arXiv subjects

H. Bock

Publications and source records attributed to H. Bock.

3 recordsLinked to original sources

arXiv2026

Charge Transport in Thin-Film Transistors Based on Liquid-Crystalline Phthalocyanines

We investigate a series of liquid-crystalline phthalocyanines (metal-free and Cu, Zn, Ni, Co complexes) by correlating their vibrational signatures with their electronic performance in organic thin-film transistors (OTFTs). Raman spectroscopy reveals metal-dependent distortions of the phthalocyanine macrocycle, reflected in systematic shifts of the C-N-C and M-N vibrational modes. When integrated into OTFTs, all compounds exhibit markedly enhanced current response under ultrahigh vacuum compared to an N2-rich environment, demonstrating that intrinsic charge transport is strongly suppressed by atmospheric species. Temperature-dependent measurements (100-300 K) show clear threshold-voltage shifts driven by deep interface and bulk traps, while all devices display thermally activated mobility with low activation energies (14-20 meV). These results highlight how mesomorphic order, metal coordination, and environmental conditions collectively govern charge transport in liquid-crystalline phthalocyanines, offering design guidelines for their use as orientable semiconducting materials in organic electronics.

cond-mat.mtrl-sci↗

arXiv2001

Day-Scale Variability of 3C 279 and Searches for Correlations in Gamma-Ray, X-Ray, and Optical Bands

Light curves of 3C 279 are presented in optical (R-band), X-rays (RXTE/PCA), and gamma rays (CGRO/EGRET) for 1999 Jan-Feb and 2000 Jan-Mar. During both of those epochs the gamma-ray levels were high, and all three observed bands demonstrated substantial variation, on time scales as short as one day. Correlation analyses provided no consistent pattern, although a rather significant optical/gamma-ray correlation was seen in 1999, with a gamma-ray lag of ~2.5 days, and there are other suggestions of correlations in the light curves. For comparison, correlation analysis is also presented for the gamma-ray and X-ray light curves during the large gamma ray flare in 1996 Feb and the two gamma-bright weeks leading up to it; the correlation at that time was strong, with a gamma-ray/X-ray offset of no more than 1 day.

astro-ph↗

arXiv1999

Unusual radio variability in the BL Lac object 0235+164

We present radio observations at three frequencies and contemporaneous optical monitoring of the peculiar BL Lac object AO 0235+164. During a three-week campaign with the VLA we observed intraday variability in this source and found a distinct peak which can be identified throughout the radio frequencies and tentatively connected to the R-band variations. This event is characterized by unusual properties: its strength increases, and its duration decreases with wavelength, and it peaks earlier at 20cm than at 3.6 and 6cm. We discuss several generic models (a `standard' shock-in-jet model, a precessing beam, free-free-absorption in a foreground screen, interstellar scattering, and gravitational microlensing), and explore whether they can account for our observations. Most attempts at explaining the data on 0235+164 require an extremely small source size, which can be reconciled with the $10^{12}$ K inverse Compton limit only when the Doppler factor of the bulk flow is of order 100. However, none of the models is completely satisfactory, and we suggest that the observed variability is due to a superposition of intrinsic and propagation effects.

astro-ph↗