arXiv subjects

Giorgio Pettinari

Publications and source records attributed to Giorgio Pettinari.

13 recordsLinked to original sources

arXiv2025

Tunable WS$_2$ Micro-Dome Open Cavity Single Photon Source

Versatile, tunable, and potentially scalable single-photon sources are a key asset in emergent photonic quantum technologies. In this work, a single-photon source based on WS$_2$ micro-domes, created via hydrogen ion irradiation, is realized and integrated into an open, tunable optical microcavity. Single-photon emission from the coupled emitter-cavity system is verified via the second-order correlation measurement, revealing a $g^{(2)}(τ=0)$ value of 0.3. A detailed analysis of the spectrally selective, cavity enhanced emission features shows the impact of a pronounced acoustic phonon emission sideband, which contributes specifically to the non-resonant emitter-cavity coupling in this system. The achieved level of cavity-emitter control highlights the potential of open-cavity systems to tailor the emission properties of atomically thin quantum emitters, advancing their suitability for real-world quantum technology applications.

quant-ph↗

arXiv2025

Extremely high excitonic $g$-factors in 2D crystals by alloy-induced admixing of band states

Monolayers (MLs) of semiconducting transition metal dichalcogenides (\mbox{S-TMDs}) emit light very efficiently and display rich spin-valley physics, with gyromagnetic ($g$-) factors of about -4. Here, we investigate how these properties can be tailored by alloying. Magneto-optical spectroscopy is used to reveal the peculiar properties of excitonic complexes in Mo$_{x}$W$_{1-x}$Se$_2$ MLs with different Mo and W concentrations. We show that the alloys feature extremely high $g$-factors for neutral excitons, that change gradually with the composition up to reaching values of the order of -10 for $x \approx 0.2$. First-principles calculations corroborate the experimental findings and provide evidence that alloying in S-TMDs results in a non-trivial band structure engineering, being at the origin of the high $g$-factors. The theoretical framework also suggests a higher strain sensitivity of the alloys, making them promising candidates for tailor-made optoelectronic devices.

cond-mat.mtrl-sci↗

arXiv2024

Giant light emission enhancement in strain-engineered InSe/MS$_2$ (M=Mo,W) van der Waals heterostructures

Two-dimensional crystals stack together through weak van der Waals (vdW) forces, offering unlimited possibilities to play with layer number, order and twist angle in vdW heterostructures (HSs). The realisation of high-performance optoelectronic devices, however, requires the achievement of specific band alignments, $k$-space matching between conduction band minima and valence band maxima, as well as efficient charge transfer between the constituent layers. Fine tuning mechanisms to design ideal HSs are lacking. Here, we show that layer-selective strain engineering can be exploited as an extra degree of freedom in vdW HSs to tailor their band alignment and optical properties. To that end, strain is selectively applied to MS$_2$ (M=Mo,W) monolayers in InSe/MS$_2$ HSs. This triggers a giant PL enhancement of the highly tuneable but weakly emitting InSe by one to three orders of magnitude. Resonant PL excitation measurements, supported by first-principle calculations, provide evidence of a strain-activated direct charge transfer from the MS$_2$ MLs toward InSe. This significant emission enhancement achieved for InSe widens its range of applications for optoelectronics.

cond-mat.mtrl-sci↗

arXiv2024

A source of entangled photons based on a cavity-enhanced and strain-tuned GaAs quantum dot

A quantum-light source that delivers photons with a high brightness and a high degree of entanglement is fundamental for the development of efficient entanglement-based quantum-key distribution systems. Among all possible candidates, epitaxial quantum dots are currently emerging as one of the brightest sources of highly entangled photons. However, the optimization of both brightness and entanglement currently requires different technologies that are difficult to combine in a scalable manner. In this work, we overcome this challenge by developing a novel device consisting of a quantum dot embedded in a circular Bragg resonator, in turn, integrated onto a micromachined piezoelectric actuator. The resonator engineers the light-matter interaction to empower extraction efficiencies up to 0.69(4). Simultaneously, the actuator manipulates strain fields that tune the quantum dot for the generation of entangled photons with corrected fidelities to a maximally entangled state up to 0.96(1). This hybrid technology has the potential to overcome the limitations of the key rates that plague QD-based entangled sources for entanglement-based quantum key distribution and entanglement-based quantum networks.

quant-ph↗

arXiv2024

OLIMPO: a Balloon-Borne SZE Imager to Probe ICM Dynamics and the WHIM

OLIMPO is a proposed Antarctic balloon-borne Sunyaev-Zel'dovich effect (SZE) imager to study gas dynamics associated with structure formation along with the properties of the warm-hot intergalactic medium (WHIM) residing in the connective filaments. During a 25 day flight OLIMPO will image a total of 10 z~0.05 galaxy clusters and 8 bridges at 145, 250, 365, and 460 GHz at an angular resolution of 1.0'-3.3'. The maps will be significantly deeper than those planned from CMB-S4 and CCAT-P, and will have excellent fidelity to the large angular scales of our low-z targets, which are difficult to probe from the ground. In combination with X-ray data from eROSITA and XRISM we will transform our current static view of galaxy clusters into a full dynamic picture by measuring the internal intra-cluster medium (ICM) velocity structure with the kinematic SZE, X-ray spectroscopy, and the power spectrum of ICM fluctuations. Radio observations from ASKAP and MeerKAT will be used to better understand the connection between ICM turbulence and shocks with the relativistic plasma. Beyond the cluster boundary, we will combine thermal SZE maps from OLIMPO with X-ray imaging from eROSITA to measure the thermodynamics of the WHIM residing in filaments, providing a better understanding of its properties and its contribution to the total baryon budget.

astro-ph.CO↗

arXiv2024

Imaging the Quantum Capacitance of Strained MoS2 Monolayers by Electrostatic Force Microscopy

We implemented radio frequency-assisted electrostatic force microscopy (RF-EFM) to investigate the electric field response of biaxially strained molybdenum disulfide (MoS2) monolayers (MLs) in the form of mesoscopic bubbles, produced via hydrogen (H)-ion irradiation of the bulk crystal. MoS2 ML, a semiconducting transition metal dichalcogenide, has recently attracted significant attention due to its promising optoelectronic properties, further tunable by strain. Here, we take advantage of the RF excitation to distinguish the intrinsic quantum capacitance of the strained ML from that due to atomic scale defects, presumably sulfur vacancies or H-passivated sulfur vacancies. In fact, at frequencies fRF larger than the inverse defect trapping time, the defect contribution to the total capacitance and to transport is negligible. Using RF-EFM at fRF = 300 MHz, we visualize simultaneously the bubble topography and its quantum capacitance. Our finite-frequency capacitance imaging technique is non-invasive and nanoscale, and can contribute to the investigation of time and spatial-dependent phenomena, such as the electron compressibility in quantum materials, which are difficult to measure by other methods.

cond-mat.mes-hall↗

arXiv2023

Localisation-to-delocalisation transition of moiré excitons in WSe$_2$/MoSe$_2$ heterostructures

Moiré excitons (MXs) are electron-hole pairs localised by the periodic (moiré) potential forming in two-dimensional heterostructures (HSs). MXs can be exploited, $e.g.$, for creating nanoscale-ordered quantum emitters and achieving or probing strongly correlated electronic phases at relatively high temperatures. Here, we studied the exciton properties of a WSe$_2$/MoSe$_2$ HS from $T$=6 K to room temperature using time-resolved and continuous-wave micro-photoluminescence, also under magnetic field. The exciton dynamics and emission lineshape evolution with temperature show clear signatures that MXs de-trap from the moiré potential and turn into free interlayer excitons (IXs) at $T\gtrsim$120 K. The MX-to-IX transition is also apparent from the exciton magnetic moment reversing its sign when the moiré potential is not capable to localise excitons at elevated temperatures. Concomitantly, the exciton formation and decay times reduce drastically. Thus, our findings establish the conditions for a truly confined nature of the exciton states in a moiré superlattice with increasing temperature.

cond-mat.mtrl-sci↗

arXiv2022

Excitons and trions in WSSe monolayers

The possibility of almost linear tuning of the band gap and of the electrical and optical properties in monolayers (MLs) of semiconducting transition metal dichalcogenide (S-TMD) alloys opens up the way to fabricate materials with on-demand characteristics. By making use of photoluminescence spectroscopy, we investigate optical properties of WSSe MLs with a S/Se ratio of 57/43 deposited on SiO$_2$/Si substrate and encapsulated in hexagonal BN flakes. Similarly to the $"parent"$ WS$_2$ and WSe$_2$ MLs, we assign the WSSe MLs to the ML family with the dark ground exciton state. We find that, in addition to the neutral bright A exciton line, three observed emission lines are associated with negatively charged excitons. The application of in-plane and out-of-plane magnetic fields allows us to assign undeniably the bright and dark (spin- and momentum-forbidden) negative trions as well as the phonon replica of the dark spin-forbidden complex. Furthermore, the existence of the single photon emitters in the WSSe ML is also demonstrated, thus prompting the opportunity to enlarge the wavelength range for potential future quantum applications of S-TMDs.

cond-mat.mes-hall↗

arXiv2022

Proton-driven patterning of bulk transition metal dichalcogenides

At the few-atom-thick limit, transition metal dichalcogenides (TMDs) exhibit a host of attractive electronic optical, and structural properties. The possibility to pattern these properties has a great impact on applied and fundamental research. Here, we demonstrate spatial control over the light emission, lattice deformation, and hydrogen storage in bulk TMDs. By low-energy proton irradiation, we create uniquely favorable conditions for the production and accumulation of molecular hydrogen just one or few monolayers beneath the crystal basal plane of bulk WS2, WSe2, WTe2, MoSe2, and MoS2 samples. H2 therein produced coalesces to form bubbles, which lead to the localized swelling of one X-M-X plane prevalently. This results eventually in the creation of atomically thin domes filled with molecular hydrogen at 10 atm. The domes emit light strongly well above room temperature and can store H2 indefinitely. They can be produced with the desired density, well-ordered positions, and size tunable from the nanometer to the micrometer scale, thus providing a template for the manageable and durable mechanical and electronic structuring of two-dimensional materials.

cond-mat.mtrl-sci↗

arXiv2021

Final results of CALDER: Kinetic inductance light detectors to search for rare events

The next generation of bolometric experiments searching for rave events, in particular for the neutrino-less double beta decay, needs fast, high-sensitivity and easy-to-scale cryogenic light detectors. The CALDER project (2014-2020) developed a new technology for light detection at cryogenic temperature. In this paper we describe the achievements and the final prototype of this project, consisting of a $5\times5$ cm$^2$, 650 $μ$m thick silicon substrate coupled to a single kinetic inductance detector made of a three-layer aluminum-titanium-aluminum. The baseline energy resolution is 34$\pm$1(stat)$\pm$2(syst) eV RMS and the response time is 120 $μ$s. These features, along with the natural multiplexing capability of kinetic inductance detectors, meet the requirements of future large-scale experiments.

physics.ins-det↗

arXiv2020

A chemically etched corrugated feedhorn array for D-band CMB observations

We present the design, manufacturing, and testing of a 37-element array of corrugated feedhorns for Cosmic Microwave Background (CMB) measurements between $140$ and $170$ GHz. The array was designed to be coupled to Kinetic Inductance Detector arrays, either directly (for total power measurements) or through an orthomode transducer (for polarization measurements). We manufactured the array in platelets by chemically etching aluminum plates of $0.3$ mm and $0.4$ mm thickness. The process is fast, low-cost, scalable, and yields high-performance antennas compared to other techniques in the same frequency range. Room temperature electromagnetic measurements show excellent repeatability with an average cross polarization level about $-20$ dB, return loss about $-25$ dB, first sidelobes below $-25$ dB and far sidelobes below $-35$ dB. Our results qualify this process as a valid candidate for state-of-the-art CMB experiments, where large detector arrays with high sensitivity and polarization purity are of paramount importance in the quest for the discovery of CMB polarization $B$-modes.

astro-ph.IM↗

arXiv2020

Reducing the impact of radioactivity on quantum circuits in a deep-underground facility

As quantum coherence times of superconducting circuits have increased from nanoseconds to hundreds of microseconds, they are currently one of the leading platforms for quantum information processing. However, coherence needs to further improve by orders of magnitude to reduce the prohibitive hardware overhead of current error correction schemes. Reaching this goal hinges on reducing the density of broken Cooper pairs, so-called quasiparticles. Here, we show that environmental radioactivity is a significant source of nonequilibrium quasiparticles. Moreover, ionizing radiation introduces time-correlated quasiparticle bursts in resonators on the same chip, further complicating quantum error correction. Operating in a deep-underground lead-shielded cryostat decreases the quasiparticle burst rate by a factor fifty and reduces dissipation up to a factor four, showcasing the importance of radiation abatement in future solid-state quantum hardware.

cond-mat.supr-con↗

arXiv2020

Engineered creation of periodic giant, non-uniform strains in MoS2 monolayers

The realization of ordered strain fields in two-dimensional crystals is an intriguing perspective in many respects, including the instauration of novel transport regimes and the achievement of enhanced device performances. In this work, we demonstrate the possibility to subject micrometric regions of atomically-thin molybdenum disulphide (MoS2) to giant strains with the desired ordering. Mechanically-deformed MoS2 membranes can be obtained by proton-irradiation of bulk flakes, leading to the formation of monolayer domes containing pressurized hydrogen. By pre-patterning the flakes via deposition of polymeric masks and electron beam lithography, we show that it is possible not only to control the size and position of the domes, but also to create a mechanical constraint. Atomic force microscopy measurements reveal that this constraint alters remarkably the morphology of the domes, otherwise subject to universal scaling laws. Upon the optimization of the irradiation and patterning processes, unprecedented periodic configurations of large strain gradients -- estimated by numerical simulations -- are created, with the highest strains being close to the rupture critical values (> 10 %). The creation of such high strains is confirmed by Raman experiments. The method proposed here represents an important step towards the strain engineering of two-dimensional crystals.

physics.app-ph↗