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Giulio Biroli

Publications and source records attributed to Giulio Biroli.

196 records · Page 11Linked to original sources

Jamming Percolation and Glass Transitions in Lattice Models

A new class of lattice gas models with trivial interactions but constrained dynamics are introduced. These are proven to exhibit a dynamical glass transition: above a critical density, rho_c, ergodicity is broken due to the appearance of an infinite spanning cluster of jammed particles. The fraction of jammed particles is discontinuous at the transition, while in the unjammed phase dynamical correlation lengths and timescales diverge as exp[C(rho_c-rho)^(-mu)]. Dynamic correlations display two-step relaxation similar to glass-formers and jamming systems.

cond-mat.stat-mech↗

A Crash Course on Aging

In these lecture notes I describe some of the main theoretical ideas emerged to explain the aging dynamics. This is meant to be a very short introduction to aging dynamics and no previous knowledge is assumed. I will go through simple examples that allow one to grasp the main results and predictions.

cond-mat.stat-mech↗

Non-linear susceptibility in glassy systems: a probe for cooperative dynamical length scales

We argue that for generic systems close to a critical point, an extended Fluctuation-Dissipation relation connects the low frequency non-linear (cubic) susceptibility to the four-point correlation function. In glassy systems, the latter contains interesting information on the heterogeneity and cooperativity of the dynamics. Our result suggests that if the abrupt slowing down of glassy materials is indeed accompanied by the growth of a cooperative length ell, then the non-linear, 3 omega response to an oscillating field should substantially increase and give direct information on the temperature (or density) dependence of ell. The analysis of the non-linear compressibility or the dielectric susceptibility in supercooled liquids, or the non-linear magnetic susceptibility in spin-glasses, should give access to a cooperative length scale, that grows as the temperature is decreased or as the age of the system increases. Our theoretical analysis holds exactly within the Mode-Coupling Theory of glasses.

cond-mat.stat-mech↗

What do we learn from the shape of the dynamical susceptibility of glass-formers?

We compute analytically and numerically the four-point correlation function that characterizes non-trivial cooperative dynamics in glassy systems within several models of glasses: elasto-plastic deformations, mode-coupling theory (MCT), collectively rearranging regions (CRR), diffusing defects and kinetically constrained models (KCM). Some features of the four-point susceptibility chi_4(t) are expected to be universal. at short times we expect an elastic regime characterized by a t or sqrt{t} growth. We find both in the beta, and the early alpha regime that chi_4 sim t^mu, where mu is directly related to the mechanism responsible for relaxation. This regime ends when a maximum of chi_4 is reached at a time t=t^* of the order of the relaxation time of the system. This maximum is followed by a fast decay to zero at large times. The height of the maximum also follows a power-law, chi_4(t^*) sim t^{*lambda}. The value of the exponents mu and lambda allows one to distinguish between different mechanisms. For example, freely diffusing defects in d=3 lead to mu=2 and lambda=1, whereas the CRR scenario rather predicts either mu=1 or a logarithmic behaviour depending on the nature of the nucleation events, and a logarithmic behaviour of chi_4(t^*). MCT leads to mu=b and lambda =1/gamma, where b and gamma are the standard MCT exponents. We compare our theoretical results with numerical simulations on a Lennard-Jones and a soft-sphere system. Within the limited time-scales accessible to numerical simulations, we find that the exponent mu is rather small, mu < 1, with a value in reasonable agreement with the MCT predictions.

cond-mat.dis-nn↗

Facilitated spin models on Bethe lattice: bootstrap percolation, mode-coupling transition and glassy dynamics

We show that facilitated spin models of cooperative dynamics introduced by Fredrickson and Andersen display on Bethe lattices a glassy behaviour similar to the one predicted by the mode-coupling theory of supercooled liquids and the dynamical theory of mean-field disordered systems. At low temperature such cooperative models show a two-step relaxation and their equilibration time diverges at a finite temperature according to a power-law. The geometric nature of the dynamical arrest corresponds to a bootstrap percolation process which leads to a phase space organization similar to the one of mean-field disordered systems. The relaxation dynamics after a subcritical quench exhibits aging and converges asymptotically to the threshold states that appear at the bootstrap percolation transition.

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Diverging length scale and upper critical dimension in the Mode-Coupling Theory of the glass transition

We show that the glass transition predicted by the Mode-Coupling Theory (MCT) is a critical phenomenon with a diverging length and time scale associated to the cooperativity of the dynamics. We obtain the scaling exponents nu and z that relate space and time scales to the distance from criticality, as well as the scaling form of the critical four-point correlation function. However, both these predictions and other well known MCT results are mean-field in nature and are thus expected to change below the upper critical dimension dc=6, as suggested by different forms of the Ginzburg criterion.

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Spatial structures and dynamics of kinetically constrained models for glasses

Kob and Andersen's simple lattice models for the dynamics of structural glasses are analyzed. Although the particles have only hard core interactions, the imposed constraint that they cannot move if surrounded by too many others causes slow dynamics. On Bethe lattices a dynamical transition to a partially frozen phase occurs. In finite dimensions there exist rare mobile elements that destroy the transition. At low vacancy density, $v$, the spacing, $Ξ$, between mobile elements diverges exponentially or faster in $1/v$. Within the mobile elements, the dynamics is intrinsically cooperative and the characteristic time scale diverges faster than any power of $1/v$ (although slower than $Ξ$). The tagged-particle diffusion coefficient vanishes roughly as $Ξ^{-d}$.

cond-mat.dis-nn↗

Dynamical arrest, tracer diffusion and Kinetically Constrained Lattice Gases

We analyze the tagged particle diffusion for kinetically constrained models for glassy systems. We present a method, focusing on the Kob-Andersen model as an example, which allows to prove lower and upper bounds for the self diffusion coefficient $D_S$. This method leads to the exact density dependence of $D_{S}$, at high density, for models with finite defects and to prove diffusivity, $D_{S}>0$, at any finite density for highly cooperative models. A more general outcome is that under very general assumptions one can exclude that a dynamical transition, like the one predicted by the Mode-Coupling-Theory of glasses, takes place at a finite temperature/chemical potential for systems of interacting particles on a lattice.

cond-mat.stat-mech↗

Lattice Glass Models

Motivated by the concept of geometrical frustration, we introduce a class of statistical mechanics lattice models for the glass transition. Monte Carlo simulations in three dimensions show that they display a dynamical glass transition which is very similar to that observed in other off-lattice systems and which does not depend on a specific dynamical rule. Whereas their analytic solution within the Bethe approximation shows that they do have a discontinuous glass transition compatible with the numerical observations.

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A note on cluster methods for strongly correlated electron systems

We develop, clarify and test various aspects of cluster methods dynamical mean field methods using a soluble toy model as a benchmark. We find that the Cellular Dynamical Mean Field Theory (C-DMFT) converges very rapidly and compare its convergence properties with those of the Dynamical Cluster Approximation (DCA). We propose and test improved estimators for the lattice self energy within C-DMFT.

cond-mat.str-el↗

Quantum TAP equations

We derive Thouless-Anderson-Palmer (TAP) equations for quantum disordered systems. We apply them to the study of the paramagnetic and glassy phases in the quantum version of the spherical p spin-glass model. We generalize several useful quantities (complexity, threshold level, etc.) and various ideas (configurational entropy crisis, etc), that have been developed within the classical TAP approach, to quantum systems. The analysis of the quantum TAP equations allows us to show that the phase diagram (temperature-quantum parameter) of the p spin-glass model should be generic. In particular, we argue that a crossover from a second order thermodynamic transition close to the classical critical point to a first order thermodynamic transition close to the quantum critical point is to be expected in a large class of systems.

cond-mat.dis-nn↗

Metastable states in glassy systems

Truly stable metastable states are an artifact of the mean-field approximation or the zero temperature limit. If such appealing concepts in glass theory as configurational entropy are to have a meaning beyond these approximations, one needs to cast them in a form involving states with finite lifetimes. Starting from elementary examples and using results of Gaveau and Schulman, we propose a simple expression for the configurational entropy and revisit the question of taking flat averages over metastable states. The construction is applicable to finite dimensional systems, and we explicitly show that for simple mean-field glass models it recovers, justifies and generalises the known results. The calculation emphasises the appearance of new dynamical order parameters.

cond-mat.stat-mech↗

Role of free energy landscape in the dynamics of mean field glassy systems

In this paper we expose the results of our recent work on the dynamical TAP approach to mean field glassy systems. Our aim is to clarify the connection between free energy landscape and out of equilibrium dynamics in solvable models. Frequently qualitative explanations of glassy behaviour are based on the ``Free Energy Landscape Paradigm''. If its relevance for equilibrium properties is clear, the relationship between free energy landscape and out of equilibrium dynamics is not well understood yet. In this paper we clarify this relationship for the class of spin glass models which reproduce phenomenologically some features of structural glasses. The method we use is a generalisation to dynamics of the Thouless, Anderson and Palmer approach to thermodynamics of mean field spin glasses. Within this framework we show to what extent the dynamics can be represented as an evolution in the free energy landscape. In particular the relationship between the long-time dynamics and the local properties of the free energy landscape shows up explicitly using this approach.

cond-mat.dis-nn↗

From inherent structures to pure states: some simple remarks and examples

The notions of pure states and inherent structures, i.e. stable configurations against 1-spin flip are discussed. We explain why these different concepts accidentally coincide in mean-field models with infinite connectivity and present an exactly solvable unidimensional model where they do not. At zero temperature pure states are to some extent related to k-spin flip stable configurations with k going to infinity after the thermodynamical limit has been taken. This relationship is supported by an explicit analysis of the TAP equations and calculation of the number of pure states and k-spin flips stable configurations in a mean-field model with finite couplings. Finally we discuss the relevance of the concepts of pure states and inherent structures in finite dimensional glassy systems.

cond-mat.dis-nn↗

Dynamical TAP approach to mean field glassy systems

The Thouless, Anderson, Palmer (TAP) approach to thermodynamics of mean field spin-glasses is generalised to dynamics. A method to compute the dynamical TAP equations is developed and applied to the p-spin spherical model. In this context we show to what extent the dynamics can be represented as an evolution in the free energy landscape. In particular the relationship between the long-time dynamics and the local properties of the free energy landscape shows up explicitly within this approach. Conversely, by an instantaneous normal modes analysis we show that the local properties of the energy landscape seen by the system during its dynamical evolution do not change qualitatively at the dynamical transition.

cond-mat.dis-nn↗

A variational description of the ground state structure in random satisfiability problems

A variational approach to finite connectivity spin-glass-like models is developed and applied to describe the structure of optimal solutions in random satisfiability problems. Our variational scheme accurately reproduces the known replica symmetric results and also allows for the inclusion of replica symmetry breaking effects. For the 3-SAT problem, we find two transitions as the ratio $α$ of logical clauses per Boolean variables increases. At the first one $α_s \simeq 3.96$, a non-trivial organization of the solution space in geometrically separated clusters emerges. The multiplicity of these clusters as well as the typical distances between different solutions are calculated. At the second threshold $α_c \simeq 4.48$, satisfying assignments disappear and a finite fraction $B_0 \simeq 0.13$ of variables are overconstrained and take the same values in all optimal (though unsatisfying) assignments. These values have to be compared to $α_c \simeq 4.27, B_0 \simeq 0.4$ obtained from numerical experiments on small instances. Within the present variational approach, the SAT-UNSAT transition naturally appears as a mixture of a first and a second order transition. For the mixed $2+p$-SAT with $p<2/5$, the behavior is as expected much simpler: a unique smooth transition from SAT to UNSAT takes place at $α_c=1/(1-p)$.

cond-mat.dis-nn↗