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Geronimo Villanueva

Publications and source records attributed to Geronimo Villanueva.

16 recordsLinked to original sources

Mars, a Post-Habitable Planet?

Mars provides a critical analog to once habitable exoplanets that have since lost their surface liquid water. The current atmospheric state of Mars retains the chemical fingerprints of that transition, including isotopic signatures of atmospheric escape and climate evolution. As the closest accessible example of a terrestrial world with definitive evidence for once supporting liquid water on its surface, Mars presents a unique opportunity to test hypotheses about planetary habitability and atmospheric evolution in a spatially and temporally resolved way.

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An Enriched Methane D/H Ratio in the Interstellar Object 3I/ATLAS

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS measured with the James Webb Space Telescope. Our results demonstrate an unexpectedly high D/H = $(3.33\pm0.31)\%$ for methane and represent an exceedingly rare detection of deuterated organic molecules in an interstellar object. This D/H ratio exceeds any other value for methane measured in the solar system, and is a factor of $14\pm2$ higher than that measured in comet 67P/Churyumov-Gerasimenko by the Rosetta spacecraft, the only other comet for which CH$_3$D has been detected. Both 3I/ATLAS and 67P/Churyumov-Gerasimenko show a higher degree of methane dueteration compared to water, consistent with trends seen in other solar system bodies and the nearby interstellar medium, where deuteration in organics exceeds that of water by up to an order of magnitude. The D/H ratio in methane itself is observationally unconstrained in extrasolar sources to date, but the enriched ratio in 3I/ATLAS is similar to those measured in methanol and formaldehyde toward primitive environments. The elevated D/H ratio for methane in 3I/ATLAS is consistent with the hypothesis that its ices formed in a cold, low metallicity interstellar or protostellar environment under a high cosmic ray irradiation rate (Cordiner et al. 2026).

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Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.95 +- 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12C/13C ratios (141-191 for CO2 and 123-172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures $\lesssim30$ K in a relatively metal-poor environment, early in the history of the Galaxy. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS accreted roughly 10-12 billion years ago, following an early period of intense star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system, and provides direct evidence for active ice chemistry and volatile-rich planetesimal formation in the young Milky Way.

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The pale blue dot: using the Planetary Spectrum Generator to simulate signals from hyper realistic exo-Earths

The atmospheres and surfaces of planets show tremendous amount of spatial variation, which has a direct effect on the spectrum of the object, even if this may not be spatially resolved. Here, we apply hyper realistic radiative simulations of Earth as an exoplanet comprising thousands of simulations and study the unresolved spectrum. The GlobES module on the Planetary Spectrum Generator was used, and we parameterized the atmosphere as described in the modern earth retrospective analysis for research and applications, MERRA2, database. The simulations were made into high spatial resolution images and compared to space based observations from the DSCOVR EPIC, at L1, and Himawari8, geostationary, satellites, confirming spatial variations and the spectral intensities of the simulations. The DSCOVR EPIC camera only functions in narrow wavelength bands, but strong agreement is demonstrated. It is shown that aerosols and small particles play an important role in defining Earths reflectance spectra, contributing significantly to its characteristic blue color. Subsequently, a comprehensive noise model is employed to constrain the exposure time required to detect O2, O3 and H2O as a function of varying ground and cloud cover for several concept observatories, including the habitable worlds observatory. Cloud coverage enhances the detectability of planets in reflected light, with important consequences for the design of the future HWO. The HWO concept would require between 3 to 10 times longer to observe the studied features than LUVOIR A but performs better than the HabEx without a starshade. The codes, routines, and the noise models are made publicly available.

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Bayesian Analysis for Remote Biosignature Identification on exoEarths (BARBIE) II: Using Grid-Based Nested Sampling in Coronagraphy Observation Simulations for O2 and O3

We present the results for the detectability of the O2 and O3 molecular species in the atmosphere of an Earth-like planet using reflected light at the visible wavelengths. By quantifying the detectability as a function of signal-to-noise ration (SNR), we can constrain the best methods to detect these biosignatures with nest-generation telescopes designed for high-contrast coronagraph. Using 25 bandpasses between 0.515 and 1 micron, and a pre-constructed grid of geometric albedo spectra, we examined the spectral sensitivity needed to detect these species for a range of molecular abundances. We first replicate a modern-Earth twin atmosphere to study the detectability of current O2 and O3 levels, and then expand to a wider range of literature-driven abundances for each molecule. We constrain the optimal 20%, 30%, and 40% bandpasses based on the effective SNR of the data, and define the requirements for the possibility of simultaneous molecular detection. We present our findings of O2 and O3 detectability as functions of SNR, wavelength, and abundance, and discuss how to use these results for optimizing future instrument designs. We find that O2 is detectable between 0.64 and 0.83 micron with moderate-SNR data for abundances near that of modern-Earth and greater, but undetectable for lower abundances consistent with a Proterozoic Earth. O3 is detectable only at very high SNR data in the case of modern-Earth abundances, however it is detectable at low-SNR data for higher O3 abundances that can occur from efficient abiotic O3 production mechanisms.

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Bayesian Analysis for Remote Biosignature Identification on exoEarths (BARBIE) I: Using Grid-Based Nested Sampling in Coronagraphy Observation Simulations for H2O

Detecting H2O in exoplanet atmospheres is the first step on the path to determining planet habitability. Coronagraphic design currently limits the observing strategy used to detect H2O, requiring the choice of specific bandpasses to optimize abundance constraints. In order to examing the optimal observing strategy for initial characterization of habitable planets using coronagraph-based direct imaging, we quantify the detectability of H2O as a function of signal-to-noise ratio (SNR) and molecular abundance across 25 bandpasses in the visible wavelength range (0.5-1 micron). We use a pre-constructed grid consisting of 1.4 million geometric albedo spectra across a range of abundance and pressure, and interpolate the produce forward models for an efficient nested sampling routine, PSGnest. We first test the detectability of H2O in atmospheres that mimix a modern-Earth twin, and then expand to examine a wider range of H2O abundances; for each abundance value, we constrain the optimal 20% bandpasses based on the effective signal-to-noise ratio (SNR) of the data. We present our findings of H2O detectability as functions of SNR, wavelength, and abundance, and discuss how to use these results for optimizing future coronographic instrument design. We find that there are specific points in wavelength where H2o can be detected down to 0.74 micron with moderate-SNR data for abundances at the upper end of Earth's presumed historical values, while at 0.9 micron, detectability is possible with low-SNR data at modern Earth abundances of H2O.

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Variability due to climate and chemistry in observations of oxygenated Earth-analogue exoplanets

The Great Oxidation Event was a period during which Earth's atmospheric oxygen (O$_2$) concentrations increased from $\sim 10^{-5}$ times its present atmospheric level (PAL) to near modern levels, marking the start of the Proterozoic geological eon 2.4 billion years ago. Using WACCM6, an Earth System Model, we simulate the atmosphere of Earth-analogue exoplanets with O$_2$ mixing ratios between 0.1% and 150% PAL. Using these simulations, we calculate the reflection/emission spectra over multiple orbits using the Planetary Spectrum Generator. We highlight how observer angle, albedo, chemistry, and clouds affect the simulated observations. We show that inter-annual climate variations, as well short-term variations due to clouds, can be observed in our simulated atmospheres with a telescope concept such as LUVOIR or HabEx. Annual variability and seasonal variability can change the planet's reflected flux (including the reflected flux of key spectral features such as O$_2$ and H$_2$O) by up to factors of 5 and 20, respectively, for the same orbital phase. This variability is best observed with a high-throughput coronagraph. For example, HabEx (4 m) with a starshade performs up to a factor of two times better than a LUVOIR B (6 m) style telescope. The variability and signal-to-noise ratio of some spectral features depends non-linearly on atmospheric O$_2$ concentration. This is caused by temperature and chemical column depth variations, as well as generally increased liquid and ice cloud content for atmospheres with O$_2$ concentrations of $<$1% PAL.

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Nitrogen Dioxide Pollution as a Signature of Extraterrestrial Technology

Nitrogen dioxide (NO$_2$) on Earth today has biogenic and anthropogenic sources. During the COVID-19 pandemic, observations of global NO$_2$ emissions have shown significant decrease in urban areas. Drawing upon this example of NO$_2$ as an industrial byproduct, we use a one-dimensional photochemical model and synthetic spectral generator to assess the detectability of NO$_2$ as an atmospheric technosignature on exoplanets. We consider cases of an Earth-like planet around Sun-like, K-dwarf and M-dwarf stars. We find that NO$_2$ concentrations increase on planets around cooler stars due to less short-wavelength photons that can photolyze NO$_2$. In cloud-free results, present Earth-level NO$_2$ on an Earth-like planet around a Sun-like star at 10pc can be detected with SNR ~5 within ~400 hours with a 15 meter LUVOIR-like telescope when observed in the 0.2 - 0.7micron range where NO$_2$ has a strong absorption. However, clouds and aerosols can reduce the detectability and could mimic the NO$_2$ feature. Historically, global NO$_2$ levels were 3x higher, indicating the capability of detecting a 40-year old Earth-level civilization. Transit and direct imaging observations to detect infrared spectral signatures of NO$_2$ on habitable planets around M-dwarfs would need several 100s of hours of observation time, both due to weaker NO$_2$ absorption in this region, and also because of masking features by dominant H$_2$O and CO$_2$ bands in the infrared part of the spectrum. Non-detection at these levels could be used to place upper limits on the prevalence of NO$_2$ as a technosignature.

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No evidence of phosphine in the atmosphere of Venus by independent analyses

The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.944513 GHz, which was observed with the James Clerk Maxwell Telescope (JCMT) in June 2017 and with the Atacama Large Millimeter/submillimeter Array (ALMA) in March 2019. This line's center is near the SO2 (J=309,21-318,24) transition at 266.943329 GHz (only 1.3 km/s away from the PH3 line) which represents a potential source of contamination. The JCMT and ALMA data, as presented in G2020, are at spectral resolutions comparable to the frequency separation of the two lines. Moreover, the spectral features identified are several km/s in width, and therefore do not permit distinct spectroscopic separation of the candidate spectral lines of PH3 and SO2. We present the radiative transfer modelling we have performed and then discuss the ALMA and JCMT analyses in turn.

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The Crucial Role of Ground- and Space-Based Remote Sensing Studies of Cometary Volatiles in the Next Decade (2023-2032)

The study of comets affords a unique window into the birth, infancy, and subsequent history of the solar system. There is strong evidence that comets incorporated pristine interstellar material as well as processed nebular matter, providing insights into the composition and prevailing conditions over wide swaths of the solar nebula at the time of planet formation. Dynamically new Oort cloud comets harbor primitive ices that have been stored thousands of astronomical units from the Sun and have suffered minimal thermal or radiative processing since their emplacement ~4.5 Gyr ago. Periodic, more dynamically evolved comets such as the Halley-type and Jupiter-family comets reveal the effects of lives spent over a range of heliocentric distances, including perihelion passages into the very inner solar system. Systematically characterizing the information imprinted in the native ice compositions of these objects is critical to understanding the formation and evolution of the solar system, the presence of organic matter and water on the terrestrial planets, the chemistry present in protoplanetary disks around other stars, and the nature of interstellar interlopers such as 2I/Borisov. Although comet rendezvous and sample return missions can provide remarkable insights into the properties of a few short-period comets, the on-sky capacity necessary to perform population-level comet studies while simultaneously remaining sensitive to the paradigm-challenging science that individual comets can reveal can only be provided by remote sensing observations. Here we report the state-of-the-art in ground- and space-based remote sensing of cometary volatiles, review the remarkable progress of the previous decade, articulate the pressing questions that ground- and space-based work will address over the next ten years, and advocate for the technology and resources necessary to realize these aspirations.

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Planetary Science with Astrophysical Assets: Defining the Core Capabilities of Platforms

We seek to compile a uniform set of basic capabilities and needs to maximize the yield of Solar System science with future Astrophysics assets while allowing those assets to achieve their Astrophysics priorities. Within considerations of cost and complexity, inclusion of capabilities that make a particular platform useable to planetary science provide a critical advantage over platforms lacking such capabilities.

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Detectability of Molecular Signatures on TRAPPIST-1e through Transmission Spectroscopy Simulated for Future Space-Based Observatories

Discoveries of terrestrial, Earth-sized exoplanets that lie within the habitable zone (HZ) of their host stars continue to occur at increasing rates. Transit spectroscopy can potentially enable the detection of molecular signatures from such worlds, providing an indication of the presence of an atmosphere and its chemical composition, including gases potentially indicative of a biosphere. Such planets around nearby M-dwarf stars - such as TRAPPIST-1 - provide relatively good signal, high signal/noise, and frequent transits for follow-up spectroscopy. However, even with these advantages, transit spectroscopy of terrestrial planets in the HZ of nearby M-stars will still be a challenge. Herein, we examine the potential for future space observatories to conduct such observations, using a Global Climate Model (GCM), a photochemical model, and a radiative transfer suite to simulate modern-Earth-like atmospheric boundary conditions on TRAPPIST-1e. The detectability of biosignatures on such an atmosphere via transmission spectroscopy is modeled for JWST, LUVOIR, HabEx, and Origins. We show that for any of these observatories, only CO2 would be detectable at the 3 sigma level in transmission spectroscopy, when clouds are included in our simulations. This is because the impacts of clouds on scale height strongly limits the detectability of molecules in the atmosphere. Synergies between space- and ground-based spectroscopy may be essential in order to overcome these difficulties.

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The Mid-InfraRed Exo-planet CLimate Explorer MIRECLE: Exploring the Nearest M-Earths Through Ultra-Stable Mid-IR Transit and Phase-Curve Spectroscopy

This White Paper presents a mission concept called MIRECLE - the Mid-InfraRed Exoplanet CLimate Explorer. With a moderately sized aperture of 2 meters, broad wavelength coverage (4 - 25 um), and next generation instruments, MIRECLE will be capable of efficiently characterizing a statistically significant sample of terrestrial planets, many of which will be in their host stars's habitable zones. Spectroscopic characterization of terrestrial atmospheres will provide constraints for the distribution of planets with tenuous vs. substantial atmospheres, on the inner and outer edges of the habitable zone, and climate models to assess the potential for habitability. For the few brightest targets, the detection of specific combinations of molecules would provide evidence of biosignatures. For all other targets, this comprehensive survey would filter out the airless, desiccated, or lifeless worlds, thus providing a subset of potentially habitable worlds ready for in-depth atmospheric characterization using a larger aperture telescope.

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The Peculiar Volatile Composition of CO-Dominated Comet C/2016 R2 (PanSTARRS)

Comet C/2016 R2 (PanSTARRS) has a peculiar volatile composition, with CO being the dominant volatile as opposed to H$_2$O and one of the largest N$_2$/CO ratios ever observed in a comet. Using observations obtained with the \textit{Spitzer Space Telescope}, NASA's Infrared Telescope Facility, the 3.5-meter ARC telescope at Apache Point Observatory, the Discovery Channel Telescope at Lowell Observatory, and the Arizona Radio Observatory 10-m Submillimeter Telescope we quantified the abundances of 12 different species in the coma of R2 PanSTARRS. We confirm the high abundances of CO and N$_2$ and heavy depletions of H$_2$O, HCN, CH$_3$OH, and H$_2$CO compared to CO reported by previous studies. We provide the first measurements (or most sensitive measurements/constraints) on H$_2$O, CO$_2$, CH$_4$, C$_2$H$_6$, OCS, C$_2$H$_2$, and NH$_3$, all of which are depleted relative to CO by at least one to two orders of magnitude compared to values commonly observed in comets. The observed species also show strong enhancements relative to H$_2$O, and even when compared to other species like CH$_4$ or CH$_3$OH most species show deviations from typical comets by at least a factor of two to three. The only mixing ratios found to be close to typical are CH$_3$OH/CO$_2$ and CH$_3$OH/CH$_4$. While R2 PanSTARRS was located at a heliocentric distance of 2.8 AU at the time of our observations in January/February 2018, we argue that this alone cannot account for the peculiar observed composition of this comet and therefore must reflect its intrinsic composition. We discuss possible implications for this clear outlier in compositional studies of comets obtained to date, and encourage future dynamical and chemical modeling in order to better understand what the composition of R2 PanSTARRS tells us about the early Solar System.

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Evolution of H$_2$O, CO, and CO$_2$ Production in Comet C/2009 P1 Garradd During the 2011-2012 Apparition

We present analysis of high spectral resolution NIR spectra of CO and H$_2$O in comet C/2009 P1 (Garradd) taken during its 2011-2012 apparition with the CSHELL instrument on NASA's Infrared Telescope Facility (IRTF). We also present analysis of observations of atomic oxygen in comet Garradd obtained with the ARCES echelle spectrometer mounted on the ARC 3.5-meter telescope at Apache Point Observatory and the Tull Coude spectrograph on the Harlan J. Smith 2.7-meter telescope at McDonald Observatory. The observations of atomic oxygen serve as a proxy for H$_2$O and CO$_2$. We confirm the high CO abundance in comet Garradd and the asymmetry in the CO/H$_2$O ratio with respect to perihelion reported by previous studies. From the oxygen observations, we infer that the CO$_2$/H$_2$O ratio decreased as the comet moved towards the Sun, which is expected based on current sublimation models. We also infer that the CO$_2$/H$_2$O ratio was higher pre-perihelion than post-perihelion. We observe evidence for the icy grain source of H$_2$O reported by several studies pre-perihelion, and argue that this source is significantly less abundant post-perihelion. Since H$_2$O, CO$_2$, and CO are the primary ices in comets, they drive the activity. We use our measurements of these important volatiles in an attempt to explain the evolution of Garradd's activity over the apparition.

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NIMBUS: The Near-Infrared Multi-Band Ultraprecise Spectroimager for SOFIA

We present a new and innovative near-infrared multi-band ultraprecise spectroimager (NIMBUS) for SOFIA. This design is capable of characterizing a large sample of extrasolar planet atmospheres by measuring elemental and molecular abundances during primary transit and occultation. This wide-field spectroimager would also provide new insights into Trans-Neptunian Objects (TNO), Solar System occultations, brown dwarf atmospheres, carbon chemistry in globular clusters, chemical gradients in nearby galaxies, and galaxy photometric redshifts. NIMBUS would be the premier ultraprecise spectroimager by taking advantage of the SOFIA observatory and state of the art infrared technologies. This optical design splits the beam into eight separate spectral bandpasses, centered around key molecular bands from 1 to 4 microns. Each spectral channel has a wide field of view for simultaneous observations of a reference star that can decorrelate time-variable atmospheric and optical assembly effects, allowing the instrument to achieve ultraprecise calibration for imaging and photometry for a wide variety of astrophysical sources. NIMBUS produces the same data products as a low-resolution integral field spectrograph over a large spectral bandpass, but this design obviates many of the problems that preclude high-precision measurements with traditional slit and integral field spectrographs. This instrument concept is currently not funded for development.

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