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Giuliana Cosentino

Publications and source records attributed to Giuliana Cosentino.

At least 19 recordsLinked to original sources

The complex organic molecular content in the L1517B starless core

Recent observations of the pre-stellar core L1544 and the younger starless core L1498 have revealed that complex organic molecules (COMs) are enhanced in the gas phase toward their outer and intermediate-density shells. Our goal is to determine the level of chemical complexity toward the starless core L1517B, which seems younger than L1498, and compare it with the other two previously studied cores to see if there is a chemical evolution within the cores. We have carried out 3 mm high-sensitivity observations toward two positions in the L1517B starless core: the core's centre and the position where the methanol emission peaks (at a distance of $\sim$5000 au from the core's centre). Our observations reveal that a lower number of COMs and COM precursors are detected in L1517B with respect to L1498 and L1544, and also show lower abundances. Besides methanol, we only detected CH$_3$O, H$_2$CCO, CH$_3$CHO, CH$_3$CN, CH$_3$NC, HCCCN, and HCCNC. Their measured abundances are $\sim$3 times larger toward the methanol peak than toward the core's centre, mimicking the behaviour found toward the more evolved cores L1544 and L1498. We propose that the differences in the chemical complexity observed between the three studied starless cores are a consequence of their evolution, with L1517B being the less evolved one, followed by L1498 and L1544. Chemical complexity in these cores seems to increase over time, with N-bearing molecules forming first and O-bearing COMs forming at a later stage as a result of the catastrophic depletion of CO.

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Low cosmic-ray ionisation at parsec scales in G035.39-00.33

Cosmic rays (CRs) regulate the chemical evolution of the gas and its coupling to the magnetic field in the densest and coldest regions of the interstellar medium (ISM). However, the CR ionisation rate of H$_2$ ($ζ_2$) is one of the most debated parameters characterising molecular clouds due to the uncertainties in its estimation. We developed a new analytical framework based on the chemistry of N$_2$H$^+$, N$_2$D$^+$ and DCO$^+$ to overcome observational limitations in current estimates of $ζ_2$ and to probe the latter and the electron fraction, $x(e)$, in the gas across multiple density regimes. We applied this method towards the parsec-scale filament of the infrared dark cloud (IRDC) G035.39-00.33 with new observations from the NOrthern Extended Array (NOEMA) at a resolution of $3''$ (or $\sim9000$ au). Ancillary observations of C$^{18}$O complete this survey to measure $x(e)$ and $ζ_2$ in G035.39-00.33. CO depletion is widespread in G035.39-00.33 with factors, $f_\mathrm{D}$, positively correlated with column and number densities of H$_2$ in the cloud. The deuterium fractions ($R_\mathrm{D}$) are enhanced towards these same sites in which the corresponding electron fraction values cluster below $\lesssim10^{-8}$. $ζ_2$ varies by three orders of magnitude in G035.39-00.33 ($\sim10^{-18}-10^{-15}$ s$^{-1}$) with a median of $\sim2.3\times10^{-18}$ s$^{-1}$, consistent with those reported for other IRDCs and giant filaments, but on average lower than the typical $ζ_2$ for the ISM. $ζ_2$ shows a functional dependence on $N(\mathrm{H_2})$, but with absolute values lower compared to those predicted by theoretical models. This behaviour suggests the presence of an overall attenuation of the CR flux taking place in G035.39-00.33. The CR flux appears to be reduced by the change in magnetic field strength and morphology previously reported in the region.

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SiO emission in the filamentary Infrared Dark Cloud G035.39-00.33: An ALMA view

Filamentary infrared dark clouds (IRDCs) are believed to represent the initial conditions for massive star and cluster formation. We investigate the IRDC G035.39-00.33 using SiO, H13CO+, CH3OH, and CS emission observed with ALMA at 3.5\arcsec\ resolution (0.05 pc). The SiO emission traces shock activity within the cloud, providing insights into current star formation and cloud formation mechanisms. We identify several regions with broad SiO emission clearly associated with outflows, pinpointing the locations of ongoing star formation across the cloud. The ALMA images also reveal a series of spatially extended SiO emission spots with narrow line profiles, aligned along an arc-like path that is also seen in CS and CH3OH emission. While the broad SiO emission is mainly associated with the main cloud filament, as seen in visual extinction, the narrow SiO arch is located at the edge of the cloud, far from the identified sites of star formation activity. The presence of these arc-like morphologies suggests that large-scale shocks may have compressed the gas in the surroundings of the G035.39-00.33 cloud, shaping its filamentary structure. By inspecting the large-scale radio continuum emission around G035.39-00.33, we find that this IRDC is part of a larger star-forming complex where the densest and coolest material appears at the interacting regions between a Supernova Remnant (SNR) and an expanding HII region. In particular, we hypothesize that this IRDC may be spatially coincident with the ionized expanding gas associated with the previously identified SNR G35.6-0.4. We suggest that collisions between giant molecular clouds and expanding gas flows from interacting SNRs and HII regions may be responsible for the observed arc-like structures. Such shock compressions could play an important role in the formation of IRDCs and in the potential triggering of star formation.

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The role of supernova remnants for the emergence of pre-biotic chemistry in molecular clouds

There is growing evidence that the Sun might have formed within a nebula impacted by at least one SNR. In this scenario, ejecta and shocks from SNRs may have provided the elements on which life as we know it is based. Investigating the chemical complexity of molecular clouds impacted by SNRs is therefore essential to unveil the star formation process and how life appeared on Earth. In this paper, we exploit this scientific questions and describe which technical specifications will drive in future generation telescopes.

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The Emergence of Prebiotic Chemistry in the ISM

Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and meteorites, could have given rise to Life itself. A large-area single-dish telescope with superb sensitivity, field-of-view and multi-band instruments will allow us to explore the limits of chemical complexity in the interstellar medium, across our Galaxy and in external galaxies, determining whether amino acids, sugars, or RNA/DNA nucleobases can form in space.

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The SOFIA Massive (SOMA) Star Formation Q-band Follow-up. II. Hydrogen Recombination Lines Toward High-Mass Protostars

Hydrogen recombination lines (HRLs) are valuable diagnostics of the physical conditions in ionized regions around high-mass stars. Understanding their broadening mechanisms and intensity trends can provide insights into the densities, temperatures, and kinematics of HII regions. We investigate the properties of ionized gas around massive protostars by analyzing hydrogen recombination lines (H-alpha and H-beta) in the Q-band. Observations were conducted using the Yebes 40m radio telescope in the Q-band (30.5~50 GHz) toward six high-mass protostars selected from the SOMA Survey (G45.12+0.13, G45.47+0.05, G28.20-0.05, G35.20-0.74, G19.08-0.29, and G31.28+0.06). The line profiles were analyzed to assess broadening mechanisms, from which electron densities and temperatures were derived. We compared our results with Q-band data from the TianMa 65m Radio Telescope (TMRT) and ALMA Band 1 Science Verification observations of Orion KL. A total of eight H-alpha (n = 51 to 58) and ten H-beta (n = 64 to 73) lines were detected toward G45.12+0.13, G45.47+0.05, and G28.20-0.05, with non-detections in the other sources. Electron densities of ~1-5$\times$10$^6$ cm$^{-3}$ and temperatures of 8000-10000 K were derived. Orion KL shows one order of magnitude lower electron density, but a similar temperature. Notably, G45.12 and G28.20 show increasing intensity with frequency for both H-alpha and H-beta, in contrast to the decreasing trend in Orion KL. The observed line widths indicate contributions from both thermal and dynamical broadening, suggesting high-temperature ionized gas affected by turbulence, outflows, rotation, or stellar winds. Pressure broadening may also play a minor role. The contrasting intensity trends likely reflect differences in local physical conditions or radiative transfer effects, warranting further study through higher-resolution observations and modeling.

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The SOFIA Massive (SOMA) Star Formation Survey. V. Clustered Protostars

We present $\sim8-40\,μ$m SOFIA-FORCAST images of seven regions of ``clustered" star formation as part of the SOFIA Massive (SOMA) Star Formation Survey. We identify a total of 34 protostar candidates and build their spectral energy distributions (SEDs). We fit these SEDs with a grid of radiative transfer models based on the Turbulent Core Accretion (TCA) theory to derive key protostellar properties, including initial core mass, $M_c$, clump environment mass surface density, $Σ_{\rm cl}$, and current protostellar mass, $m_*$. We also carry out empirical graybody (GB) estimation of $Σ_{\rm cl}$, which allows a case of restricted SED fitting within the TCA model grid. We also release version 2.0 of the open-source Python package \emph{sedcreator}, designed to automate the aperture photometry and SED building and fitting process for sources in clustered environments, where flux contamination from close neighbors typically complicates the process. Using these updated methods, SED fitting yields values of $M_c\sim30-200\:M_{\odot}$, $Σ_{\text{cl,SED}}\sim0.1-3\:{\rm{g\:cm}}^{-2}$, and $m_*\sim4-50\:M_{\odot}$. The graybody fitting yields smaller values of $Σ_{\text{cl,GB}}\lesssim1\:{\rm{g\:cm}}^{-2}$. From these results, we do not find evidence for a critical $Σ_{\rm{cl}}$ needed to form massive ($\gtrsim 8\:M_\odot$) stars. However, we do find tentative evidence for a dearth of the most massive ($m_*\gtrsim30\:M_\odot$) protostars in the clustered regions suggesting a potential impact of environment on the stellar initial mass function.

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The Core Mass Function Across Galactic Environments. IV. The Galactic Center

The origin of the stellar Initial Mass Function (IMF) and how it may vary with galactic environment is a matter of debate. Certain star formation theories involve a close connection between the IMF and the Core Mass Function (CMF) so it is important to measure this CMF in a range of Milky Way locations. Here we study the CMF of three Galactic Center clouds: G0.253+0.016 ("The Brick"), Sgr B2 (Deep South field) and Sgr C. We use ALMA 1 mm continuum images and identify cores as peaks in thermal dust emission via the dendrogram algorithm. We develop a completeness correction method via synthetic core insertion, utilizing a realistic mass-dependent size distribution. A power law $\text{d}N/\text{d}\log M \propto M^{-α}$ is fit to the CMFs $>2\:M_\odot$. The Brick has a Salpeter-like index $α=1.28\pm0.09$, while the other regions have shallower indices: Sgr C has $α=0.99\pm0.06$; Sgr B2-DS has $α=0.70\pm0.03$. When smoothed to a common resolution, the differences between the Brick and the others increase as we obtain $α=1.36\pm0.12$, $α=0.66\pm0.06$ and $α=0.62\pm0.04$, respectively, for masses $\gtrsim3\:M_\odot$. Furthermore, we analyze the spatial distribution and mass segregation of cores: Sgr C and Sgr B2-DS show signs of mass segregation, but the Brick does not. We compare our results to several other CMFs from different Galactic regions derived with the same methods. Finally, we discuss how our results may help define an evolutionary sequence of star cluster formation and be used to test star formation theories.

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The SOFIA Massive (SOMA) Star Formation Q-band follow-up I. Carbon-chain chemistry of intermediate-mass protostars

Evidence for similar chemical characteristics around low- and high-mass protostars has been found: in particular, a variety of carbon-chain species and complex organic molecules (COMs) are formed around them. On the other hand, the chemical compositions around intermediate-mass (IM; $2 M_{\odot} < m_* <8 M_{\odot}$) protostars have not been studied with large samples. In particular, it is unclear the extent to which carbon-chain species are formed around them. We aim to obtain the chemical compositions, particularly focusing on carbon-chain species, towards a sample of IM protostars. We have conducted Q-band (31.5-50 GHz) line survey observations towards eleven mainly intermediate-mass protostars with the Yebes 40 m radio telescope. The target protostars were selected from a sub-sample of the source list of the SOFIA Massive (SOMA) Star Formation project. Nine carbon-chain species (HC$_3$N, HC$_5$N, C$_3$H, C$_4$H, $linear-$H$_2$CCC, $cyclic-$C$_3$H$_2$, CCS, C$_3$S, and CH$_3$CCH), three COMs (CH$_3$OH, CH$_3$CHO, and CH$_3$CN), H$_2$CCO, HNCO, and four simple sulfur (S)-bearing species ($^{13}$CS, C$^{34}$S, HCS$^+$, H$_2$CS) have been detected. The rotational temperatures of HC$_5$N are derived to be $\sim20-30$ K in three IM protostars and they are very similar compared to those around low- and high-mass protostars. These results indicate that carbon-chain molecules are formed in lukewarm ($\sim20-30$ K) gas around the IM protostars by the Warm Carbon-Chain Chemistry (WCCC) process. Carbon-chain formation occurs ubiquitously in the warm gas around protostars across a wide range of stellar masses. Carbon-chain molecules and COMs coexist around most of the target IM protostars, which is similar to the situation in low- and high-mass protostars. The chemical characteristics around protostars are common in the low-, intermediate- and high-mass regimes.

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Polarized Light from Massive Protoclusters (POLIMAP). I. Dissecting the role of magnetic fields in the massive infrared dark cloud G28.37+0.07

Magnetic fields may play a crucial role in setting the initial conditions of massive star and star cluster formation. To investigate this, we report SOFIA-HAWC+ $214\:μ$m observations of polarized thermal dust emission and high-resolution GBT-Argus C$^{18}$O(1-0) observations toward the massive Infrared Dark Cloud (IRDC) G28.37+0.07. Considering the local dispersion of $B$-field orientations, we produce a map of $B$-field strength of the IRDC, which exhibits values between $\sim0.03 - 1\:$mG based on a refined Davis-Chandrasekhar-Fermi (r-DCF) method proposed by Skalidis \& Tassis. Comparing to a map of inferred density, the IRDC exhibits a $B-n$ relation with a power law index of $0.51\pm0.02$, which is consistent with a scenario of magnetically-regulated anisotropic collapse. Consideration of the mass-to-flux ratio map indicates that magnetic fields are dynamically important in most regions of the IRDC. A virial analysis of a sample of massive, dense cores in the IRDC, including evaluation of magnetic and kinetic internal and surface terms, indicates consistency with virial equilibrium, sub-Alfvénic conditions and a dominant role for $B-$fields in regulating collapse. A clear alignment of magnetic field morphology with direction of steepest column density gradient is also detected. However, there is no preferred orientation of protostellar outflow directions with the $B-$field. Overall, these results indicate that magnetic fields play a crucial role in regulating massive star and star cluster formation and so need to be accounted for in theoretical models of these processes.

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Astrochemical Diagnostics of the Isolated Massive Protostar G28.20-0.05

We study the astrochemical diagnostics of the isolated massive protostar G28.20-0.05. We analyze data from ALMA 1.3~mm observations with resolution of 0.2 arcsec ($\sim$1,000 au). We detect emission from a wealth of species, including oxygen-bearing (e.g., $\rm{H_2CO}$, $\rm{CH_3OH}$, $\rm{CH_3OCH_3}$), sulfur-bearing (SO$_2$, H$_2$S) and nitrogen-bearing (e.g., HNCO, NH$_2$CHO, C$_2$H$_3$CN, C$_2$H$_5$CN) molecules. We discuss their spatial distributions, physical conditions, correlation between different species and possible chemical origins. In the central region near the protostar, we identify three hot molecular cores (HMCs). HMC1 is part of a mm continuum ring-like structure, is closest in projection to the protostar, has the highest temperature of $\sim300\:$K, and shows the most line-rich spectra. HMC2 is on the other side of the ring, has a temperature of $\sim250\:$K, and is of intermediate chemical complexity. HMC3 is further away, $\sim3,000\:$au in projection, cooler ($\sim70\:$K) and is the least line-rich. The three HMCs have similar mass surface densities ($\sim10\:{\rm{g\:cm}}^{-2}$), number densities ($n_{\rm H}\sim10^9\:{\rm{cm}}^{-3}$) and masses of a few $M_\odot$. The total gas mass in the cores and in the region out to $3,000\:$au is $\sim 25\:M_\odot$, which is comparable to that of the central protostar. Based on spatial distributions of peak line intensities as a function of excitation energy, we infer that the HMCs are externally heated by the protostar. We estimate column densities and abundances of the detected species and discuss the implications for hot core astrochemistry.

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The SOFIA Massive (SOMA) Star Formation Survey. IV. Isolated Protostars

We present $\sim10-40\,μ$m SOFIA-FORCAST images of 11 isolated protostars as part of the SOFIA Massive (SOMA) Star Formation Survey, with this morphological classification based on 37 $μ$m imaging. We develop an automated method to define source aperture size using the gradient of its background-subtracted enclosed flux and apply this to build spectral energy distributions (SEDs). We fit the SEDs with radiative transfer models, developed within the framework of turbulent core accretion (TCA) theory, to estimate key protostellar properties. Here, we release the sedcreator python package that carries out these methods. The SEDs are generally well fitted by the TCA models, from which we infer initial core masses $M_c$ ranging from $20-430\:M_\odot$, clump mass surface densities $Σ_{\rm cl}\sim0.3-1.7\:{\rm{g\:cm}}^{-2}$ and current protostellar masses $m_*\sim3-50\:M_\odot$. From a uniform analysis of the 40 sources in the full SOMA survey to date, we find that massive protostars form across a wide range of clump mass surface density environments, placing constraints on theories that predict a minimum threshold $Σ_{\rm cl}$ for massive star formation. However, the upper end of the $m_*-Σ_{\rm cl}$ distribution follows trends predicted by models of internal protostellar feedback that find greater star formation efficiency in higher $Σ_{\rm cl}$ conditions. We also investigate protostellar far-IR variability by comparison with IRAS data, finding no significant variation over an $\sim$40 year baseline.

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Isolated Massive Star Formation in G28.20-0.05

We report high-resolution 1.3~mm continuum and molecular line observations of the massive protostar G28.20-0.05 with ALMA. The continuum image reveals a ring-like structure with 2,000~au radius, similar to morphology seen in archival 1.3~cm VLA observations. Based on its spectral index and associated H$30α$ emission, this structure mainly traces ionised gas. However, there is evidence for $\sim30$~M$_{\odot}$ of dusty gas near the main mm continuum peak on one side of the ring, as well as in adjacent regions within 3,000~au. A virial analysis on scales of $\sim$2,000~au from hot core line emission yields a dynamical mass of $\sim80\:M_\odot$. A strong velocity gradient in the H$30α$ emission is evidence for a rotating, ionized disk wind, which drives a larger-scale molecular outflow. An infrared SED analysis indicates a current protostellar mass of $m_*\sim40\:M_\odot$ forming from a core with initial mass $M_c\sim300\:M_\odot$ in a clump with mass surface density of $Σ_{\rm cl}\sim 0.8\:{\rm g\:cm}^{-2}$. Thus the SED and other properties of the system can be understood in the context of core accretion models. Structure-finding analysis on the larger-scale continuum image indicates G28.20-0.05 is forming in a relatively isolated environment, with no other concentrated sources, i.e., protostellar cores, above $\sim 1\:M_\odot$ found from $\sim$0.1 to 0.4~pc around the source. This implies that a massive star can form in relative isolation and the dearth of other protostellar companions within the $\sim1$~pc environs is a strong constraint on massive star formation theories that predict the presence of a surrounding protocluster.

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Astrochemical modelling of infrared dark clouds

Infrared dark clouds (IRDCs) are cold, dense regions of the interstellar medium (ISM) that are likely to represent the initial conditions for massive star formation. It is thus important to study the physical and chemical conditions of IRDCs to provide constraints and inputs for theoretical models of these processes. We aim to determine the astrochemical conditions, especially cosmic ray ionisation rate (CRIR) and chemical age, in different regions of the massive IRDC G28.37+00.07 by comparing observed abundances of multiple molecules and molecular ions with the predictions of astrochemical models. We have computed a series of single-zone astrochemical models with a gas-grain network that systematically explores the parameter space of density, temperature, CRIR, and visual extinction. We have also investigated the effects of choices of CO ice binding energy and temperatures achieved in transient heating of grains when struck by cosmic rays. We selected 10 positions across the IRDC that are known to have a variety of star formation activity. We utilised mid-infrared (MIR) extinction maps and sub-mm emission maps to measure the mass surface densities of these regions, needed for abundance and volume density estimates. The sub-mm emission maps were also used to measure temperatures. We then used IRAM-30m observations of various tracers to estimate column densities and thus abundances. Using estimates of the abundances of CO, HCO$^+$ and N$_2$H$^+$ we find consistency with astrochemical models that have relatively low CRIRs of $ζ\sim10^{-18}$ to $\sim10^{-17}\:{\rm s}^{-1}$, with no evidence for systematic variation with the level of star formation activity. Astrochemical ages are found to be < 1 Myr. We discuss potential sources of systematic uncertainties in these results and the overall implications for IRDC evolutionary history and astrochemical models.(abridged for arXiv)

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Ionise hard: interstellar PO$^{+}$ detection

We report the first detection of the phosphorus monoxide ion (PO$^{+}$) in the interstellar medium. Our unbiased and very sensitive spectral survey towards the G+0.693$-$0.027 molecular cloud covers four different rotational transitions of this molecule, two of which ($J$=1$-$0 and $J$=2$-$1) appear free of contamination from other species. The fit performed, assuming Local Thermodynamic Equilibrium conditions, yields a column density of $N$=(6.0$\pm$0.7)$\times$10$^{11}$ cm$^{-2}$. The resulting molecular abundance with respect to molecular hydrogen is 4.5$\times$10$^{-12}$. The column density of PO$^{+}$ normalised by the cosmic abundance of P is larger than those of NO$^{+}$ and SO$^{+}$, normalised by N and S, by factors of 3.6 and 2.3, respectively. The $N$(PO$^{+}$)/$N$(PO) ratio is 0.12$\pm$0.03, more than one order of magnitude higher than those of $N$(SO$^{+}$)/$N$(SO) and $N$(NO$^{+}$)/$N$(NO). These results indicate that P is more efficiently ionised in the ISM than N and S. We have performed new chemical models that confirm that the PO$^+$ abundance is strongly enhanced in shocked regions with high values of cosmic-ray ionisation rates (10$^{-15}-$10$^{-14}$ s$^{-1}$), as occurs in the G+0.693$-$0.027 molecular cloud. The shocks sputter the interstellar icy grain mantles, releasing into the gas phase most of their P content, mainly in the form of PH$_3$, which is converted into atomic P, and then ionised efficiently by cosmic rays, forming P$^+$. Further reactions with O$_2$ and OH produce PO$^{+}$. The cosmic-ray ionisation of PO might also contribute significantly, which would explain the high $N$(PO$^{+}$)/$N$(PO) observed. The relatively high gas-phase abundance of PO$^{+}$ with respect to other P-bearing species stresses the relevance of this species in the interstellar chemistry of P.

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SiO Outflows as Tracers of Massive Star Formation in Infrared Dark Clouds

To study the early phases of massive star formation, we present ALMA observations of SiO(5-4) emission and VLA observations of 6 cm continuum emission towards 32 Infrared Dark Cloud (IRDC) clumps, spatially resolved down to $\lesssim 0.05$ pc. Out of the 32 clumps, we detect SiO emission in 20 clumps, and in 11 of them the SiO emission is relatively strong and likely tracing protostellar outflows. Some SiO outflows are collimated, while others are less ordered. For the six strongest SiO outflows, we estimate basic outflow properties. In our entire sample, where there is SiO emission, we find 1.3 mm continuum and infrared emission nearby, but not vice versa. We build the spectral energy distributions (SEDs) of cores with 1.3 mm continuum emission and fit them with radiative transfer (RT) models. The low luminosities and stellar masses returned by SED fitting suggest these are early stage protostars. We see a slight trend of increasing SiO line luminosity with bolometric luminosity, which suggests more powerful shocks in the vicinity of more massive YSOs. We do not see a clear relation between the SiO luminosity and the evolutionary stage indicated by $L/M$. We conclude that as a protostar approaches a bolometric luminosity of $\sim 10^2 \: L_{\odot}$, the shocks in the outflow are generally strong enough to form SiO emission. The VLA 6 cm observations toward the 15 clumps with the strongest SiO emission detect emission in four clumps, which is likely shock ionized jets associated with the more massive ones of these protostellar cores.

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The Core Mass Function Across Galactic Environments. III. Massive Protoclusters

The stellar initial mass function (IMF) is fundamental for many areas of astrophysics, but its origin remains poorly understood. It may be inherited from the core mass function (CMF) or arise as a result of more chaotic, competitive accretion. Dense, gravitationally bound cores are seen in molecular clouds and some observations have suggested that the CMF is similar in shape to the IMF, though translated to higher masses by a factor of $\sim3$. Here we measure the CMF in 28 dense clumps within 3.5 kpc that are likely to be central regions of massive protoclusters, observed via $1.3\:{\rm{mm}}$ dust continuum emission by the ALMAGAL project. We identify 222 cores using the dendrogram algorithm with masses ranging from 0.04 to $252\:M_{\odot}$. We apply completeness corrections for flux and number recovery, estimated from core insertion and recovery experiments. At higher masses, the final derived CMF is well described by a single power law of the form $dN/d\:{\textrm{log}}\:M\propto\:M^{-α}$ with $α\simeq0.94\pm0.08$. However, we find evidence of a break in this power-law behavior between $\sim5$ and $15\:M_{\odot}$, which is, to our knowledge, the first time such a break has been found in distant ($\gtrsim 1$ kpc) regions by ALMA. We compare this massive protocluster CMF with those derived using the same methods in the G286 protocluster and a sample of Infrared Dark Clouds. The massive protocluster CMF is significantly different, i.e., containing more massive cores, which is a potential indication of the role of environment on the CMF and IMF.

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The complex organic molecular content in the L1498 starless core

Observations carried out toward starless and pre-stellar cores have revealed that complex organic molecules are prevalent in these objects, but it is unclear what chemical processes are involved in their formation. Recently, it has been shown that complex organics are preferentially produced at an intermediate-density shell within the L1544 pre-stellar core at radial distances of ~4000 au with respect to the core center. However, the spatial distribution of complex organics has only been inferred toward this core and it remains unknown whether these species present a similar behaviour in other cores. We report high-sensitivity observations carried out toward two positions in the L1498 pre-stellar core, the dust peak and a position located at a distance of ~11000 au from the center of the core where the emission of CH$_3$OH peaks. Similarly to L1544, our observations reveal that small O-bearing molecules and N-bearing species are enhanced by factors ~4-14 toward the outer shell of L1498. However, unlike L1544, large O-bearing organics such as CH3CHO, CH3OCH3 or CH3OCHO are not detected within our sensitivity limits. For N-bearing organics, these species are more abundant toward the outer shell of the L1498 pre-stellar core than toward the one in L1544. We propose that the differences observed between O-bearing and N-bearing species in L1498 and L1544 are due to the different physical structure of these cores, which in turn is a consequence of their evolutionary stage, with L1498 being younger than L1544.

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