arXiv subjects

Gonzalo Álvarez-Pérez

Publications and source records attributed to Gonzalo Álvarez-Pérez.

At least 19 recordsLinked to original sources

arXiv2026

Nonreciprocal plasmonic response of drift-biased two-dimensional metals

We develop a nonlocal electrodynamic framework for drift-biased two-dimensional electron gases (2DEGs) with Dirac (linear) and parabolic (quadratic) dispersions, deriving closed-form drift-dependent conductivity tensors from the Boltzmann transport equation. We obtain the plasmon dispersion and near-field emission of a point dipole, revealing nonreciprocal propagation in both systems. At equal drift parameter, the parabolic 2DEG exhibits stronger nonreciprocity than the Dirac system, although we find that a larger drift parameter does not by itself produce stronger nonreciprocity: the response is set by the interplay of drift and plasmon nonlocality. As such, the combination of strong nonlocality and experimentally accessible drift velocities of semiconductor 2DEGs identifies parabolic systems as a promising platform for tunable, nonreciprocal plasmonics.

cond-mat.mes-hall↗

arXiv2026

Nonlocal-nonlinear phonon polaritons

When light is confined to deeply subwavelength volumes, optical responses can become nonlocal. Yet how nonlocality reshapes nonlinear light-matter interactions remains largely unexplored, particularly in dielectrics. Here, we theoretically uncover a new class of nonlinear optical processes arising from the interplay between optical-phonon propagation and ionic-bond anharmonicity in polar crystals. We show that, unlike conventional local nonlinearities, this mechanism enables second-order responses even in centrosymmetric materials. Moreover, these responses can be tuned by the confinement and resonantly enhanced near optical-phonon resonances. Using density functional perturbation theory, we quantify the resulting nonlocal second-order susceptibilities in representative polar crystals. Our results establish nonlocal-nonlinear optics as a new regime of light-matter interaction in dielectrics.

physics.optics↗

arXiv2026

Twistoptics in Planar Heterostructures with an Arbitrary Number of Rotated 3D Thin Layers and 2D Conductive Sheets

Twistoptics has recently emerged as a branch of nano-optics that explores light propagation in stacks of thin anisotropic layers rotated relative to one another. The concept is particularly relevant for polaritons -- hybrid light-matter quasiparticles -- in van der Waals (vdW) materials, where strong in-plane anisotropy and deep subwavelength confinement make the polaritonic dispersion highly sensitive to interlayer twist angles. This sensitivity enables exotic phenomena such as canalization, i.e., diffraction-free propagation, with potential applications ranging from thermal management to super-resolution imaging. Despite rapid progress, a general analytical framework to describe polariton propagation in twisted planar heterostructures has been missing. Here we present an analytical model for planar stacks comprising an arbitrary number of finite-thickness anisotropic (biaxial) layers and infinitesimally thin anisotropic conductive sheets. The formalism and its high-momentum and thin-film approximations predict key polaritonic observables, such as wavelength, propagation length, and electromagnetic field distributions. We also provide open-access numerical scripts implementing the model to support their practical use. Together, these results provide a general theoretical foundation for twistoptics and should facilitate the discovery and accelerate the implementation of twist-engineered polaritonic phenomena across the electromagnetic spectrum.

physics.optics↗

arXiv2026

Fast Programming of In-Plane Hyperbolic Phonon Polariton Optics Through van der Waals Crystals using the Phase-Change Material In3SbTe2

The high directionality of hyperbolic phonon polaritons (HPhPs) has opened radically new ways to route and steer the flow of energy at the nanoscale. However, launching HPhPs requires fabricating efficient and precisely aligned polariton launching structures, which remains time-consuming and expensive with conventional nanofabrication approaches. Recently, using optical laser pulses, polariton launching structures have been programmed into the plasmonic phase-change material In3SbTe2. Here, we leverage this approach to reconfigure HPhPs by programming a variety of launching and confining nanostructures through α-MoO3 flakes deposited onto In3SbTe2. Importantly, optical programming after flake deposition enables alignment of launching stripes to the [001]-axis of the flake, essential to control the directional polariton propagation. We showcase these capabilities in a variety of structures: i) an optically programmed disk, showing similar tuning ranges and confinement as focusing by gold disks; and ii) a cavity for in-plane HPhPs created by reconfiguring the single disk to a double disk structure, tailoring the confinement by simply reprogramming the disk distance. Our fabrication scheme offers fast turn-around times, flexible alignment and the opportunity to reconfigure the structures. Thus, it is a fast, efficient and versatile way to tailor propagation and confinement of highly directional polaritons on demand.

physics.optics↗

arXiv2026

Long-range mid-infrared energy transfer mediated by hyperbolic phonon polaritons

We provide a framework to theoretically describe long-range energy transfer in single and twisted two-dimensional hyperbolic slabs. We demonstrate that phonon polaritons (PhPs, quantum superpositions of photons and lattice vibrations in polar dielectrics) can mediate and enhance room-temperature energy transfer at ranges far exceeding those of conventional mid-infrared (MIR) platforms, and with extreme directionality. This is because the dipole-dipole interaction potential energy diverges along the asymptotes of the real-space hyperbolic opening angle. Our findings allow us to extend classical and quantum interactions between dipoles, typically strictly confined to the near-field, beyond several free-space MIR wavelengths. We use $α$-MoO$_3$ as a representative material, but this mechanism is not limited to the MIR: it is general to anisotropic media across the whole electromagnetic spectrum.

physics.optics↗

arXiv2026

Tailoring phonon-driven responses in α-MoO3 through isotopic enrichment

The implementation of polaritonic materials into nanoscale devices requires selective tuning of parameters to realize desired spectral or thermal responses. One robust material is α-MoO3, which as an orthorhombic crystal boasts three distinct phonon dispersions, providing three polaritonic dispersions of hyperbolic phonon polaritons (HPhPs) across the mid-infrared (MIR). Here, the tunability of both optical and thermal responses in isotopically enriched α-MoO3 (98MoO3, Mo18O3 and 98Mo18O3) are explored. A uniform ~5 % spectral redshift from 18O enrichment is observed in both Raman- and IR-active TO phonons. Both the in- and out-of-plane thermal conductivities for the isotopic variations are reported. Ab initio calculations both replicate experimental findings and analyze the select-mode three-phonon scattering contributions. The HPhPs from each isotopic variation are probed with s-SNOM and their Q- factors are reported. A Q-factor maxima increase of ~50 % along the [100] in the RB2 and ~100 % along the [001] in the RB3 are reported for HPhPs supported in 98Mo18O3. Observations in both real and Fourier space of higher-order HPhP modes propagating in single slabs of isotopically enriched α-MoO3 without the use of a subdiffractional surface scatterer are presented here. This work illustrates the tunability of α-MoO3 for thermal and nanophotonic applications.

cond-mat.mtrl-sci↗

arXiv2025

Directional strong coupling at the nanoscale between hyperbolic polaritons and organic molecules

Strong coupling (SC) is a fundamental concept in physics that describes extreme interactions between light and matter. Recent experiments have demonstrated SC at the nanometer scale, where strongly confined polaritons, rather than photons, couple to quantum emitters or molecular vibrations. Coupling with the latter is generally referred to as vibrational SC (VSC) and is of significant fundamental and technological interest, as it can be an effective tool for modifying molecular properties. However, the implementation of VSC, especially at the nanoscale, depends on the development of tuning mechanisms that allow control over the coupling strength and, eventually, its directionality, opening the door for the selective coupling of specific molecular vibrations. Here we report the observation of directional VSC. Specifically, we show nanoscale images of propagating hyperbolic phonon polaritons (PhPs) coupled to pentacene molecules revealing that the fingerprint of VSC for propagating polaritons -- a marked anti-crossing in their dispersion at the vibrational resonance -- can be modulated as a function of the direction of propagation. In addition, we show that VSC can exhibit an optimal condition for thin molecular layers, characterized by a maximum coupling strength along one single direction. This phenomenon is understood by analysing the overlap of the polariton field with molecular layers of varying thicknesses. Apart from their fundamental importance, our findings promise novel applications for directional sensing or local directional control of chemical properties at the nanoscale.

cond-mat.mtrl-sci↗

arXiv2025

Modulating Low-Power Threshold Optical Bistability by Electrically Reconfigurable Free-Electron Kerr Nonlinearity

We propose a microscopic mechanism to electrically reconfigure the Kerr nonlinearity by modulating the concentration of free electrons in heavily doped semiconductors under a static bias. Our theory incorporates electrostatic and hydrodynamic frameworks to describe the electronic dynamics, demonstrating electrically tunable linear and nonlinear modulations. The power threshold of achieving optical bistability shows unprecedented tunability over two orders of magnitude, reaching values as low as 10 $μ$W through surface charge control. These findings offer new insights into understanding and actively controlling Kerr nonlinearities, paving the way for efficient refractive index engineering as well as the development of advanced linear and nonlinear electro-optical modulators.

physics.optics↗

arXiv2025

Misalignment between the Directions of Propagation and Decay of Nanoscale-confined Polaritons

Anisotropic van der Waals crystals have gained significant attention in nanooptics and optoelectronics due to their unconventional optical properties, including anomalous reflection, canalization, and nanofocusing. Polaritons -- light coupled to matter excitations -- govern these effects, with their complex wavevector encoding key parameters such as wavelength, lifetime, field confinement, and propagation direction. However, determining the complex wavevector, particularly the misalignment between its real and imaginary parts, has remained a challenge due to the complexity of the dispersion relation. Here, using near-field nanoimaging, we introduce a self-consistent method to extract the complex wavevector from polaritonic near-field images. We experimentally reveal a strong misalignment between the real and imaginary components of the wavevector, significantly impacting the interpretation of near-field experiments. Our findings establish a new paradigm for optical nanoimaging, providing a robust framework for accurately extracting polariton parameters and advancing the broader field of nanooptics of lossy anisotropic crystals.

physics.optics↗

arXiv2025

Roadmap for Photonics with 2D Materials

Triggered by the development of exfoliation and the identification of a wide range of extraordinary physical properties in self-standing films consisting of one or few atomic layers, two-dimensional (2D) materials such as graphene, transition metal dichalcogenides (TMDs), and other van der Waals (vdW) crystals currently constitute a wide research field protruding in multiple directions in combination with layer stacking and twisting, nanofabrication, surface-science methods, and integration into nanostructured environments. Photonics encompasses a multidisciplinary collection of those directions, where 2D materials contribute with polaritons of unique characteristics such as strong spatial confinement, large optical-field enhancement, long lifetimes, high sensitivity to external stimuli (e.g., electric and magnetic fields, heating, and strain), a broad spectral range from the far infrared to the ultraviolet, and hybridization with spin and momentum textures of electronic band structures. The explosion of photonics with 2D materials as a vibrant research area is producing breakthroughs, including the discovery and design of new materials and metasurfaces with unprecedented properties as well as applications in integrated photonics, light emission, optical sensing, and exciting prospects for applications in quantum information, and nanoscale thermal transport. This Roadmap summarizes the state of the art in the field, identifies challenges and opportunities, and discusses future goals and how to meet them through a wide collection of topical sections prepared by leading practitioners.

cond-mat.mtrl-sci↗

arXiv2025

Ultrahigh free-electron Kerr nonlinearity in all-semiconductor waveguides for all-optical nonlinear modulation of mid-infrared light

Nonlinear optical waveguides, particularly those harnessing the optical Kerr effect, are promising for advancing next-generation photonic technologies. Despite the Kerr effect`s ultrafast response, its inherently weak nonlinearity has hindered practical applications. Here, we explore free-electron-induced Kerr nonlinearities in all-semiconductor waveguides, revealing that longitudinal bulk plasmons (inherently nonlocal excitations) can generate exceptionally strong Kerr nonlinearities. We specifically develop a nonlinear eigenmode analysis integrated with semiclassical hydrodynamic theory to compute the linear and nonlinear optical responses originating from the quantum behavior of free electrons in heavily doped semiconductors. These waveguides achieve ultrahigh nonlinear coefficients exceeding 10$^7$ W$^{-1}$km$^{-1}$ and support long-propagating modes with propagation distances over 100 $μ$m. Additionally, we confirm the robustness of the nonlinear response under realistic conditions by considering viscoelastic and nonlinear damping mechanisms. Finally, we implement our all-semiconductor waveguides in a Mach-Zehnder interferometer, demonstrating efficient nonlinear modulation of the transmittance spectrum via the free-electron Kerr effect. This work evidences the transformative potential of free-electron nonlinearities in heavily doped semiconductors for photonic integrated circuits, paving the way for scalable on-chip nonlinear nanophotonic systems.

physics.optics↗

arXiv2025

Broad Spectral Tuning of Ultra-Low Loss Polaritons in a van der Waals Crystal by Intercalation

Phonon polaritons (PhPs) -- light coupled to lattice vibrations -- in polar van der Waals (vdW) crystals are promising candidates for controlling the flow of energy at the nanoscale due to their strong field confinement, anisotropic propagation, and ultra-long lifetime in the picosecond range \cite{ref1,ref2,ref3,ref4,ref5}. However, the lack of tunability in their narrow and material-specific spectral range -- the Reststrahlen Band (RB) -- severely limits their technological implementation. Here, we demonstrate that the intercalation of Na atoms in the vdW semiconductor $α$-V$_2$O$_5$ enables a broad spectral shift of RBs, and that the PhPs excited exhibit ultra-low losses (lifetime of $4 \pm 1$~ps), similar to PhPs in the non-intercalated crystal (lifetime of $6 \pm 1$ ps). We expect our intercalation method to be applicable to other vdW crystals, opening the door for the use of PhPs in broad spectral bands in the mid-infrared domain.

physics.optics↗

arXiv2024

Unveiling the Mechanism of Phonon-Polariton Damping in α-MoO_3

Phonon polaritons (PhPs) (light coupled to lattice vibrations) in the highly anisotropic polar layered material molybdenum trioxide (α-MoO_3) are currently the focus of intense research efforts due to their extreme subwavelength field confinement, directional propagation and unprecedented low losses. Nevertheless, prior research has primarily concentrated on exploiting the squeezing and steering capabilities of α-MoO_3 PhPs, without inquiring much into the dominant microscopic mechanism that determines their long lifetimes, key for their implementation in nanophotonic applications. This study delves into the fundamental processes that govern PhP damping in α-MoO_3 by combining ab initio calculations with scattering-type scanning near-field optical microscopy (s-SNOM) and Fourier-transform infrared (FTIR) spectroscopy measurements across a broad temperature range (from 8 to 300 K). The remarkable agreement between our theoretical predictions and experimental observations allows us to identify third-order anharmonic phonon-phonon scattering as the main damping mechanism of α-MoO_3 PhPs. These findings shed light on the fundamental limits of low-loss PhPs, a crucial factor for assessing their implementation into nanophotonic devices.

cond-mat.mtrl-sci↗

arXiv2024

Low-power threshold optical bistability enabled by hydrodynamic Kerr nonlinearity of free-carriers in heavily doped semiconductors

We demonstrate nanoscale optical bistability at an exceptionally low power threshold of 1 mW by leveraging Kerr-type hydrodynamic nonlinearities due to the heavily doped semiconductor's free carriers. This high nonlinearity is enabled by a strong coupling between metallic nanopatch surface plasmons and longitudinal bulk plasmons (LBP) that arise in heavily doped semiconductors due to the nonlocality. Through the coupling, an efficient, near-unity conversion of far-field energy into LBP states could be achieved. These findings offer a viable approach to experimentally probe LBPs and lay the groundwork for developing efficient and ultrafast all-optical nonlinear devices.

physics.optics↗

arXiv2024

Canalization-based super-resolution imaging using a single van der Waals layer

Canalization is an optical phenomenon that enables unidirectional propagation of light in a natural way, i.e., without the need for predefined waveguiding designs. Predicted years ago, it was recently demonstrated using highly confined phonon polaritons (PhPs) in twisted layers of the van der Waals (vdW) crystal alpha-MoO3, offering unprecedented possibilities for controlling light-matter interactions at the nanoscale. However, despite this finding, applications based on polariton canalization have remained elusive so far, which can be explained by the complex sample fabrication of twisted stacks. In this work, we introduce a novel canalization phenomenon, arising in a single vdW thin layer (alpha-MoO3) when it is interfaced with a substrate exhibiting a given negative permittivity, that allows us to demonstrate a proof-of-concept application based on polariton canalization: super-resolution (up to ~λ0/220) nanoimaging. Importantly, we find that canalization-based imaging transcends conventional projection constraints, allowing the super-resolution images to be obtained at any desired location in the image plane. This versatility stems from the synergetic manipulation of three distinct parameters: incident frequency, rotation angle of the thin vdW layer, and thickness. These results provide valuable insights into the fundamental properties of canalization and constitute a seminal step towards multifaceted photonic applications, encompassing imaging, data transmission, and ultra-compact photonic integration.

physics.optics↗

arXiv2023

Fundamentals of polaritons in strongly anisotropic thin crystal layers

Polaritons in strongly anisotropic thin layers have recently captured the attention in nanophotonics because of their directional propagation at the nanoscale, which offers unique possibilities for nanooptical applications. However, exploiting the full potential of anisotropic polaritons requires a thorough understanding of their properties, including field confinement, energy and phase propagation direction and losses. Here we fill this critical gap by providing fundamental insights into the propagation of anisotropic polaritons in thin biaxial layers. In particular, we introduce a novel methodology that allows us to represent isofrequency curves of polaritons in strongly anisotropic materials considering that the real and imaginary parts of the wavevector are not parallel. In fact, we analytically show that the direction of the imaginary part of the wavevector is parallel to the group velocity, which can have different, even perpendicular or opposite, directions with respect to the phase velocity. This finding is crucial for understanding polaritonic phenomena in anisotropic media, yet it has so far been widely overlooked in the literature. Additionally, we introduce a criterion for classifying the polaritonic modes in biaxial layers into volume and surface categories, and analyze their dispersion, field structure, and losses. Finally, we discover the existence of anisotropic transverse electric modes, which can exhibit natural canalization. Taken together, our results shed light on hitherto unexplored areas of the theory of electromagnetic modes in thin biaxial layers. Although exemplified for van der Waals MoO3 layers, our findings are general for polaritons in other strongly anisotropic biaxial hyperbolic crystals.

physics.optics↗

arXiv2023

Terahertz Twistoptics -- engineering canalized phonon polaritons

The terahertz (THz) frequency range is key to study collective excitations in many crystals and organic molecules. However, due to the large wavelength of THz radiation, the local probing of these excitations in smaller crystalline structures or few-molecular arrangements, requires sophisticated methods to confine THz light down to the nanometer length scale, as well as to manipulate such a confined radiation. For this purpose, in recent years, taking advantage of hyperbolic phonon polaritons (HPhP) in highly anisotropic van der Waals (vdW) materials has emerged as a promising approach, offering a multitude of manipulation options such as control over the wavefront shape and propagation direction. Here, we demonstrate the first THz application of twist-angle-induced HPhP manipulation, designing the propagation of confined THz radiation between 8.39 and 8.98 THz in the vdW material alpha-molybdenum trioxide ($α-MoO_{3}$), hence extending twistoptics to this intriguing frequency range. Our images, recorded by near-field optical microscopy, show the frequency- and twist-angle-dependent change between hyperbolic and elliptic polariton propagation, revealing a polaritonic transition at THz frequencies. As a result, we are able to allocate canalization (highly collimated propagation) of confined THz radiation by carefully adjusting these two parameters, i.e. frequency and twist angle. Specifically, we report polariton canalization in $α-MoO_{3}$ at 8.67 THz for a twist angle of 50°. Our results demonstrate an unprecedented control and the manipulation of highly-confined collective excitations at THz frequencies, offering novel possibilities for nanophotonic applications.

physics.optics↗

arXiv2021

Germanium monosulfide as a natural platform for highly anisotropic THz polaritons

Terahertz (THz) electromagnetic radiation is key to optically access collective excitations such as magnons (spins), plasmons (electrons), or phonons (atomic vibrations), thus bridging between optics and solid-state physics. Confinement of THz light to the nanometer length scale is desirable for local probing of such excitations in low dimensional systems, thereby inherently circumventing the large footprint and low spectral density of far-field THz optics. For that purpose, phonon polaritons (PhPs, i.e., light coupled to lattice vibrations in polar crystals) in anisotropic van der Waals (vdW) materials have recently emerged as a promising platform for THz nanooptics; yet the amount of explored, viable materials is still exiguous. Hence, there is a demand for the exploration of novel materials that feature not only THz PhPs at different spectral regimes, but also exhibit unique anisotropic (directional) electrical, thermoelectric, and vibronic properties. To that end, we introduce here the semiconducting alpha-germanium(II) sulfide (GeS) as an intriguing candidate. By employing THz nano-spectroscopy supported by theoretical analysis, we provide a thorough characterization of the different in-plane hyperbolic and elliptical PhP modes in GeS. We find not only PhPs with long life times ($τ$ > 2 ps) and excellent THz light confinement ($λ_0/λ$ > 45), but also an intrinsic, phonon-induced anomalous dispersion as well as signatures of naturally occurring PhP canalization within one single GeS slab.

physics.optics↗