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George Pennington

Publications and source records attributed to George Pennington.

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Quantum Approximate Optimization via Noise-Directed Adaptive Warm-Starting

Progress towards a quantum advantage using known heuristic methods for combinatorial optimization is impeded by hardware noise and limited qubit count. Here, we propose a noise-aware adaptive approach to quantum approximate optimization, Noise-Directed Adaptive Warm-Starting (ND-AWS), that builds on recent concepts such as Warm-Start QAOA and Noise-Directed Adaptive Remapping. By leveraging bitflip gauge transformations, our algorithm exploits amplitude-damping-like noise components. We experimentally implement high-performance quantum optimization ans\"atze on 100-qubit Ising Hamiltonians, showing that ND-AWS generally improves the performance over a non-gauge-transformed iterative Warm-Starting variant, at no additional circuit cost. This places our results among the highest-quality demonstrations of quantum optimization with similar ans\"atze at this scale. Crucially, the simplicity of the framework opens the door for future enhancements such as adaptive bias schedules, and integration with classical solvers.

quant-ph

Setting angles in quantum approximate optimization at utility-scale

The quantum approximate optimization algorithm (QAOA) is a powerful heuristic that seeks to solve combinatorial optimization problems using quantum hardware and classical optimization in tandem. Various methods exist to train the parameterized quantum circuits that serve as an ansatz in QAOA. However, which method works best to identify optimal angles for a given problem instance remains poorly understood, especially at utility-scale, i.e., $100$ qubits or more. In this work, we address this challenge through utility-scale benchmarks from which we distill operational guidance for QAOA practitioners. First, we investigate approximation techniques, such as matrix product states and Pauli propagation, to find optimal angles. Second, we train QAOA on small-scale representative problems and transfer the angles to larger ones. We then validate the results on quantum hardware for utility-scale problem instances that can be meaningfully executed. In this way, we identify insights for QAOA angle setting strategies that work best for problems at the utility scale, including as a function of resource cost for the search. Crucially, the operational implications we draw from our benchmarks will help quantum optimization practitioners execute QAOA end-to-end pipelines efficiently on current and future hardware.

quant-ph

Preparing 100-qubit symmetry-protected topological order on a digital quantum computer

Symmetry-protected topological (SPT) phases extend the Landau paradigm of quantum matter by admitting distinct symmetry-preserving phases that lack any local order parameter. Demonstrating these phases at scale on programmable quantum processors is a key milestone in using quantum hardware to probe emergent many-body phenomena, yet it is impeded by the circuit depth normally required to capture non-trivial entanglement. Here we use a tensor network based approximate quantum compiling (AQC) protocol to construct shallow quantum circuits (18-39 CNOT depth), which prepare 100-site ground states of the spin-1/2 bond-alternating Heisenberg chain in both SPT phases, to 97.9-99.0% fidelity. Upon executing the circuits on IBM quantum hardware, the resulting states exhibit all defining signatures of SPT order including non-local string order for strings of up to length 20, characteristic degeneracies in the entanglement spectrum and clear evidence of symmetry-protected edge modes. The simultaneous observation of these independent diagnostics establishes current quantum computers as versatile platforms for large-scale studies of symmetry-protected quantum matter. More broadly, our results establish a practical foundation for probing non-equilibrium quench dynamics of such systems in regimes that challenge classical computational methods.

quant-ph

Boosting Sparsity in Graph Decompositions with QAOA Sampling

We study the problem of decomposing a graph into a weighted sum of a small number of matchings, a task that arises in network resource allocation problems such as peer-to-peer energy exchange. Computing such decompositions is challenging for classical algorithms, even for small instances. To address this problem, we propose E-FCFW, a hybrid quantum-classical algorithm based on the Fully-Corrective Frank-Wolfe (FCFW) algorithm that incorporates a matching-sampling subroutine. We design a QAOA version of this subroutine and benchmark it against classical approaches (random sampling and simulated annealing) on demand graphs derived from complete, bipartite, and heavy-hex topologies. The quantum subroutine is executed using the Qiskit Aer state-vector and MPS simulators and on IBM Kingston hardware (7-111 qubits). On complete and bipartite graphs with 6-10 nodes, E-FCFW with QAOA yields consistently sparser decompositions than the classical baselines, and even beats the best-known solution for one instance. On heavy-hex graphs with 50, 70 and 100 nodes, E-FCFW with QAOA outperforms the other methods in terms of approximation error, demonstrating performance on utility-scale quantum hardware. For the largest graphs (100 nodes) E-FCFW with QAOA performs much better when using MPS circuit simulation, compared to using quantum hardware. This indicates that at this scale, the performance is severely impacted by hardware noise.

quant-ph

Approximate quantum circuit compilation for proton-transfer kinetics on quantum processors

Proton transfer reactions are fundamental to many chemical and biological systems, where quantum effects such as tunneling, delocalization, and zero-point motion play key kinetic control roles. However, classical methods capable of accurately capturing these phenomena scale prohibitively with system size. Here, we develop and demonstrate quantum computing algorithms based on the Nuclear-Electronic Orbital framework, treating the transferring proton quantum mechanically. We assess the potential of current quantum devices for simulating proton transfer kinetics with high accuracy. We first construct a deep initial ans\"atze within a truncated orbital space by employing the frozen natural orbital approximation. Then, to balance circuit depth against state fidelity, we implement an adaptive form of approximate quantum compiling. Using resulting circuits at varying compression levels transpiled for the ibm_fez device, we compute barrier heights and delocalised proton densities along the proton transfer pathway using a realistic hardware noise model. We find that, although current quantum hardware introduces significant noise relative to the demanding energy tolerances involved, our approach allows substantial circuit simplification while maintaining energy barrier estimates within 13% of the reference value. Despite present hardware limitations, these results offer a practical means of approximating key circuit segments in near-term devices and early fault-tolerant quantum computing systems.

quant-ph

Variational preparation of normal matrix product states on quantum computers

Preparing matrix product states (MPSs) on quantum computers is an essential routine in the simulation of many-body physics. However, widely-used schemes based on staircase circuits are often too deep to execute on current hardware. Here we demonstrate that MPSs with short-range correlations can be prepared with shallow circuits by leveraging heuristics from approximate quantum compiling (AQC). We achieve this with ADAPT-AQC, an adaptive-ansatz preparation algorithm, and introduce a generalised initialisation procedure for the existing AQC-Tensor algorithm. We first compare these methods for the task of preparing a molecular electronic structure ground state. We then use them to prepare an antiferromagnetic (AFM) ground state of the 50-site Heisenberg XXZ spin chain near the AFM-XY phase boundary. Through the execution of circuits with up to 59 CZ depth and 1251 CZ gates, we perform a global quench and observe the relaxation of magnetic ordering in a parameter regime previously inaccessible due to deep ground state preparation circuits. Our results demonstrate how the integration of quantum and classical resources can push the boundary of what can be studied on quantum computers.

quant-ph