arXiv subjects

Guangwei Fu

Publications and source records attributed to Guangwei Fu.

At least 19 recordsLinked to original sources

arXiv2026

Evidence for LP 890-9d via Transit Timing Variations

LP 890-9, also known as SPECULOOS-2 and TOI-4306, is a nearby late-M dwarf hosting two confirmed transiting rocky exoplanets. We analyze 20 JWST/NIRSpec PRISM transits of LP 890-9b and LP 890-9c obtained as part of GO program 7073 and detect statistically significant transit timing variations (TTVs), with peak-to-peak amplitudes of ~17 s and ~35 s, respectively. Using analytic linear TTV theory, we find that the known two-planet configuration cannot reproduce the measured TTV amplitudes or super-period, whereas three-planet models provide substantially better fits. The best-fit configuration places the candidate third planet, LP 890-9d, between planets b and c, with an orbital period of ~4.4 days; however, the current data do not uniquely determine its orbital architecture, and periods spanning 4.0-6.9 days remain plausible. TESS is insensitive to transits of LP 890-9d and we find no evidence for the candidate in JWST observations, although the phase coverage (ranging from ~50% to ~80%) depends strongly on the candidate orbital period. Additional high-precision transit observations of LP 890-9b and LP 890-9c are needed to refine their TTV solutions and further constrain the orbital properties of the third planet.

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arXiv2026

A Clearer View of HAT-P-1 b: JWST NIRSpec G395H Reveals Water, Carbon Dioxide, and Possibly Hydrogen Sulfide

As part of JWST's Exoplanet Grand Tour Survey, we use panchromatic transmission spectroscopy to connect HAT-P-1 b's previously studied optical and near-infrared atmosphere to the longer-wavelength molecular bands accessible with JWST. We present JWST NIRSpec G395H transmission spectroscopy of the hot Jupiter HAT-P-1 b over 2.7--5.3~$\mu$m, and combine the new spectrum with archival HST STIS and WFC3 observations for a 0.3--5.3~$\mu$m atmospheric analysis. We independently reduce the JWST data with the Eureka!, FIREFLy, and Tswift pipelines, finding mutually consistent transmission spectra across the G395H bandpass. Atmospheric retrievals yield strong evidence for H$_2$O and CO$_2$ with Bayes factors of $\log_{10}B_{\mathrm{H_2O}}=8.9$ and $\log_{10}B_{\mathrm{CO_2}}=52.3$, while providing tentative evidence for H$_2$S ($\log_{10}B_{\mathrm{H_2S}}=1.4$). The joint H$_2$O and CO$_2$ constraints favor an atmosphere near chemical equilibrium, with $\log_{10} \text{M/H}=0.99^{+0.19}_{-0.14}$, corresponding to $\sim10\times$ Solar or $\sim9\times$ relative to the near-solar metallicity host star, and a 3$\sigma$ upper limit of C/O $<0.52$. Because H$_2$O and CO$_2$ provide a metallicity comparatively insensitive to vertical mixing in this temperature regime, their combined detection suggests the composition is dominated by bulk enrichment rather than strong disequilibrium transport. We find no significant evidence for clouds; instead, the persistence of molecular structure across the spectrum argues against strong cloud muting. The tentative H$_2$S signal, if confirmed, would further suggest limited photochemical processing at the pressures probed. Together, the molecular inventory, enriched metallicity, and low C/O ratio point to an oxygen-rich atmosphere and establish HAT-P-1 b as a benchmark for comparative studies of hot-Jupiter atmospheric composition.

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arXiv2026

JWST color sequence of transiting exoplanets and directly imaged substellar objects

Color-magnitude diagrams (CMDs) have been foundational across astrophysics, from galaxies and stars to brown dwarfs, and JWST now extends them to transiting exoplanets and self-luminous substellar objects at overlapping temperatures. We compile JWST dayside emission spectra for 13 transiting giant planets, 57 self-luminous objects, and the irradiated brown dwarf ZTF J0038+2030 B, spanning ~350-2600 K and log g = 2.5-5.5, plus ~2150 SPHEREx ultracool dwarfs, converted to synthetic photometry in 2MASS J/Ks and five NIRCam medium bands isolating H2O, CH4, CO2, and CO. Low gravity and inflated radii make transiting planets resemble young substellar objects, with shallower features and redder colors from high-altitude clouds that raise the photosphere. Transiting planets follow the L-dwarf sequence on the J versus J-K CMD, with WASP-80 b (T_eq~800 K) showing no T-dwarf-like blueward turn, suggesting a delayed or suppressed L/T transition in irradiated, low-gravity atmospheres. Methane onset is delayed from substellar to transiting-planet atmospheres, and cloudy radiative-convective models indicate that lower gravity and cloud back-warming shift atmospheres toward CO-dominated chemistry, suppressing photospheric CH4. The irradiated but old, high-gravity brown dwarf ZTF J0038+2030 B (T_day = 1049 K, log g = 5.4) shows a deep, field-T-dwarf-like dayside methane band, implicating gravity rather than irradiation as the dominant control. CO2-to-CO diagnostics place transiting and directly imaged planetary-mass companions at stronger relative CO2 absorption than field brown dwarfs, consistent with metallicity enhancement from planetesimal accretion. These CMD sequences provide a unified, model-testable map for self-luminous and irradiated atmospheres.

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arXiv2026

Asymmetric Aerosol Distribution on the Terminators of the Warm Saturn WASP-69 b Revealed by JWST NIRISS/SOSS

How aerosols form, are transported, and cycle between condensation and evaporation across exoplanet temperature regimes remains poorly understood. Recent models and observations suggest that warm giant planets near $800$--$1000$ K may span a transition between homogeneous and longitudinally heterogeneous aerosol distributions. We present a robust detection of aerosol asymmetry in a giant planet with $T_{\rm eq}\lesssim1000$ K, using the $0.86$--$2.82~\mu$m JWST NIRISS/SOSS transmission spectrum of WASP-69 b. The evening limb shows prominent 1.4 $\mu$m H$_2$O absorption ($\Delta\mathrm{BIC}_{\rm H_2O}=+22.7$), whereas H$_2$O is not detected on the morning limb ($\Delta\mathrm{BIC}_{\rm H_2O}=-8.7$). Atmospheric retrievals reveal significant aerosol opacity on both limbs, with high-altitude, optically thick clouds muting molecular features on the morning limb and lower cloud opacity allowing H$_2$O to emerge on the evening limb. The evening terminator is hotter by $304^{+62}_{-91}$ K, consistent with morning-limb condensates partially evaporating during transport toward the evening limb. This mechanism is independently verified with 3D general circulation models. Stellar contamination or aerosols dominated by photochemical haze do not readily explain the asymmetry. From a limb-resolved analysis, we infer a stellar-to-superstellar atmospheric metallicity, with $\rm[M/H]=0.11^{+0.40}_{-0.46}$ from the equilibrium retrieval and [O/H]$=1.38^{+0.44}_{-0.79}$ from the free retrieval. We also detect an escaping metastable-helium tail extending to $3.08^{+0.50}_{-0.45}\,R_p$. WASP-69 b anchors the cooler edge of the emerging population of planets with asymmetric aerosol distributions and suggests that substantial aerosol opacity may persist on both limbs across this transition.

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arXiv2026

No Helium Detected in LHS 1140 b from Four JWST NIRISS/SOSS Transits

In the effort to determine which low-mass exoplanets have atmospheres, LHS 1140 b remains one of the most favorable targets. Its large size (5.6 $\rm M_{\oplus}$ and 1.7 $\rm R_{\oplus}$) and relatively long orbital period (24.7 days) imply an atmosphere may be likely, and notably, recent interior models favor either a hydrogen-dominated "mini-Neptune" or a "water world" over a true terrestrial planet. Another possibility is that it has a helium-rich atmosphere. This hypothesis is supported by recent ground-based observations that detected the metastable helium triplet during transit. These observations indicated there may be current helium escape from the planet's upper atmosphere, yet the signal was not detected during a subsequent observation, suggesting time-variable escape. Here we present four observations of LHS 1140 b with JWST NIRISS/SOSS, which covers the metastable helium triplet, obtained between 2023 and 2026. These observations span the epoch of the ground-based measurements, and although none were contemporaneous with the ground-based transits, all four are sensitive to helium absorption at the previously reported level. However, we detect no helium absorption in any visit. We reject the best-fit ground-based model at $>3\sigma$ in each visit, and find no clear trend in mass-loss with time. Our results suggest the reported ground-based detection may be spurious, although variability cannot be excluded if detectable helium absorption occurs in $\lesssim50\%$ of transits. The nature of LHS 1140 b thus remains a mystery until future transmission and emission analyses are complete.

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arXiv2026

Mitigating Charge Migration in JWST NIRISS Reveals That KELT-7 b is a Metal-enriched Ultra-hot Jupiter Orbiting a Young Metal-rich Star

We present the first panchromatic JWST transmission spectrum of an ultra-hot Jupiter, combining NIRISS and NIRSpec observations to constrain KELT-7\,b's atmospheric properties. We show evidence for charge migration in our NIRISS SOSS observation between 1--1.5~$\mu$m, a wavelength range crucial to test for enhanced H$^-$ previously inferred from HST WFC3/IR G141 observations. We mitigate charge migration by fitting the ramp after extracting 1D stellar spectra at the group level. This ``late-ramp-fit'' method accurately calculates KELT-7\,b's transmission spectrum between 1--1.5~$\mu$m at higher signal-to-noise. Using the transit-derived stellar mean density during stellar property inference reveals that KELT-7 is a $640\pm100$ Myr-old, $[\text{Fe}/\text{H}]=0.46\pm0.02$ star. Combined with NIRSpec and re-reduced WFC3/UVIS G280 data, our free retrieval analysis shows strong evidence for H$_2$O, CO$_2$, and TiO among high-temperature species, but not H$^-$ or clouds. Unaccounted-for systematics may therefore bias longer-wavelength WFC3/IR G141 transit depths shallower. Our free retrieval, two equilibrium retrievals, and self-consistent grid fit all prefer a high metallicity but find discrepant C/O ratios. Agglomerated together, we constrain a super-stellar $\text{M/H}=92^{+24}_{-23}\times$~Solar and C/O~$\leq0.9$, suggesting enhanced metal accretion in the later stages of KELT-7\,b's formation. Our GCMs explain the observed lack of limb asymmetry with superrotating jet-driven efficient horizontal mixing. The stark contrast between our panchromatic analysis and prior analyses on subsets of these data demonstrates the value of broad wavelength coverage for the comprehensive study of exoplanet atmospheres.

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arXiv2026

C, N, O, S, and photochemistry in a temperate giant planet orbiting a late M dwarf

We report the JWST NIRSpec/PRISM transit spectrum of TOI-6894b, an exceptional 420 K sub-Saturn that is the only known giant planet transiting a late M dwarf. Remarkably, both the light curve and the transit spectrum exhibit almost no stellar contamination. The spectrum is dominated by prominent absorption features from CH$_4$ and the photochemical product CS$_2$. For the first time in a transit spectrum, NH$_3$ is visually evident, while subtler features from H$_2$O, and CO$_2$ can also be seen. We significantly improve upon state-of-the-art photochemical reaction networks, and use our new network to run radiative-convective photochemical models at different metallicities. These models show that the spectrum--in particular the size of the NH$_3$ and CO$_2$ features relative to the CH$_4$ and H$_2$O features--is most consistent with a metallicity of 3--10$\times$ solar. Using a semi-free retrieval framework that perturbs the self-consistent model's abundance and temperature profiles to fit the data, we find that the planet's C/O, N/O, and S/O ratios are broadly consistent with solar values. A grid retrieval on 1D radiative-convective photochemical equilibrium (RCPE) models reveals a similar result: $[M/H]=0.46 \pm 0.08$ and C/O=$0.69 \pm 0.06$. The planet's atmospheric metallicity, abundance ratios, and bulk metal fraction are all strikingly similar to that of Jupiter, Saturn, and other gas giant exoplanets, despite orbiting a very low-mass star.

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arXiv2026

Photochemical Production of CS2 in Temperate-to-Warm Gas Giant Exoplanet Atmospheres

Sulfur chemistry has emerged as an important probe of exoplanet atmospheres in the JWST era, although observational constraints have thus far been largely limited to SO2 and H2S in warm and hot exoplanets. Recent JWST observations have revealed CS2 in several cooler gas-giant exoplanets, yielding a new tracer of sulfur chemistry. However, the detailed chemical pathways responsible for the formation of CS2 remain poorly understood. Here, we use TOI-6894 b, a temperate gas giant with evidence for CS2, as a test case for one-dimensional photochemical kinetic-transport modeling and sensitivity analyses of CS2 chemistry. We show that CS2 is produced through coupled thermochemical and photochemical processes involving CH4 and H2S as the primary carbon and sulfur reservoirs, with S2 photolysis driving disequilibrium sulfur chemistry. Our models provide a physically consistent explanation for the observed CS2 feature in TOI-6894 b. Extending our analysis to gas giant exoplanets spanning a wide range of Teq, we find that CS2 abundance peaks in temperate to warm atmospheres (Teq ~ 500 - 700 K), and declines toward both lower and higher temperatures. This temperature dependence provides a unified framework for interpreting current CS2 observations, accounting for reported detections in temperate to warm planets and the lack of detections in colder and hotter giant exoplanets. Our results establish CS2 as a complementary probe of sulfur inventories and atmospheric metallicity in cool gas giant exoplanets

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arXiv2026

Atmospheric asymmetries in WASP-121 b revealed by rotational transits detected with JWST

Close-in exoplanets are tidally locked to their host star and thus exhibit extreme atmospheric temperature gradients. It has been theorized that the fraction of star light absorbed by such planets during transit changes as a function of orbital phase as progressively hotter or colder atmospheric gas rotates into view, but this effect has not been observed so far. Here, we show that two transits of the ultra-hot Jupiter WASP-121 b, acquired with JWST/NIRSpec and NIRISS, exhibit asymmetric transit light curves caused by the planet's rotation during transit. We observe increasing CO absorption and slightly decreasing H$_2$O absorption in the transmission spectrum, as the planet rotates. These results are indicative of a stronger longitudinal temperature gradient across the evening than across the morning terminator, consistent with higher temperatures in the eastern half than in the western half of the dayside. The observed changes of the transmission spectrum with orbital phase are in line with the temperature increase causing thermal dissociation of H$_2$O, while CO remains abundant. The observation of longitudinal gradients of atmospheric temperature and chemistry from the planet's rotational transit provides a new probe for constraining atmospheric heterogeneity using JWST beyond differences between morning and evening terminators from limb asymmetries.

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arXiv2026

The Third Option: Color Phase Curves to Characterize the Atmospheres of Temperate Rocky Exoplanets

Detecting and characterizing the atmospheres of rocky exoplanets has proven to be challenging for JWST. Transit spectroscopy of the TRAPPIST-1 planets has been impacted by the effects of spots and faculae on the host star. Secondary eclipses have detected hot rocks, but evidence for atmospheres has been difficult to obtain. However, there is a third option that we call color phase curves. This method will apply to synchronously rotating non-transiting planets as well as transiting planets. A color phase curve uses photometry at a long-IR wavelength where the planetary thermal emission is strong (e.g., 21 microns) divided by photometry at a shorter wavelength where the star dominates (e.g., 12 microns). We avoid wavelengths having potentially strong molecular absorption (e.g., 15 microns) to minimize degeneracies in the color phase curve, and we aim to detect and characterize the planetary atmosphere via its longitudinal heat transfer. The ratio of two wavelengths observed nearly simultaneously is designed to isolate thermal emission from the planet, discriminate against the star, and largely cancel instrumental systematic effects. Moreover, we show that invoking mass-radius relations, and using self-consistent physical models, will permit the longitudinal heat transfer to be measured independent of the orbital inclination. Radial velocity surveys are detecting many new exoplanets, including temperate rocky worlds with Earth-like masses. Most of those planets will not transit, but color phase curves have the potential to detect and characterize their atmospheres.

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arXiv2025

Methane on the temperate exo-Saturn TOI-199b

Temperate ($T_{\rm eq}<400$ K) gas giants represent an unexplored frontier in exoplanet atmospheric spectroscopy. Orbiting a G-type star every $\sim100$ days, the Saturn-mass exoplanet TOI-199 b ($T_{\rm eq}=350$ K) is one of the most favorable low-temperature gas giants for atmospheric study. Here, we present its transmission spectrum from a single transit observed with JWST's NIRSpec G395M mode. Despite lower-than-nominal precision due to a pointing misalignment, the spectrum reveals the presence of CH$_4$ (Bayes factor of $\sim$700 in a cloudy atmosphere), corresponding to a metallicity of $\rm{C/H}=13^{+78}_{-12}\times$ solar, although the absence of detectable CO and CO$_2$ at the current precision disfavors metallicities $\gtrsim50\times$ solar. We also tested several haze prescriptions (Titan-like tholin, soot, and water-rich tholin), but the preference for these models is weak (Bayes factors of $\sim 2$ relative to the clear case). The spectrum also shows an increase in transit depth near 3 $\mu$m, which our self-consistent models attribute to either NH$_3$ or, less likely, HCN. Follow-up observations could distinguish between these species, helping determine the planet's vertical mixing regime. The TOI-199 system exhibits strong transit timing variations (TTVs) due to an outer non-transiting giant planet. For planet c, our TTV analysis reduces its mass uncertainty by 50% and prefers a slightly longer orbital period (but still within the conservative habitable zone) and higher eccentricity relative to previous studies. TOI-199 b serves as the first data point for studying clouds and hazes in temperate gas giants, with the detection of spectral features in its transmission spectrum indicating that temperate gas giants are promising targets for detailed atmospheric characterization.

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arXiv2025

The Library of Exoplanet Atmospheric Composition Measurements: Population Level Trends in Exoplanet Composition with ExoComp

The present-day bulk elemental composition of an exoplanet can provide insight into a planet's formation and evolutionary history. Such information is now being measured for dozens of planets with state-of-the-art facilities using Bayesian atmosphere retrievals. We collect measurements of exoplanet composition of gas giants into a Library of Exoplanet Atmospheric Composition Measurements for comparison on a population level. We develop an open-source toolkit, ExoComp, to standardize between solar abundance, metallicity, and C/O ratio definitions. We find a systematic enhancement in the metallicity of exoplanets compared to T-dwarf and stellar populations, a strict bound in C/O between 0 and 1, and statistically significant differences between measurements from direct, eclipse, and transmission spectroscopy. In particular, the transit spectroscopy population exhibits a systematically lower C/O ratio compared to planets observed with eclipse and direct spectroscopy. While such differences may be astrophysical signals, we discuss many of the challenges and subtleties of such a comparison. We characterize the mass-metallicity trend, finding a slope consistent between planets measured in transit versus eclipse, but offset in metallicity. Compared to the Solar System and constraints from interior modeling, gas giant atmospheres appear to exhibit a steeper mass-metallicity trend. We hope that the tools available in ExoComp and the data in the Library of Exoplanet Atmospheric Composition Measurements can enhance the science return of the wide-array of space- and ground-based exoplanet science being undertaken by the community.

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arXiv2025

A carbon-rich atmosphere on a windy pulsar planet

A handful of enigmatic Jupiter-mass objects have been discovered orbiting pulsars. One such object, PSR\,J2322-2650b, uniquely resembles a hot Jupiter exoplanet due to its minimum density of 1.8 g/cm^3 and its ~1900 K equilibrium temperature. We use JWST to observe PSR J2322-2650b's emission spectrum across an entire orbit. In stark contrast to every known exoplanet orbiting a main-sequence star, we find an atmosphere rich in molecular carbon (C3, C2) with strong westward winds. Our observations open up new exoplanetary chemical (ultra-high C/O and C/N ratios of >100 and >10,000, respectively) and dynamical regimes (ultra-fast rotation with external irradiation) to observational study. The extreme carbon enrichment poses a severe challenge to the current understanding of ``black widow'' companions, which were expected to consist of a wider range of elements due to their origins as stripped stellar cores.

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arXiv2025

Additional JWST/NIRSpec Transits of the Rocky M Dwarf Exoplanet GJ 1132 b Reveal a Featureless Spectrum

As an archetypal M-dwarf rocky exoplanet, GJ 1132 b has a varied history of atmospheric measurements. At 1.13 $\rm R_{\oplus}$, 1.66 $\rm M_{\oplus}$, and 580 K, it orbits a bright, slowly rotating M dwarf in a 1.6-day period, making it a prime target for characterization. In this study, we combine two JWST NIRSpec/G395H transits previously reported by May and MacDonald et al. 2023 with two new NIRSpec/G395M transits to constrain the presence of an atmosphere. This marks the first time the G395H and G395M modes have been combined for a single target, and we report no difference in the quality of data between the two modes. For rocky M-dwarf studies, G395H may still be preferred if stacking transits to utilize the high-resolution flux-calibrated stellar spectra and assess evolving stellar heterogeneity. GJ 1132 b's co-added transmission spectrum is best-fit with a flat line. A thin steam atmosphere is also consistent with the data, but this interpretation is driven almost entirely by the first transit, which suggests an increase in cool spot coverage-fraction derived from the flux-calibrated stellar spectra. This demonstrates the importance of always considering stellar heterogeneity evolution in multi-visit transits, and also the importance of a "leave-one-transit-out" approach in modeling efforts of co-added transits. We combine these results with MIRI/LRS emission data (Xue et al. 2024) to show that together, transmission and emission are consistent with only the thinnest of atmospheres. Given GJ 1132 b's age and distance from the star, a thin atmosphere is not likely stable. Therefore, the simplest explanation is that GJ 1132 b is indeed a bare rock.

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arXiv2025

Overcast mornings and clear evenings in hot Jupiter exoplanet atmospheres

Aerosols is an old topic in the young field of exoplanet atmospheres. Understanding what they are, how they form, and where they go has long provided a fertile playground for theorists. For observers, however, aerosols have been a multi-decade migraine, as their chronic presence hides atmospheric features. For hot Jupiters, the large day-night temperature contrast drives inhomogeneous thermal structures and aerosol distribution, leading to different limb properties probed by transit spectra. We present JWST NIRISS/SOSS spectra of morning and evening limbs for nine gas giants with equilibrium temperatures of ~800-1700 K. By measuring feature size of the 1.4 $\mu$m water band for both limbs, we found three planets (WASP-39 b, WASP-94 Ab, and WASP-17 b) show prominent ($>$5$\sigma$) limb-limb atmospheric opacity difference with muted morning and clear evening limbs. The heavily muted water features on morning limbs indicate high-altitude (0.1 to 0.01 mbar) aerosols. To simultaneously have clear evening limbs requires processes with timescales ($\sim$day) comparable to advection to remove these lofted grains, and we found that both downwelling flow and dayside cloud evaporation could be plausible mechanisms. We hypothesize an empirical boundary--termed the "asymmetry horizon"--in temperature-gravity space that marks the transition where inhomogeneous aerosol coverage begins to emerge. Heterogeneous aerosol coverage is common among hot Jupiters. If unrecognized, limb averaging suppresses spectral features, mimicking high-mean-molecular-weight atmospheres, inflating inferred metallicity by up to 2 dex, and underestimating limb temperatures by as much as half. Finally, we introduce the Limb Spectroscopy Metric (LSM) to predict limb spectral feature size based on planet parameters.

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arXiv2025

The James Webb Space Telescope NIRSpec-PRISM Transmission Spectrum of the Super-Puff, Kepler-51d

Kepler-51 is a 500 Myr G dwarf hosting three "super-puffs" and one low-mass non-transiting planet. Kepler-51d, the coolest (T_eq ~ 350 K) transiting planet in this system, is also one of the lowest density super-puffs known to date (rho_p = 0.038 +/- 0.009 g/cm^3). With a planetary mass of Mp = 5.6 +/- 1.2 Earth masses and a radius of Rp = 9.32 +/- 0.18 Earth radii, the observed properties of this planet are not readily explained by most planet formation theories. Hypotheses explaining Kepler-51d's low density range from a substantial H/He envelope comprising more than 30% of its mass, to a high-altitude haze layer, to a tilted ring system. To test these hypotheses, we present the NIRSpec-PRISM 0.6-5.3 micron transmission spectrum of Kepler-51d observed by the James Webb Space Telescope. We find a spectrum best fit by a sloped line covering the entire wavelength range. Based on forward modeling and atmosphere retrievals, Kepler-51d likely possesses a low-metallicity atmosphere with high-altitude hazes of submicron particle sizes spanning pressures of 1-100 microbars. However, the spectrum could also be explained by a tilted ring with an estimated lifetime on the order of ~0.1 Myr. We also investigate the stellar activity of this young Sun-like star, extracting a spot temperature significantly hotter than sunspots and spot covering fractions on the order of 0.1-10%, depending on the assumed spot parameters.

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arXiv2025

Cloudy mornings and clear evenings on a gas giant exoplanet

The spectra of exoplanet atmospheres are affected by aerosols (clouds and hazes) of uncertain origin. Proposed aerosol formation mechanisms include gas condensation or photochemical reactions. We measure the transmission spectrum of the tidally locked gas giant exoplanet WASP-94A b and identify asymmetry in its atmosphere. The morning limb is cooler and cloudy, while the evening limb is hotter and exhibits gaseous H$_2$O absorption features. We interpret this difference as due to the formation of cloud droplets near the morning limb, which evaporate during circulation to the evening limb. The dominant aerosols are clouds cycling between the day and night sides of the atmosphere, not photochemical hazes. The resulting asymmetry can severely bias chemical abundance measurements, unless limb-resolved spectroscopy is available.

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arXiv2025

HST Transmission Spectra of the Hot-Neptune HD 219666 b: Detection of Water and the Challenge of Constraining Both Water and Methane

Although Neptunian-sized (2 - 5 R$_{Earth}$) planets appear to be extremely common in the Galaxy, many mysteries remain about their overall nature. To date, only 11 Neptunian-sized planets have had their atmospheres spectroscopically characterized, and these observations hint at interesting diversity within this class of planets. Much of our understanding of these worlds and others derive from transmission spectroscopy with the Hubble Space Telescope's Wide Field Camera 3 (HST/WFC3). One key outcome of HST/WFC3 observations has been the consistent detection of water but no methane in Neptunian atmospheres, though recent James Webb Space Telescope (JWST) observations are potentially starting to overturn this "missing methane" paradigm. In this work, we present the transmission spectrum of the hot Neptune HD 219666 b from 1.1 - 1.6 $\mu$m from two transit observations using HST/WFC3 G141. Our fiducial atmospheric retrieval detects water at ~3-$\sigma$ in HD 219666 b's atmosphere and prefers no contribution from methane, similar to these previous observations of other planets. Motivated by recent detections of methane in Neptunian atmospheres by JWST, we explore additional models and find that a methane-only scenario could adequately fit the data, though it is not preferred and likely unphysical. We discuss the impact of this methane detection challenge on our understanding of planetary atmospheres based on HST/WFC3 observations alone, and where JWST observations offer a solution.

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