arXiv subjects

Giorgio Sangiovanni

Publications and source records attributed to Giorgio Sangiovanni.

At least 37 records · Page 2Linked to original sources

arXiv2026

Robust spin splitting and fermiology in a layered altermagnet

Altermagnetism defies conventional classifications of collinear magnetic phases, standing apart from ferromagnetism and antiferromagnetism with its unique combination of spin-dependent symmetries, net-zero magnetization, and anomalous Hall transport. Although altermagnetic states have been realized experimentally, their integration into functional devices has been hindered by the structural rigidity and poor tunability of existing materials. First, through cobalt intercalation of the superconducting 2H-NbSe$_2$ polymorph, we induce and stabilize a robust altermagnetic phase and using both theory and experiment, we directly observe the lifting of Kramers degeneracy. Additionally, we present spectroscopic insight into a previously hinted low-temperature phase, and provide evidence of its electronic origin. While shedding light on overlooked aspects of altermagnetism, these findings open pathways to spin-based technologies and lay a foundation for advancing the emerging field of altertronics.

cond-mat.str-el↗

arXiv2025

Tunable Electronic Correlations in 135-Kagome Metals

Kagome metals exhibit rich correlated-electron physics, yet a systematic understanding of the degree of correlation across transition-metal species remains elusive. Using density-functional theory plus multi-orbital slave-spin mean-field theory, we investigate electronic correlations in the Ti-, V-, and Cr-based 135 compounds with Sb and Bi pnictogens. We find that the significantly stronger degree of correlation of the Cr-based materials compared to Ti and V can only be explained through the synergy of two effects: the larger electron filling of the $d$-shell and the reduced characteristic kinetic energy. We put forward that the substitution of Sb with Bi strengthens correlations in all compounds and make the prediction that the-yet-to-be-synthesized CsCr$_3$Bi$_5$ must be the most strongly correlated member of the entire family. These findings provide a quantitative, band-structure-based framework for understanding and predicting correlation strength in Kagome metals.

cond-mat.str-el↗

arXiv2025

Effective enhancement of the electron-phonon coupling driven by nonperturbative electronic density fluctuations

We present a dynamical mean-field study of the nonperturbative electronic mechanisms, which may lead to significant enhancements of the electron-phonon coupling in correlated electron systems. Analyzing the effects of electronic correlations on the lowest-order electron-phonon processes, we show that in the proximity of the Mott metal-to-insulator transition of the doped square lattice Hubbard model, where the isothermal charge response becomes particularly large at small momenta, the coupling of electrons to the lattice is strongly increased. This, in turn, induces significant corrections to both the electronic self-energy and phonon-mediated pairing interaction, indicating the possible onset of a strong interplay between lattice and electronic degrees of freedom even for small values of the bare electron-phonon coupling.

cond-mat.str-el↗

arXiv2025

Superconductivity governed by Janus-faced fermiology in strained bilayer nickelates

High-temperature superconductivity in pressurized and strained bilayer nickelates (La,Pr)$_3$Ni$_2$O$_7$ has emerged as a new frontier. One of the key unresolved issues concerns the fermiology that underlies superconductivity. On both theoretical and experimental sides, no general consensus has been reached, and conflicting results exist regarding whether the relevant Fermi surface involves a $γ$ pocket -- a hole pocket with $d_{z^2}$-orbital character centered at the Brillouin zone corner. Here, we address this issue by unveiling a Janus-faced role of the $γ$ pocket in spin-fluctuation-mediated superconductivity. We show that this pocket simultaneously induces dominant pair-breaking and pair-forming channels for the leading $s_\pm$-wave pairing. Consequently, an optimal superconducting transition temperature $T_\mathrm{c}$ is achieved when the $γ$ pocket surfaces at the Fermi level, placing the system near a Lifshitz transition. This suggests that superconductivity can emerge, provided the maximum energy level of the $γ$ pocket lies sufficiently close to the Fermi level, either from below or above. Our finding not only reconciles two opposing viewpoints on the fermiology, but also naturally explains recent experiments on (La,Pr)$_3$Ni$_2$O$_7$ thin films, including the superconductivity under compressive strain, two conflicting measurements on the Fermi surface, and the dome shape of $T_\mathrm{c}$ as a function of hole doping.

cond-mat.supr-con↗

arXiv2025

Kagome metals

Three important driving forces for creating qualitatively new phases in quantum materials are the topology of the materials' electronic band structures, frustration in the electrons' motion or magnetic interactions, and strong correlations between their charge, spin, and orbital degrees of freedom. In very few material systems do all of these aspects come together to contribute on an equal footing to stabilize new electronic states with unprecedented properties; however the search for such systems can be guided by models of configurational motifs or key sublattices that can host such physics. One of the most fascinating structural motifs for realizing this rich interplay of frustration, electronic topology, and electron correlation effects is the kagome lattice. In this review, we provide an overview of the theoretical underpinnings driving the physics of kagome lattices, and we then discuss experimental progress in realizing novel states enabled by kagome networks in crystalline materials. Different material classes are discussed with an emphasis on the phenomenologies of their electronic states and how they map to interactions arising from their kagome lattices.

cond-mat.str-el↗

arXiv2025

Local-moment magnetism in Mn-based pnictides

We report a comprehensive study of electronic-correlation effects in Manganese-based antiferromagnetic pnictides BaMn$_2$Pn$_2$ (Pn=P,As,Sb,Bi). Our density functional theory plus slave-spin mean-field simulations indicate that all the compounds lie on the strong-coupling side of an itinerant-to-localized moment crossover, corresponding to the critical interaction strength for the Mott transition in the high-temperature paramagnetic phase. We also show that the experimental Néel temperature of each compound scales with the distance from this crossover.

cond-mat.str-el↗

arXiv2025

Robust Orbital-Selective Flat Bands in Transition-Metal Oxychlorides

Flat electronic bands, which amplify electron correlations by quenching kinetic energy, provide an ideal foundation for exotic quantum phases. However, prevailing strategies -- including geometrically frustrated lattices, moire superlattices and heavy-fermion physics -- suffer from inherent trade-offs among robustness, tunability and orbital selectivity, limiting their broad applicability. Here, we unveil an intrinsic orbital-selective flat-band mechanism in the van der Waals materials NbOCl2 and TaOCl2, directly observed by angle-resolved photoemission spectroscopy (ARPES) and understood through density functional theory (DFT) and Wannier analysis. Crucially, we experimentally demonstrate that this momentum-independent flat band exhibits remarkable robustness, surviving from the bulk crystal down to the few-layer limit at room temperature. Our theoretical analysis traces its origin to the hybridization between Nb-dz2 orbital chains and the Lieb-like dx2-y2 sublattice, which is further reinforced by Peierls dimerization. Our findings not only establish transition-metal oxychlorides as a robust and tunable platform for flat-band-driven correlated phases under ambient conditions, but also uncover a new orbital-selective design principle for realizing flat bands in quantum materials.

cond-mat.str-el↗

arXiv2025

Next-generation EDIpack: A Lanczos-based package for quantum impurity models featuring general broken-symmetry phases, flexible bath topologies and multi-platform interoperability

We present a next-generation version of EDIpack, a flexible, high-performance numerical library using Lanczos-based exact diagonalization to solve generic quantum impurity problems, such as those introduced in Dynamical Mean-Field Theory to describe extended strongly correlated materials. This new release efficiently solves impurity problems allowing for different broken-symmetry solutions, including superconductivity, featuring local spin-orbit coupling and/or electron-phonon coupling. It provides quick access to dynamical correlation functions on the entire complex frequency plane at zero and low-temperatures. The modular architecture of the software not only provides Fortran APIs but also includes bindings to C/C++, interfaces with Python and Julia or with TRIQS and w2dynamics research platforms, thus ensuring unprecedented level of inter-operability. The outlook includes further extensions to study quantum materials and cold atoms quantum simulators, as well as quantum information applications.

cond-mat.str-el↗

arXiv2025

Obtaining the Spectral Function of Moiré Graphene Heavy-Fermions Using Iterative Perturbation Theory

The spectral functions of twisted bilayer graphene (TBG) in the absence of strain have recently been investigated in both the symmetric and symmetry-broken phases using dynamical mean-field theory (DMFT). The theoretically predicted Mott-Hubbard bands and gapless semimetallic state at half-filling have since been confirmed experimentally. Here, we develop several second-order perturbation theory approaches to the topological heavy-fermion (THF) model of TBG and twisted symmetric trilayer graphene (TSTG). In the symmetric phase, we adapt, implement, and benchmark an iterative perturbation theory (IPT) impurity solver within DMFT, enabling computationally efficient yet accurate spectral function calculations. We present momentum- and energy-resolved spectra over a broad range of temperatures and fillings for both symmetric and symmetry-broken states. In addition, we derive analytic expressions for the spectral function within the ``Hubbard-I'' approximation of the THF model and, as expected, find that while it provides a tractable description of Mott physics, it does not capture the low-energy Kondo peak or the finite lifetime broadening of the bands. Our methodology can be extended to include strain, lattice relaxation, and parameter variations, thereby allowing systematic predictions of TBG and TSTG spectral properties across a wide range of physical regimes. Because our perturbative approaches are far less computationally intensive than DMFT with numerically exact impurity solvers, they can be used to efficiently benchmark and scan extensive phase diagrams of the THF parameters, paving the way for full DMFT analyses of the TBG spectral function in the presence of strain and relaxation.

cond-mat.str-el↗

arXiv2025

Probing Green's Function Zeros by Co-tunneling through Mott Insulators

Quantum tunneling experiments have provided deep insights into basic excitations occurring as Green's function poles in the realm of complex quantum matter. However, strongly correlated quantum materials also allow for Green's functions zeros (GFZ) that may be seen as an antidote to the familiar poles, and have so far largely eluded direct experimental study. Here, we propose and investigate theoretically how co-tunneling through Mott insulators enables direct access to the shadow band structure of GFZ. In particular, we derive an effective Hamiltonian for the GFZ that is shown to govern the co-tunneling amplitude and reveal fingerprints of many-body correlations clearly distinguishing the GFZ structure from the underlying free Bloch band structure of the system. Our perturbative analytical results are corroborated by numerical data both in the framework of exact diagonalization and matrix product state simulations for a one-dimensional model system consisting of a Su-Schrieffer-Heeger-Hubbard model coupled to two single level quantum dots.

cond-mat.str-el↗

arXiv2025

Optically Tunable Spin Transport in Bilayer Altermagnetic Mott Insulators

Altermagnets are a novel class of materials that combine antiferromagnetic spin ordering with non-relativistic spin splitting (NRSS) in their band structure, making them promising candidates for spintronics applications without requiring strong spin-orbit coupling. In this work, we investigate a two-dimensional bilayer Mott insulator that exhibits altermagnetic order. The interplay between spin and layer degrees of freedom gives rise to a complex symmetry-breaking pattern involving both magnetic and interlayer-coherent components. A key control parameter in the system is the layer polarization, which can be tuned via an external gate voltage. We show that applying an in-plane electric field with opposite signs in the two layers induces a polarization current that drives a spin current in each layer. While the polarization current is isotropic, the resulting spin current exhibits strong anisotropy and can be reversed by adjusting the photon energy. These findings suggest new avenues for manipulating spin transport in altermagnetic systems via electric and optical means.

cond-mat.str-el↗

arXiv2025

Inducing ferromagnetism by structural engineering in a strongly spin-orbit coupled oxide

Magnetic materials with strong spin-orbit coupling (SOC) are essential for the advancement of spin-orbitronic devices, as they enable efficient spin-charge conversion, complex magnetic structures, spin-valley physics, topological phases and other exotic phenomena. 5d transition-metal oxides such as SrIrO3 feature large SOC, but usually show paramagnetic behavior due to broad bands and a low density of states at the Fermi level, accompanied by a relatively low Coulomb repulsion. Here, we unveil ferromagnetism in 5d SrIrO3 thin films grown on SrTiO3 (111). Through substrate-induced structural engineering, a zigzag stacking of three-unit-cell thick layers along the [111] direction is achieved, stabilizing a ferromagnetic state at the interfaces. Magnetotransport measurements reveal an anomalous Hall effect below ~30 K and hysteresis in the Hall conductivity below 7 K, indicating ferromagnetic ordering. X-ray magnetic circular dichroism further supports these results. Theoretical analysis suggests that the structural engineering of the IrO6 octahedral network enhances the density of states at the Fermi level and thus stabilizes Stoner ferromagnetism. This work highlights the potential of structurally engineered 5d oxides for spin-orbitronic devices, where efficient control of SOC-induced magnetic phases by electric currents can lead to lower energy consumption and improved performance in next-generation device technologies.

cond-mat.mtrl-sci↗

arXiv2025

Resolving Intervalley Gaps and Many-Body Resonances in Moiré Superconductor

Magic-angle twisted multilayer graphene stands out as a highly tunable class of moiré materials that exhibit strong electronic correlations and robust superconductivity. However, understanding the relations between the low-temperature superconducting phase and the preceding correlated phases established at higher temperatures remains a challenge. Here, we employ scanning tunneling microscopy and spectroscopy to track the formation sequence of correlated phases established by the interplay of dynamic correlations, intervalley coherence, and superconductivity in magic-angle twisted trilayer graphene (MATTG). We discover the existence of two well-resolved gaps pinned at the Fermi level within the superconducting doping range. While the outer gap, previously associated with pseudogap phase, persists at high temperatures and magnetic fields, the newly revealed inner gap is more fragile in line with superconductivity MATTG transport experiments. Andreev reflection spectroscopy taken at the same location confirms a clear trend that closely follows the doping behaviour of the inner gap, and not the outer one. Moreover, spectroscopy taken at nanoscale domain boundaries further corroborates the contrasting behavior of the two gaps, with the inner gap remaining resilient to structural variations, as expected from the finite superconducting coherence length. By comparing our findings with recent topological heavy-fermion models, we identify that the outer gap originates from the splitting of the Abrikosov-Suhl-Kondo resonance due to the breaking of the valley symmetry arising from correlation-driven effects. Our results suggest an intricate but tractable hierarchy of correlated phases in twisted multilayer graphene.

cond-mat.supr-con↗

arXiv2025

Phonon fluctuation diagnostics: Origin of charge order in AV$_3$Sb$_5$ kagome metals

The microsopic origin of the charge-density wave (CDW) in AV$_3$Sb$_5$ (A = K, Rb, Cs) kagome metals remains a longstanding question, often revolving around electron-phonon coupling and purely electronic mechanisms involving Van Hove scenarios, nesting, and sublattice interference. To reveal the processes driving the CDW transition, we combine ab-initio calculations analysis of the phonon self-energy and angle-resolved photoemission spectroscopy (ARPES). Our momentum-resolved study, supported by ARPES data, reveals that lattice instabilities in the V-135 family of kagome metals appear to also be driven by electronic states far from high-symmetry points, where these states exhibit the strongest coupling with the phonon modes responsible for the CDW distortion. Footing on an interpretation scheme based on phonon fluctuation diagnostics, our work challenges and revises theories that so far have exclusively attributed CDW formation to nesting effects close to the Fermi level.

cond-mat.str-el↗

arXiv2025

Topologically enabled superconductivity: possible implications for rhombohedral graphene

We present a topological mechanism for superconductivity emerging from Chern-2 insulators. While, naively, time-reversal symmetry breaking is expected to prevent superconductivity, it turns out that the opposite is the case: An explicit model calculation for a generalized attractive-U Haldane-Hubbard model demonstrates that superconductivity is only stabilized near the quantum anomalous Hall state, but not near a trivial, time-reversal symmetric band insulator. As standard Bardeen-Cooper-Schrieffer-like mean-field theory fails to capture any superconducting state, we explain this using an effective fractionalized field theory involving fermionic chargeons, bosonic colorons and an emergent U(1) gauge field. When the chargeons form a gapped topological band structure, the proliferation of single monopoles of this gauge field is forbidden. However, long-ranged monopole-antimonopole correlations emerge, and we argue that those correspond to superconducting order. Using random phase approximation on top of extensive slave-rotor mean-field calculations we characterize coherence length and stiffness of the superconductor. Thereby, we deduce the phase diagram in parameter space and furthermore discuss the effect of doping, temperature and an external magnetic field. We complement the fractionalized theory with calculations using an effective spin model and Gutzwiller projected wavefunctions. While mostly based on a simple toy model, we argue that our findings contribute to a better understanding of superconductivity emerging out of spin- and valley polarized rhombohedral graphene multilayers in a parameter regime with nearby quantum anomalous Hall insulators.

cond-mat.str-el↗

arXiv2025

Backscattering in Topological Edge States Despite Time-Reversal Symmetry

Spin-momentum-locked edge states of quantum spin Hall insulators (QSHIs) provide a compelling platform for spintronic applications, owing to their intrinsic protection against backscattering from non-magnetic disorder. This protection emerges from time-reversal symmetry, which pairs Kramers partners of helical edge modes with opposite spin and momentum, thereby strictly forbidding elastic single-particle backscattering within the pair. Yet, contrary to the idealized notion of linear edge bands, the non-monotonic dispersions of realistic materials can host multiple Kramers pairs, reintroducing backscattering channels between them without violating time-reversal symmetry. Here, we investigate inter-Kramers pair backscattering in the non-linear edge bands of the QSHI indenene, highlighting a critical aspect of edge-state stability. Using quasiparticle interference in scanning tunneling spectroscopy -- a direct probe of backscattering -- we observe pairwise coupling between energy-degenerate Kramers pairs, while energy regions with only a single Kramers pair remain strictly protected. Supported by theoretical analysis, our findings provide an unprecedented experimental demonstration of edge state backscattering fully consistent with their underlying topological protection. This insight has profound implications for numerous QSHI candidates, emphasizing that the mere presence of gap-traversing edge modes does not inherently guarantee their protection against backscattering.

cond-mat.mes-hall↗

arXiv2025

Anomalous spin-optical helical effect in Ti-based kagome metal

The kagome lattice stands as a rich platform for hosting a wide array of correlated quantum phenomena, ranging from charge density waves and superconductivity to electron nematicity and loop current states. Direct detection of loop currents in kagome systems has remained a formidable challenge due to their intricate spatial arrangements and the weak magnetic field signatures they produce. This has left their existence and underlying mechanisms a topic of intense debate. In this work, we uncover a hallmark reconcilable with loop currents: spin handedness-selective signals that surpass conventional dichroic, spin, and spin-dichroic responses. We observe this phenomenon in the kagome metal CsTi$_3$Bi$_5$ and we call it the anomalous spin-optical helical effect. This effect arises from the coupling of light' s helicity with spin-orbital electron correlations, providing a groundbreaking method to visualize loop currents in quantum materials. Our discovery not only enriches the debate surrounding loop currents but also paves the way for new strategies to exploit the electronic phases of quantum materials via light-matter interaction.

cond-mat.str-el↗

arXiv2025

Hund flat band in a frustrated spinel oxide

Electronic flat bands associated with quenched kinetic energy and heavy electron mass have attracted great interest for promoting strong electronic correlations and emergent phenomena such as high-temperature charge fractionalization and superconductivity. Intense experimental and theoretical research has been devoted to establishing the rich non-trivial metallic and heavy fermion phases intertwined with such localized electronic states. Here, we investigate the transition metal oxide spinel LiV2O4, an enigmatic heavy fermion compound lacking localized f orbital states. We use angle-resolved photoemission spectroscopy and dynamical mean field theory to reveal a new kind of correlation-induced flat band with suppressed inter-atomic electron hopping arising from intra-atomic Hund coupling. The appearance of heavy quasiparticles is ascribed to a proximate orbital-selective Mott state characterized by fluctuating local moments as evidenced by complementary magnetotransport measurements. The spectroscopic fingerprints of long-lived quasiparticles and their disappearance with increasing temperature further support the emergence of a high-temperature bad metal state observed in transport data. This work resolves a long-standing puzzle on the origin of heavy fermion behavior and unconventional transport in LiV2O4. Simultaneously, it opens a new path to achieving flat bands through electronic interactions in d-orbital systems with geometrical frustration, potentially enabling the realization of exotic phases of matter such as the fractionalized Fermi liquids.

cond-mat.str-el↗