arXiv subjects

Guillaume Blanquart

Publications and source records attributed to Guillaume Blanquart.

8 recordsLinked to original sources

arXiv2026

State-Specific Kinetic Modeling of Atomic H for H$_2$/ He Entry Flows

An 11-species thermochemical model for H$_2$/ He mixtures with state-specific kinetics for atomic H is developed and used to simulate 1-D shocks at conditions relevant for ice and gas giant entry flows. To implement this kinetic model, a literature review of the state-specific excitation and ionization rate constants of atomic H is first performed. While electron-impact rate constants from various sources are found to be in good agreement, large discrepancies are found in the limited data available on heavy-particle-impact rate constants. To validate the kinetic model, 1-D steady shocks are simulated using a space-marching code that explicitly accounts for shock tube boundary layer effects. The resulting radiance profiles are compared to experimental data from the NASA Ames Electric Arc Shock Tube (EAST) facility, and are found to reproduce the measured values reasonably accurately while capturing the distinct induction zone behavior observed in the experiments. A sensitivity analysis of the kinetic rates and boundary layer treatment reveals avenues for further improvement of the model. Finally, a comparison to alternate models from the literature underscores the improved accuracy of the present model in predicting ionization and radiation profiles.

physics.chem-ph↗

arXiv2026

A theoretical one-dimensional model for variable-density Rayleigh-Taylor turbulence

In an early theoretical work published in 1965, Belen'kii & Fradkin proposed a turbulent diffusivity model for Rayleigh--Taylor (RT) mixing. We review its derivation and present alternative arguments leading to the same final similarity equation. The original work then introduced an approximation that led to a simplified ordinary differential equation (ODE), which was used primarily to derive the important scaling result, $h \sim (\ln R)gt^2$. Here, we extend the analysis by examining the solutions to both the full similarity ODE and the simplified ODE in detail. It is shown that the full similarity equation captures many now well-known features of non-Boussinesq RT flows, including asymmetric spike and bubble growth and a systematic shift of velocity statistics toward the light-fluid side. Comparisons of the theoretical model with numerical and experimental studies show reasonable agreement in both spatial profiles and growth trends of mixing layer heights. We further show that a global mass correction applied to the simplified solution closely approximates the full solution, highlighting that, to leading order, RT mixing is governed by the competing dynamics between diffusion of $\ln \barρ$ and mass conservation.

physics.flu-dyn↗

arXiv2025

Self-similar scaling of variable-density Rayleigh-Taylor turbulence

The dynamics of self-similar Rayleigh-Taylor (RT) mixing layers are investigated across a broad range of Atwood and Reynolds numbers using the statistically stationary Rayleigh-Taylor (SRT) flow configuration - a computational framework that enables simulation of self-similar RT flows at reduced cost compared to conventional temporally growing mixing layers. Normalizations are developed for all dominant non-transport terms in the continuity, mixed mass, and turbulent kinetic energy budgets in terms of the input parameters: the mixing layer height $h$, gravitational acceleration $g$, and fluid densities $ρ_H$ and $ρ_L$. Most normalized quantities collapse well across the parameter space. In some cases, variations in the Atwood number $A$ (or equivalently, the density ratio $R$) lead to consistent integral magnitudes but spatially shifted profiles. These shifts are primarily related to a division by density and are similarly observed in the analytical solution of the one-dimensional variable-density diffusion problem. The analysis introduces a reference density for the mixed mass, examines trends in Favre-averaged statistics, and derives a scaling law for the growth rate of the mixing layer. For height definitions encompassing the full extent of the layer, the conventional growth parameter, $α= \dot{h}^2/4Agh$, varies with Atwood number. Our analysis leads to an alternative formulation using an effective Atwood number, $A^*= (\ln R)/2$, that is consistent with the scaling proposed by Belen'kii & Fradkin (Trudy FIAN, vol. 29, 1965, pp. 207-238). The corresponding growth parameter, $α^*=\dot{h}^2/4A^*gh$, remains nearly constant across all Atwood numbers considered, offering a unified scaling for variable-density RT flows.

physics.flu-dyn↗

arXiv2025

Treatment of Thermal Non-Equilibrium Dissociation Rates: Application to $\rm H_2$

This work presents a detailed description of the thermochemical non-equilibrium dissociation of diatomic molecules, and applies this theory to the case of $\rm H_2$ dissociation. The master equations are used to derive corresponding aggregate rate constant expressions that hold for any degree of thermochemical non-equilibrium. These general expressions are analyzed in three key limits/ regimes: the thermal equilibrium limit, the quasi-steady-state (QSS) regime, and the pre-QSS regime. Under several simplifying assumptions, an analytical source term expression that holds in all of these regimes, and is only a function of the translational temperature, $T_{\rm t}$, and the fraction of dissociation, $ϕ_{\rm A}$, is proposed. This expression has two input parameters: the QSS dissociation rate constant in the absence of recombination, $k_{\rm d,nr}(T_{\rm t})$, and a pre-QSS correction factor, $η(T_{\rm t})$. The value of $η(T_{\rm t})$ is evaluated by comparing the predictions of the proposed expression against existing master equation simulations of a 0-D isothermal and isochoric reactor for the case of $\rm H_2$ dissociation with the third-bodies $\rm H_2$, $\rm H$, and $\rm He$. Despite its simple functional form, the proposed expression is able to reproduce the master equation results for the majority of the tested conditions. The best fit of $k_{\rm d,nr}(T_{\rm t})$ is then evaluated by conducting a detailed literature review. Data from a wide range of experimental and computational studies are considered for the third-bodies $\rm H_2$, $\rm H$, and inert gases, and fits that are valid from 200 to 20,000 K are proposed. From this review, the uncertainty of the proposed fits are estimated to be less than a factor of two.

physics.chem-ph↗

arXiv2023

Isolating effects of large and small scale turbulence on thermodiffusively unstable premixed hydrogen flames

Lean turbulent premixed hydrogen/air flames have substantially increased flame speeds, commonly attributed to differential diffusion effects. In this work, the effect of turbulence on lean hydrogen combustion is studied through Direct Numerical Simulation using detailed chemistry and detailed transport. Simulations are conducted at six Karlovitz numbers and three integral length scales. A general expression for the burning efficiency is proposed which depends on the conditional mean chemical source term and gradient of a progress variable. At a fixed Karlovitz number, the normalized turbulent flame speed and area both increase linearly with the integral length scale ratio. The effect on the mean source term profile is minimal, indicating that the increase in flame speed can solely be attributed to the increase in flame area. At a fixed integral length scale, both the flame speed and area first increase with Karlovitz number before decreasing. At higher Karlovitz numbers, the diffusivity is enhanced due to penetration of turbulence into the reaction zone, significantly dampening differential diffusion effects.

physics.flu-dyn↗

arXiv2020

Assessing the impact of multicomponent diffusion in direct numerical simulations of premixed, high-Karlovitz, turbulent flames

Implementing multicomponent diffusion models in numerical combustion studies is computationally expensive; to reduce cost, numerical simulations commonly use mixture-averaged diffusion treatments or simpler models. However, the accuracy and appropriateness of mixture-averaged diffusion has not been verified for three-dimensional, turbulent, premixed flames. In this study we evaluated the role of multicomponent mass diffusion in premixed, three-dimensional high Karlovitz-number hydrogen, n-heptane, and toluene flames, representing a range of fuel Lewis numbers. We also studied a premixed, unstable two-dimensional hydrogen flame due to the importance of diffusion effects in such cases. Our comparison of diffusion flux vectors revealed differences of 10-20% on average between the mixture-averaged and multicomponent diffusion models, and greater than 40% in regions of high flame curvature. Overall, however, the mixture-averaged model produces small differences in diffusion flux compared with global turbulent flame statistics. To evaluate the impact of these differences between the two models, we compared normalized turbulent flame speeds and conditional means of species mass fraction and source term. We found differences of 5-20% in the mean normalized turbulent flame speeds, which seem to correspond to differences of 5-10% in the peak fuel source terms. Our results motivate further study into whether the mixture-averaged diffusion model is always appropriate for DNS of premixed turbulent flames.

physics.flu-dyn↗

arXiv2019

A fast, low-memory, and stable algorithm for implementing multicomponent transport in direct numerical simulations

Implementing multicomponent diffusion models in reacting-flow simulations is computationally expensive due to the challenges involved in calculating diffusion coefficients. Instead, mixture-averaged diffusion treatments are typically used to avoid these costs. However, to our knowledge, the accuracy and appropriateness of the mixture-averaged diffusion models has not been verified for three-dimensional turbulent premixed flames. In this study we propose a fast,efficient, low-memory algorithm and use that to evaluate the role of multicomponent mass diffusion in reacting-flow simulations. Direct numerical simulation of these flames is performed by implementing the Stefan-Maxwell equations in NGA. A semi-implicit algorithm decreases the computational expense of inverting the full multicomponent ordinary diffusion array while maintaining accuracy and fidelity. We first verify the method by performing one-dimensional simulations of premixed hydrogen flames and compare with matching cases in Cantera. We demonstrate the algorithm to be stable, and its performance scales approximately with the number of species squared. Then, as an initial study of multicomponent diffusion, we simulate premixed, three-dimensional turbulent hydrogen flames, neglecting secondary Soret and Dufour effects. Simulation conditions are carefully selected to match previously published results and ensure valid comparison. Our results show that using the mixture-averaged diffusion assumption leads to a 15% under-prediction of the normalized turbulent flame speed for a premixed hydrogen-air flame. This difference in the turbulent flame speed motivates further study into using the mixture-averaged diffusion assumption for DNS of moderate-to-high Karlovitz number flames.

physics.flu-dyn↗

arXiv2013

Turbulence-Flame Interaction

A fluid dynamics video was created using data from a Direct Numerical Simulation of a premixed n-heptane flame at high Karlovitz number. The magnitude of vorticity and progress variable(a monotonically increasing variable through the flame) illustrate the turbulence-flame interaction.

physics.flu-dyn↗