arXiv subjects

H. D. Zhou

Publications and source records attributed to H. D. Zhou.

121 records · Page 7Linked to original sources

arXiv2011

High pressure sequence of Ba_3NiSb_2O_9 structural phases: new $S = 1$ quantum spin-liquids based on Ni^{2+}

By using a high pressure, high temperature (HPHT) technique, the antiferromagnetically ordered ($T_N$ = 13.5 K) 6H-A phase of Ba$_3$NiSb$_2$O$_9$ was transformed into two new gapless quantum spin liquid(QSL) candidates with S=1 (Ni$^{2+}$) moments: the 6H-B phase with a Ni$^{2+}$-triangular lattice and the 3C-phase with a Ni$^{2+}$-three-dimensional (3D) edge-shared tetrahedral lattice. Both compounds show no magnetic order down to 0.35 K despite Curie-Weiss temperatures $θ_{CW}$ of -75.5 K (6H-B) and -182.5 K (3C), respectively. Below $\sim 25$ K the magnetic susceptibility of the 6H-B phase saturates to a constant value $χ_0 = 0.013 $ emu/mol which is followed below 7 K, by a linear-temperature dependent magnetic specific heat ($C_M$) displaying a giant coefficient $γ$ = 168 mJ/mol-K$^2$. Both observations suggest the development of a Fermi-liquid like ground state characterized by a Wilson ratio of 5.6 in this insulating material. For the 3C phase, the $C_M \propto T^2$ behavior indicates a unique S=1, 3D QSL ground-state.

cond-mat.str-el↗

arXiv2011

AC Susceptibility and Electron Spin Resonance Studies of Spin Dynamics in n Ba$_3$NbFe$_3$Si$_2$O$_{14}$: A Geometrically Frustrated Lattice

We report ac susceptibility and high-frequency electron spin resonance (ESR) measurements on the geometrically frustrated compound Ba$_3$NbFe$_3$Si$_2$O$_{14}$ with the Néel temperature $T_N=27 K$. An unusually large frequency-dependence of ac susceptibility in the temperature range of 20 - 100 K reveals a spin-glass-like behavior, signalling the presence of frustration related slow magnetic fluctuations. ESR experiments show a multi-step magnetic and spin chirality ordering process. For temperatures above 30 K, the weak temperature dependence of the ESR linewidth $ΔH_{pp}\propto T^{-p}$ with $p=0.8$ evidences the development of short-range correlated spin clusters. The critical broadening with $p =1.8$, persisting down to 14 K, indicates the coexistence of the short-range ordered spin clusters within a helically ordered state. Below 9.5 K, the anomalously large decrease of the linewidth reveals the stabilization of a long-range ordered state with one chirality.

cond-mat.str-el↗

arXiv2010

Rapidly fluctuating orbital occupancy above the orbital ordering transition in spin-gap compounds

Several spin systems with low dimensionality develop a spin-dimer phase within a molecular orbital below TS, competing with long-range antiferromagnetic order. Very often, preferential orbital occupancy and ordering are the actual driving force for dimerization, as in the so-called orbitally-driven spin-Peierls compounds (MgTi2O4, CuIr2S4, La4Ru2O10, NaTiSi2O6, etc.). Through a microscopic analysis of the thermal conductivity k (T) in La4Ru2O10, we show that the orbital occupancy fluctuates rapidly above TS, resulting in an orbital-liquid state. The strong orbital-lattice coupling introduces dynamic bond-length fluctuations that scatter the phonons to produce a k (T) proportional to T (i.e. glass-like) above TS. This phonon-glass to phonon-crystal transition is shown to occur in other spin-dimer systems, like NaTiSi2O6, pointing to a general phenomenon.

cond-mat.str-el↗

arXiv2010

Surface Reconstruction of Hexagonal Y-doped HoMnO3 and LuMnO3 studied using low-energy electron diffraction

We have investigated the (0001) surfaces of several hexagonal manganite perovskites by low-energy electron diffraction (LEED) in order to determine if the surface periodicity is different from that of the bulk materials. These LEED studies were conducted using near-normal incidence geometry with a low energy electron microscope (LEEM)/LEED apparatus from room temperature to 1200 degrees Celsius and with an electron energy in the range of 15-50 eV. Diffraction patterns showed features of bulk-terminated periodicity as well as a 2\times2 surface reconstruction. Possible origins for this surface reconstruction structure are discussed and comparisons are made with surface studies of other complex oxides.

cond-mat.str-el↗

arXiv2009

Magnetic field induced quantum phase transition of the $S = 1/2$ antiferromagnet $K_2NaCrO_8$

The magnetic properties of alkali-metal peroxychromate K$_2$NaCrO$_8$ are governed by the $S = 1/2$ pentavalent chromium cation, Cr$^{5+}$. Specific heat, magnetocalorimetry, ac magnetic susceptibility, torque magnetometry, and inelastic neutron scattering data have been acquired over a wide range of temperature, down to 60 mK, and magnetic field, up to 18 T. The magnetic interactions are quasi-two-dimensional prior to long-range ordering, where $T_N = 1.66$ K in $H = 0$. In the $T \to 0$ limit, the magnetic field tuned antiferromagnetic-ferromagnetic phase transition suggests a critical field $H_c = 7.270$ T and a critical exponent $α= 0.481 \pm 0.004$. The neutron data indicate the magnetic interactions may extend over intra-planar nearest-neighbors and inter-planar next-nearest-neighbor spins.

cond-mat.str-el↗

arXiv2009

Two inequivalent sublattices and orbital ordering in MnV2O4 studied by 51V NMR

We report detailed 51V NMR spectra in a single crystal of MnV2O4. The vanadium spectrum reveals two peaks in the orbitally ordered state, which arise from different internal hyperfine fields at two different V sublattices. These internal fields evolve smoothly with externally applied field, and show no change in structure that would suggest a change of the orbital ordering. The result is consistent with the orbital ordering model recently proposed by Sarkar et al. [Phys. Rev. Lett. 102, 216405 (2009)] in which the same orbital that is a mixture of t_2g orbitals rotates by about 45$^\circ$ alternately within and between orbital chains in the I4_1/a tetragonal space group.

cond-mat.str-el↗

arXiv2008

Dynamical Behavior of Spins in the Rare-Earth Kagomé Pr$_3$Ga$_5$SiO$_{14}$

We report on the use of $^{69,71}$Ga nuclear magnetic resonance to probe spin dynamics in the rare-earth kagomé system Pr$_3$Ga$_5$SiO$_{14}$. We find that the spin-lattice relaxation rate $^{69}1/T_1$ exhibits a maximum around 30 K, below which the Pr$^{3+}$ spin correlation time $τ$ shows novel field-dependent behavior consistent with a field-dependent gap in the excitation spectrum. The spin-spin relaxation rate $^{69}1/T_{2}$ exhibits a peak at a lower temperature (10 K) below which field-dependent power-law behavior close to $T^{2}$ is observed. These results point to field-induced formation of nanoscale magnetic clusters consistent with recent neutron scattering measurements.

cond-mat.str-el↗

arXiv2008

Nanoscale freezing of the 2D spin liquid Pr$_{3}$Ga$_{5}$SiO$_{14}$

In this letter, we report on the single crystal growth and physical characterization of the distorted kagomé system Pr$_3$Ga$_5$SiO$_{14}$. It is found that at zero magnetic field the system shows no magnetic order down to 0.035 K and exhibits a $T^{2}$ behavior for the specific heat at low temperatures, indicative of a gapless 2D spin liquid state. Application of an applied field induces nanoscale islands of ordered spins, with a concomitant reduction of the $T^{2}$ specific heat term. This state could be a possible ferro-spin nematic ordering stabilized out of an unusual spin liquid state.

cond-mat.str-el↗

arXiv2008

Itinerant spin excitations near the hidden order transition in URu2Si2

By means of neutron scattering we show that the high-temperature precursor to the hidden order state of the heavy fermion superconductor URu$_{2}$Si$_{2}$ exhibits heavily damped incommensurate paramagnons whose strong energy dispersion is very similar to that of the long-lived longitudinal f-spin excitations that appear below T$_{0}$. Since the underlying local f-exchange is preserved we expect only the f-d interactions to change across the phase transition and to cause the paramagnetic damping. The damping exhibits single-ion behavior independent of wave vector and vanishes below the hidden order transition. We suggest that this arises from a transition from valence fluctuations to a hybridized f-d state below T$_{0}$. Here we present evidence that the itinerant excitations, like those in chromium, are due to Fermi surface nesting of hole and electron pockets so that the hidden order phase likely originates from a Fermi-surface instability. We identify wave vectors that span nested regions of a band calculation and that match the neutron spin crossover from incommensurate to commensurate on approach to the hidden order phase.

cond-mat.str-el↗

arXiv2007

Gapped itinerant spin excitations account for missing entropy in the hidden order state of URu$_2$Si$_2$

One of the primary goals of modern condensed matter physics is to elucidate the nature of the ground state in various electronic systems. Many correlated electron materials, such as high temperature superconductors, geometrically frustrated oxides, and low-dimensional magnets are still the objects of fruitful study because of the unique properties which arise due to poorly understood many-body effects. Heavy fermion metals - materials which have high effective electron masses due to these effects - represent a class of materials with exotic properties, such as unusual magnetism, unconventional superconductivity, and "hidden order" parameters. The heavy fermion superconductor URu2Si2 has held the attention of physicists for the last two decades due to the presence of a "hidden order" phase below 17.5 K. Neutron scattering measurements indicate that the ordered moment is 0.03 $μ_{B}$, much too small to account for the large heat capacity anomaly at 17.5 K. We present recent neutron scattering experiments which unveil a new piece of this puzzle - the spin excitation spectrum above 17.5 K exhibits well-correlated, itinerant-like spin excitations up to at least 10 meV emanating from incommensurate wavevectors. The gapping of these excitations corresponds to a large entropy release and explains the reduction in the electronic specific heat through the transition.

cond-mat.str-el↗

arXiv2007

AC susceptibility and $^{51}$V NMR study of MnV$_2$O$_4$

We report $^{51}$V zero-field NMR of manganese vanadate spinel of MnV$_2$O$_4$, together with both ac and dc magnetization measurements. The field and temperature dependence of ac susceptibilities show a reentrant-spin-glass-like behavior below the ferrimagnetic(FEM) ordering temperature. The zero-field NMR spectrum consists of multiple lines ranging from 240 MHz to 320 MHz. Its temperature dependence reveals that the ground state is given by the simultaneous formation of a long-range FEM order and a short-range order component. We attribute the spin-glass-like anomalies to freezing and fluctuations of the short-range ordered state caused by the competition between spin and orbital ordering of the V site.

cond-mat.str-el↗

arXiv2006

Quasi-2D superconductivity and Fermi-liquid behavior in bulk CaC$_6$

The intercalated graphite superconductor CaC6 with Tc ~ 11.5 K has been synthesized and characterized with magnetoresistance measurements. Above the transition, the resistivity follows a T^2 dependence up to 50 K, which suggests Fermi liquid behavior. Above 50 K, the data can be fit to the Bloch-Gruneisen model providing a Debye temperature of theta = 263 K. By using McMillan formula, we estimate the electron-phonon coupling constant of lambda = 0.85 which places this material in the intermediate-coupling regime. The upper critical field is determined parallel and perpendicular to the superconducting planes, and the dependence of the upper critical field as a function of angle suggests that this is a quasi-2D superconductivity. All of these measurements are consistent with BCS-like superconductivity.

cond-mat.supr-con↗

arXiv2002

Jahn-Teller effect and stability of the charge-ordered state in La1-xCaxMnO3 (0.5<x<0.9) manganites

The longitudinal ultrasonic sound velocity and attenuation, the resistivity, and lattice parameters were studied as a function of temperature from 30 K to 300 K in La1-xCaxMnO3 (0.5<x<0.9). For all the samples, a dramatic stiffening of the sound velocity below the charge ordering transition temperature TCO was directly driven by distinct changes of the lattice parameters due to the formation of long range ordering of Jahn-Teller distorted MnO6 octahedra. The relative change of the sound velocity (DeltaV/V) below TCO depends on the Ca concentration x and reaches the maximum at x=0.75, implying that the effective strength of electron-lattice interaction with the Jahn-Teller distortion is the strongest at x=0.75 and hence the charge ordered state is mostly stabilized near x=0.75 and insensitive to the application of a magnetic field, which is supported by the charge transport properties under high magnetic fields up to 14T.

cond-mat.str-el↗