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Guanghan Cao

Publications and source records attributed to Guanghan Cao.

At least 55 records · Page 3Linked to original sources

Heavy fermion quantum criticality at dilute carrier limit in CeNi$_{2-δ}$(As$_{1-x}$P$_{x}$)$_{2}$

We study the quantum phase transitions in the nickel pnctides, CeNi$_{2-δ}$(As$_{1-x}$P$_{x}$)$_{2}$ ($δ$ $\approx$ 0.07-0.22). This series displays the distinct heavy fermion behavior in the rarely studied parameter regime of dilute carrier limit. We systematically investigate the magnetization, specific heat and electrical transport down to low temperatures. Upon increasing the P-content, the antiferromagnetic order of the Ce-4$f$ moment is suppressed continuously and vanishes at $x_c \sim$ 0.55. At this doping, the temperature dependences of the specific heat and longitudinal resistivity display non-Fermi liquid behavior. Both the residual resistivity $ρ_0$ and the Sommerfeld coefficient $γ_0$ are sharply peaked around $x_c$. When the P-content reaches close to 100\%, we observe a clear low-temperature crossover into the Fermi liquid regime. In contrast to what happens in the parent compound $x$ = 0.0 as a function of pressure, we find a surprising result that the non-Fermi liquid behavior persists over a nonzero range of doping concentration, $x_c<x<0.9$. In this doping range, at the lowest measured temperatures, the temperature dependence of the specific-heat coefficient is logarithmically divergent and that of the electrical resistivity is linear. We discuss the properties of CeNi$_{2-δ}$(As$_{1-x}$P$_{x}$)$_{2}$ in comparison with those of its 1111 counterpart, CeNi(As$_{1-x}$P$_{x}$)O. Our results indicate a non-Fermi liquid phase in the global phase diagram of heavy fermion metals.

cond-mat.str-el↗

Visualization of Magnetic Flux Structure in Phosphorus-Doped EuFe$_2$As$_2$ Single Crystals

Magnetic flux structure on the surface of EuFe$_2$(As$\rm_{1-x}$P$\rm_x$)$_2$ single crystals with nearly optimal phosphorus doping levels $x=0.20$, and $x=0.21$ is studied by low-temperature magnetic force microscopy and decoration with ferromagnetic nanoparticles. The studies are performed in a broad temperature range. It is shown that the single crystal with $x=0.21$ in the temperature range between the critical temperatures $T_{\rm SC}=22$ K and $T_{\rm C}=17.7$ K of the superconducting and ferromagnetic phase transitions, respectively, has the vortex structure of a frozen magnetic flux, typical for type-II superconductors. The magnetic domain structure is observed in the superconducting state below $T_{\rm C}$. The nature of this structure is discussed.

cond-mat.supr-con↗

Correlation between non-centrosymmetry and superconductivity in quasi-one-dimensional compounds A2Cr3As3 (A=K, Rb)

Non-centrosymmetric superconductors, whose crystal structure is absent of inversion symmetry, have recently received special attentions due to the expectation of unconventional pairings and exotic physics associated with such pairings. The newly discovered superconductors A2Cr3As3 (A=K, Rb), featured by the quasi-one dimensional structure with conducting CrAs chains, belongs to such kind of superconductor. In this study, we are the first to report the finding that the superconductivity of A2Cr3As3 (A=K, Rb) has a positive correlation with the extent of non-centrosymmetry. Our in-situ high pressure ac susceptibility and synchrotron x-ray diffraction measurements reveal that the larger bond angle of As-Cr-As in the CrAs chains can be taken as a key factor controlling superconductivity. While the smaller bond angle and the distance between the CrAs chains also affect the superconductivity due to their structural connections with the angle. We find that the larger value of the difference between the larger and samller angles, which is associated with the extent of the non-centrosymmetry of the lattice structure, is in favor of superconductivity. These results are expected to shed a new light on the underlying mechanism of the superconductivity in these Q1D superconductors and also to provide new perspective in understanding other non-centrosymmetric superconductors.

cond-mat.supr-con↗

Role of valence changes and nanoscale atomic displacements in BiS2-based superconductors

Superconductivity within layered crystal structures has attracted sustained interest among condensed matter community, primarily due to their exotic superconducting properties. EuBiS2F is a newly discovered member in the BiS2-based superconducting family, which shows superconductivity at 0.3 K without extrinsic doping. With 50 at.% Ce substitution for Eu, superconductivity is enhanced with Tc increased up to 2.2 K. However, the mechanisms for the Tc enhancement have not yet been elucidated. In this study, the Ce-doping effect on the self-electron-doped superconductor EuBiS2F was investigated by X-ray absorption spectroscopy (XAS). We have established a relationship between Ce-doping and the Tc enhancement in terms of Eu valence changes and nanoscale atomic displacements. The new finding sheds light on the interplay among superconductivity, charge and local structure in BiS2-based superconductors.

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$^{133}$Cs and $^{75}$As NMR investigation of the normal metallic state of the quasi-one-dimensional Cs$_2$Cr$_3$As$_3$

We report $^{133}$Cs NMR and $^{75}$As Nuclear Quadrupole Resonance (NQR) measurements on the normal metallic state above $T_c$ of a quasi-one-dimensional superconductor Cs$_2$Cr$_3$As$_3$ ($T_c < 1.6$~K). From the $^{133}$Cs NMR Knight shift $^{133}K$ measured at the Cs1 site, we show that the uniform spin susceptibility $χ_{spin}$ increases from 295~K to $\sim$ 60~K, followed by a mild suppression; $χ_{spin}$ then levels off below $\sim$10~K. In contrast, a vanishingly small magnitude of $^{133}K$ indicates that Cs2 sites contribute very little to electrical conduction and the exchange interactions between 3d electrons at Cr sites. Low frequency Cr spin dynamics, reflected on $^{75}$As $1/T_1T$ (the nuclear spin-lattice relaxation rate $1/T_1$ divided by temperature $T$), shows an analogous trend as $χ_{spin}$. Comparison with the results of $1/T_1T$ near $T_c$ with Rb$_2$Cr$_3$As$_3$ ($T_c=6.1$~K) and Rb$_2$Cr$_3$As$_3$ ($T_c=4.8$~K) establishes a systematic trend that substitution of K$^{+}$ ions with larger alkali ions progressively suppresses Cr spin fluctuations together with $T_c$.

cond-mat.supr-con↗

Reversible tuning of superconductivity in pressurized qausi-one-dimensional A2Cr3As3 (A=K and Rb)

In-situ hydrostatic and uniaxial high pressure studies were performed on recently discovered CrAs-based qausi-one-dimensional superconductors A2Cr3As3 (A=K and Rb). The established Pressure-Temperature phase diagram in this study clearly demonstrates that either hydrostatic pressure or uniaxial pressure globally suppresses the superconducting transition temperature (Tc), and the latter is more effective than the former. Interestingly, in the same hydrostatic pressure environment, the suppressing rate of Tc in Rb2Cr3As3 is nearly twice as that of K2Cr3As3. Significantly, the reduced Tc in these superconductors can fully recover to its ambient-pressure value after the applied pressure is entirely released. Our results suggest that the bonding distance and angle between Cr-Cr in the Cr3As3 chains are the key factor in determining Tc and that the optimal lattice for superconductivity is hosted in the pristine K2Cr3As3.

cond-mat.supr-con↗

Electronic structure of quasi-one-dimensional superconductor K$_2$Cr$_3$As$_3$ from first-principles calculations

The electronic structure of quasi-one-dimensional superconductor K$_2$Cr$_3$As$_3$ is studied through systematic first-principles calculations. The ground state of K$_2$Cr$_3$As$_3$ is paramagnetic but very close to a ferromagnetic instability. Close to the Fermi level, the Cr-3d$_{z^2}$, d$_{xy}$, and d$_{x^2-y^2}$ orbitals dominate the electronic states, and three bands cross $E_F$ to form one 3D Fermi surface sheet and two quasi-1D sheets. The electron DOS at $E_F$ is less than 1/3 of the experimental value, indicating an intermediate electron renormalization factor around $E_F$. Despite of the relatively small atomic numbers, the antisymmetric spin-orbit coupling splitting is sizable ($\approx$ 60 meV) on the 3D Fermi surface sheet as well as on one of the quasi-1D sheets. Finally, the imaginary part of bare electron susceptibility shows large peaks at $Γ$, suggesting the existence of large ferromagnetic spin fluctuation in the compound.

cond-mat.supr-con↗

Quasi-linear magnetoresistance and the violation of Kohler's rule in the quasi-one-dimensional Ta$_4$Pd$_3$Te$_{16}$ superconductor

We report on the quasi-linear in field intrachain magnetoresistance in the normal state of a quasi-one-dimensional superconductor Ta$_4$Pd$_3$Te$_{16}$ ($T_c$$\sim$4.6 K). Both the longitudinal and transverse in-chain magnetoresistance shows a power-law dependence, $Δρ$$\propto$B$^α$, with the exponent $α$ close to 1 over a wide temperature and field range. The magnetoresistance shows no sign of saturation up to 50 tesla studied. The linear magnetoresistance observed in Ta$_4$Pd$_3$Te$_{16}$ is found to be overall inconsistent with the interpretations based on the Dirac fermions in the quantum limit, charge conductivity fluctuations as well as quantum electron-electron interference. Moreover, it is observed that the Kohler's rule, regardless of the field orientations, is violated in its normal state. This result suggests the loss of charge carriers in the normal state of this chain-containing compound, due presumably to the charge-density-wave fluctuations.

cond-mat.supr-con↗

Coexistence of superconductivity and ferromagnetism in Sr0.5Ce0.5FBiS2

Through the combination of X-ray diffraction, electrical transport, magnetic susceptibility, and the heat capacity measurements, we studied the effect of Ce doping in the newly discovered SrFBiS${2}$ system. It is found that Sr${0.5}$Ce${0.5}$FBiS${2}$ undergoes a second-order transition below $7.5 K, followed by a superconducting transition with the critical temperature Tc=2.8 K. Our transport, specific heat and DC-magnetization results suggest the presence of bulk ferromagneticcorrelation of Ce ion below 7.5 K that coexist with superconductivity when the temperature is further lowered below 2.8 K.

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Correlation-induced self-doping in intercalated iron-pnictide superconductor Ba2Ti2Fe2As4O

The electronic structure of the intercalated iron-based superconductor Ba2Ti2Fe2As4O (Tc - 21.5 K) has been investigated by using angle-resolved photoemission spectroscopy and combined local density approximation and dynamical mean field theory calculations. The electronic states near the Fermi level are dominated by both the Fe 3d and Ti 3d orbitals, indicating that the spacing layers separating different FeAs layers are also metallic. By counting the enclosed volumes of the Fermi surface sheets, we observe a large self-doping effect, i.e. 0.25 electrons per unit cell are transferred from the FeAs layer to the Ti2As2O layer, leaving the FeAs layer in a hole-doped state. This exotic behavior is successfully reproduced by our dynamical mean field calculations, in which the self-doping effect is attributed to the electronic correlations in the Fe 3d shell. Our work provides an alternative route of effective doping without element substitution for iron-based superconductors.

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Sr$_{0.9}$K$_{0.1}$Zn$_{1.8}$Mn$_{0.2}$As$_{2}$: a ferromagnetic semiconductor with colossal magnetoresistance

A bulk diluted magnetic semiconductor (Sr,K)(Zn,Mn)$_{2}$As$_{2}$ was synthesized with decoupled charge and spin doping. It has a hexagonal CaAl$_{2}$Si$_{2}$-type structure with the (Zn,Mn)$_{2}$As$_{2}$ layer forming a honeycomb-like network. Magnetization measurements show that the sample undergoes a ferromagnetic transition with a Curie temperature of 12 K and \revision{magnetic moment reaches about 1.5 $μ_{B}$/Mn under $μ_0H$ = 5 T and $T$ = 2 K}. Surprisingly, a colossal negative magnetoresistance, defined as $[ρ(H)-ρ(0)]/ρ(0)$, up to $-$38\% under a low field of $μ_0H$ = 0.1 T and to $-$99.8\% under $μ_0H$ = 5 T, was observed at $T$ = 2 K. The colossal magnetoresistance can be explained based on the Anderson localization theory.

cond-mat.str-el↗

Heavy Fermion Quantum Criticality and Destruction of the Kondo Effect in a Nickel Oxypnictide

A quantum critical point arises at a continuous transformation between distinct phases of matter at zero temperature. Studies in antiferromagnetic heavy fermion materials have revealed that quantum criticality has several classes, with an unconventional type that involves a critical destruction of the Kondo entanglement. In order to understand such varieties, it is important to extend the materials basis beyond the usual setting of intermetallic compounds. Here we show that a nickel oxypnictide, CeNiAsO, displays a heavy-fermion antiferromagnetic quantum critical point as a function of either pressure or P/As substitution. At the quantum critical point, non-Fermi liquid behavior appears, which is accompanied by a divergent effective carrier mass. Across the quantum critical point, the low-temperature Hall coefficient undergoes a rapid sign change, suggesting a sudden jump of the Fermi surface and a destruction of the Kondo effect. Our results imply that the enormous materials basis for the oxypnictides, which has been so crucial to the search for high temperature superconductivity, will also play a vital role in the effort to establish the universality classes of quantum criticality in strongly correlated electron systems.

cond-mat.str-el↗

Electronic Nematicity Revealed by Torque Magnetometry in Iron Arsenide EuFe$_2$(As$_{1-x}$P$_x$)$_2$

Electronic nematics, an electron orientational order which breaks the underlying rotational symmetry, have been observed in iron pnictide superconductors several years after their discovery. However, the universality of the doping dependence of this phase and its relation to other symmetry-breaking orders (such as superconductivity) in distinct families of iron pnictides, remain outstanding questions. Here we use torque magnetometry as a probe to study the rotational symmetry breaking in EuFe$_2$(As$_{1-x}$P$_x$)$_2$ without introducing external pressure. The nematic phase is found to proliferate well above the structural transition and to persist into the superconducting regime at optimal doping, after which it becomes absent or very weak, in sharp contrast to the behaviour observed in BaFe$_2$(As$_{1-x}$P$_x$)$_2$. These measurements suggest a putative quantum nematic transition near optimal doping under the superconducting dome.

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Electronic phase diagram in the new BiS2-based Sr1-xLaxFBiS2 system

In this paper, we systematically study the electron doping effect in a new BiS2-based system Sr1-xLaxFBiS2(0 0.3, reaching its maximal superconducting transition temperature Tc=3.5 K at x=0.55. In the normal state of superconducting samples, it is clearly seen that there exists a crossover from metallic to semiconducting state below a temperature Tmin, which shifts to lower temperatures with increasing La content. Based on these measurements, the associated electronic phase diagram of Sr1-xLaxFBiS2 system has thus been established.

cond-mat.supr-con↗

K and Mn co-doped BaCd2As2: a hexagonal structured bulk diluted magnetic semiconductor with large magnetoresistance

A bulk diluted magnetic semiconductor was found in the K and Mn co-doped BaCd2As2 system. Different from recently reported tetragonal ThCr2Si2-structured II-II-V based(Ba,K)(Zn,Mn)2As2, the Ba1-yKyCd2-xMnxAs2 system has a hexagonal CaAl2Si2-type structure with the Cd2As2 layer forming a honeycomb-like network. The Mn concentration reaches up to its x ? 0.4. Magnetization measurements show that the samples undergo ferromagnetic transitions with Curie temperature up to 16 K. With low coercive field less than 10 Oe and large magnetoresistence of about -70%, the hexagonal structured Ba1-yKyCd2-xMnxAs2 can be served as a promising candidate for spin manipulations.

cond-mat.str-el↗

Li$_2$RhO$_3$: A spin-glassy relativistic Mott insulator

Motivated by the rich interplay among electronic correlation, spin-orbit coupling (SOC), crystal-field splitting, and geometric frustrations in the honeycomb-like lattice, we systematically investigated the electronic and magnetic properties of Li$_2$RhO$_3$. The material is semiconducting with a narrow band gap of $Δ\sim$78 meV, and its temperature dependence of resistivity conforms to 3D variable range hopping mechanism. No long-range magnetic ordering was found down to 0.5 K, due to the geometric frustrations. Instead, single atomic spin-glass behavior below the spin-freezing temperature ($\sim$6 K) was observed and its spin dynamics obeys the universal critical slowing down scaling law. First principle calculations suggested it to be a relativistic Mott insulator mediated by both electronic correlation and SOC. With moderate strength of electronic correlation and SOC, our results shed new light to the research of Heisenberg-Kitaev model in realistic materials.

cond-mat.str-el↗

Evidence for two energy gaps and Fermi liquid behavior in SrPt$_2$As$_2$ superconductor

We report a detailed calorimetric study on single crystals of the 5$d$-transition metal pnictide SrPt2As2 with a superconducting critical temperature $T_c$ $\sim$5K. The peculiar field dependence of the electronic specific heat coefficient $γ$ can be decomposed into two linear components. Moreover, the temperature evolution of the electronic specific heat below $T_c$ is best described by a two-gap model. These findings suggest that two energy gaps are associated with the superconductivity. In parallel, we show that the spin-lattice relaxation time $T_1$, through nuclear magnetic resonance measurement, obeys the so-called Korringa relation well. This, along with the $T^2$ dependence of resistivity at low temperatures, points to a Fermi liquid ground state in this material.

cond-mat.supr-con↗

Superconductivity induced by La doping in Sr1-xLaxFBiS2 system

Through a combination of X-ray diffraction, electrical transport, magnetic susceptibility, and heat capacity measurements, we report the effect of La doping on Sr in the newly discovered SrFBiS2 system. Superconducting transition with critical temperature Tc of 2.8 K, developed from a semiconducting-like normal state, was found in Sr0.5La0.5FBiS2. A strong diamagnetic signal and a clear specific heat anomaly associated with this transition were observed, confirming bulk superconductivity. The upper critical field Hc2(0) was estimated to be 1 Tesla by using the Ginzburg-Landau approach. Our experiments therefore demonstrate that bulk superconductivity can be achieved by electron doping in the SrFBiS2 system.

cond-mat.supr-con↗