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Guanqun Zhang

Publications and source records attributed to Guanqun Zhang.

7 recordsLinked to original sources

Unique quantum metallic state in the titanium sesquioxide heterointerface superconductor

The emergence of quantum metallic state marked by a saturating finite electrical resistance in the zero-temperature limit in a variety of two-dimensional superconductors injects an exciting momentum to the realm of heterostructure superconductivity. Despite much research efforts over last few decades, there is not yet a general consensus on the nature of this unexpected quantum metal. Here, we report the observation of a unique quantum metallic state within the hallmark of Bose-metal in the titanium sesquioxide heterointerface superconductor Ti$_2$O$_3$/GaN. Remarkably, the quantum bosonic metallic state continuously tuned by a magnetic field in the vicinity of the two-dimensional superconductivity-metal transition persists in the normal phase, indicating the existence of composite bosons formed by electron Cooper pairs even in the normal phase. Our findings provide a distinct evidence for electron pairing in the normal phase of heterointerface superconductors, and shed fresh light on the pairing nature underlying heterointerface superconductivity.

cond-mat.supr-con↗

Coexistence of ferromagnetism and superconductivity at KTaO$_3$ heterointerfaces

The coexistence of superconductivity and ferromagnetism is a long-standing issue in superconductivity due to the antagonistic nature of these two ordered states. Experimentally identifying and characterizing novel heterointerface superconductors that coexist with magnetism presents significant challenges. Here, we report the experimental observation of two-dimensional long-range ferromagnetic order in the KTaO$_3$ heterointerface superconductor, showing the coexistence of superconductivity and ferromagnetism. Remarkably, our direct current superconducting quantum interference device measurements reveal an in-plane magnetization hysteresis loop persisting above room temperature. Moreover, the first-principles calculations and X-ray magnetic circular dichroism measurements provide decisive insights into the origin of the observed robust ferromagnetism, attributing it to oxygen vacancies that localize electrons in nearby Ta 5$d$ states. Our findings not only suggest KTaO$_3$ heterointerfaces as time-reversal symmetry breaking superconductors, but also inject fresh momentum into the exploration of the intricate interplay between superconductivity and magnetism, enhanced by the strong spin-orbit coupling inherent to the heavy Ta in 5$d$ orbitals of KTaO$_3$ heterointerfaces.

cond-mat.supr-con↗

Nonreciprocal charge transport in the titanium sesquioxide heterointerface superconductor

Nonreciprocal charge transport in heterostructural superconductors exhibits appealing quantum physical phenomena and holds the promising potential for superconducting circuits applications. Realizing a nonreciprocity is, however, fundamentally and technologically challenging, as it requires a material structure without a centre of inversion, which is scarce among superconducting materials. Here, we report an evidence of helical superconductivity, in which the Rashba spin-orbit coupling induces momentum-dependent superconducting gap in the inversion symmetry breaking heterointerface superconductor consisting of Mott insulating Ti$_2$O$_3$ and polar semiconducting GaN. Remarkably, the nonlinear responses emerge in the superconducting transition regime, when the magnetic field is precisely aligned in-plane orientations perpendicular to the applied current. In particular, the observed nonreciprocal supercurrent is extremely sensitive to the direction of the magnetic field for 0.5 degree, suggestive of a crossover from a symmetry breaking state to a symmetric one. Our finding not only unveils the underlying rich physical properties in heterointerface superconductors, but also provides an exciting opportunity for the development of novel mesoscopic superconducting devices.

cond-mat.supr-con↗

Spontaneous rotational symmetry breaking in KTaO$_3$ heterointerface superconductors

Broken symmetries play a fundamental role in superconductivity and influence many of its properties in a profound way. Understanding these symmetry breaking states is essential to elucidate the various exotic quantum behaviors in non-trivial superconductors. Here, we report an experimental observation of spontaneous rotational symmetry breaking of superconductivity at the heterointerface of amorphous (a)-YAlO$_3$/KTaO$_3$(111) with a superconducting transition temperature of 1.86 K. Both the magnetoresistance and superconducting critical field in an in-plane field manifest striking twofold symmetric oscillations deep inside the superconducting state, whereas the anisotropy vanishes in the normal state, demonstrating that it is an intrinsic property of the superconducting phase. We attribute this behavior to the mixed-parity superconducting state, which is an admixture of \emph{s}-wave and \emph{p}-wave pairing components induced by strong spin-orbit coupling inherent to inversion symmetry breaking at the heterointerface of a-YAlO$_3$/KTaO$_3$. Our work suggests an unconventional nature of the underlying pairing interaction in the KTaO$_3$ heterointerface superconductors, and brings a new broad of perspective on understanding non-trivial superconducting properties at the artificial heterointerfaces.

cond-mat.supr-con↗

Improving CNN-base Stock Trading By Considering Data Heterogeneity and Burst

In recent years, there have been quite a few attempts to apply intelligent techniques to financial trading, i.e., constructing automatic and intelligent trading framework based on historical stock price. Due to the unpredictable, uncertainty and volatile nature of financial market, researchers have also resorted to deep learning to construct the intelligent trading framework. In this paper, we propose to use CNN as the core functionality of such framework, because it is able to learn the spatial dependency (i.e., between rows and columns) of the input data. However, different with existing deep learning-based trading frameworks, we develop novel normalization process to prepare the stock data. In particular, we first empirically observe that the stock data is intrinsically heterogeneous and bursty, and then validate the heterogeneity and burst nature of stock data from a statistical perspective. Next, we design the data normalization method in a way such that the data heterogeneity is preserved and bursty events are suppressed. We verify out developed CNN-based trading framework plus our new normalization method on 29 stocks. Experiment results show that our approach can outperform other comparing approaches.

q-fin.ST↗

Evidence for unconventional superconductivity in a spinel oxide

The charge frustration with the mixed-valence state inherent to LiTi$_2$O$_4$, which is found to be a unique spinel oxide superconductor, is the impetus for paying special attention to reveal the existence of intriguing superconducting properties. Here, we report a pronounced fourfold rotational symmetry of the superconductivity in high-quality single-crystalline LiTi$_2$O$_4$ (001) thin films. Both the magnetoresistivity and upper critical field under an applied magnetic field manifest striking fourfold oscillations deep inside the superconducting state, whereas the anisotropy vanishes in the normal state, demonstrating that it is an intrinsic property of the superconducting phase. We attribute this behavior to the unconventional $d$-wave superconducting Cooper pairs with the irreducible representation of $E_g$ protected by $O_h$ point group in LiTi$_2$O$_4$. Our findings demonstrate the unconventional character of the pairing interaction in a three-dimensional spinel oxide superconductor and shed new light on the pairing mechanism of unconventional superconductivity.

cond-mat.supr-con↗

Two-Dimensional Superconductivity at the Titanium Sesquioxide Heterointerface

The study of exotic superconductivity in two dimensions has been a central theme in solid state and materials research communities. Experimentally exploring and identifying new fascinating interface superconductors with a high transition temperature ($T_c$) is challenging. Here, we report an experimental observation of intriguing two-dimensional superconductivity with a $T_c$ up to 3.8 K at the interface between Mott insulator Ti$_2$O$_3$ and polar semiconductor GaN. At the verge of superconductivity, we also observe a striking quantum metallic-like state, demonstrating that it is a precursor to the two-dimensional superconductivity as the temperature is decreased. Our work is the first time finding this intriguing superconducting state at the heterointerface, which not only brings a new broad of perspective on the emergent quantum phenomena at the heterointerfaces but also sheds new light on exploiting the novel heterointerface superconductivity with high-$T_c$ via heterostructure engineering.

cond-mat.supr-con↗