arXiv subjects

Giambattista Giacomin

Publications and source records attributed to Giambattista Giacomin.

47 records · Page 3Linked to original sources

arXiv2008

Large scale behavior of semiflexible heteropolymers

We consider a general discrete model for heterogeneous semiflexible polymer chains. Both the thermal noise and the inhomogeneous character of the chain (the disorder) are modeled in terms of random rotations. We focus on the quenched regime, i.e., the analysis is performed for a given realization of the disorder. Semiflexible models differ substantially from random walks on short scales, but on large scales a Brownian behavior emerges. By exploiting techniques from tensor analysis and non-commutative Fourier analysis, we establish the Brownian character of the model on large scale and we obtain an expression for the diffusion constant. We moreover give conditions yielding quantitative mixing properties.

math.PR↗

arXiv2008

Renewal sequences, disordered potentials, and pinning phenomena

We give an overview of the state of the art of the analysis of disordered models of pinning on a defect line. This class of models includes a number of well known and much studied systems (like polymer pinning on a defect line, wetting of interfaces on a disordered substrate and the Poland-Scheraga model of DNA denaturation). A remarkable aspect is that, in absence of disorder, all the models in this class are exactly solvable and they display a localization-delocalization transition that one understands in full detail. Moreover the behavior of such systems near criticality is controlled by a parameter and one observes, by tuning the parameter, the full spectrum of critical behaviors, ranging from first order to infinite order transitions. This is therefore an ideal set-up in which to address the question of the effect of disorder on the phase transition,notably on critical properties. We will review recent results that show that the physical prediction that goes under the name of Harris criterion is indeed fully correct for pinning models. Beyond summarizing the results, we will sketch most of the arguments of proof.

math-ph↗

arXiv2007

A renewal theory approach to periodic copolymers with adsorption

We consider a general model of a heterogeneous polymer chain fluctuating in the proximity of an interface between two selective solvents. The heterogeneous character of the model comes from the fact that the monomer units interact with the solvents and with the interface according to some charges that they carry. The charges repeat themselves along the chain in a periodic fashion. The main question concerning this model is whether the polymer remains tightly close to the interface, a phenomenon called localization, or whether there is a marked preference for one of the two solvents, thus yielding a delocalization phenomenon. In this paper, we present an approach that yields sharp estimates for the partition function of the model in all regimes (localized, delocalized and critical). This, in turn, makes possible a precise pathwise description of the polymer measure, obtaining the full scaling limits of the model. A key point is the closeness of the polymer measure to suitable Markov renewal processes, Markov renewal theory being one of the central mathematical tools of our analysis.

math.PR↗

arXiv2007

Renewal convergence rates and correlation decay for homogeneous pinning models

A class of discrete renewal processes with super-exponentially decaying inter-arrival distributions coincides with the infinite volume limit of general homogeneous pinning models in their localized phase. Pinning models are statistical mechanics systems to which a lot of attention has been devoted both for their relevance for applications and because they are solvable models exhibiting a non-trivial phase transition. The spatial decay of correlations in these systems is directly mapped to the speed of convergence to equilibrium for the associated renewal processes. We show that close to criticality, under general assumptions, the correlation decay rate, or the renewal convergence rate, coincides with the inter-arrival decay rate. We also show that, in general, this is false away from criticality. Under a stronger assumption on the inter-arrival distribution we establish a local limit theorem, capturing thus the sharp asymptotic behavior of correlations.

math.PR↗

arXiv2007

Tightness conditions for polymer measures

We give sufficient conditions for tightness in the space C([0,1]) for sequences of probability measures which enjoy a suitable decoupling between zero level set and excursions. Applications of our results are given in the context of (homogeneous, periodic and disordered) random walk models for polymers and interfaces.

math.PR↗

arXiv2006

Infinite volume limits of polymer chains with periodic charges

The aim of this paper is twofold: - To give an elementary and self-contained proof of an explicit formula for the free energy for a general class of polymer chains interacting with an environment through periodic potentials. This generalizes a result in [Bolthausen and Giacomin, AAP 2005] in which the formula is derived by using the Donsker-Varadhan Large Deviations theory for Markov chains. We exploit instead tools from renewal theory. - To identify the infinite volume limits of the system. In particular, in the different regimes we encounter transient, null recurrent and positive recurrent processes (which correspond to delocalized, critical and localized behaviors of the trajectories). This is done by exploiting the sharp estimates on the partition function of the system obtained by the renewal theory approach. The precise characterization of the infinite volume limits of the system exposes a non-uniqueness problem. We will however explain in detail how this (at first) surprising phenomenon is instead due to the presence of a first-order phase transition.

math.PR↗

arXiv2005

On constrained annealed bounds for pinning and wetting models

The free energy of quenched disordered systems is bounded above by the free energy of the corresponding annealed system. This bound may be improved by applying the annealing procedure, which is just Jensen inequality, after having modified the Hamiltonian in a way that the quenched expressions are left unchanged. This procedure is often viewed as a partial annealing or as a constrained annealing, in the sense that the term that is added may be interpreted as a Lagrange multiplier on the disorder variables. In this note we point out that, for a family of models, some of which have attracted much attention, the multipliers of the form of empirical averages of local functions cannot improve on the basic annealed bound from the viewpoint of characterizing the phase diagram. This class of multipliers is the one that is suitable for computations and it is often believed that in this class one can approximate arbitrarily well the quenched free energy.

math.PR↗

arXiv2005

Sharp asymptotic behavior for wetting models in (1+1)-dimension

We consider continuous and discrete (1+1)-dimensional wetting models which undergo a localization/delocalization phase transition. Using a simple approach based on Renewal Theory we determine the precise asymptotic behavior of the partition function, from which we obtain the scaling limits of the models and an explicit construction of the infinite volume measure (thermodynamic limit) in all regimes, including the critical one.

math.PR↗

arXiv2005

Periodic copolymers at selective interfaces: A Large Deviations approach

We analyze a (1+1)-dimension directed random walk model of a polymer dipped in a medium constituted by two immiscible solvents separated by a flat interface. The polymer chain is heterogeneous in the sense that a single monomer may energetically favor one or the other solvent. We focus on the case in which the polymer types are periodically distributed along the chain or, in other words, the polymer is constituted of identical stretches of fixed length. The phenomenon that one wants to analyze is the localization at the interface: energetically favored configurations place most of the monomers in the preferred solvent and this can be done only if the polymer sticks close to the interface. We investigate, by means of large deviations, the energy-entropy competition that may lead, according to the value of the parameters (the strength of the coupling between monomers and solvents and an asymmetry parameter), to localization. We express the free energy of the system in terms of a variational formula that we can solve. We then use the result to analyze the phase diagram.

math.PR↗

arXiv2005

Estimates on path delocalization for copolymers at selective interfaces

We consider a directed random walk model of a random heterogeneous polymer in the proximity of an interface separating two selective solvents. This model exhibits a localization/delocalization transition. A positive value of the free energy corresponds to the localized regime and strong results on the polymer path behavior are known in this case. We focus on the interior of the delocalized phase, which is characterized by the free energy equal to zero, and we show in particular that in this regime there are O(log N) monomers in the unfavorable solvent (N is the length of the polymer). The previously known result was o(N). Our approach is based on concentration bounds on suitably restricted partition functions. The same idea allows also to interpolate between different types of disorder in the weak coupling limit. In this way we show the universal nature of this limit, previously considered only for binary disorder.

math.PR↗

arXiv2001

Enhanced interface repulsion from quenched hard-wall randomness

We consider the harmonic crystal on the d-dimensional lattice, d larger or equal to 3, that is the centered Gaussian field $ϕ$ with covariance given by the Green function of the simple random walk on $Z^d$. Our main aim is to obtain quantitative information on the repulsion phenomenon that arises when we condition the field to be larger than an IID field $σ$ (which is also independent of $ϕ$), for every x in a large region $D_N=ND\cap \Z^d$, with N a positive integer and $D \subset\R^d$. We are mostly motivated by results for given typical realizations of the $σ$ (quenched set-up), since the conditioned harmonic crystal may be seen as a model for an equilibrium interface, constrained not to go below a inhomogeneous substrate that acts as a hard wall. We consider various types of substrate and we observe that the interface is pushed away from the wall much more than in the case of a flat wall as soon as the upward tail of $σ$ is heavier than Gaussian, while essentially no effect is observed if the tail is sub--Gaussian. In the critical case, that is the one of approximately Gaussian tail, the interplay of the two sources of randomness, $ϕ$ and $σ$, leads to an enhanced repulsion effect of additive type.

math.PR↗