arXiv subjects

H. Martín-Caballero

Publications and source records attributed to H. Martín-Caballero.

2 recordsLinked to original sources

arXiv2026

CHemical Evolution in MassIve star-forming COres (CHEMICO). II. Molecular ions, electron fraction, and cosmic-ray ionisation rate

Molecular ions are crucial in initiating and regulating the formation of molecules in the interstellar medium, and are expected to be sensitive tracers of evolution in star-forming regions. Within the framework of the project `CHemical Evolution of MassIve star-forming COres' (CHEMICO), we investigate the temporal evolution of molecular ions towards three high-mass star-forming cores that represent three sequential evolutionary stages. CHEMICO is based on an unbiased spectral line survey of the bandwidth at 3, 2, and 1.2~mm carried out with the 30m telescope of the Insitut de Radioastronomie millimétrique. We detect 19 molecular ions, including isotopologues. From a local thermodynamic equilibrium analysis, we derive the following main results: (i) Overall, the physical parameters of sulphur-bearing ions are the most sensitive to evolution, whereas those of nitrogen-bearing ions are the least; (ii) The molecular abundances that exhibit the most pronounced temporal variations are those of SO+, DCO+, and N2D+; (iii) A simple analytic approach tailored for warm gas conditions provides cosmic-ray ionisation rates of H2 several orders of magnitude above the canonical values measured in the interstellar medium and with a marked increase with evolution; (iv) The abundance ratio of protonated-to-neutral species increases with the proton affinity of the neutral regardless of the evolutionary stage of the source, indicating that proton-transfer appears to proceed similarly in both cold and warm interstellar environments. Molecular ions exhibit distinct evolutionary trends in high-mass star-forming regions, with sulphur-bearing species and the abundances of N2D+, DCO+, and SO+ emerging as particularly sensitive tracers of evolution. Measured electron fractions and cosmic-ray ionisation rates are in line with an internal production of cosmic-rays that becomes increasingly efficient with time.

astro-ph.GA↗

arXiv2025

CHemical Evolution in MassIve star-forming COres (CHEMICO). I. Evolution of the temperature structure

Increasing evidence shows that most stars in the Milky Way, including the Sun, are born in star-forming regions containing also high-mass stars, but due to both observational and theoretical challenges, our comprehension of their chemical evolution is far less clear than that of their low-mass counterparts. We present the project "CHemical Evolution of MassIve star-froming COres" (CHEMICO). The project aims at investigating any aspect of the chemical evolution of high-mass star-forming cores by observing representatives of the three main evolutionary categories: high-mass starless cores, high-mass protostellar objects, and ultra-compact HII regions. We carried out an unbiased spectral line survey of the entire bandwidth at 3, 2, and 1.2 mm with the 30m telescope of the Insitut de Radioastronomie millimetrique towards three targets that represent the three evolutionary stages. The number of lines and species detected increases with evolution. In this first work, we derive the temperature structure of the targets through the analysis of the carbon-bearing species C2H, c-C3H, c-C3H2, C4H, CH3CCH, HC3N, CH3CN, and HC5N. The excitation temperature, Tex, increases with evolution in each species, although not in the same way. Hydrocarbons tend to be associated with the smallest Tex values and enhancements with evolution, while cyanides are associated with the highest Tex values and enhancements. In each target, the higher the number of atoms in the molecule, the higher Tex tends to be. The temperature structure evolves from a cold, uniform envelope traced by simple hydrocarbons in the high-mass starless core stage, to a more stratified envelope in the protostellar stage (made by a hot core, a shell with intermediate Tex, and a larger cold envelope), to finally a hot core surrounded only by a cold envelope in the Ultracompact HII stage.

astro-ph.GA↗