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H Olivares-Pilon

Publications and source records attributed to H Olivares-Pilon.

2 recordsLinked to original sources

Nodal algebraic curves and entropy diagnostics in degenerate two-dimensional harmonic-oscillator shells

Degeneracy allows the nodal structure of a quantum state to vary without changing its energy. We study this effect for real superpositions in the fixed-energy shells of the two-dimensional isotropic harmonic oscillator. In Cartesian coordinates $(x,y)$, any such state in the $N$th shell has the parametrized form $ψ_N(x,y;\mathbf{c})=ψ_0(x,y)\,P_N(x,y;\mathbf{c})$, where $ψ_0$ is the non-vanishing ground state and the real coefficients $\mathbf{c}$ determine the polynomial factor $P_N$. The nodal set is exactly the algebraic curve $P_N=0$. Thus, varying $\mathbf{c}$ reshapes this curve at fixed energy. We show that its topology can change only when it develops a finite singular point, $P_N=\nabla P_N=0$, or when two asymptotic nodal directions merge. We characterize this geometry using three diagnostics: the nodal-domain entropy $S_{\rm dom}$, the Cartesian mutual information $I(x;y)$, and the entropic uncertainty sum $S_r+S_p$, which respectively probe probability redistribution among nodal domains, coordinate correlations, and global position-momentum delocalization. The lowest shells reveal a clear hierarchy. For $N=1$, mixing only rotates a nodal line. Along a representative $N=2$ path, a closed conic passes through parallel lines into a hyperbola-type curve; $S_{\rm dom}$ clearly detects this transition, while $S_r+S_p$ remains smooth. For $N=3$, merging asymptotic directions brings smooth cubic branches close together and enhances both $S_{\rm dom}$ and $I(x;y)$. These signatures are accessible in Hermite-Gaussian structured light and nearly isotropic trapped oscillators.

quant-ph

Helium-like ions $(Z,e,e)$ in Lagrange Mesh method, interpolating the highly-accurate energy spectra vs. Z

Two alternative approaches for studying Helium-like atomic ions in non-relativistic quantum mechanics are proposed: (I) a numerical approach, based on the Lagrange-mesh method which can easily reach up to 14-15 significant digits in the energy spectrum for any nuclear charge $Z$ with modest CPU time in single processor mode and (II) a highly-accurate, few-parametric interpolation formula for the energies {\it vs.} $Z$. The interpolation formula of general nature is proposed, it can be applied to the energies of any excited state of the helium-like sequence. It is based on matching the $1/Z$-expansion at large $Z$ and the Puiseux expansion with integer and half-integer powers around the so-called second critical charge $Z_B$, introduced by F and D Stillinger (1969, 1974), confirmed by the present authors in 2019 for the ground state $1^1 S$, then revisited here, and extended to the excited states in the present work. For example for the first two spin-singlet $1^1 S$, $2^1 S$ and the first two spin-triplet $2^3 S$, $3^3 S$ states this interpolation formula with nine free parameters can reach an accuracy of 10-14 significant digits (s.d.) in the energies for any physically-relevant nuclear charge $Z$, giving absolute accuracy at large $Z$. Many results are obtained for the first time.

quant-ph