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Gonzalo Manzano

Publications and source records attributed to Gonzalo Manzano.

At least 37 records · Page 2Linked to original sources

Quantum thermodynamics under continuous monitoring: a general framework

The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. Here we provide an introduction to the general theoretical framework to establish and interpret thermodynamics for quantum systems whose nonequilibrium evolution is continuously monitored. We review the formalism of quantum trajectories and its consistent application to the thermodynamic scenario, where main quantities such as work, heat, and entropy production can be defined at the stochastic level. The connection to irreversibility and fluctuation theorems is also discussed, together with some recent developments, and we provide some simple examples to illustrate the general theoretical framework.

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Collective effects on the performance and stability of quantum heat engines

Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study from both a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is its performance, but, additionally, its constancy, i.e. the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency and constancy scale with the number of spins composing the engine and introduce a well-defined macroscopic limit where analytical expressions are obtained. Our results predict power enhancements, both in finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, accompanied by coherence-enhanced constancy for finite sizes. We discuss these quantities in connection to Thermodynamic Uncertainty Relations (TUR).

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Inferring work by quantum superposing forward and time-reversal evolutions

The study of thermodynamic fluctuations allows one to relate the free energy difference between two equilibrium states with the work done on a system through processes far from equilibrium. This finding plays a crucial role in the quantum regime, where the definition of work becomes non-trivial. Based on these relations, here we develop a simple interferometric method allowing a direct estimation of the work distribution and the average dissipative work during a driven thermodynamic process by superposing the forward and time-reversal evolutions of the process. We show that our scheme provides useful upper bounds on the average dissipative work even without full control over the thermodynamic process, and we propose methodological variations depending on the possible experimental limitations encountered. Finally, we exemplify its applicability by an experimental proposal for implementing our method on a quantum photonics system, on which the thermodynamic process is performed through polarization rotations induced by liquid crystals acting in a discrete temporal regime.

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Survival and extreme statistics of work, heat, and entropy production in steady-state heat engines

We derive universal bounds for the finite-time survival probability of the stochastic work extracted in steady-state heat engines and the stochastic heat dissipated to the environment. We also find estimates for the time-dependent thresholds that these quantities does not surpass with a prescribed probability. At long times, the tightest thresholds are proportional to the large deviation functions of stochastic entropy production. Our results entail an extension of martingale theory for entropy production, for which we derive universal inequalities involving its maximum and minimum statistics that are valid for generic Markovian dynamics in non-equilibrium stationary states. We test our main results with numerical simulations of a stochastic photoelectric device.

cond-mat.stat-mech↗

Non-Abelian Quantum Transport and Thermosqueezing Effects

Modern quantum experiments provide examples of transport with non-commuting quantities, offering a tool to understand the interplay between thermal and quantum effects. Here we set forth a theory for non-Abelian transport in the linear response regime. Our key insight is to use generalized Gibbs ensembles with non-commuting charges as the basic building blocks and strict charge-preserving unitaries in a collisional setup. The linear response framework is then built using a collisional model between two reservoirs. We show that the transport coefficients obey Onsager reciprocity. Moreover, we find that quantum coherence, associated to the non-commutativity, acts so as to reduce the net entropy production, when compared to the case of commuting transport. This therefore provides a clear connection between quantum coherent transport and dissipation. As an example, we study heat and squeezing fluxes in bosonic systems, characterizing a set of thermosqueezing coefficients with potential applications in metrology and heat-to-work conversion in the quantum regime.

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Quantum superposition of thermodynamic evolutions with opposing time's arrows

Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the "forward" temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its "time-reversal" counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time's arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Remarkably, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.

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Comment on "Steady-State Coherences by Composite System-Bath Interactions"

In a recent Letter, Guarnieri et al. [1] reported on the possibility of generating steady-state coherence (SSC) in the energy basis of a two-level system by the sole action of a single thermal bath also for weak system-bath coupling and due to a composite form of this interaction. The results are based on a time-local Bloch-Redfield master equation without secular approximation and the associated set of Bloch equations, all derived in the Supplemental Material (SM) of Ref. [1]. We comment that the results reported by the authors present both technical flaws and conceptual limitations that substantially impact some of their main conclusions. Our objections mainly concern (a) technical errors in the calculation of SSC (Eqs.(2)-(4) in [1]) and (b) negativity issues associated with the weak-coupling master equation employed by the authors.

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Optimizing autonomous thermal machines powered by energetic coherence

The characterization and control of quantum effects in the performance of thermodynamic tasks may open new avenues for small thermal machines working in the nanoscale. We study the impact of coherence in the energy basis in the operation of a small thermal machine which can act either as a heat engine or as a refrigerator. We show that input coherence may enhance the machine performance and allow it to operate in otherwise forbidden regimes. Moreover, our results also indicate that, in some cases, coherence may also be detrimental, rendering optimization of particular models a crucial task for benefiting from coherence-induced enhancements.

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Thermodynamics of Gambling Demons

We introduce and realize demons that follow a customary gambling strategy to stop a nonequilibrium process at stochastic times. We derive second-law-like inequalities for the average work done in the presence of gambling, and universal stopping-time fluctuation relations for classical and quantum non-stationary stochastic processes. We test experimentally our results in a single-electron box, where an electrostatic potential drives the dynamics of individual electrons tunneling into a metallic island. We also discuss the role of coherence in gambling demons measuring quantum jump trajectories.

cond-mat.stat-mech↗

Hybrid Thermal Machines: Generalized Thermodynamic Resources for Multitasking

Thermal machines perform useful tasks--such as producing work, cooling, or heating--by exchanging energy, and possibly additional conserved quantities such as particles, with reservoirs. Here we consider thermal machines that perform more than one useful task simultaneously, terming these "hybrid thermal machines". We outline their restrictions imposed by the laws of thermodynamics and we quantify their performance in terms of efficiencies. To illustrate their full potential, reservoirs that feature multiple conserved quantities, described by generalized Gibbs ensembles, are considered. A minimal model for a hybrid thermal machine is introduced, featuring three reservoirs and two conserved quantities, e.g., energy and particle number. This model can be readily implemented in a thermoelectric setup based on quantum dots, and hybrid regimes are accessible considering realistic parameters.

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Synchronization along quantum trajectories

We employ a quantum trajectory approach to characterize synchronization and phase-locking between open quantum systems in nonequilibrium steady states. We exemplify our proposal for the paradigmatic case of two quantum Van der Pol oscillators interacting through dissipative coupling. We show the deep impact of synchronization on the statistics of phase-locking indicators and other correlation measures defined for single trajectories, spotting a link between the presence of synchronization and the emergence of large tails in the probability distribution for the entanglement along trajectories. Our results shed new light on fundamental issues regarding quantum synchronization providing new methods for its precise quantification.

quant-ph↗

Boosting the performance of small autonomous refrigerators via common environmental effects

We explore the possibility of enhancing the performance of small thermal machines by the presence of common noise sources. In particular, we study a prototypical model for an autonomous quantum refrigerator comprised by three qubits coupled to thermal reservoirs at different temperatures. Our results show that engineering the coupling to the reservoirs to act as common environments lead to relevant improvements in the performance. The enhancements arrive to almost double the cooling power of the original fridge without compromising its efficiency. The greater enhancements are obtained when the refrigerator may benefit from the presence of a decoherence-free subspace. The influence of coherent effects in the dissipation due to one- and two-spin correlated processes is also examined by comparison with an equivalent incoherent yet correlated model of dissipation.

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Work estimation and work fluctuations in the presence of non-ideal measurements

From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in non-equilibrium processes and for the fundamental structure of the work fluctuations when one assumes that the measurements are non-ideal. We show that obtaining work estimates and their statistical moments at finite work cost implies an imperfection of the estimates themselves: more accurate estimates incur higher costs. Our results provide a qualitative relation between the cost of obtaining information about work and the trustworthiness of this information. Moreover, we show that Jarzynski's equality can be maintained exactly at the expense of a correction that depends only on the system's energy scale, while the more general fluctuation relation due to Crooks no longer holds when the cost of the work estimation procedure is finite. We show that precise links between dissipation and irreversibility can be extended to the non-ideal situation.

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Quantum Martingale Theory and Entropy Production

We develop a martingale theory to describe fluctuations of entropy production for open quantum systems in nonequilbrium steady states. Using the formalism of quantum jump trajectories, we identify a decomposition of entropy production into an exponential martingale and a purely quantum term, both obeying integral fluctuation theorems. An important consequence of this approach is the derivation of a set of genuine universal results for stopping-time and infimum statistics of stochastic entropy production. Finally we complement the general formalism with numerical simulations of a qubit system.

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Autonomous thermal machine for amplification and control of energetic coherence

We present a model for an autonomous quantum thermal machine comprised of two qubits capable of manipulating and even amplifying the local coherence in a non-degenerate external system. The machine uses only thermal resources, namely, contact with two heat baths at different temperatures, and the external system has a non-zero initial amount of coherence. The method we propose allows for an interconversion between energy, both work and heat, and coherence in an autonomous configuration working in out-of-equilibrium conditions. This model raises interesting questions about the role of fundamental limitations on transformations involving coherence and opens up new possibilities in the manipulation of coherence by autonomous thermal machines.

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The squeezed thermal reservoir as a generalized equilibrium reservoir

We explore the perspective of considering the squeezed thermal reservoir as an equilibrium reservoir in a generalized Gibbs ensemble with two non-commuting conserved quantities. We outline the main properties of such a reservoir in terms of the exchange of energy, both heat and work, and entropy, giving some key examples to clarify its physical interpretation. This new paradigm allows for a correct and insightful interpretation of all thermodynamical features of the squeezed thermal reservoir, as well as other similar non-thermal reservoirs, including the characterization of reversibility and the first and second laws of thermodynamics.

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Optimal work extraction and thermodynamics of quantum measurements and correlations

We analyze the role of indirect quantum measurements in work extraction from quantum systems in nonequilibrium states. In particular, we focus on the work that can be obtained by exploiting the correlations shared between the system of interest and an additional ancilla, where measurement backaction introduces a nontrivial thermodynamic tradeoff. We present optimal state-dependent protocols for extracting work from both classical and quantum correlations, the latter being measured by discord. We show that, while the work content of classical correlations can be fully extracted by performing local operations on the system of interest, the amount of work related to quantum discord requires a specific driving protocol that includes interaction between system and ancilla.

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Quantum fluctuation theorems for arbitrary environments: adiabatic and non-adiabatic entropy production

We analyze the production of entropy along non-equilibrium processes in quantum systems coupled to generic environments. First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation theorem in detailed and integral forms. Second, we discuss the decomposition of the entropy production into two positive contributions, adiabatic and non-adiabatic, based on the existence of invariant states of the local dynamics. Fluctuation theorems for both contributions hold only for evolutions verifying a specific condition of quantum origin. We illustrate our results with three relevant examples of quantum thermodynamic processes far from equilibrium.

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