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H. Linz

Publications and source records attributed to H. Linz.

At least 73 records · Page 4Linked to original sources

Earliest phases of star formation (EPoS): Dust temperature distributions in isolated starless cores

Constraining the temperature and density structure of dense molecular cloud cores is fundamental for understanding the initial conditions of star formation. We use Herschel observations of the thermal FIR dust emission from nearby isolated molecular cloud cores and combine them with ground-based submillimeter continuum data to derive observational constraints on their temperature and density structure. The aim of this study is to verify the validity of a ray-tracing inversion technique developed to derive the dust temperature and density structure of isolated starless cores directly from the dust emission maps and to test if the resulting temperature and density profiles are consistent with physical models. Using this ray-tracing inversion technique, we derive the dust temperature and density structure of six isolated starless cloud cores. We employ self-consistent radiative transfer modeling to the derived density profiles, treating the ISRF as the only heating source. The best-fit values of local strength of the ISRF and the extinction by the outer envelope are derived by comparing the self-consistently calculated temperature profiles with those derived by the ray-tracing method. We find that all starless cores are significantly colder inside than outside, with the core temperatures showing a strong negative correlation with peak column density. This suggests that their thermal structure is dominated by external heating from the ISRF and shielding by dusty envelopes. The temperature profiles derived with the ray-tracing inversion method can be well-reproduced with self-consistent radiative transfer models.

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Inferring the evolutionary stages of the internal structures of NGC 7538 S and IRS1 from chemistry

To unambiguously diagnose the detailed physical mechanisms and the evolutionary status of high-mass star-forming regions (HMSFRs), we have performed 0.4" ($\sim1000$ AU) resolution observations towards NGC7538S and IRS1, using the Plateau de Bure Interferometer (PdBI). This paper presents a joint analysis of the 1.37 mm continuum emission and the line intensity of 15 molecular species. Assuming local thermal equilibrium, we derived molecular column densities and molecular abundances for each internal gas substructure which is spatially resolved. These derived quantities are compared with a suite of 1-D gas-grain models. NGC7538S is resolved into at least three dense gas condensations. Despite the comparable continuum intensity of these condensations, their differing molecular line emission is suggestive of an overall chemical evolutionary trend from the northeast to the southeast. Since these condensations are embedded within the same parent gas core, their differing chemical properties are the most likely due to the different warm-up histories, rather than the different dynamic timescales. Despite remaining spatially unresolved, in IRS1 we detect abundant complex organic molecules, indicating that IRS1 is the most chemically evolved hot molecular core presented here. We observe a continuum that is dominated by absorption features with at least three strong emission lines, potentially from $\rm CH_3OH$. The $\rm CH_3OH$ lines which are purely in emission have higher excitation than the ones showing purely absorption. Potential reasons for that difference are discussed. This is the first comprehensive comparison of observations of the high-mass cores NGC7538S and IRS1 and a chemical model. We have found that different chemical evolutionary stages can coexist in the same natal gas core. Our achievement illustrates the strength of chemical analysis for understanding HMSFRs.

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Far-infrared photometric observations of the outer planets and satellites with Herschel-PACS

We present all Herschel PACS photometer observations of Mars, Saturn, Uranus, Neptune, Callisto, Ganymede, and Titan. All measurements were carefully inspected for quality problems, were reduced in a (semi-)standard way, and were calibrated. The derived flux densities are tied to the standard PACS photometer response calibration, which is based on repeated measurements of five fiducial stars. The overall absolute flux uncertainty is dominated by the estimated 5% model uncertainty of the stellar models in the PACS wavelength range between 60 and 210 micron. A comparison with the corresponding planet and satellite models shows excellent agreement for Uranus, Neptune, and Titan, well within the specified 5%. Callisto is brighter than our model predictions by about 4-8%, Ganymede by about 14-21%. We discuss possible reasons for the model offsets. The measurements of these very bright point-like sources, together with observations of stars and asteroids, show the high reliability of the PACS photometer observations and the linear behavior of the PACS bolometer source fluxes over more than four orders of magnitude (from mJy levels up to more than 1000 Jy). Our results show the great potential of using the observed solar system targets for cross-calibration purposes with other ground-based, airborne, and space-based instruments and projects. At the same time, the PACS results will lead to improved model solutions for future calibration applications.

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Dust properties across the CO snowline in the HD 163296 disk from ALMA and VLA observations

To characterize the mechanisms of planet formation it is crucial to investigate the properties and evolution of protoplanetary disks around young stars, where the initial conditions for the growth of planets are set. Our goal is to study grain growth in the disk of the young, intermediate mass star HD163296 where dust processing has already been observed, and to look for evidence of growth by ice condensation across the CO snowline, already identified in this disk with ALMA. Under the hypothesis of optically thin emission we compare images at different wavelengths from ALMA and VLA to measure the opacity spectral index across the disk and thus the maximum grain size. We also use a Bayesian tool based on a two-layer disk model to fit the observations and constrain the dust surface density. The measurements of the opacity spectral index indicate the presence of large grains and pebbles ($\geq$1 cm) in the inner regions of the disk (inside $\sim$50 AU) and smaller grains, consistent with ISM sizes, in the outer disk (beyond 150 AU). Re-analysing ALMA Band 7 Science Verification data we find (radially) unresolved excess continuum emission centered near the location of the CO snowline at $\sim$90 AU. Our analysis suggests a grain size distribution consistent with an enhanced production of large grains at the CO snowline and consequent transport to the inner regions. Our results combined with the excess in infrared scattered light found by Garufi et al. (2014) suggests the presence of a structure at 90~AU involving the whole vertical extent of the disk. This could be evidence for small scale processing of dust at the CO snowline.

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Continuum sources from the THOR survey between 1 and 2 GHz

We carried out a large program with the Karl G. Jansky Very Large Array (VLA): "THOR: The HI, OH, Recombination line survey of the Milky Way". We observed a significant portion of the Galactic plane in the first quadrant of the Milky Way in the 21cm HI line, 4 OH transitions, 19 radio recombination lines, and continuum from 1 to 2 GHz. In this paper we present a catalog of the continuum sources in the first half of the survey (l=14.0-37.9deg and l=47.1-51.2deg, |b|<1.1deg) at a spatial resolution of 10-25", with a spatially varying noise level of ~0.3-1 mJy/beam. The catalog contains ~4400 sources. Around 1200 of these are spatially resolved, and ~1000 are possible artifacts, given their low signal-to-noise ratios. Since the spatial distribution of the unresolved objects is evenly distributed and not confined to the Galactic plane, most of them are extragalactic. Thanks to the broad bandwidth of the observations from 1 to 2 GHz, we are able to determine a reliable spectral index for ~1800 sources. The spectral index distribution reveals a double-peaked profile with maxima at spectral indices of alpha = -1 and alpha = 0 , corresponding to steep declining and flat spectra, respectively. This allows us to distinguish between thermal and non-thermal emission, which can be used to determine the nature of each source. We examine the spectral index of ~300 known HII regions, for which we find thermal emission with spectral indices around alpha = 0. In contrast, supernova remnants (SNR) show non-thermal emission with alpha = -0.5 and extragalactic objects generally have a steeper spectral index of alpha = -1. Using the spectral index information of the THOR survey, we investigate potential SNR candidates. We classify the radiation of four SNR candidates as non-thermal, and for the first time, we provide strong evidence for the SNR origin of these candidates.

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A multi-wavelength analysis for interferometric (sub-)mm observations of protoplanetary disks: radial constraints on the dust properties and the disk structure

Theoretical models of grain growth predict dust properties to change as a function of protoplanetary disk radius, mass, age and other physical conditions. We lay down the methodology for a multi-wavelength analysis of (sub-)mm and cm continuum interferometric observations to constrain self-consistently the disk structure and the radial variation of the dust properties. The computational architecture is massively parallel and highly modular. The analysis is based on the simultaneous fit in the uv-plane of observations at several wavelengths with a model for the disk thermal emission and for the dust opacity. The observed flux density at the different wavelengths is fitted by posing constraints on the disk structure and on the radial variation of the grain size distribution. We apply the analysis to observations of three protoplanetary disks (AS 209, FT Tau, DR Tau) for which a combination of spatially resolved observations in the range ~0.88mm to ~10mm is available (from SMA, CARMA, and VLA), finding evidence of a decreasing maximum dust grain size (a_max) with radius. We derive large a_max values up to 1 cm in the inner disk between 15 and 30 AU and smaller grains with a_max~1 mm in the outer disk (R > 80AU). In this paper we develop a multi-wavelength analysis that will allow this missing quantity to be constrained for statistically relevant samples of disks and to investigate possible correlations with disk or stellar parameters.

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Hierarchical fragmentation and collapse signatures in a high-mass starless region

Aims: Understanding the fragmentation and collapse properties of the dense gas during the onset of high-mass star formation. Methods: We observed the massive (~800M_sun) starless gas clump IRDC18310-4 with the Plateau de Bure Interferometer (PdBI) at sub-arcsecond resolution in the 1.07mm continuum andN2H+(3-2) line emission. Results: Zooming from a single-dish low-resolution map to previous 3mm PdBI data, and now the new 1.07mm continuum observations, the sub-structures hierarchically fragment on the increasingly smaller spatial scales. While the fragment separations may still be roughly consistent with pure thermal Jeans fragmentation, the derived core masses are almost two orders of magnitude larger than the typical Jeans mass at the given densities and temperatures. However, the data can be reconciled with models using non-homogeneous initial density structures, turbulence and/or magnetic fields. While most sub-cores remain (far-)infrared dark even at 70mum, we identify weak 70mum emission toward one core with a comparably low luminosity of ~16L_sun, re-enforcing the general youth of the region. The spectral line data always exhibit multiple spectral components toward each core with comparably small line widths for the individual components (in the 0.3 to 1.0km/s regime). Based on single-dish C18O(2-1) data we estimate a low virial-to-gas-mass ratio <=0.25. We discuss that the likely origin of these spectral properties may be the global collapse of the original gas clump that results in multiple spectral components along each line of sight. Even within this dynamic picture the individual collapsing gas cores appear to have very low levels of internal turbulence.

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THOR - The HI, OH, Recombination Line Survey of the Milky Way - The pilot study: HI observations of the giant molecular cloud W43

To study the atomic, molecular and ionized emission of Giant Molecular Clouds (GMCs), we have initiated a Large Program with the VLA: 'THOR - The HI, OH, Recombination Line survey of the Milky Way'. We map the 21cm HI line, 4 OH lines, 19 H_alpha recombination lines and the continuum from 1 to 2 GHz of a significant fraction of the Milky Way (l=15-67deg, |b|<1deg) at ~20" resolution. In this paper, we focus on the HI emission from the W43 star-formation complex. Classically, the HI 21cm line is treated as optically thin with column densities calculated under this assumption. This might give reasonable results for regions of low-mass star-formation, however, it is not sufficient to describe GMCs. We analyzed strong continuum sources to measure the optical depth, and thus correct the HI 21cm emission for optical depth effects and weak diffuse continuum emission. Hence, we are able to measure the HI mass of W43 more accurately and our analysis reveals a lower limit of M=6.6x10^6 M_sun, which is a factor of 2.4 larger than the mass estimated with the assumption of optically thin emission. The HI column densities are as high as N(HI)~150 M_sun/pc^2 ~ 1.9x10^22 cm^-2, which is an order of magnitude higher than for low mass star formation regions. This result challenges theoretical models that predict a threshold for the HI column density of ~10 M_sun/pc^2, at which the formation of molecular hydrogen should set in. By assuming an elliptical layered structure for W43, we estimate the particle density profiles. While at the cloud edge atomic and molecular hydrogen are well mixed, the center of the cloud is strongly dominated by molecular hydrogen. We do not identify a sharp transition between hydrogen in atomic and molecular form. Our results are an important characterization of the atomic to molecular hydrogen transition in an extreme environment and challenges current theoretical models.

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Kinematic and Thermal Structure at the onset of high-mass star formation

We want to understand the kinematic and thermal properties of young massive gas clumps prior to and at the earliest evolutionary stages of high-mass star formation. Do we find signatures of gravitational collapse? Do we find temperature gradients in the vicinity or absence of infrared emission sources? Do we find coherent velocity structures toward the center of the dense and cold gas clumps? To determine kinematics and gas temperatures, we used ammonia, because it is known to be a good tracer and thermometer of dense gas. We observed the NH$_3$(1,1) and (2,2) lines within seven very young high-mass star-forming regions with the VLA and the Effelsberg 100m telescope. This allows us to study velocity structures, linewidths, and gas temperatures at high spatial resolution of 3-5$"$, corresponding to $\sim$0.05 pc. We find on average cold gas clumps with temperatures in the range between 10 K and 30 K. The observations do not reveal a clear correlation between infrared emission peaks and ammonia temperature peaks. We report an upper limit for the linewidth of $\sim$1.3 km s$^{-1}$, at the spectral resolution limit of our VLA observation. This indicates a relatively low level of turbulence on the scale of the observations. Velocity gradients are present in almost all regions with typical velocity differences of 1 to 2 km s$^{-1}$ and gradients of 5 to 10 km s$^{-1}$ pc$^{-1}$. These velocity gradients are smooth in most cases, but there is one exceptional source (ISOSS23053), for which we find several velocity components with a steep velocity gradient toward the clump centers that is larger than 30 km s$^{-1}$ pc$^{-1}$. This steep velocity gradient is consistent with recent models of cloud collapse. Furthermore, we report a spatial correlation of ammonia and cold dust, but we also find decreasing ammonia emission close to infrared emission sources.

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Chemical evolution in the early phases of massive star formation II: Deuteration

The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong temperature dependence of deuterium isotopic fractionation. We observed a sample of 59 sources including 19 infrared dark clouds, 20 high-mass protostellar objects, 11 hot molecular cores and 9 ultra-compact HII regions in the (3-2) transitions of the four deuterated molecules, DCN, DNC, DCO+ and N2D+ as well as their non-deuterated counterpart. The overall detection fraction of DCN, DNC and DCO+ is high and exceeds 50% for most of the stages. N2D+ was only detected in a few infrared dark clouds and high-mass protostellar objects. It can be related to problems in the bandpass at the frequency of the transition and to low abundances in the more evolved, warmer stages. We find median D/H ratios of ~0.02 for DCN, ~0.005 for DNC, ~0.0025 for DCO+ and ~0.02 for N2D+. While the D/H ratios of DNC, DCO+ and N2D+ decrease with time, DCN/HCN peaks at the hot molecular core stage. We only found weak correlations of the D/H ratios for N2D+ with the luminosity of the central source and the FWHM of the line, and no correlation with the H2 column density. In combination with a previously observed set of 14 other molecules (Paper I) we fitted the calculated column densities with an elaborate 1D physico-chemical model with time-dependent D-chemistry including ortho- and para-H2 states. Good overall fits to the observed data have been obtained the model. It is one of the first times that observations and modeling have been combined to derive chemically based best-fit models for the evolution of high-mass star formation including deuteration.

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Study of morphology and stellar content of the Galactic HII region IRAS 16148-5011

An investigation of the IRAS 16148-5011 region - a cluster at a distance of 3.6 kpc - is presented here, carried out using multiwavelength data in near-infrared (NIR) from the 1.4m Infrared Survey Facility telescope, mid-infrared (MIR) from the archival Spitzer GLIMPSE survey, far-infrared (FIR) from the Herschel archive, and low-frequency radio continuum observations at 1280 and 843 MHz from the Giant Metrewave Radio Telescope (GMRT) and Molonglo Survey archive, respectively. A combination of NIR and MIR data is used to identify 7 Class I and 133 Class II sources in the region. Spectral Energy Distribution (SED) analysis of selected sources reveals a 9.6 Msolar, high-mass source embedded in nebulosity. However, Lyman continuum luminosity calculation using radio emission - which shows a compact HII, region - indicates the spectral type of the ionizing source to be earlier than B0-O9.5. Free-free emission SED modelling yields the electron density as 138 cm^{-3}, and thus the mass of the ionized hydrogen as ~16.4 Msolar. Thermal dust emission modelling, using the FIR data from Herschel and performing modified blackbody fits, helped us construct the temperature and column density maps of the region, which show peak values of 30 K and 3.3x10^{22} cm^{-2}, respectively. The column density maps reveal an AV > 20 mag extinction associated with the nebular emission, and weak filamentary structures connecting dense clumps. The clump associated with this IRAS object is found to have dimensions of ~1.1 pc x 0.8 pc, and a mass of 1023 Msolar.

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The dynamics and star-forming potential of the massive Galactic centre cloud G0.253+0.016

The massive infrared dark cloud G0.253+0.016 projected 45pc from the Galactic centre contains ~10^5Msun of dense gas whilst being mostly devoid of observed star-formation tracers. To scrutinise the physical properties, dynamics and structure of this cloud with reference to its star-forming potential, we have carried out a concerted SMA and IRAM 30m study of this cloud in dust continuum, CO isotopologues, shock tracing molecules, as well as H$_2$CO to trace the gas temperature. We detect and characterise the dust cores within G0.253+0.016 at ~1.3 mm and find that the kinetic temperature of the gas is >320K on size-scales of ~0.15 pc. Analysis of the position-velocity diagrams of our observed lines show broad linewidths and strong shock emission in the south of the cloud, indicating that G0.253+0.016 is colliding with another cloud at v(LSR)~70 km/s. We confirm via an analysis of the observed dynamics in the CMZ that it is an elongated structure, orientated with Sgr B2 closer to the Sun than Sgr A*, however our results suggest that the actual geometry may be more complex than an elliptical ring. We find that the column density PDF of G0.253+0.016 is log-normal with no discernible power-law tail, consistent with little star formation, and that its width can be explained in the framework of theory predicting the density structure of clouds created by supersonic, magnetised turbulence. We also present the delta-variance spectrum of this region, and show it is consistent with that expected for clouds with no star formation. Using G0.253+0.016 as a test-bed of the conditions required for star formation in a different physical environment to that of nearby clouds, we also conclude that there is not one column density threshold for star formation, but instead this value is dependant on the local physical conditions. [Abbrv.]

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A near-IR spectroscopic survey of massive jets towards EGOs

We aim at deriving the main physical properties of massive jets from near-IR observations, comparing them to those of a large sample of jets from low-mass YSOs, and relating them to the main features of their driving sources. We present a NIR imaging (H2 and Ks) and low-resolution spectroscopic (0.95-2.50 um) survey of 18 massive jets towards GLIMPSE extended green objects, driven by intermediate- and high-mass YSOs, which have Lbol between 4x10^2 and 10^5 Lsun. As in low-mass jets, H2 is the primary NIR coolant, detected in all the analysed flows, whereas the most important ionic tracer is [FeII], detected in half of the sampled jets. Our analysis indicates that the emission lines originate from shocks at high temperatures and densities. No fluorescent emission is detected along the flows, regardless of the source Lbol. On average, the physical parameters of these massive jets (i.e. Av, temperature, column density, mass, and luminosity) have higher values than those measured in their low-mass counterparts. The morphology of the H2 flows is varied, mostly depending on the complex, dynamic, and inhomogeneous environment in which these massive jets form and propagate. All flows and jets in our sample are collimated, showing large precession angles. Additionally, the presence of both knots and jets suggests that the ejection process is continuous with burst episodes, as in low-mass YSOs. We compare the flow H2 luminosity with the source Lbol confirming the tight correlation between these two quantities. Five sources, however, display a lower L(H2)/Lbol efficiency, which might be related to YSO evolution. Most important, the inferred L(H2) vs Lbol relationship agrees well with the correlation between the momentum flux of the CO outflows and the bolometric luminosities of high-mass YSOs indicating that outflows from high-mass YSOs are momentum driven, as are their low-mass counterparts.

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Carbon in different phases ([CII], [CI], and CO) in infrared dark clouds: Cloud formation signatures and carbon gas fractions

Context: How do molecular clouds form out of the atomic phase? And what are the relative fractions of carbon in the ionized, atomic and molecular phase? These are questions at the heart of cloud and star formation. Methods: Using multiple observatories from Herschel and SOFIA to APEX and the IRAM 30m telescope, we mapped the ionized, atomic and molecular carbon ([CII]@1900GHz, [CI]@492GHz and C18O(2-1)@220GHz) at high spatial resolution (12"-25") in four young massive infrared dark clouds (IRDCs). Results: The three carbon phases were successfully mapped in all four regions, only in one source the [CII] line remained a non-detection. Both the molecular and atomic phases trace the dense structures well, with [CI] also tracing material at lower column densities. [CII] exhibits diverse morphologies in our sample, from compact to diffuse structures probing the cloud environment. In at least two out of the four regions, we find kinematic signatures strongly indicating that the dense gas filaments have formed out of a dynamically active and turbulent atomic/molecular cloud, potentially from converging gas flows. The atomic-to-molecular carbon gas mass ratios are low between 7% and 12% with the lowest values found toward the most quiescent region. In the three regions where [CII] is detected, its mass is always higher by a factor of a few than that of the atomic carbon. The ionized carbon emission depends as well on the radiation field, however, we also find strong [CII] emission in a region without significant external sources, indicating that other processes, e.g., energetic gas flows can contribute to the [CII] excitation as well.

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The Earliest Phases of Star formation (EPoS): Temperature, density, and kinematic structure of the star-forming core CB 17

Context: The initial conditions for the gravitational collapse of molecular cloud cores and the subsequent birth of stars are still not well constrained. The characteristic cold temperatures (about 10 K) in such regions require observations at sub-millimetre and longer wavelengths. The Herschel Space Observatory and complementary ground-based observations presented in this paper have the unprecedented potential to reveal the structure and kinematics of a prototypical core region at the onset of stellar birth. Aims: This paper aims to determine the density, temperature, and velocity structure of the star-forming Bok globule CB 17. This isolated region is known to host (at least) two sources at different evolutionary stages: a dense core, SMM1, and a Class I protostar, IRS. Methods: We modeled the cold dust emission maps from 100 micron to 1.2 mm with both a modified blackbody technique to determine the optical depth-weighted line-of-sight temperature and column density and a ray-tracing technique to determine the core temperature and volume density structure. Furthermore, we analysed the kinematics of CB17 using the high-density gas tracer N2H+. Results: From the ray-tracing analysis, we find a temperature in the centre of SMM1 of 10.6 K, a flat density profile with radius 9500 au, and a central volume density of n(H) = 2.3x10^5 cm-3. The velocity structure of the N2H+ observations reveal global rotation with a velocity gradient of 4.3 km/s/pc. Superposed on this rotation signature we find a more complex velocity field, which may be indicative of differential motions within the dense core. Conclusions: SMM is a core in an early evolutionary stage at the verge of being bound, but the question of whether it is a starless or a protostellar core remains unanswered.

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Herschel observations of gamma-ray burst host galaxies: implications for the topology of the dusty interstellar medium

Long-duration gamma-ray bursts (GRBs) are indisputably related to star formation, and their vast luminosity in gamma rays pin-points regions of star formation independent of galaxy mass. As such, GRBs provide a unique tool for studying star forming galaxies out to high-z independent of luminosity. Most of our understanding of the properties of GRB hosts (GRBHs) comes from optical and near-infrared (NIR) follow-up observations, and we therefore have relatively little knowledge of the fraction of dust-enshrouded star formation that resides within GRBHs. Currently ~20% of GRBs show evidence of significant amounts of dust along the line of sight to the afterglow through the host galaxy, and these GRBs tend to reside within redder and more massive galaxies than GRBs with optically bright afterglows. In this paper we present Herschel observations of five GRBHs with evidence of being dust-rich, targeted to understand the dust attenuation properties within GRBs better. Despite the sensitivity of our Herschel observations, only one galaxy in our sample was detected (GRBH 070306), for which we measure a total star formation rate (SFR) of ~100Mstar/yr, and which had a relatively high stellar mass (log[Mstar]=10.34+0.09/-0.04). Nevertheless, when considering a larger sample of GRBHs observed with Herschel, it is clear that stellar mass is not the only factor contributing to a Herschel detection, and significant dust extinction along the GRB sightline (A_{V,GRB}>1.5~mag) appears to be a considerably better tracer of GRBHs with high dust mass. This suggests that the extinguishing dust along the GRB line of sight lies predominantly within the host galaxy ISM, and thus those GRBs with A_{V,GRB}>1~mag but with no host galaxy Herschel detections are likely to have been predominantly extinguished by dust within an intervening dense cloud.

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ATLASGAL --- Complete compact source catalogue: 280\degr\ $ <\ell <$ 60\degr

The APEX Telescope Large Area Survey of the Galaxy (ATLASGAL) is the largest and most sensitive systematic survey of the inner Galactic plane in the submillimetre wavelength regime. The observations were carried out with the Large APEX Bolometer Camera (LABOCA), an array of 295 bolometers observing at 870\,$μ$m (345 GHz). Aim: In this research note we present the compact source catalogue for the 280\degr\ $ <\ell <$ 330\degr\ and 21\degr\ $ <\ell <$ 60\degr\ regions of this survey. Method: The construction of this catalogue was made with the source extraction routine \sex\ using the same input parameters and procedures used to analyse the inner Galaxy region presented in an earlier publication (i.e., 330\degr\ $ <\ell <$ 21\degr). Results: We have identified 3523 compact sources and present a catalogue of their properties. When combined with the regions already published this provides a comprehensive and unbiased database of ~10163 massive, dense clumps located across the inner Galaxy.

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Chemical evolution in the early phases of massive star formation. I

Understanding the chemical evolution of young (high-mass) star-forming regions is a central topic in star formation research. Chemistry is employed as a unique tool 1) to investigate the underlying physical processes and 2) to characterize the evolution of the chemical composition. We observed a sample of 59 high-mass star-forming regions at different evolutionary stages varying from the early starless phase of infrared dark clouds to high-mass protostellar objects to hot molecular cores and, finally, ultra-compact HII regions at 1mm and 3mm with the IRAM 30m telescope. We determined their large-scale chemical abundances and found that the chemical composition evolves along with the evolutionary stages. On average, the molecular abundances increase with time. We modeled the chemical evolution, using a 1D physical model where density and temperature vary from stage to stage coupled with an advanced gas-grain chemical model and derived the best-fit chi^2 values of all relevant parameters. A satisfying overall agreement between observed and modeled column densities for most of the molecules was obtained. With the best-fit model we also derived a chemical age for each stage, which gives the timescales for the transformation between two consecutive stages. The best-fit chemical ages are ~10,000 years for the IRDC stage, ~60,000 years for the HMPO stage, ~40,000 years for the HMC stage, and ~10,000 years for the UCHII stage. The total chemical timescale for the entire evolutionary sequence of the high-mass star formation process is on the order of 10^5 years, which is consistent with theoretical estimates. Furthermore, based on the approach of a multiple-line survey of unresolved data, we were able to constrain an intuitive and reasonable physical and chemical model. The results of this study can be used as chemical templates for the different evolutionary stages in high-mass star formation.

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