arXiv subjects

Grzegorz Szamel

Publications and source records attributed to Grzegorz Szamel.

At least 37 records · Page 2Linked to original sources

arXiv2022

Single active particle in a harmonic potential: non-existence of the Jarzynski relation

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the exponential average of work done in an arbitrary process connecting two equilibrium states with the difference of the free energies of these states. Using a simple model system, a single thermal active Ornstein-Uhlenbeck particle in a harmonic potential, we show that if the standard stochastic thermodynamics definition of work is used, the Jarzynski relation is not generally valid for processes between stationary states of active matter systems.

cond-mat.stat-mech↗

arXiv2022

Scaling of the Non-Phononic Spectrum of Two-Dimensional Glasses

Low-frequency vibrational harmonic modes of glasses are frequently used to understand their universal low-temperature properties. One well studied feature is the excess low-frequency density of states over the Debye model prediction. Here we examine the system size dependence of the density of states for two-dimensional glasses. For systems of fewer than 100 particles, the density of states scales with the system size as if all the modes were plane-wave-like. However, for systems greater than 100 particles we find a different system-size scaling of the cumulative density of states below the first transverse sound mode frequency, which can be derived from the assumption that these modes are quasi-localized. Moreover, for systems greater than 100 particles, we find that the cumulative density of states scales with frequency as a power law with the exponent that leads to the exponent $β=3.5$ for the density of states independent of system size.

cond-mat.dis-nn↗

arXiv2022

Scaling of the Non-Phononic Spectrum of Two-Dimensional Glasses

The scaling of the non-phononic spectrum for 2D systems has been recently debated. Here we provide evidence that the non-phononic spectrum $D_{ex}(ω) \sim ω^β$ where $β\approx 3.5$ and there is no clear evidence of a finite size effect in beta for systems greater than 100 particles.

cond-mat.dis-nn↗

arXiv2022

An alternative, dynamic density functional-like theory for time-dependent density fluctuations in glass-forming fluids

We propose an alternative theory for the relaxation of density fluctuations in glass-forming fluids. We derive an equation of motion for the density correlation function which is local in time and is similar in spirit to the equation of motion for the average non-uniform density profile derived within the dynamic density functional theory. We identify the Franz-Parisi free energy functional as the non-equilibrium free energy for the evolution of the density correlation function. An appearance of a local minimum of this functional leads to a dynamic arrest. Thus, the ergodicity breaking transition predicted by our theory coincides with the dynamic transition of the static approach based on the same non-equilibrium free energy functional.

cond-mat.soft↗

arXiv2022

Microscopic analysis of sound attenuation in low-temperature amorphous solids reveals quantitative importance of non-affine effects

Sound attenuation in low temperature amorphous solids originates from their disordered structure. However, its detailed mechanism is still being debated. Here we analyze sound attenuation starting directly from the microscopic equations of motion. We derive an exact expression for the zero-temperature sound damping coefficient. We verify that the sound damping coefficients calculated from our expression agree very well with results from independent simulations of sound attenuation. The small wavevector analysis of our expression shows that sound attenuation is primarily determined by the non-affine displacements' contribution to the sound wave propagation coefficient coming from the frequency shell of the sound wave. Our expression involves only quantities that pertain to solids' static configurations. It can be used to evaluate the low temperature sound damping coefficients without directly simulating sound attenuation.

cond-mat.dis-nn↗

arXiv2021

On the Dynamics of Liquids in the Large-Dimensional Limit

In this work, we analytically derive the exact closed dynamical equations for a liquid with short-ranged interactions in large spatial dimensions using the same statistical mechanics tools employed to analyze Brownian motion. Our derivation greatly simplifies the original path-integral-based route to these equations and provides new insight into the physical features associated with high-dimensional liquids and glass formation. Most importantly, our construction provides a facile route to the exact dynamical analysis of important related dynamical problems, as well as a means to devise cluster generalizations of the exact solution in infinite dimensions. This latter fact opens the door to the construction of increasingly accurate theories of vitrification in three-dimensional liquids.

cond-mat.stat-mech↗

arXiv2021

Low-frequency excess vibrational modes in two-dimensional glasses

Glasses possess more low-frequency vibrational modes than predicted by Debye theory. These excess modes are crucial for the understanding the low temperature thermal and mechanical properties of glasses, which differ from those of crystalline solids. Recent simulational studies suggest that the density of the excess modes scales with their frequency $ω$ as $ω^4$ in two and higher dimensions. Here, we present extensive numerical studies of two-dimensional model glass formers over a large range of glass stabilities. We find that the density of the excess modes follows $D_\text{exc}(ω)\sim ω^2 $ up to around the boson peak, regardless of the glass stability. The stability dependence of the overall scale of $D_\text{exc}(ω)$ correlates with the stability dependence of low-frequency sound attenuation. However, we also find that in small systems, where the first sound mode is pushed to higher frequencies, at frequencies below the first sound mode there are excess modes with a system size independent density of states that scales as $ω^3$.

cond-mat.dis-nn↗

arXiv2021

Interplay between percolation and glassiness in the random Lorentz gas

The random Lorentz gas (RLG) is a minimal model of transport in heterogeneous media. It also models the dynamics of a tracer in a glassy system. These two perspectives, however, are fundamentally inconsistent. Arrest in the former is related to percolation, and hence continuous, while glass-like arrest is discontinuous. In order to clarify the interplay between percolation and glassiness in the RLG, we consider its exact solution in the infinite-dimensional $d\rightarrow\infty$ limit, as well as numerics in $d=2\ldots 20$. We find that the mean field solutions of the RLG and glasses fall in the same universality class, and that instantonic corrections related to rare cage escapes destroy the glass transition in finite dimensions. This advance suggests that the RLG can be used as a toy model to develop a first-principle description of hopping in structural glasses.

cond-mat.stat-mech↗

arXiv2021

Mean-field caging in a random Lorentz gas

The random Lorentz gas (RLG) is a minimal model of both percolation and glassiness, which leads to a paradox in the infinite-dimensional, $d\rightarrow\infty$ limit: the localization transition is then expected to be continuous for the former and discontinuous for the latter. As a putative resolution, we have recently suggested that as $d$ increases the behavior of the RLG converges to the glassy description, and that percolation physics is recovered thanks to finite-$d$ perturbative and non-perturbative (instantonic) corrections [Biroli et al. arXiv:2003.11179]. Here, we expand on the $d\rightarrow\infty$ physics by considering a simpler static solution as well as the dynamical solution of the RLG. Comparing the $1/d$ correction of this solution with numerical results reveals that even perturbative corrections fall out of reach of existing theoretical descriptions. Comparing the dynamical solution with the mode-coupling theory (MCT) results further reveals that although key quantitative features of MCT are far off the mark, it does properly capture the discontinuous nature of the $d\rightarrow\infty$ RLG. These insights help chart a path toward a complete description of finite-dimensional glasses.

cond-mat.dis-nn↗

arXiv2021

Tagged active particle: probability distribution in a slowly varying external potential is determined by effective temperature obtained from the Einstein relation

We derive a distribution function for the position of a tagged active particle in a slowly varying in space external potential, in a system of interacting active particles. The tagged particle distribution has the form of the Boltzmann distribution but with an effective temperature that replaces the temperature of the heat bath. We show that the effective temperature that enters the tagged particle distribution is the same as the effective temperature defined through the Einstein relation, i.e. it is equal to the ratio of the self-diffusion and tagged particle mobility coefficients. This shows that this effective temperature, which is defined through a fluctuation-dissipation ratio, is relevant beyond the linear response regime. We verify our theoretical findings through computer simulations. Our theory fails when an additional large length scale appears in our active system. This length scale is associated with long-wavelength density fluctuations that emerge upon approaching motility-induced phase separation.

cond-mat.soft↗

arXiv2021

Long-ranged velocity correlations in dense systems of self-propelled particles

Model systems of self-propelled particles reproduce many phenomena observed in laboratory active matter systems that defy our thermal equilibrium-based intuition. In particular, in stationary states of self-propelled systems, it is recognized that velocities of different particles exhibit non-trivial equal-time correlations. Such correlations are absent in equivalent equilibrium systems. Recently, researchers found that the range of the velocity correlations increases with increasing persistence time of the self-propulsion and can extend over many particle diameters. Here we review the initial studies of long-ranged velocity correlations in solid-like systems of self-propelled particles. Then, we demonstrate that the long-ranged velocity correlations are also present in dense fluid-like systems. We show that the range of velocity correlations in dense systems of self-propelled particles is determined by the combination of the self-propulsion and the virial bulk modulus that originates from repulsive interparticle interactions.

cond-mat.soft↗

arXiv2020

Single active particle engine utilizing a non-reciprocal coupling between particle's position and self-propulsion

We recently argued that a self-propelled particle is formally equivalent to a system consisting of two subsystems coupled by a non-reciprocal interaction [Phys. Rev. E 100, 050603(R) (2019)]. Here we show that this non-reciprocal coupling allows to extract useful work from a single self-propelled particle maintained at constant temperature, by using an aligning interaction to influence correlations between the particle's position and self-propulsion.

cond-mat.soft↗

arXiv2020

Active matter: quantifying the departure from equilibrium

Active matter systems are driven out of equilibrium at the level of individual constituents. One widely studied class are systems of athermal particles that move under the combined influence of interparticle interactions and self-propulsions, with the latter evolving according to the Ornstein-Uhlenbeck stochastic process. Intuitively, these so-called active Ornstein-Uhlenbeck particles (AOUPs) systems are farther from equilibrium for longer self-propulsion persistence times. Quantitatively, this is confirmed by the increasing equal-time velocity correlations (which are trivial in equilibrium) and by the increasing violation of the Einstein relation between the self-diffusion and mobility coefficients. In contrast, the entropy production rate, calculated from the ratio of the probabilities of the position space trajectory and its time-reversed counterpart, has a non-monotonic dependence on the persistence time. Thus, it does not properly quantify the departure of AOUPs systems from equilibrium.

cond-mat.soft↗

arXiv2020

Sound attenuation in finite-temperature stable glasses

The temperature dependence of the thermal conductivity of amorphous solids is markedly different from that of their crystalline counterparts, but exhibits universal behaviour. Sound attenuation is believed to be related to this universal behaviour. Recent computer simulations demonstrated that in the harmonic approximation sound attenuation $Γ$ obeys quartic, Rayleigh scattering scaling for small wavevectors $k$ and quadratic scaling for wavevectors above the Ioffe-Regel limit. However, simulations and experiments do not provide a clear picture of what to expect at finite temperatures where anharmonic effects become relevant. Here we study sound attenuation at finite temperatures for model glasses of various stability, from unstable glasses that exhibit rapid aging to glasses whose stability is equal to those created in laboratory experiments. We find several scaling laws depending on the temperature and stability of the glass. First, we find the large wavevector quadratic scaling to be unchanged at all temperatures. Second, we find that at small wavectors $Γ\sim k^{1.5}$ for an aging glass, but $Γ\sim k^2$ when the glass does not age on the timescale of the calculation. For our most stable glass, we find that $Γ\sim k^2$ at small wavevectors, then a crossover to Rayleigh scattering scaling $Γ\sim k^4$, followed by another crossover to the quadratic scaling at large wavevectors. Our computational observation of this quadratic behavior reconciles simulation, theory and experiment, and will advance the understanding of the temperature dependence of thermal conductivity of glasses.

cond-mat.soft↗

arXiv2019

Stochastic thermodynamics for self-propelled particles

We propose a generalization of stochastic thermodynamics to systems of active particles, which move under the combined influence of stochastic internal self-propulsions (activity) and a heat bath. The main idea is to consider joint trajectories of particles' positions and self-propulsions. It is then possible to exploit formal similarity of an active system and a system consisting of two subsystems interacting with different heat reservoirs and coupled by a non-symmetric interaction. The resulting thermodynamic description closely follows the standard stochastic thermodynamics. In particular, total entropy production, $Δs_\text{tot}$, can be decomposed into housekeeping, $Δs_\text{hk}$, and excess, $Δs_\text{ex}$, parts. Both $Δs_\text{tot}$ and $Δs_\text{hk}$ satisfy fluctuation theorems. The average rate of the steady-state housekeeping entropy production can be related to the violation of the fluctuation-dissipation theorem via a Harada-Sasa relation. The excess entropy production enters into a Hatano-Sasa-like relation, which leads to a generalized Clausius inequality involving the change of the system's entropy and the excess entropy production. Interestingly, although the evolution of particles' self-propulsions is free and uncoupled from that of their positions, non-trivial steady-state correlations between these variables lead to the non-zero excess dissipation in the reservoir coupled to the self-propulsions.

cond-mat.soft↗

arXiv2019

Energy Transport in Glasses

The temperature dependence of the thermal conductivity is linked to the nature of the energy transport at a frequency omega, which is quantified by thermal diffusivity d(omega). Here we study d(omega) for a poorly annealed glass and a highly stable glass prepared using the swap Monte Carlo algorithm. To calculate d(omega), we excite wave packets and find that the energy moves diffusively for high frequencies up to a maximum frequency, beyond which the energy stays localized. At intermediate frequencies, we find a linear increase of the square of the width of the wave packet with time, which allows for a robust calculation of d(omega), but the wave packet is no longer well described by a Gaussian as for high frequencies. In this intermediate regime, there is a transition from a nearly frequency independent thermal diffusivity at high frequencies to d(omega) ~ omega^(-4) at low frequencies. For low frequencies the sound waves are responsible for energy transport and the energy moves ballistically. The low frequency behavior can be predicted using sound attenuation coefficients.

cond-mat.soft↗

arXiv2019

Stability dependence of local structural heterogeneities of stable amorphous solids

The universal anomalous vibrational and thermal properties of amorphous solids are believed to be related to the local variations of the elasticity. Recently it has been shown that the vibrational properties are sensitive to the glass's stability. Here we study the stability dependence of the local elastic constants of a simulated glass former over a broad range of stabilities, from a poorly annealed glass to a glass whose stability is comparable to laboratory exceptionally stable vapor deposited glasses. We show that with increasing stability the glass becomes more uniform as evidenced by a smaller variance of local elastic constants. We find that, according to the definition of local elastic moduli used in this work, the local elastic moduli are not spatially correlated.

cond-mat.soft↗

arXiv2019

Sound attenuation in stable glasses

Understanding the difference between universal low-temperature properties of amorphous and crystalline solids requires an explanation of the stronger damping of long-wavelength phonons in amorphous solids. A longstanding sound attenuation scenario, resulting from a combination of experiments, theories, and simulations, leads to a quartic scaling of sound attenuation with the wavevector, which is commonly attributed to Rayleigh scattering of the sound. Modern computer simulations offer conflicting conclusions regarding the validity of this picture. We simulate glasses with an unprecedentedly broad range of stabilities to perform the first microscopic analysis of sound damping in model glass formers across a range of experimentally relevant preparation protocols. We present a convincing evidence that quartic scaling is recovered for small wavevectors irrespective of the glass's stability. With increasing stability, the wavevector where the quartic scaling begins increases by approximately a factor of three and the sound attenuation decreases by over an order of magnitude. Our results uncover an intimate connection between glass stability and sound damping.

cond-mat.soft↗