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Guillaume Boussinot

Publications and source records attributed to Guillaume Boussinot.

3 recordsLinked to original sources

Pattern formation during melting of lamellar eutectics

We present a study of the melting dynamics of a two-phase eutectic solid. In situ, thin-sample experiments using a transparent eutectic alloy and two-dimensional phase field simulations calibrated for the very same alloy are combined to assess pattern formation during directional melting in a temperature gradient. Depending on the melting velocity $V_m$ and the spacing $\lambda$ of the pre-solidified lamellar microstructure, an unexpectedly rich diversity of melting patterns is observed, with good agreement between experiments and simulations. We unravel the different physical mechanisms leading to this diversity, and establish the scaling behaviors of (i) the penetration of the liquid along the solid-solid interface at large $V_m$, (ii) the thickening of the primary-phase fingers at low $V_m$, and (iii) a period-doubling instability for small $\lambda$ values. Our study provides a fundamental basis for further investigations of eutectic melting, including additive manufacturing during which melting/solidification cycles take place.

cond-mat.mtrl-sci

Bi-phasic lithiation/delithiation dynamics in Li-ion batteries: application of the Smoothed Boundary Method in the phase field model

An appropriate description of the lithiation/delithiation dynamics in bi-phasic primary cathode particles of Li-ion batteries requires an accurate treatment of the conditions holding at the interface between the particle and the surrounding liquid electrolyte. We propose a phase field model based on the Allen-Cahn approach within which the particle-electrolyte interface is smooth (Smoothed Boundary Method - SBM), in order to simulate arbitrarily shaped particles. Surface terms are added to the evolution equations, and SBM calculations are compared with benchmark simulations for which the boundary conditions are explicitly imposed at the borders of the calculation domain. We find that strengthening factors for the surface terms are needed in order to achieve the desired conditions for the phase and elastic fields, and to correctly reproduce the level of stress within the particle. This reveals crucial in the context of Li-ion batteries for an accurate prediction of the Li insertion/extraction rate and the Li diffusion behavior. We perform also a simulation under potentio-static conditions with a full coupling of the different physical processes at play. It illustrates the applicability of our approach and demonstrates the capabilities of the SBM for a simulation of lithiation/delithiation dynamics with coupled electrochemistry and mechanics.

cond-mat.mtrl-sci

Modeling of grain boundary dynamics using amplitude equations

We discuss the modelling of grain boundary dynamics within an amplitude equations description, which is derived from classical density functional theory or the phase field crystal model. The relation between the conditions for periodicity of the system and coincidence site lattices at grain boundaries is investigated. Within the amplitude equations framework we recover predictions of the geometrical model by Cahn and Taylor for coupled grain boundary motion, and find both $\langle100\rangle$ and $\langle110\rangle$ coupling. No spontaneous transition between these modes occurs due to restrictions related to the rotational invariance of the amplitude equations. Grain rotation due to coupled motion is also in agreement with theoretical predictions. Whereas linear elasticity is correctly captured by the amplitude equations model, open questions remain for the case of nonlinear deformations.

cond-mat.mtrl-sci