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H. A. Bunn

Publications and source records attributed to H. A. Bunn.

2 recordsLinked to original sources

Tracing the sulfur depletion in starless and pre-stellar cores

Sulfur is one of the most abundant elements in the Universe, yet the sulfur budget inferred from the observed sulfur-bearing molecules in dense cores is significantly lower than expected. Starless and pre-stellar cores represent the earliest stages of star formation and provide a laboratory for studying the physical and chemical processes that cause sulfur depletion. We aim to constrain sulfur chemistry in dense cores by measuring abundances of sulfur-bearing molecules and how they reflect core evolution and environmental effects. We observed nine cores in the Taurus Molecular Cloud, targeting 13 sulfur-bearing molecules, including CS, CCS, C$_3$S, OCS, SO, SO$_2$, H$_2$CS, and isotopologs. Molecular abundances and six abundance ratios were compared to three evolutionary tracers: H$_2$ column density, N$_2$D$^+$/N$_2$H$^+$, and the CO depletion factor. We also compared observations with 0D chemical models with different initial sulfur abundances. We find variations in abundances across cores. L1517B exhibits low abundances and a high depletion factor, whereas L1495B shows enhanced levels in oxygen-bearing species within the L1495 filament. Ratios tracing carbon- and oxygen-bearing species (CCS/$^{34}$SO and C$^{34}$S/$^{34}$SO) decrease with increasing H$_2$ column density and N$_2$D$^+$/N$_2$H$^+$ ratio. Other species and ratios show weak or no correlation with tracers. Models reproduce OCS, H$_2$CS, and HDCS reasonably well, but not all species simultaneously, especially between carbon- and oxygen-bearing molecules. The variations and lack of consistent correlations suggest that a single evolutionary parameter cannot describe sulfur chemistry and that the local environmental conditions strongly influence the observed abundances. Reproducing the full sample of sulfur-bearing molecules would require improved chemical networks and models that account for the core's physical structure.

astro-ph.GA

High deuteration of methanol in L1544

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical conditions greatly favor deuteration processes. Deuteration maps are a measure of the effectiveness of the deuteration across the core, and they are useful to study both the deuteration as well as the formation mechanism of the main species. Methanol is the simplest O-bearing complex organic molecule (COM) detected in the interstellar medium (ISM). It represents the beginning of molecular complexity in star-forming regions, thus a complete understanding of its formation and deuteration is a necessary step to understand the development of further chemical complexity. In this paper, we use single-dish observations with the IRAM 30 m telescope and state-of-the-art chemical models to investigate the deuteration of methanol towards the prototypical pre-stellar core L1544. We also compare the results of the chemical models with previous observations of deuterated methanol towards the pre-stellar cores HMM1 and L694-2. The spectra extracted from the CHD$_2$OH map show that the emission is concentrated in the center and towards the north-west of the core. Using deep observations towards the dust and the methanol peaks of the core, we derive a very large deuterium fraction for methanol ($\sim20\%$) towards both peaks. The comparison of our observational results with chemical models has highlighted the importance of H-abstraction processes in the formation and deuteration of methanol. Deep observations combined with state-of-the-art chemical models are of fundamental importance in understanding the development of molecular complexity in the ISM. Our analysis also shows the importance of non-LTE effects when measuring the D/H ratios in methanol.

astro-ph.GA