arXiv subjects

Giorgio Carugno

Publications and source records attributed to Giorgio Carugno.

5 recordsLinked to original sources

arXiv2024

Liquid Hopfield model: retrieval and localization in multicomponent liquid mixtures

Biological mixtures, such as the cellular cytoplasm, are composed of a large number of different components. From this heterogeneity, ordered mesoscopic structures emerge, such as liquid phases with controlled composition. These structures compete with each other for the same components. This raises several questions, such as what types of interactions allow the retrieval of multiple ordered mesoscopic structures, and what are the physical limitations for the retrieval of said structures. In this work, we develop an analytically tractable model for liquids capable of retrieving states with target compositions. We name this model the liquid Hopfield model in reference to corresponding work in the theory of associative neural networks. By solving this model, we show that non-linear repulsive interactions are necessary for retrieval of target structures. We demonstrate that this is because liquid mixtures at low temperatures tend to transition to phases with few components, a phenomenon that we term localization. Taken together, our results demonstrate a trade-off between retrieval and localization phenomena in liquid mixtures.

physics.bio-ph↗

arXiv2024

Dynamical fluctuations of random walks in higher-order networks

Although higher-order interactions are known to affect the typical state of dynamical processes giving rise to new collective behavior, how they drive the emergence of rare events and fluctuations is still an open problem. We investigate how fluctuations of a dynamical quantity of a random walk exploring a higher-order network arise over time. \newtext{In the quenched case, where the hypergraph structure is fixed, through large deviation theory we show that the appearance of rare events is hampered in nodes with many higher-order interactions, and promoted elsewhere. Dynamical fluctuations are further boosted in an annealed scenario, where both the diffusion process and higher-order interactions evolve in time. Here, extreme fluctuations generated by optimal higher-order configurations can be predicted in the limit of a saddle-point approximation.} Our study lays the groundwork for a wide and general theory of fluctuations and rare events in higher-order networks.

cond-mat.dis-nn↗

arXiv2022

Delocalization-localization dynamical phase transition of random walks on graphs

We consider random walks evolving on two models of connected and undirected graphs and study the exact large deviations of a local dynamical observable. We prove, in the thermodynamic limit, that this observable undergoes a first-order dynamical phase transition (DPT). This is interpreted as a `co-existence' of paths in the fluctuations that visit the highly connected bulk of the graph (delocalization) and paths that visit the boundary (localization). The methods we used also allow us to characterize analytically the scaling function that describes the finite size crossover between the localized and delocalized regimes. Remarkably, we also show that the DPT is robust with respect to a change in the graph topology, which only plays a role in the crossover regime. All results support the view that a first-order DPT may also appear in random walks on infinite-size random graphs.

cond-mat.stat-mech↗

arXiv2022

Graph-combinatorial approach for large deviations of Markov chains

We consider discrete-time Markov chains and study large deviations of the pair empirical occupation measure, which is useful to compute fluctuations of pure-additive and jump-type observables. We provide an exact expression for the finite-time moment generating function, which is split in cycles and paths contributions, and scaled cumulant generating function of the pair empirical occupation measure via a graph-combinatorial approach. The expression obtained allows us to give a physical interpretation of interaction and entropic terms, and of the Lagrange multipliers, and may serve as a starting point for sub-leading asymptotics. We illustrate the use of the method for a simple two-state Markov chain.

cond-mat.stat-mech↗

arXiv2022

Instabilities of complex fluids with partially structured and partially random interactions

We develop a theory for thermodynamic instabilities of complex fluids composed of many interacting chemical species organised in families. This model includes partially structured and partially random interactions and can be solved exactly using tools from random matrix theory. The model exhibits three kinds of fluid instabilities: one in which the species form a condensate with a local density that depends on their family (family condensation); one in which species demix in two phases depending on their family (family demixing); and one in which species demix in a random manner irrespective of their family (random demixing). We determine the critical spinodal density of the three types of instabilities and find that the critical spinodal density is finite for both family condensation and family demixing, while for random demixing the critical spinodal density grows as the square root of the number of species. We use the developed framework to describe phase-separation instability of the cytoplasm induced by a change in pH.

physics.bio-ph↗