arXiv subjects

Gian Marcello Andolina

Publications and source records attributed to Gian Marcello Andolina.

At least 19 recordsLinked to original sources

arXiv2026

Electrostatics-induced breakdown of the integer quantum Hall effect in cavity QED

We address the prevailing theoretical explanation of the recently observed breakdown of the integer quantum Hall effect in a two-dimensional electron gas embedded in a metallic split-ring resonator. Within the same single-particle description of quantized Hall conductance, we compare previously proposed vacuum-induced transport modifications against an alternative mechanism that explains this breakdown in terms of non-chiral edge channels arising solely from electrostatic boundary effects. This direct comparison shows that for experimentally relevant parameters, the electrostatic contribution exceeds that of any vacuum-induced conductance modifications by many orders of magnitude and yields characteristic transport signatures and energy scales that align well with experimental observations. This finding sheds new light on this puzzling phenomenon, supporting an electrostatic rather than a vacuum-related interpretation that can be directly tested in experiments.

cond-mat.mes-hall↗

arXiv2026

Molecular triplets and other metastable states for excitonic quantum batteries

Excitonic quantum batteries, based on organic fluorescent molecules embedded in optical microcavities, offer a room-temperature platform for studying collective effects in energy storage and developing applications. Recent experiments have offered evidence of superabsorption, a collective enhancement to the light absorption rate of organic molecules which leads to a scalable power density. However, they have also highlighted the challenge posed by rapid radiative decay of fluorescent molecules, which limits the energy storage lifetime. Current strategies to overcome this trade-off focus on controlling the coupling between the absorbing manifold and that used for energy storage. In this chapter, we review three implementations of this design principle: transferring energy from optically excited states to long-lived dark triplet states, generating triplet pairs and higher-spin states through singlet exciton fission, and forming charge-separated states. We discuss each mechanism from both theoretical and experimental perspectives, with particular emphasis on recent device implementations that have extended storage times by several orders of magnitude. We conclude with a cross-platform outlook on the role of metastable states across coherent and room-temperature implementations, from neutral atom arrays to masers and colour centres.

quant-ph↗

arXiv2026

Interplay between photon condensation and electron-electron interactions in molecular systems

We investigate a minimal molecular model consisting of square planar plaquettes hosting multiple electrons, whose dynamics is governed by a tight-binding Hamiltonian supplemented by on-site Hubbard repulsion. By coupling this system to a spatially nonuniform cavity mode, we analyze the emergence of a magnetostatic instability, namely photon condensation, originating from the paramagnetic Van Vleck mechanism. The global behavior of the system is analyzed for different electronic filling factors, and we find that, except for the special cases of half-filling and single electron, where the transition, if it occurs, is necessarily a second order phase transition, the global system may also undergo a first order transition because of the action of the electron-electron interaction. The polaritonic excitation energies are analyzed, providing clear spectroscopic signatures of the magnetostatic instability and of its order.

cond-mat.mes-hall↗

arXiv2026

Quantum Electrodynamics of graphene Landau levels in a deep-subwavelength hyperbolic phonon polariton cavity

The confinement of electromagnetic radiation within extremely small volumes offers an effective means to significantly enhance light-matter interactions, to the extent that zero-point quantum vacuum fluctuations can influence and control the properties of materials. Here, we develop a theoretical framework for the quantum electrodynamics of graphene Landau levels embedded in a deep subwavelength hyperbolic cavity, where light is confined into ultrasmall mode volumes. By studying the spectrum, we discuss the emergence of polaritons, and disentangle the contributions of resonant quantum vacuum effects from those of purely electrostatic interactions. Finally, we study the hybridization between magnetoplasmons and the cavity's electromagnetic modes.

cond-mat.mes-hall↗

arXiv2026

Plasmonic metamaterial time crystal

Periodically driven optical materials and metamaterials have recently emerged as a promising platform for realizing photonic time crystals (PTCs), which are systems whose optical properties are strongly and periodically modulated on timescales comparable to the optical cycle of light. These time-varying structures are the temporal counterparts of spatial photonic crystals (SPCs), for which a large and periodic dielectric contrast is achieved spatially on wavelength scales. Just as SPCs have revolutionized control over light-matter interactions by engineering the photonic density of states in space, PTCs promise comparable breakthroughs from a fundamentally new perspective: a temporal one. However, harnessing such phenomena all-optically poses severe experimental challenges, as it requires order-unity modulation depths of a material's optical properties on ultrafast timescales comparable to the light cycle, a regime that has remained elusive to date. Here, we demonstrate the first all-optical realization of a photonic time crystal, achieved with a surface plasmon cavity metamaterial operating at Terahertz (THz) frequencies. We demonstrate strong (near-unity) and coherent (sub-optical cycle) periodic driving of the plasmonic metamaterial enabled by field-induced dynamical modulation of the carriers' kinetic energy and effective mass - reaching up to 80% of their rest mass. Our spectroscopic measurements reveal a transition into the PTC regime mediated by an exceptional point, at which two Floquet-driven optical eigenmodes coalesce. In the PTC regime, emergent gain is shown to reduce plasmonic losses by more than 50% and we predict plasmonic lasing to be within experimental reach. These results pave the way for temporal engineering of losses and light-matter interactions in plasmonic systems, and establish a robust new platform for time-domain photonics.

physics.optics↗

arXiv2025

Floquet Theory of lattice electrons coupled to an off-resonant cavity

We use Floquet theory and the High-Frequency expansion to derive an effective Hamiltonian for electrons coupled to an off resonant cavity mode, either in its vacuum or driven by classical light. For vacuum fields, we show that long-range hopping and cavity-mediated interactions arise as a direct consequence of quantum fluctuations. As an application, this method is applied to the Su-Schrieffer-Heeger (SSH) model. At high light-matter coupling, our results reveal significant deviations from mean-field predictions, with our framework capturing light-matter entanglement through the Floquet micromotion. Furthermore, the cavity-mediated interactions appearing at first order are shown to be crucial to the description of the system at sufficiently strong light-matter coupling for a fixed cavity frequency. Finally, a drive resonant with the cavity is added with the SSH chain displaying dynamical behavior dependent on the cavity parameters.

cond-mat.str-el↗

arXiv2025

Genuine quantum advantage in non-linear bosonic quantum batteries

Finding a quantum battery model that displays a genuine quantum advantage, while being prone to experimental fabrication, is an extremely challenging task. In this Letter we propose a deceptively simple quantum battery model that displays a genuine quantum advantage, saturating the quantum speed limit. It consists of two harmonic oscillators (the charger and the battery), coupled during the non-equilibrium charging dynamics by a non-linear interaction. We first present the model, then certify the genuine quantum advantage, and finally briefly discuss how the battery can be fabricated through the use of superconducting circuits.

quant-ph↗

arXiv2025

Many-body enhancement of energy storage in a waveguide-QED quantum battery

Quantum batteries have demonstrated remarkable charging properties, showing that a quantum advantage is possible in the realm of quantum thermodynamics. However, finding an effective strategy to store energy for long periods remains crucial in these systems. Here, we investigate different configurations of a waveguide-QED system acting as a quantum battery and show that, in this context, collective effects can slow down the self-discharging time of the battery, thus improving the storage time. Specifically, when the artificial atoms of the array are arranged randomly, the energy and ergotropy of the optical system are shown to decay at a subexponential rate over long periods, in contrast to the energy decay of a single atom in a waveguide. In the case of atoms arranged in an ordered lattice, collective effects slow down dissipative discharging only for a specific lattice spacing. Thus, in both configurations, collective effects can be used to boost the energy-protection properties of optical systems.

quant-ph↗

arXiv2025

Deep quantum Monte Carlo approach for polaritonic chemistry

Recent years have witnessed a surge of experimental and theoretical interest in controlling the properties of matter, such as its chemical reactivity, by confining it in optical cavities, where the enhancement of the light-matter coupling strength leads to the creation of hybrid light-matter states known as polaritons. However, ab initio calculations that account for the quantum nature of both the electromagnetic field and matter are challenging and have only started to be developed in recent years. We introduce a deep learning variational quantum Monte Carlo method to solve the electronic and photonic Schrödinger equation of molecules trapped in optical cavities. We extend typical electronic neural network wavefunction ansatzes to describe joint fermionic and bosonic systems, i.e. electron-photon systems, in a quantum Monte Carlo framework. We apply our method to hydrogen molecules in a cavity, computing both ground and excited states. We assess their energy, dipole moment, charge density shift due to the cavity, the state of the photonic field, and the entanglement developed between the electrons and photons. When possible, we compare our results with more conventional quantum chemistry methods proposed in the literature, finding good qualitative agreement, thus extending the range of scientific problems that can be tackled using machine learning techniques.

physics.chem-ph↗

arXiv2025

Dicke superradiant enhancement of the heat current in circuit QED

Collective effects, such as Dicke superradiant emission, can enhance the performance of a quantum device. Here, we study the heat current flowing between a cold and a hot bath through an ensemble of $N$ qubits, which are collectively coupled to the thermal baths. We find a regime where the collective coupling leads to a quadratic scaling of the heat current with $N$ in a finite-size scenario. Conversely, when approaching the thermodynamic limit, we prove that the collective scenario exhibits a parametric enhancement over the non-collective case. We then consider the presence of a third uncontrolled {\it parasitic} bath, interacting locally with each qubit, that models unavoidable couplings to the external environment. Despite having a non-perturbative effect on the steady-state currents, we show that the collective enhancement is robust to such an addition. Finally, we discuss the feasibility of realizing such a Dicke heat valve with superconducting circuits. Our findings indicate that in a minimal realistic experimental setting with two superconducting qubits, the collective advantage offers an enhancement of approximately $10\%$ compared to the non-collective scenario.

quant-ph↗

arXiv2025

Reinforcement learning optimization of the charging of a Dicke quantum battery

Quantum batteries are energy-storing devices, governed by quantum mechanics, that promise high charging performance thanks to collective effects. Due to its experimental feasibility, the Dicke battery - which comprises $N$ two-level systems coupled to a common photon mode - is one of the most promising designs for quantum batteries. However, the chaotic nature of the model severely hinders the extractable energy (ergotropy). Here, we use reinforcement learning to optimize the charging process of a Dicke battery either by modulating the coupling strength, or the system-cavity detuning. We find that the ergotropy and quantum mechanical energy fluctuations (charging precision) can be greatly improved with respect to standard charging strategies by countering the detrimental effect of quantum chaos. Notably, the collective speedup of the charging time can be preserved even when nearly fully charging the battery.

quant-ph↗

arXiv2024

Light-matter interactions in the vacuum of ultra-strongly coupled systems

We theoretically study how the peculiar properties of the vacuum state of an ultra-strongly coupled system can affect basic light-matter interaction processes. In this unconventional electromagnetic environment, an additional emitter no longer couples to the bare cavity photons, but rather to the polariton modes emerging from the ultra-strong coupling. As such, the effective light-matter interaction strength is sensitive to the properties of the distorted vacuum state. Different interpretations of our predictions in terms of modified quantum fluctuations in the vacuum state and of radiative reaction in classical electromagnetism are critically discussed. Whereas our discussion is focused on the experimentally most relevant case of intersubband polaritons in semiconductor devices, our framework is fully general and applies to generic material systems.

quant-ph↗

arXiv2024

Photon condensation, Van Vleck paramagnetism, and chiral cavities

We introduce a gauge-invariant model of planar, square molecules coupled to a quantized spatially-varying cavity electromagnetic vector potential A(r). Specifically, we choose a temporally chiral cavity hosting a uniform magnetic field B, as this is the simplest instance in which a transverse spatially-varying A(r) is at play. We show that when the molecules are in the Van Vleck paramagnetic regime, an equilibrium quantum phase transition to a photon condensate state occurs.

cond-mat.mes-hall↗

arXiv2024

Amperean superconductivity cannot be induced by deep subwavelength cavities in a two-dimensional material

Amperean superconductivity is an exotic phenomenon stemming from attractive effective electron-electron interactions (EEEIs) mediated by a transverse gauge field. Originally introduced in the context of quantum spin liquids and high-Tc superconductors, Amperean superconductivity has been recently proposed to occur at temperatures on the order of 1-20 K in two-dimensional, parabolic-band, electron gases embedded inside deep sub-wavelength optical cavities. In this work, we first generalize the microscopic theory of cavity-induced Amperean superconductivity to the case of graphene and then argue that this superconducting state cannot be achieved in the deep sub-wavelength regime. In the latter regime, indeed, a cavity induces only EEEIs between density fluctuations rather than the current-current interactions which are responsible for Amperean pairing.

cond-mat.supr-con↗

arXiv2023

Valley-hybridized gate-tunable 1D exciton confinement in MoSe2

Controlling excitons at the nanoscale in semiconductor materials represents a formidable challenge in the fields of quantum photonics and optoelectronics. Achieving this control holds great potential for unlocking strong exciton-exciton interaction regimes, enabling exciton-based logic operations, exploring exotic quantum phases of matter, facilitating deterministic positioning and tuning of quantum emitters, and designing advanced optoelectronic devices. Monolayers of transition metal dichalcogenides (TMDs) offer inherent two-dimensional confinement and possess significant binding energies, making them particularly promising candidates for achieving electric-field-based confinement of excitons without dissociation. While previous exciton engineering strategies have predominantly focused on local strain gradients, the recent emergence of electrically confined states in TMDs has paved the way for novel approaches. Exploiting the valley degree of freedom associated with these confined states further broadens the prospects for exciton engineering. Here, we show electric control of light polarization emitted from one-dimensional (1D) quantum confined states in MoSe2. By employing non-uniform in-plane electric fields, we demonstrate the in-situ tuning of the trapping potential and reveal how gate-tunable valley-hybridization gives rise to linearly polarized emission from these localized states. Remarkably, the polarization of the localized states can be entirely engineered through either the spatial geometry of the 1D confinement potential or the application of an out-of-plane magnetic field.

cond-mat.mes-hall↗

arXiv2023

Deep Subwavelength Topological Edge State in a Hyperbolic Medium

Topological nanophotonics presents the potential for cutting-edge photonic systems, with a core aim revolving around the emergence of topological edge states. These states are primed to propagate robustly while embracing deep subwavelength confinement that defies diffraction limits. Such attributes make them particularly appealing for nanoscale applications, where achieving these elusive states has remained challenging. We unveil the first experimental proof of deep subwavelength topological edge states by implementing periodic modulation of hyperbolic phonon polaritons within a Van der Waals heterostructure. This finding represents a significant milestone in the field of nanophotonics, and it can be directly extended to and hybridized with other Van der Waals materials in various applications. The extensive scope for material substitution facilitates broadened operational frequency ranges, streamlined integration of diverse polaritonic materials, and compatibility with electronic and excitonic systems.

physics.optics↗

arXiv2023

Topological protection of Majorana polaritons in a cavity

Cavity embedding is an emerging paradigm for the control of quantum matter, offering avenues to manipulate electronic states and potentially drive topological phase transitions. In this work, we address the stability of a one-dimensional topological superconducting phase to the vacuum quantum fluctuations brought by a global cavity mode. By employing a quasi-adiabatic analytical approach completed by density matrix renormalization group calculations, we show that the Majorana end modes evolve into composite polaritonic modes while maintaining the topological order intact and robust to disorder. These Majorana polaritons keep their non-abelian exchange properties and protect a twofold exponentially degenerate ground state for an open chain.

cond-mat.mes-hall↗

arXiv2023

Colloquium: Quantum Batteries

Recent years have witnessed an explosion of interest in quantum devices for the production, storage, and transfer of energy. In this Colloquium, we concentrate on the field of quantum energy storage by reviewing recent theoretical and experimental progress in quantum batteries. We first provide a theoretical background discussing the advantages that quantum batteries offer with respect to their classical analogues. We then review the existing quantum many-body battery models and present a thorough discussion of important issues related to their open nature. We finally conclude by discussing promising experimental implementations, preliminary results available in the literature, and perspectives.

quant-ph↗