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Gwo-Tzong Huang

Publications and source records attributed to Gwo-Tzong Huang.

2 recordsLinked to original sources

In-Plane Differentiation and Out-of-Plane Coherence in Superconducting K$_{2-x}$Fe$_{4+y}$Se$_5$

The structural link between superconductivity and anomalous $d_2$ diffraction signatures in K$_{2-x}$Fe$_{4+y}$Se$_5$ remains unresolved. Their appearance is accompanied by pronounced host-lattice evolution rather than a static structural background. Using high-resolution synchrotron X-ray diffraction, we show that excess Fe alters the vacancy-ordered host lattice, with structural differences between superconducting and nonsuperconducting states emerging before the $d_2$ features appear. All observed $d_2$ reflections can be described using two characteristic in-plane spacings and a nearly common low-temperature $c$ parameter. Temperature-dependent measurements reveal that superconductivity is associated with persistent in-plane differentiation and enhanced Fe-layer coherence along the $c$ axis. These results establish host-lattice evolution as the common structural origin linking the $d_2$ family and superconductivity, and suggest that the host-lattice differentiation identified here represents a structural analogue of the symmetry redistribution in FeSe.

cond-mat.supr-con↗

Role of the Extra-Fe in K2-xFe4+ySe5 superconductors

The exact superconducting phase of K2-xFe4+ySe5 has yet conclusively decided since its discovery due to its intrinsic multiphase in early material. In an attempt to resolve the mystery, we have carried out systematic structural studies on a set of well controlled samples with exact chemical stoichiometry K2-xFe4+xSe5 (x=0~0.3) that are heat-treated at different temperatures. Our investigations, besides the determination of superconducting transition, focus on the detailed temperature evolution of the crystalline phases using high resolution synchrotron radiation X-ray diffraction. Our results show that superconductivity appears only in those samples been treated at high enough temperature and then quenched to room temperature. The volume fraction of superconducting transition strongly depends on the annealing temperature used. The most striking result is the observation of a clear contrast in crystalline phase between the non-superconducting parent compound K2Fe4Se5 and the superconducting K2-xFe4+ySe5 samples. The x-ray diffraction patterned can be well indexed to the phase with I4/m symmetry in all temperature investigated. However, we need two phases with similar I4/m symmetry but different parameters to best fit the data at temperature below the Fe-vacancy order temperature. The results strongly suggest that superconductivity in K2-xFe4+ySe5 critically depends on the occupation of Fe atoms on the originally empty 4d site.

cond-mat.supr-con↗