arXiv subjects

H. M. Pastawski

Publications and source records attributed to H. M. Pastawski.

At least 19 recordsLinked to original sources

arXiv2024

Universal stability of coherently diffusive 1D systems with respect to decoherence

Static disorder in a 3D crystal degrades the ideal ballistic dynamics until it produces a localized regime. This Metal-Insulator Transition is often preceded by coherent diffusion. By studying three paradigmatic 1D models, namely the Harper-Hofstadter-Aubry-André and Fibonacci tight-binding chains, along with the power-banded random matrix model, we show that whenever coherent diffusion is present, transport is exceptionally stable against decoherent noise. This is completely at odds with what happens for coherently ballistic and localized dynamics, where the diffusion coefficient strongly depends on the environmental decoherence. A universal dependence of the diffusion coefficient on the decoherence strength is analytically derived: the diffusion coefficient remains almost decoherence-independent until the coherence time becomes comparable with the mean elastic scattering time. Thus, systems with a quantum diffusive regime could be used to design robust quantum wires. Moreover our results might shed new light on the functionality of many biological systems, which often operate at the border between the ballistic and localized regimes.

quant-ph↗

arXiv2015

Molecular dissociation in presence of catalysts: Interpreting bond breaking as a quantum dynamical phase transition

In this work we show that the molecular chemical bond formation and dissociation in presence of the d-band of a metal catalyst can be described as a Quantum Dynamical Phase Transition (QDPT). This agree with DFT calculations that predict sudden jumps in some observables as the molecule breaks. According to our model this phenomenon emerges because the catalyst provides for a non- Hermitian Hamiltonian. We show that when the molecule approaches the surface, as occurs in the Heyrovsky reaction of H 2, the bonding H 2 orbital has a smooth crossover into a bonding molecular orbital built with the closest H orbital and the surface metal d-states. The same occurs for the antibonding state. Meanwhile, two resonances appear within the continuous spectrum of the d- band which are associated with bonding and antibonding orbitals between the furthest H atom and the d-states at the second metallic layer. These move towards the band center where they collapse into a pure metallic resonance and an almost isolated H orbital. This phenomenon constitutes a striking example of the non-trivial physics enabled when one deals with non-Hermitian Hamiltonian beyond the usual wide band approximation.

physics.chem-ph↗

arXiv2009

Non-Markovian decay beyond the Fermi Golden Rule: Survival Collapse of the polarization in spin chains

The decay of a local spin excitation in an inhomogeneous spin chain is evaluated exactly: I) It starts quadratically up to a spreading time t_{S}. II) It follows an exponential behavior governed by a self-consistent Fermi Golden Rule. III) At longer times, the exponential is overrun by an inverse power law describing return processes governed by quantum diffusion. At this last transition time t_{R} a survival collapse becomes possible, bringing the polarization down by several orders of magnitude. We identify this strongly destructive interference as an antiresonance in the time domain. These general phenomena are suitable for observation through an NMR experiment.

quant-ph↗

arXiv2009

Effective one-body dynamics in multiple-quantum NMR experiments

A suitable NMR experiment in a one-dimensional dipolar coupled spin system allows one to reduce the natural many-body dynamics into effective one-body dynamics. We verify this in a polycrystalline sample of hydroxyapatite (HAp) by monitoring the excitation of NMR many-body superposition states: the multiple-quantum coherences. The observed effective one-dimensionality of HAp relies on the quasi 1d structure of the dipolar coupled network that, as we show here, is dynamically enhanced by the quantum Zeno effect. Decoherence is also probed through a Loschmidt echo experiment, where the time reversal is implemented on the double-quantum Hamiltonian, I_{i,+}I_{j,+} + I_{i,-}I_{j,-}. We contrast the decoherence of adamantane, a standard 3d system, with that of HAp. While the first shows an abrupt Fermi-type decay, HAp presents a smooth exponential law.

quant-ph↗

arXiv2009

Survival Probability of a Local Excitation in a Non-Markovian Environment: Survival Collapse, Zeno and Anti-Zeno effects

The decay dynamics of a local excitation interacting with a non-Markovian environment, modeled by a semi-infinite tight-binding chain, is exactly evaluated. We identify distinctive regimes for the dynamics. Sequentially: (i) early quadratic decay of the initial-state survival probability, up to a spreading time $t_{S}$, (ii) exponential decay described by a self-consistent Fermi Golden Rule, and (iii) asymptotic behavior governed by quantum diffusion through the return processes and leading to an inverse power law decay. At this last cross-over time $t_{R}$ a survival collapse becomes possible. This could reduce the survival probability by several orders of magnitude. The cross-overs times $t_{S}$ and $t_{R}$ allow to assess the range of applicability of the Fermi Golden Rule and give the conditions for the observation of the Zeno and Anti-Zeno effect.

quant-ph↗

arXiv2007

Comment on "Nonexponential Decay Via Tunneling in Tight-Binding Lattices and the Optical Zeno Effect"

S. Longhi [1] studied the survival probability P(t) of an unstable state coupled to a tight-binding lattice finding an exact analytical solution that describes the nonexponential decay. When the first coupling is smaller than the others, he shows that P(t) has a natural decomposition into two terms; one is the exponential decay, consistent with the Gamow's approach, and the other is the correction to this decay. The first purpose of this Comment is to show that the condition imposed on the system; the site energy of the first site is set in the center of the band, limits the generality of the results. A decomposition based on the spectral properties of the system removes this restriction [2]. Other point of this Comment is that, for the weak coupling limit, the author stated that a Zeno effect occurs for t less than t*, where t* is the smallest root of the equation g_eff(t*)=g_0, and for the strong coupling limit an anti-Zeno effect occurs for t close to t**, where t** is the first peak of g_eff. By using a spectral formulation we show that, the anti-Zeno effect not only requires a strong coupling limit, also is necessary to choose the resonance energy and width such that a destructive interference can occur. We present this interference and give an analytical expression and physically interpretation for t* and t**.

quant-ph↗

arXiv2006

Dynamical phase transition in vibrational surface modes

We consider the dynamical properties of a simple model of vibrational surface modes. We obtain the exact spectrum of surface excitations and discuss their dynamical features. In addition to the usually discussed localized and oscillatory regimes we also find a second phase transition where surface mode frequency becomes purely imaginary and describes an overdamped regime. Noticeably, this transition has an exact correspondence to the oscillatory - overdamped transition of the standard oscillator with a frictional force proportional to velocity.

cond-mat.mes-hall↗

arXiv2006

Survival probability of surface excitations in a 2d lattice: non-Markovian effects and Survival Collapse

The evolution of a surface excitation in a two dimentional model is analyzed. I) It starts quadratically up to a spreading time t_{S}. II) It follows an exponential behavior governed by a self-consistent Fermi Golden Rule. III) At longer times, the exponential is overrun by an inverse power law describing return processes governed by quantum diffusion. At this last transition time t_{R} a survival collapse becomes possible, bringing the survival probability down by several orders of magnitude. We identify this strongly destructive interference as an antiresonance in the time domain.

quant-ph↗

arXiv2005

Surface effects on the statistics of the local density of states in metallic nanoparticles: manifestation on the NMR spectra

In metallic nanoparticles, shifts in the ionization energy of surface atoms with respect to bulk atoms can lead to surface bands. Within a simple Tight Binding model we find that the projection of the electronic density of states on these sites presents two overlapping structures. One of them is characterized by the level spacing coming from bulk states and the other arises from the surface states. In very small particles, this contributes to an over-broadening of the NMR absorption spectra, determined by the Knight shift distribution of magnetic nuclei. We compare our calculated Knight shifts with experiments on aluminum nanoparticles, and show that the deviation of the scaling law as a function of temperature and particle size can be explained in terms of surface states.

cond-mat.mes-hall↗

arXiv2005

Antiresonances as precursors of decoherence

We show that, in presence of a complex spectrum, antiresonances act as a precursor for dephasing enabling the crossover to a fully decoherent transport even within a unitary Hamiltonian description. This general scenario is illustrated here by focusing on a quantum dot coupled to a chaotic cavity containing a finite, but large, number of states using a Hamiltonian formulation. For weak coupling to a chaotic cavity with a sufficiently dense spectrum, the ensuing complex structure of resonances and antiresonances leads to phase randomization under coarse graining in energy. Such phase instabilities and coarse graining are the ingredients for a mechanism producing decoherence and thus irreversibility. For the present simple model one finds a conductance that coincides with the one obtained by adding a ficticious voltage probe within the Landauer-Buettiker picture. This sheds new light on how the microscopic mechanisms that produce phase fluctuations induce decoherence.

cond-mat.mes-hall↗

arXiv2003

Coherent versus sequential electron tunneling in quantum dots

Manifestations of quantum coherence in the electronic conductance through nearly closed quantum dots in the Coulomb blockade regime are addressed. We show that quantum coherent tunneling processes explain some puzzling statistical features of the conductance peak-heights observed in recent experiments at low temperatures. We employ the constant interaction model and the random matrix theory to model the quantum dot electronic interactions and its single-particle statistical fluctuations, taking full account of the finite decay width of the quantum dot levels.

cond-mat.mes-hall↗

arXiv2002

Electron-Phonon interaction and electronic decoherence in molecular conductors

We perform a brief but critical review of the Landauer picture of transport that clarifies how decoherence appears in this approach. On this basis, we present different models that allow the study of the coherent and decoherent effects of the interaction with the environment in the electronic transport. These models are particularly well suited for the analysis of transport in molecular wires. The effects of decoherence are described through the D'Amato-Pastawski model that is explained in detail. We also consider the formation of polarons in some models for the electron-vibrational interaction. Our quantum coherent framework allows us to study many-body interference effects. Particular emphasis is given to the occurrence of anti-resonances as a result of these interferences. By studying the phase fluctuations in these soluble models we are able to identify inelastic and decoherence effects. A brief description of a general formulation for the consideration of time-dependent transport is also presented.

cond-mat.mes-hall↗

arXiv2001

Measuring the Lyapunov exponent using quantum mechanics

We study the time evolution of two wave packets prepared at the same initial state, but evolving under slightly different Hamiltonians. For chaotic systems, we determine the circumstances that lead to an exponential decay with time of the wave packet overlap function. We show that for sufficiently weak perturbations, the exponential decay follows a Fermi golden rule, while by making the difference between the two Hamiltonians larger, the characteristic exponential decay time becomes the Lyapunov exponent of the classical system. We illustrate our theoretical findings by investigating numerically the overlap decay function of a two-dimensional dynamical system.

nlin.CD↗

arXiv2001

Decoherence as Decay of the Loschmidt Echo in a Lorentz Gas

Classical chaotic dynamics is characterized by the exponential sensitivity to initial conditions. Quantum mechanics, however, does not show this feature. We consider instead the sensitivity of quantum evolution to perturbations in the Hamiltonian. This is observed as an atenuation of the Loschmidt Echo, $M(t)$, i.e. the amount of the original state (wave packet of width $σ$) which is recovered after a time reversed evolution, in presence of a classically weak perturbation. By considering a Lorentz gas of size $L$, which for large $L$ is a model for an {\it unbounded} classically chaotic system, we find numerical evidence that, if the perturbation is within a certain range, $M(t)$ decays exponentially with a rate $1/τ_ϕ$ determined by the Lyapunov exponent $λ$ of the corresponding classical dynamics. This exponential decay extends much beyond the Eherenfest time $t_{E}$ and saturates at a time $t_{s}\simeq λ^{-1}\ln (\widetilde{N})$, where $\widetilde{N}\simeq (L/σ)^2$ is the effective dimensionality of the Hilbert space. Since $τ_ϕ$ quantifies the increasing uncontrollability of the quantum phase (decoherence) its characterization and control has fundamental interest.

cond-mat.dis-nn↗

arXiv2001

Tuning a Resonance in the Fock Space: Optimization of Phonon Emission in a Resonant Tunneling Device

Phonon-assisted tunneling in a double barrier resonant tunneling device can be seen as a resonance in the electron-phonon Fock space which is tuned by the applied voltage. We show that the geometrical parameters can induce a symmetry condition in this space that can strongly enhance the emission of longitudinal optical phonons. For devices with thin emitter barriers this is achieved by a wider collector's barrier.

cond-mat.mes-hall↗

arXiv2001

Dynamical Origin of Decoherence in Clasically Chaotic Systems

The decay of the overlap between a wave packet evolved with a Hamiltonian H and the same state evolved with H}+$Σ$ serves as a measure of the decoherence time $τ_ϕ$. Recent experimental and analytical evidence on classically chaotic systems suggest that, under certain conditions, $τ_ϕ$ depends on H but not on $Σ$. By solving numerically a Hamiltonian model we find evidence of that property provided that the system shows a Wigner-Dyson spectrum (which defines quantum chaos) and the perturbation exceeds a crytical value defined by the parametric correlations of the spectra.

cond-mat.mes-hall↗

arXiv2001

Anomalous Diffusion in Quasi One Dimensional Systems

In order to perform quantum Hamiltonian dynamics minimizing localization effects, we introduce a quasi-one dimensional tight-binding model whose mean free path is smaller than the size of the sample. This one, in turn, is smaller than the localization length. We study the return probability to the starting layer of the system by means of direct diagonalization of the Hamiltonian. We create a one dimensional excitation and observe sub-diffusive behavior for times larger than the Debye time but shorter than the Heisenberg time. The exponent corresponds to the fractal dimension $d^{*} \sim 0.72$ which is compared to that calculated from the eigenstates by means of the inverse participation number.

cond-mat.mes-hall↗

arXiv2001

The terahertz phonon laser: a full quantum treatment

The aim of this work is to describe the behavior of a device capable to generate high frequency (~THz) acoustic phonons. This device consists in a GaAs-AlGaAs double barrier heterostructure that, when an external bias is applied, produces a high rate of longitudinal optical LO phonons. These LO phonons are confined and they decay by stimulated emission of a pair of secondary longitudinal optical (LO_2) and transversal acoustic (TA) phonons. The last ones form an intense beam of coherent acoustic phonons. To study this effect, we start from a tight binding Hamiltonian that take into account the electron-phonon (e-ph) and phonon-phonon (ph-ph) interactions. We calculate the electronic current through the double barrier and we obtain a set of five coupled kinetic equations that describes the electron and phonon populations. The results obtained here confirm the behavior of the terahertz phonon laser, estimated by rougher treatments.

cond-mat.mes-hall↗