arXiv subjects

George Tynan

Publications and source records attributed to George Tynan.

3 recordsLinked to original sources

arXiv2026

Fragmenting Diffusion Pathways Confers Extraordinary Radiation Resistance in Refractory Multicomponent Alloys

The accumulation and growth of vacancy clusters under irradiation is a pivotal degradation mode for structural materials in extreme environments. Even tungsten undergoes rapid defect coarsening compromising its integrity. Here we show a tungsten multicomponent alloy that effectively fragments the vacancy diffusion network, kinetically trapping defects within localized domains. This effect originates from a broad spectrum of migration barriers and substantial vacancy-jump heterogeneity, which drives the interconnectivity of diffusion paths below the percolation threshold. Starving clusters of the necessary vacancy supply, irradiation experiments and atomic-scale defect characterizations confirm negligible defect growth as radiation doses increase by four orders of magnitude. These results provide a fundamental paradigm for percolation-engineered kinetics, offering a predictive pathway for tailoring defect diffusion and discovering inherently radiation-tolerant materials.

cond-mat.mtrl-sci↗

arXiv2025

Parameter-free prediction of irradiation defect structures in tungsten at room temperature using stochastic cluster dynamics

The foundations of irradiation damage theory were laid in the 1950s and 60s within the framework of chemical reaction kinetics. While helpful to analyze qualitative aspects of irradiation damage, the theory contained gaps that delayed its implementation and applicability as a predictive tool. The advent of computer simulations with atomistic resolution in the 80s and 90s revealed a series of mechanisms that have proved essential to understand key aspects of irradiation damage in crystalline solids. However, we still lack a comprehensive model that can connect atomic-level defect physics with experimental measurements of quantitative features of the irradiated microstructure. In this work, we present a mesoscale model that draws from our improved understanding of irradiation damage processes collected over the last few decades, bridging knowledge gained from our most sophisticated atomistic simulations with defect kinetics taking place over time scales many orders of magnitude larger than atomic interaction times. Importantly, the model contains no adjustable parameters and combines several essential pieces of irradiation damage physics: each playing an irreplaceable role in the context of the full model but of limited utility if considered in isolation. Crucially, we carry out a set of experiments carefully designed to isolate the key irradiation damage variables and facilitate validation. Using tungsten as a model material, we find exceptionally good agreement between our numerical predictions and experimental measurements of defect densities and defect cluster sizes.

cond-mat.mtrl-sci↗

arXiv2025

Physics-Informed Unit Commitment Framework for Nuclear Reactors

Nuclear reactors are often modeled as inflexible baseload generators with fixed downtimes and restrictive ramping constraints. In practice, however, a reactor's operational flexibility is closely tied to its fuel cycle and associated reactivity margin. A key physical constraint for power maneuverability is xenon poisoning, caused from the transient buildup of neutron-absorbing xenon following a power reduction. This transient can delay or prevent subsequent power ramp-up due to suppressed core reactivity. Additionally, if a reactor is shutdown during periods of low reactivity, restart times can vary significantly, leading to prolonged downtimes. This work introduces a physics-informed modeling framework that embeds fuel cycle dynamics within a unit commitment (UC) formulation. The framework tracks reactivity margin, dynamically enforces xenon induced constraints, and endogenously schedules refueling outages based on core conditions. By capturing intracycle reactivity evolution, the model enables operation dependent nuclear dispatch that reflects both techno-economic requirements and irreducible nuclear physics limits. Application to a representative reactor fleet shows that flexible operation can slow reactivity degradation and extend fuel cycles. Results further demonstrate that different operational modes substantially affect VRE utilization, curtailment, and nuclear fleet capacity factors. These findings highlight the importance of fuel cycle aware flexibility modeling for accurate reactor scheduling and integration of nuclear power into energy system models.

eess.SY↗