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H. G. E. Hentschel

Publications and source records attributed to H. G. E. Hentschel.

At least 19 recordsLinked to original sources

Creep failure of amorphous solids under tensile stress

Applying constant tensile stress to a piece of amorphous solid results in a slow extension, followed by an eventual rapid mechanical collapse. This "creep" process is of paramount engineering concern, and as such was the subject of study in a variety of materials, for more than a century. Predictive theories for $τ_w$, the expected time of collapse, are lacking, mainly due to its dependence on a bewildering variety of parameters, including temperature, system size, tensile force, but also the detailed microscopic interactions between constituents. The complex dependence of the collapse time on all the parameters is discussed below, using simulations of strip of amorphous material. Different scenarios are observed for ductile and brittle materials, resulting in serious difficulties in creating an all-encompassing theory that could offer safety measures for given conditions. A central aim of this paper is to employ scaling concepts, to achieve data collapse for the probability distribution function (pdf) of $\ln{τ_w}$. The scaling ideas result in a universal function which provides a prediction of the pdf of $\ln{τ_w}$ for out-of-sample systems, from measurements at other values of these parameters. The predictive power of the scaling theory is demonstrated for both ductile and brittle systems. Finally, we present a derivation of universal scaling function for brittle materials. The ductile case appears to be due to a plastic necking instability and is left for future research.

cond-mat.soft↗

Scaling Theory for Wöhler plots in amorphous solids under cyclic forcing

In mechanical engineering Wöhler plots serve to measure the average number of load cycles before materials break, as a function of the maximal stress in each cycle. Although such plots are prevalent in engineering for more than 150 years, their theoretical understanding is lacking. Recently a scaling theory of Wöhler plots in the context of cyclic bending was offered [1]. Here we elaborate further on cyclic bending and extend the considerations to cyclic tensile loads on an amorphous strip of material; the scaling theory applies to both types of cyclic loading equally well. On the basis of atomistic simulations we conclude that the crucial quantities to focus on are the accumulated damage and the average damage per cycle. The dependence of these quantities on the loading determines the statistics of the number of cycles to failure. Finally we consider the probability distribution functions of the number of cycles to failure and demonstrate that the scaling theory allows prediction of these distributions at one value of the forcing amplitude from measurements and another value.

cond-mat.soft↗

Fatigue and Collapse of Cyclically Bent Strip of Amorphous Solid

Fatigue caused by cyclic bending of a piece of material, resulting in its mechanical failure, is a phenomenon that had been studied for ages by engineers and physicists alike. In this Letter we study such fatigue in a strip of athermal amorphous solid. On the basis of atomistic simulations we conclude that the crucial quantity to focus on is the {\em accumulated damage}. Although this quantity exhibits large sample-to-sample fluctuations, its dependence on the loading determines the statistics of the number of cycles to failure. Thus we can provide a scaling theory for the Wöhler plots of mean number of cycles for failure as a function of the loading amplitude.

cond-mat.soft↗

Fatigue and failure of a polymer chain under tension

The rupture of a polymer chain maintained at temperature $T$ under fixed tension is prototypical to a wide array of systems failing under constant external strain and random perturbations. Past research focused on analytic and numerical studies of the mean rate of collapse of such a chain. Surprisingly, an analytic calculation of the probability distribution function (PDF) of collapse rates appears to be lacking. Since rare events of rapid collapse can be important and even catastrophic, we present here a theory of this distribution, with a stress on its tail of fast rates. We show that the tail of the PDF is a power law with a {\em universal} exponent that is theoretically determined. Extensive numerics validate the offered theory. Lessons pertaining to other problems of the same type are drawn.

cond-mat.soft↗

Diffusion in Agitated Frictional Granular Matter Near the Jamming Transition

We study agitated frictional disks in two dimensions with the aim of developing a scaling theory for their diffusion over time. As a function of the area fraction $ϕ$ and mean-square velocity fluctuations $\langle v^2\rangle$ the mean-square displacement of the disks $\langle d^2\rangle$ spans 4-5 orders of magnitude. The motion evolves from a subdiffusive form to a complex diffusive behabvior at long times. The statistics of $\langle d^n\rangle$ at all times are multiscaling, since the probability distribution function (pdf) of displacements has very broad wings. Even where a diffusion constant can be identified it is a complex function of $ϕ$ and $\langle v^2\rangle$. By identifying the relevant length and time scales and their interdependence one can rescale the data for the mean square displacement and the pdf of displacements into collapsed scaling functions for all $ϕ$ and $\langle v^2\rangle$. These scaling functions provide a predictive tool, allowing to infer from one set of measurements (at a given $ϕ$ and $\langle v^2\rangle$) what are the expected results at any value of $ϕ$ and $\langle v^2\rangle$.

cond-mat.soft↗

Stochastic Approach to Plasticity and Yield in Amorphous Solids

We focus on the probability distribution function (pdf) $P(Δγ; γ)$ where $Δγ$ are the {\em measured} strain intervals between plastic events in an athermal strained amorphous solids, and $γ$ measures the accumulated strain. The tail of this distribution as $Δγ\to 0$ (in the thermodynamic limit) scales like $Δγ^η$. The exponent $η$ is related via scaling relations to the tail of the pdf of the eigenvalues of the {\em plastic modes} of the Hessian matrix $P(λ)$ which scales like $λ^θ$, $η=(θ-1)/2$. The numerical values of $η$ or $θ$ can be determined easily in the unstrained material and in the yielded state of plastic flow. Special care is called for in the determination of these exponents between these states as $γ$ increases. Determining the $γ$ dependence of the pdf $P(Δγ; γ)$ can shed important light on plasticity and yield. We conclude that the pdf's of both $Δγ$ and $λ$ are not continuous functions of $γ$. In slowly quenched amorphous solids they undergo two discontinuous transitions, first at $γ=0^+$ and then at the yield point $γ=γ_{_{\rm Y}}$ to plastic flow. In quickly quenched amorphous solids the second transition is smeared out due to the non existing stress peak before yield. The nature of these transitions and scaling relations with the system size dependence of $\langle Δγ\rangle$ are discussed.

cond-mat.soft↗

Derivation of the Johnson-Samwer $T^{(2/3)}$ Temperature Dependence of the Yield Strain in Metallic Glasses

Metallic Glasses are prone to fail mechanically via a shear-banding instability. In a remarkable paper Johnson and Samwer demonstrated that this failure enjoys a high degree of universality in the sense that a large group of metallic glasses appears to possess a yield-strain that decreases with temperature following a $-T^{2/3}$ law up to logarithmic corrections. In this Letter we offer a theoretical derivation of this law. We show that our formula fits very well simulational data on typical amorphous solids.

cond-mat.soft↗

Local elastic response measured near the colloidal glass transition

We examine the response of a dense colloidal suspension to a local force applied by a small magnetic bead. For small forces, we find a linear relationship between the force and the displacement, suggesting the medium is elastic, even though our colloidal samples macroscopically behave as fluids. We interpret this as a measure of the strength of colloidal caging, reflecting the proximity of the samples' volume fractions to the colloidal glass transition. The strain field of the colloidal particles surrounding the magnetic probe appears similar to that of an isotropic homogeneous elastic medium. When the applied force is removed, the strain relaxes as a stretched exponential in time. We introduce a model that suggests this behavior is due to the diffusive relaxation of strain in the colloidal sample.

cond-mat.soft↗

Temperature-dependent proximity magnetism in Pt

We experimentally demonstrate the existence of magnetic coupling between two ferromagnets separated by a thin Pt layer. The coupling remains ferromagnetic regardless of the Pt thickness, and exhibits a significant dependence on temperature. Therefore, it cannot be explained by the established mechanisms of magnetic coupling across nonmagnetic spacers. We show that the experimental results are consistent with the presence of magnetism induced in Pt in proximity to ferromagnets, in direct analogy to the well-known proximity effects in superconductivity.

cond-mat.mtrl-sci↗

The Plastic Response of Magnetoelastic Amorphous Solids

We address the cross effects between mechanical strains and magnetic fields on the plastic response of magnetoelastic amorphous solids. It is well known that plasticity in non-magnetic amorphous solids under external strain $γ$ is dominated by the co-dimension 1 saddle-node bifurcation in which an eigenvalue of the Hessian matrix vanishes at $γ_P$ like $\sqrt{γ_P-γ}$. This square-root singularity determines much of the statistical physics of elasto-plasticity, and in particular that of the stress-strain curves under athermal-quasistatic conditions. In this Letter we discuss the much richer physics that can be expected in magnetic amorphous solids. Firstly, magnetic amorphous solids exhibit co-dimension 2 plastic instabilities, when an external strain and an external magnetic field are applied simultaneously. Secondly, the phase diagrams promise a rich array of new effects that have been barely studied; this opens up a novel and extremely rich research program for magnetoplastic materials.

cond-mat.stat-mech↗

Statistical Mechanics of Glass Formation in Molecular Liquids with OTP as an Example

We extend our statistical mechanical theory of the glass transition from examples consisting of point particles to molecular liquids with internal degrees of freedom. As before, the fundamental assertion is that super-cooled liquids are ergodic, although becoming very viscous at lower temperatures, and are therefore describable in principle by statistical mechanics. The theory is based on analyzing the local neighborhoods of each molecule, and a statistical mechanical weight is assigned to every possible local organization. This results in an approximate theory that is in very good agreement with simulations regarding both thermodynamical and dynamical properties.

cond-mat.stat-mech↗

Do Athermal Amorphous Solids Exist?

We study the elastic theory of amorphous solids made of particles with finite range interactions in the thermodynamic limit. For the elastic theory to exist one requires all the elastic coefficients, linear and nonlinear, to attain a finite thermodynamic limit. We show that for such systems the existence of non-affine mechanical responses results in anomalous fluctuations of all the nonlinear coefficients of the elastic theory. While the shear modulus exists, the first nonlinear coefficient B_2 has anomalous fluctuations and the second nonlinear coefficient B_3 and all the higher order coefficients (which are non-zero by symmetry) diverge in the thermodynamic limit. These results put a question mark on the existence of elasticity (or solidity) of amorphous solids at finite strains, even at zero temperature. We discuss the physical meaning of these results and propose that in these systems elasticity can never be decoupled from plasticity: the nonlinear response must be very substantially plastic.

cond-mat.stat-mech↗

The Effective Temperature in Elasto-Plasticity of Amorphous Solids

An effective temperature $T_{\rm eff}$ which differs from the bath temperature is believed to play an essential role in the theory of elasto-plasticity of amorphous solids. The definition of a measurable $T_{\rm eff}$ in the literature on sheared solids suffers however from being connected to a fluctuation-dissipation theorem which is correct only in equilibrium. Here we introduce a natural definition of $T_{\rm eff}$ based on measurable structural features without recourse to any questionable assumption. The value of $T_{\rm eff}$ is connected, using theory and scaling concepts, to the flow stress and the mean energy that characterize the elasto-plastic flow.

cond-mat.stat-mech↗

Size of Plastic Events in Strained Amorphous Solids at Finite Temperatures

We address the system-size dependence of typical plastic flow events when an amorphous solid is put under a fixed external strain rate at a finite temperature. For system sizes that are accessible to numerical simulations at reasonable strain rates and at low temperatures the magnitude of plastic events grows with the system size. We explain however that this must be a finite size effect; for larger systems there exist two cross-over length-scales $ξ_1$ and $ξ_2$, the first determined by the elastic time-scale and the second by the thermal energy-scale. For system of linear size $L$ larger than any of these scales the magnitude of plastic events must be bounded. For systems of size $L\gg ξ$ there must exist $(L/ξ)^d$ uncorrelated plastic events which occur simultaneously. We present a scaling theory that culminates with the dependence of the cross-over scales on temperature and strain rate. Finally we relate these findings to the temperature and size dependence of the stress fluctuations. We comment on the importance of these considerations for theories of elasto-plasticity.

cond-mat.stat-mech↗

Theory of Specific Heat in Glass Forming Systems

Experimental measurements of the specific heat in glass-forming systems reveal anomalies in the temperature dependence of the specific heat, including the so called "specific heat peak" in the vicinity of the glass transition. The aim of this paper is to provide theoretical explanations of these anomalies in general and a quantitative theory in the case of a simple model of glass-formation. We first present new simulation results for the specific heat in a classical model of a binary mixture. We show that in addition to the formerly observed specific heat peak there is a second peak at lower temperatures which was not observable in earlier simulations. Second, we present a general relation between the specific heat and the bulk modulus and thus offer a smooth connection between the liquid and amorphous solid states. The central result of this paper is a connection between the micro-melting of clusters in the system and the appearance of specific heat peaks. We relate the two peaks to changes in the bulk and shear moduli. We propose that the phenomenon of glass-formation is accompanied by a fast change in the bulk and the shear moduli, but these fast changes occur in different ranges of the temperature. Lastly, we demonstrate how to construct a theory of the frequency dependent complex specific heat, expected from heterogeneous clustering in the liquid state of glass formers. A specific example is provided in the context of our model for the dynamics of glycerol. The theoretical frequency dependent specific heat agrees well with experimental measurements on glycerol. We conclude the paper by stating that there is nothing universal about the temperature dependence of the specific heat in glass formers - unfortunately one needs to understand each case by itself.

cond-mat.stat-mech↗

Non-Universality of the Specific Heat in Glass Forming Systems

We present new simulation results for the specific heat in a classical model of a binary mixture glass-former in two dimensions. We show that in addition to the formerly observed specific heat peak there is a second peak at lower temperatures which was not observable in earlier simulations. This is a surprise, as most texts on the glass transition expect a single specific heat peak. We explain the physics of the two specific heat peaks by the micro-melting of two types of clusters. While this physics is easily accessible, the consequences are that one should not expect any universality in the temperature dependence of the specific heat in glass formers.

cond-mat.mtrl-sci↗

Theory of Relaxation Dynamics in Glass-Forming Hydrogen-Bonded Liquids

We address the relaxation dynamics in hydrogen-bonded super-cooled liquids near the glass transition, measured via Broad-Band Dielectric Spectroscopy (BDS). We propose a theory based on decomposing the relaxation of the macroscopic dipole moment into contributions from hydrogen bonded clusters of $s$ molecules, with $s_{min}\le s \le s_{max}$. The existence of $s_{max}$ is due to dynamical arrest and its value may depend on the cooling protocol and on the aging time. The existence of $s_{max}$ is translated into a sum-rule on the concentrations of clusters of size $s$. We construct the statistical mechanics of the super-cooled liquid subject to this sum-rule as a constraint, to estimate the temperature-dependent density of clusters of size $s$. With a theoretical estimate of the relaxation time of each cluster we provide predictions for the real and imaginary part of the frequency dependent dielectric response. The predicted spectra and their temperature dependence are in accord with measurements, explaining a host of phenomenological fits like the Vogel-Fulcher fit and the stretched exponential fit. Using glycerol as a particular example we demonstrate quantitative correspondence between theory and experiments. The theory also demonstrates that the $α$ peak and the "excess wing" stem from the same physics in this material. The theory also shows that in other hydrogen -bonded glass formers the "excess wing" can develop into a $β$ peak, depending on the molecular material parameters (predominantly the surface energy of the clusters). We thus argue that $α$ and $β$ peaks can stem from the same physics. Finally we address the BDS in constrained geometries (pores) and explain why recent experiments on glycerol did not show a deviation from bul k spectra.

cond-mat.soft↗

Entropic Studies of Cytoskeletal Motors Jamming

Can the different causes for disruption of intracellular transport be traced from the trajectories of the molecular motors on the cytoskeletal filaments? We will attempt to answer this important question in a Monte Carlo model of microtubule-motor protein interaction from the point of view of information theory.

cond-mat.soft↗