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Giovanni Pellegrini

Publications and source records attributed to Giovanni Pellegrini.

14 recordsLinked to original sources

Robust inverse design of non-periodic Bloch surface wave sensors

One-dimensional photonic crystals supporting Bloch surface waves (BSWs) have emerged as highly sensitive platforms for label-free refractometric sensing. However, the practical performance of these sensors is limited by their vulnerability to fabrication-induced thickness variations. In this Letter, we address this challenge by introducing a robust inverse design framework based on multi-objective genetic optimization. This framework jointly maximizes intensity sensitivity and resilience against manufacturing errors, demonstrating that non-periodic multilayers achieve inherently superior sensitivity-robustness trade-offs, with a pronounced gain in device resilience over conventional periodic designs. By analyzing the optimized designs, we uncover an intrinsic compensation mechanism that physically governs the trade-off and effectively stabilizes the sensor response against structural perturbations. By unlocking the expanded design space of non-periodic multilayers, our optimization strategy paves the way for the practical realization of next-generation BSW sensors.

physics.optics

Polarization-Multiplexed Bloch Surface Wave Sensing of Single-Strand DNA Growth

Refractometric biosensing is a vital label-free tool for the real time detection and interaction analysis of biological and chemical substances. Nanophotonic platforms like Surface Plasmon Resonance (SPR) have played a critical role in providing refractometric sensing capabilities for clinical diagnostics and environmental monitoring. However, traditional systems operating in a single-polarization state cannot fully characterize complex optical properties such as birefringence, which is crucial to resolve many complex biological interactions. Although Bloch Surface Wave (BSW) sensors can support both TE and TM modes, a key capability SPR lacks, they have historically been implemented in single-mode configurations. In this paper, we present a polarization multiplexed BSW refractometric sensing system, simultaneously tracking the resonant wavelength shifts of both TE and TM BSW modes through time. Our technique was applied to investigate single-strand DNA growth during rolling circle amplification (RCA). To accurately recover the time-dependent birefringence, capturing dynamics of the DNA growth and orientation of its chains, we implemented a two-stage modeling approach based on the TMM. First, we utilized a wavelength-dependent surface sensitivity model, confining refractive index changes to the immediate layer above the crystal, to distinguish isotropic background dynamics from birefringent signals. Following the onset of RCA, we transitioned to a model that accounted for the vertical growth of the DNA layers in time. By fitting this model to the TE and TM resonant shifts, we monitor the growth rate of the single-strand DNA layer as well as the refractive index along the two polarization components. Our findings demonstrate the platform's ability to resolve the structural evolution of complex bimolecular interactions associated with conformational changes.

physics.optics

Leveraging Low Index Contrast to Reduce the Polarization Anisotropy in One-Dimensional Photonic Crystals

One-dimensional photonic crystals (1DPCs) are widely used platforms for guiding, filtering, and enhancing light at the nanoscale. Traditionally, designs have favored high refractive index contrast to maximize the photonic band gap (PBG) size. Here, we demonstrate that low-index contrast systems offer a powerful and underexplored route to achieving improved optical functionalities. In particular, we show that low index contrast enables more closely aligned PBGs for transverse electric (TE) and transverse magnetic (TM) polarizations, allowing for broadband superposition of TE and TM Bloch Surface Waves (BSWs). As a demonstration of this functionality, we use this approach to design 1DPCs capable of generating planar superchiral fields for enhanced circular dichroism spectroscopy. To realize such structures, we use an automated design framework based on multi-objective genetic optimization. By comparing optimized designs in both high and low index contrast regimes, we find that low index contrast systems yield significantly greater overlap between the TE and TM BSW dispersion relations and exhibit a pronounced reduction in optical anisotropy - both of which contribute to enhanced optical chirality across the operational bandwidth. Furthermore, simulations reveal that these low index contrast structures offer improved robustness to fabrication tolerances and support a wider dynamic range of chiral analyte concentrations. In addition to their optical performance advantages, low-index contrast systems are naturally compatible with polymeric materials, which offer benefits such as low cost, sustainability, and mechanical flexibility. While this work focuses on mode alignment and its consequences for surface wave behavior, the underlying principles have broader implications for polarization-independent photonic technologies, including optical sensing, computing, and spectral filtering.

physics.optics

Fairness for All: Investigating Harms to Within-Group Individuals in Producer Fairness Re-ranking Optimization -- A Reproducibility Study

Recommender systems are widely used to provide personalized recommendations to users. Recent research has shown that recommender systems may be subject to different types of biases, such as popularity bias, leading to an uneven distribution of recommendation exposure among producer groups. To mitigate this, producer-centered fairness re-ranking (PFR) approaches have been proposed to ensure equitable recommendation utility across groups. However, these approaches overlook the harm they may cause to within-group individuals associated with colder items, which are items with few or no interactions. This study reproduces previous PFR approaches and shows that they significantly harm colder items, leading to a fairness gap for these items in both advantaged and disadvantaged groups. Surprisingly, the unfair base recommendation models were providing greater exposure opportunities to these individual cold items, even though at the group level, they appeared to be unfair. To address this issue, the study proposes an amendment to the PFR approach that regulates the number of colder items recommended by the system. This modification achieves a balance between accuracy and producer fairness while optimizing the selection of colder items within each group, thereby preventing or reducing harm to within-group individuals and augmenting the novelty of all recommended items. The proposed method is able to register an increase in sub-group fairness (SGF) from 0.3104 to 0.3782, 0.6156, and 0.9442 while also improving group-level fairness (GF) (112% and 37% with respect to base models and traditional PFR). Moreover, the proposed method achieves these improvements with minimal or no reduction in accuracy (or even an increase sometimes). We evaluate the proposed method on various recommendation datasets and demonstrate promising results independent of the underlying model or datasets.

cs.IR

A Review of Modern Fashion Recommender Systems

The textile and apparel industries have grown tremendously over the last few years. Customers no longer have to visit many stores, stand in long queues, or try on garments in dressing rooms as millions of products are now available in online catalogs. However, given the plethora of options available, an effective recommendation system is necessary to properly sort, order, and communicate relevant product material or information to users. Effective fashion RS can have a noticeable impact on billions of customers' shopping experiences and increase sales and revenues on the provider side. The goal of this survey is to provide a review of recommender systems that operate in the specific vertical domain of garment and fashion products. We have identified the most pressing challenges in fashion RS research and created a taxonomy that categorizes the literature according to the objective they are trying to accomplish (e.g., item or outfit recommendation, size recommendation, explainability, among others) and type of side-information (users, items, context). We have also identified the most important evaluation goals and perspectives (outfit generation, outfit recommendation, pairing recommendation, and fill-in-the-blank outfit compatibility prediction) and the most commonly used datasets and evaluation metrics.

cs.IR

Phase-Retrieval with Incomplete Autocorrelations Using Deep Convolutional Autoencoders

Phase-retrieval techniques aim to recover the original signal from just the modulus of its Fourier transform, which is usually much easier to measure than its phase, but the standard iterative techniques tend to fail if only part of the modulus information is available. We show that a neural network can be trained to perform phase retrieval using only incomplete information, and we discuss advantages and limitations of this approach.

eess.IV

Learning Aggregation Functions

Learning on sets is increasingly gaining attention in the machine learning community, due to its widespread applicability. Typically, representations over sets are computed by using fixed aggregation functions such as sum or maximum. However, recent results showed that universal function representation by sum- (or max-) decomposition requires either highly discontinuous (and thus poorly learnable) mappings, or a latent dimension equal to the maximum number of elements in the set. To mitigate this problem, we introduce a learnable aggregation function (LAF) for sets of arbitrary cardinality. LAF can approximate several extensively used aggregators (such as average, sum, maximum) as well as more complex functions (e.g., variance and skewness). We report experiments on semi-synthetic and real data showing that LAF outperforms state-of-the-art sum- (max-) decomposition architectures such as DeepSets and library-based architectures like Principal Neighborhood Aggregation, and can be effectively combined with attention-based architectures.

cs.LG

Plasmonic superchiral lattice resonances in the mid-infrared

Recent efforts in the field of surface-enhanced spectroscopies have focused on the paradigm of superchirality, entailing the engineering of the local electromagnetic fields to boost the enantiospecific interaction between light and chiral molecules. In this framework, approaches based on both metallic and dielectric nanostructures have been proposed and have also recently been extended to vibrational circular dichroism in the mid-infrared. In this work, we design, fabricate and characterize arrays of chiral plasmonic slits featuring enhanced chiral fields in the mid-infrared. We exploit collective lattice resonances to further enhance the local intensity and to generate sharp features in the circular dichroism spectra of the platform. Such features are ideally suited to test the superchiral coupling with the vibrational resonances of chiral molecules.

cond-mat.mes-hall

Evidence for cascaded third harmonic generation in non-centrosymmetric gold nanoantennas

The optimization of nonlinear optical processes at the nanoscale is a crucial step for the development of nanoscale photon sources for quantum-optical networks. The development of innovative plasmonic nanoantenna designs and hybrid nanostructures to enhance optical nonlinearities in very small volumes represents one of the most promising routes. In such systems, the upconversion of photons can be achieved with high efficiencies via third-order processes, such as third harmonic generation (THG), thanks to the resonantly-enhanced volume currents. Conversely, second-order processes, such as second harmonic generation (SHG), are often inhibited by the symmetry of metal lattices and of common nanoantenna geometries. SHG and THG processes in plasmonic nanostructures are generally treated independently, since they both represent a small perturbation in the light-matter interaction mechanisms. In this work, we demonstrate that this paradigm does not hold in general, by providing evidence of a cascaded process in THG, which is fueled by SHG and sizably contributes to the overall yield. We address this mechanism by unveiling an anomalous fingerprint in the polarization state of the nonlinear emission from non-centrosymmetric gold nanoantennas and point out that such cascaded processes may also appear for structures that exhibit only moderate SHG yields - signifying its general relevance in plasmon-enhanced nonlinear optics. The presence of this peculiar mechanism in THG from plasmonic nanoantennas at telecommunication wavelengths allows gaining further insight on the physics of plasmon-enhanced nonlinear optical processes. This could be crucial in the realization of nanoscale elements for photon conversion and manipulation operating at room-temperature.

cond-mat.mes-hall

Superchiral Surface Waves for All-Optical Enantiomer Separation

We introduce the use of superchiral surface waves for the all-optical separation of chiral compounds. Using a combination of electrodynamics modeling and analytical techniques, we show that the proposed approach provides chiral optical forces two orders of magnitude larger than those obtained with circularly polarized plane waves. Superchiral surface waves allow for enantiomer separation on spatial, temporal and size scales than would not be achievable with alternative techniques, thus representing a viable route towards all-optical enantiomer separation.

cond-mat.mes-hall

Mid Infrared Nonlinear Plasmonics using Germanium Nanoantennas on Silicon Substrates

We demonstrate third harmonic generation in plasmonic antennas made of highly doped germanium and designed to be resonant in the mid infrared. Owing to the near-field enhancement, the result is an ultrafast, sub-diffraction, coherent light source tunable between 3 and 5 micrometer wavelength on a silicon substrate. To observe nonlinearity in this challenging spectral region, a high-power femtosecond laser system equipped with parametric frequency conversion in combination with an all-reflective confocal microscope setup is employed. We show spatially resolved maps of the linear scattering cross section and the nonlinear emission of single isolated antenna structures. A clear third order power dependence as well as the mid-infrared emission spectra prove the nonlinear nature of the light emission. Simulations support the observed resonance length of the double rod antenna and demonstrate that the field enhancement inside the antenna material is responsible for the nonlinear frequency mixing.

physics.app-ph

Plasmon-enhanced second harmonic sensing

It has been recently suggested that the nonlinear optical processes in plasmonic nanoantennas allow for a substantial boost in the sensitivity of plasmonic sensing platforms. Here we present a sensing device based on an array of non-centrosymmetric plasmonic nanoantennas featuring enhanced second harmonic generation (SHG) integrated in a microfluidic chip. We evaluate its sensitivity both in the linear and nonlinear regime using a figure of merit (FOM = $(ΔI/I)/Δn$) that accounts for the relative change in the measured intensity, \textit{I}, against the variation of the environmental refractive index \textit{n}. While the signal-to-noise ratio achieved in both regimes allows the detection of a minimum refractive index variation $Δn_{min} \approx 10^{-3}$, the platform operation in the nonlinear regime features a sensitivity (i.e. the FOM) that is at least 3 times higher than the linear one. Thanks to the surface sensitivity of plasmon-enhanced SHG, our results show that the development of such SHG sensing platforms with sensitivity performances exceeding those of their linear counterparts is within reach.

cond-mat.mes-hall

Chiral Surface Waves for Enhanced Circular Dichroism

We present a novel chiral sensing platform that combines a one-dimensional photonic crystal design with a birefringent surface defect. The platform sustains simultaneous transverse electric and transverse magnetic surface modes, which are exploited to generate chiral surface waves. The present design provides homogeneous and superchiral fields of both handednesses over arbitrarily large areas in a wide spectral range, resulting in the enhancement of the circular dichroism signal by two orders of magnitude, thus paving the road toward the successful combination of surface-enhanced spectroscopies and electromagnetic superchirality.

physics.optics

Local field enhancement: comparing self-similar and dimer nanoantennas

We study the local field enhancement properties of self-similar nanolenses and compare the obtained results with the performance of standard dimer nanoantennas. We report that, despite the additional structural complexity, self-similar nanolenses are unable to provide significant improvements over the field enhancement performance of standard plasmonic dimers.

physics.optics