCN columns remain broadly typical. We find that these molecular ratios are best explained by enhancement of both hydrocarbons and water, driven by inward drift and sublimation of icy pebbles and by thermal processing of carbonaceous grains at the soot line. ISO-Oph 37 thus demonstrates that carbon-rich inner-disk chemistry can be established early in disk evolution and that it can be directly probed through molecular absorption in disk winds.

astro-ph.EP↗

arXiv2026

The compositions of the HR 8799 planets reflect accretion of both solids and metal-enriched gas

With four giant planets ($m\sim5-10~M_{\rm Jup}$, $T_\rm{eff}\sim900-1200$ K) orbiting between 15-70 au, HR 8799 provides an unparalleled testbed for studying giant planet formation and probing compositional trends across the protoplanetary disk. We present new JWST/NIRSpec IFU observations ($2.85-5.3~μ$m, $R\approx2700$) that now include the spectrum of HR 8799 b, and higher S/N spectra for HR 8799 c, d, and e compared to that in Ruffio & Xuan et al. We detect CO, CH$_4$, H$_2$O, H$_2$S, CO$_2$, and for planet b, NH$_3$. We combine the NIRSpec spectra with $1-5 μ$m photometry to perform atmospheric retrievals that account for disequilibrium chemistry and clouds, and allow C/H, O/H, N/H, and S/H to scale independently. While the four planets are similarly enriched in carbon and oxygen, with C/H and O/H between $3-5\times$ stellar, we observe a tentative trend of increasing S/H - a tracer of refractory solids - from $2-5 \times$ stellar with increasing orbital distance. From HR 8799 b's NH$_3$ abundance, we estimate $\rm N/H=21.2^{+16.2}_{-8.8}\times$ stellar, suggesting the outer planet accreted significant amounts of N-rich gas. Overall, the elemental abundance patterns we observe are consistent with a picture where planet b formed between the CO snowline and the more-distant N$_2$ snowline, while the inner planets accreted $3 \times$ stellar CO-enriched disk gas within the CO snowline. The excess volatile mass from pebble drift and evaporation implies an integrated pebble flux of $750 \pm 200~M_{\oplus}$. The increase in the planets' S/H with orbital distance implies more solid accretion further out, which is quantitatively compatible with expectations from both pebble and planetesimal accretion ($2 \times$ Minimum Mass Solar Nebula) paradigms.

astro-ph.EP↗

arXiv2026

Distinct Rotational Evolution of Giant Planets and Brown Dwarf Companions

We present a rotational velocity (vsini) survey of 32 stellar/substellar objects and giant planets using Keck/KPIC high-resolution spectroscopy, including 6 giant planets (2-7 M$_\mathrm{Jup}$) and 25 substellar/stellar companions (12-88 M$_\mathrm{Jup}$). Adding companions with spin measurements from the literature, we construct a curated spin sample for 43 benchmark stellar/substellar companions and giant planets and 54 free-floating brown dwarfs and planetary mass objects. We compare their spins, parameterized as fractional breakup velocities at 10 Myr, assuming constant angular momentum evolution. We find the first clear evidence that giant planets exhibit distinct spins versus low-mass brown dwarf companions (10 to 40 M$_\mathrm{Jup}$) at 4-4.5 $σ$ significance assuming inclinations aligned with their orbits, while under randomly oriented inclinations the significance is at 1.6-2.1 $σ$. Our findings hold when considering various assumptions about planets, and the mass ratio below 0.8% gives a clean cut for rotation between giant planets and brown dwarf companions. The higher fractional breakup velocities of planets can be interpreted as less angular momentum loss through circumplanetary disk braking during the planet formation phase. Brown dwarf companions exhibit evidence of slower rotation compared to isolated brown dwarfs, while planets and planetary mass objects show similar spins. Finally, our analysis of specific angular momentum versus age of 221 stellar/substellar objects below 0.1 M$_{\odot}$ with spin measurements in the literature indicates that the substellar objects of 5-40 M$_\mathrm{Jup}$ retain much higher angular momenta compared to stellar and substellar objects of 40-100 M$_\mathrm{Jup}$ after 10 Myr, when their initial angular momenta were set.

astro-ph.EP↗

arXiv2026

H$_2^{18}$O in the terrestrial planet-forming regions of protoplanetary disks

Isotopologues play an important role in solar system cosmochemistry studies, revealing details of early planet formation physics and chemistry. Oxygen isotopes, as measured in solar system materials, reveal evidence for both mass-dependent fractionation processes and a mass-independent process commonly attributed to isotope-selective photodissociation of CO in the solar nebula. The sensitivity of JWST's MIRI-MRS enables studies of isotopologues in the terrestrial planet-forming regions around nearby young stars. We report here on a search for H$_2^{18}$O in 22 disks from the JDISC Survey with evidence for substantial water vapor reservoirs, with the goal of measuring H$_2^{16}$O/H$_2^{18}$O ratios, and potentially revealing the predicted enhancement of H$_2^{18}$O caused by isotope-selective photodissociation. We find marginal detections of H$_2^{18}$O in six disks, and a more significant detection of H$_2^{18}$O in the disk around WSB 52. Modeling of the detected H$_2^{18}$O lines assuming an ISM ratio of H$_2^{16}$O/H$_2^{18}$O predicts H$_2^{18}$O features consistent with observations for four of the modeled disks, but stronger H$_2^{18}$O features than are observed in three of the modeled disks, which includes WSB 52. Therefore, these latter three disks require a higher H$_2^{16}$O/H$_2^{18}$O ratio than the ISM in the water-emitting region, in contrast to long-standing theoretical expectations. We suggest that either the H$_2^{18}$O-rich water has been removed from the emitting region and replaced by H$_2^{18}$O-poor water formed by reactions with $^{18}$O-poor CO, or that the gas-phase water is depleted in $^{18}$O via mass-dependent fractionation processes at the water snowline.

astro-ph.EP↗

arXiv2026

Protoplanetary disk cavities with JWST-MIRI: a dichotomy in molecular emission

The evolution of planet-forming regions in protoplanetary disks is of fundamental importance to understanding planet formation. Disks with a central deficit in dust emission, a "cavity", have long attracted interest as potential evidence for advanced disk clearing by protoplanets and/or winds. Before JWST, infrared spectra showed that these disks typically lack the strong molecular emission observed in full disks. In this work, we combine a sample of 12 disks with millimeter cavities of a range of sizes ($\sim2$-70 au) and different levels of millimeter and infrared continuum deficits. We analyze their molecular spectra as observed with MIRI on JWST, homogeneously reduced with the new JDISCS pipeline. This analysis demonstrates a stark dichotomy in molecular emission where "molecule-rich" (MR) cavities follow global trends between water, CO, and OH luminosity and accretion luminosity as in full disks, while "molecule-poor" (MP) cavities are significantly sub-luminous in all molecules except sometimes OH. Disk cavities generally show sub-luminous organic emission, higher OH/H$_2$O ratios, and suggest a lower water column density. The sub-thermal excitation of CO and water vibrational lines suggests a decreased gas density in the emitting layer in all cavities, supporting model expectations for C$_2$H$_2$ photodissociation. We discover a bifurcation in infrared index (lower in MR cavities) suggesting that the molecular dichotomy is linked to residual $μ$m-size dust within millimeter disk cavities. Put together, these results suggest a feedback process between dust depletion, gas density decrease, and molecule dissociation. Disk cavities may have a common evolutionary sequence where MR switch into MP over time.

astro-ph.EP↗

arXiv2025

The Role of THz Phonons in the Ionic Conduction Mechanism of $Li_7La_3Zr_2O_{12}$ Polymorphs

Superionic conduction in solid-state materials is governed not only by static factors, such as structure and composition, but also by dynamic interactions between the mobile ion and the crystal lattice. Specifically, the dynamics of lattice vibrations, or phonons, have attracted interest because of their hypothesized ability to facilitate superionic conduction. However, direct experimental measurement of the role of phonons in ionic conduction is challenging due to the fast intrinsic timescales of ion hopping and the difficulty of driving relevant phonon modes, which often lie in the low-energy THz regime. To overcome these limitations, we use laser-driven ultrafast impedance spectroscopy (LUIS). LUIS resonantly excites phonons using a THz field and probes ion hopping with picosecond time resolution. We apply LUIS to understand the dynamical role of phonons in $Li_7La_3Zr_2O_{12}$ (LLZO). When in its cubic phase (c-LLZO), this garnet-type solid electrolyte has an ionic conductivity two orders of magnitude greater than its tetragonal phase (t-LLZO). T-LLZO is characterized by an ordered and filled $Li^+$ sublattice necessitating synchronous ion hopping. In contrast, c-LLZO is characterized by a disordered and vacancy-rich $Li^+$ sublattice, and has a conduction mechanism dominated by single hops. We find that, upon excitation of phonons in the 0.5-7.5 THz range, the impedance of t-LLZO experiences a longer ion hopping decay signal in comparison to c-LLZO. The results suggest that phonon-mediated ionic conduction by THz modes may lead to larger ion displacements in ordered and fully occupied mobile ion sublattices as opposed to those that are disordered and vacancy-rich. Overall, this work highlights the interplay between static and dynamic factors that enables improved ionic conductivity in otherwise poorly conducting inorganic solids.

cond-mat.mtrl-sci↗

arXiv2025

Correlated Terahertz phonon-ion interactions control ion conduction in a solid electrolyte

Ionic conduction in solids that exceeds 1 mS/cm is predicted to involve coupled phonon-ion interactions in the crystal lattice. Here, we use theory and experiment to measure the possible contribution of coupled phonon-ion hopping modes which enhance Li+ migration in Li0.5La0.5TiO3 (LLTO). The ab initio calculations predict that the targeted excitation of individual TiO6 rocking modes greatly increases the Li+ jump rate as compared to the excitation of vibrational modes associated with heating. Experimentally, coherently driving TiO6 rocking modes via terahertz (THz) illumination leads to a ten-fold decrease in the differential impedance compared to the excitation of acoustic and optical phonons. Additionally, we differentiate the ultrafast responses of LLTO due to ultrafast heating and THz-range vibrations using laser-driven spectroscopy (LUIS), finding a unique long-lived response for the THz-range excitation. These findings provide new insights into coupled ion migration mechanisms, indicating the important role of THz-range coupled phonon-ion hopping modes in enabling fast ion conduction at room temperature.

cond-mat.mtrl-sci↗

arXiv2025

Soot Planets instead of Water Worlds

Some low-density exoplanets are thought to be water-rich worlds that formed beyond the snow line of their protoplanetary disc, possibly accreting coequal portions of rock and water. However, the compositions of bodies within the Solar System and the stability of volatile-rich solids in accretionary disks suggest that a planet rich in water should also acquire as much as 40% refractory organic carbon (``soot''). This would reduce the water mass fraction well below 50%, making the composition of these planets similar to those of Solar System comets. Here we show that soot-rich planets, with or without water, can account for the low average densities of exoplanets that were previously attributed to a binary combination of rock and water. Formed in locations beyond the soot and/or snow lines in disks, these planets are likely common in our galaxy and already observed by JWST. The surfaces and interiors of soot-rich planets will be influenced by the chemical and physical properties of carbonaceous phases, and the atmospheres of such planets may contain plentiful methane and other hydrocarbons, with implications for photochemical haze generation and habitability.

astro-ph.EP↗

arXiv2025

Unveiling the Chemical Complexity and C/O Ratio of the HD 163296 Protoplanetary Disk: Constraints from Multi-line ALMA Observations of Organics, Nitriles, Sulfur-bearing, and Deuterated Molecules

The physical and chemical conditions within a protoplanetary disk play a crucial role in determining its chemical composition, which is subsequently inherited by any forming planets. To probe these conditions, high-resolution molecular line observations, coupled with modelling, are essential. In this study, we investigate the chemistry of the nearby, massive, and relatively line-rich protoplanetary disk around HD 163296 using high-resolution observations from ALMA across Bands 3, 4, 6, and 7. We constrain the disk-averaged and radial distributions of column density and excitation temperature for the detected molecules using the new retrieval code DRive. The disk chemistry is modelled using the astrochemical code PEGASIS, with variations in the initial elemental C/O ratio. Our modelling, informed by molecular observations of HCO+, DCO+, HCN, DCN, CS, HC3N, H2CO, CH3OH, HNCO, and NH2CHO, allows us to place strong constraints on the C/O ratio, with a best-fit value of 1.1 that is broadly consistent with previous estimates. We present the highest-resolution DCO+ emission map of this disk to date, revealing triple-ringed chemical substructures that closely align with the dust continuum rings. Additionally, our results provide the first and most stringent upper limits on the column densities of NH2CHO and HNCO in this protoplanetary disk, measured at < 7e11 cm-2 and < 1e11 cm-2, respectively. Our chemical models suggest that NH2CHO and HNCO predominantly form on grain surfaces within the disk. However, physico-chemical desorption mechanisms are inefficient at releasing these species into detectable gas-phase abundances, yet they remain promising targets for future ALMA observations.

astro-ph.EP↗