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H. Ouerdane

Publications and source records attributed to H. Ouerdane.

At least 37 records · Page 2Linked to original sources

Parameters for Cold Collisions of Lithium and Caesium Atoms

We calculate the s-wave scattering length and effective range and the p-wave scattering volume for $^7$Li atoms interacting with $^{133}$Cs atoms via the X$^1Σ^+_g$ molecular potential. The length and volume are found by fitting the log-derivative of the zero energy wave function evaluated at short range to a long range expression that accounts for the leading van der Waals dispersion potential and then incorporating the remaining long range dispersion contributions to first order. The effective range is evaluated from a quadrature formula. The calculated parameters are checked from the zero energy limits of the scattering phase shifts. We comment on ill-conditioning in the calculated s-wave scattering length.

physics.atom-ph↗

Green thermoelectrics: Observation and analysis of plant thermoelectric response

Plants are sensitive to thermal and electrical effects; yet the coupling of both, known as thermoelectricity, and its quantitative measurement in vegetal systems never were reported. We recorded the thermoelectric response of bean sprouts under various thermal conditions and stress. The obtained experimental data unambiguously demonstrate that a temperature difference between the roots and the leaves of a bean sprout induces a thermoelectric voltage between these two points. Basing our analysis of the data on the force-flux formalism of linear response theory, we found that the strength of the vegetal equivalent to the thermoelectric coupling is one order of magnitude larger than that in the best thermoelectric materials. Experimental data also show the importance of the thermal stress variation rate in the plant's electrophysiological response. Therefore, thermoelectric effects are sufficiently important to partake in the complex and intertwined processes of energy and matter transport within plants.

physics.bio-ph↗

Equivalent parameters for series thermoelectrics

We study the physical processes at work at the interface of two thermoelectric generators (TEGs) thermally and electrically connected in series. We show and explain how these processes impact on the system's performance: the derivation of the equivalent electrical series resistance yields a term whose physical meaning is thoroughly discussed. We demonstrate that this term must exist as a consequence of thermal continuity at the interface, since it is related to the variation of the junction temperature between the two TEGs associated in series as the electrical current varies. We then derive an expression for the equivalent series figure of merit. Finally we highlight the strong thermal/electrical symmetry between the parallel and series configurations and we compare our derivation with recent published results for the parallel configuration.

cond-mat.mtrl-sci↗

Influence of thermal environment on optimal working conditions of thermoelectric generators

Optimization analyses of thermoelectric generators operation is of importance both for practical applications and theoretical considerations. Depending on the desired goal, two different strategies are possible to achieve high performance: through optimization one may seek either power output maximization or conversion efficiency maximization. Recent literature reveals the persistent flawed notion that these two optimal working conditions may be achieved simultaneously. In this article, we lift all source of confusion by correctly posing the problem and solving it. We assume and discuss two possibilities for the environment of the generator to govern its operation: constant incoming heat flux, and constant temperature difference between the heat reservoirs. We demonstrate that, while power and efficiency are maximized simultaneously if the first assumption is considered, this is not possible with the second assumption. This latter corresponds to the seminal analyses of Ioffe who put forth and stressed the importance of the thermoelectric figure of merit $ZT$. We also provide a simple procedure to determine the different optimal design parameters of a thermoelectric generator connected to heat reservoirs through thermal contacts with a finite and fixed thermal conductance.

cond-mat.other↗

Comment on "Effective thermal conductivity in thermoelectric materials"

In a recent article, Baranowski et al. [J. Appl. Phys. 113, 204904 (2013)] proposed a model that allegedly facilitates optimization of thermoelectric generators operation as these latter are in contact with hot and cold temperature baths through finite conductance heat exchangers. In this Comment, we argue that the results and analyses presented by these authors are misleading since their model is incomplete and rests on an inappropriate assumption derived from thermoelectric compatibility theory.

cond-mat.other↗

Revisiting Feynman's ratchet with thermoelectric transport theory

We show how the formalism used for thermoelectric transport may be adapted to Smoluchowski's seminal thought experiment also known as Feynman's ratchet and pawl system. Our analysis rests on the notion of useful flux, which for a thermoelectric system is the electrical current and for Feynman's ratchet is the effective jump frequency. Our approach yields original insight into the derivation and analysis of the system's properties. In particular we define an entropy per tooth in analogy with the entropy per carrier or Seebeck coefficient, and we derive the analogue to Kelvin's second relation for Feynman's ratchet. Owing to the formal similarity between the heat fluxes balance equations for a thermoelectric generator (TEG) and those for Feynman's ratchet, we introduce a distribution parameter that quantifies the amount of heat that flows through the cold and hot sides of both heat engines. While it is well established that $γ$ = 1/2 for a TEG, it is equal to 1 for Feynman's ratchet. This implies that no heat may be rejected in the cold reservoir for the latter case. Further, the analysis of the efficiency at maximum power shows that the so-called Feynman efficiency corresponds to that of an exoreversible engine, with $γ$ = 1. Then, turning to the nonlinear regime, we generalize the approach based on the convection picture and introduce two different types of resistance to distinguish the dynamical behavior of the considered system from its ability to dissipate energy. We finally put forth the strong similarity between the original Feynman ratchet and a mesoscopic thermoelectric generator with a single conducting channel.

cond-mat.stat-mech↗

Structural analysis of strained LaVO$_3$ thin films

While structure refinement is routinely achieved for simple bulk materials, the accurate structural determination still poses challenges for thin films due on the one hand to the small amount of material deposited on the thicker substrate and, on the other hand, to the intricate epitaxial relationships that substantially complicate standard X-ray diffraction analysis. Using a combined approach, we analyze the crystal structure of epitaxial LaVO$_3$ thin films grown on (100)-oriented SrTiO$_3$. Transmission electron microscopy study reveals that the thin films are epitaxially grown on SrTiO$_3$ and points to the presence of 90$^{\circ}$ oriented domains. The mapping of the reciprocal space obtained by high resolution X-ray diffraction permits refinement of the lattice parameters. We finally deduce that strain accommodation imposes a monoclinic structure onto the LaVO$_3$ film. The reciprocal space maps are numerically processed and the extracted data computed to refine the atomic positions, which are compared to those obtained using precession electron diffraction tomography. We discuss the obtained results and our methodological approach as a promising thin film structure determination for complex systems.

cond-mat.mtrl-sci↗

Comment on "Heat dissipation in atomic-scale junctions"

We discuss the recent results of Lee et al. [Nature 498, 209 (2013)] using the notion of thermoelectric convection. In particular, we highlight the fact that this contribution to the thermal flux is not a dissipative process.

cond-mat.mes-hall↗

A linear nonequilibrium thermodynamics approach to optimization of thermoelectric devices

Improvement of thermoelectric systems in terms of performance and range of applications relies on progress in materials science and optimization of device operation. In this chapter, we focuse on optimization by taking into account the interaction of the system with its environment. For this purpose, we consider the illustrative case of a thermoelectric generator coupled to two temperature baths via heat exchangers characterized by a thermal resistance, and we analyze its working conditions. Our main message is that both electrical and thermal impedance matching conditions must be met for optimal device performance. Our analysis is fundamentally based on linear nonequilibrium thermodynamics using the force-flux formalism. An outlook on mesoscopic systems is also given.

physics.class-ph↗

Internal convection in thermoelectric generator models

Coupling between heat and electrical currents is at the heart of thermoelectric processes. From a thermal viewpoint this may be seen as an additional thermal flux linked to the appearance of electrical current in a given thermoelectric system. Since this additional flux is associated to the global displacement of charge carriers in the system, it can be qualified as convective in opposition to the conductive part associated with both phonons transport and heat transport by electrons under open circuit condition, as, e.g., in the Wiedemann-Franz relation. In this article we demonstrate that considering the convective part of the thermal flux allows both new insight into the thermoelectric energy conversion and the derivation of the maximum power condition for generators with realistic thermal coupling.

cond-mat.mtrl-sci↗

Irreversibilities and efficiency at maximum power of heat engines: illustrative case of a thermoelectric generator

Thermoelectric generators are particularly suitable to investigate the irreversible processes which govern the coupled transport of matter and heat in solid-state systems. We study the efficiency at maximum power in the strong coupling regime, where the thermal flux is proportionnal to the electrical current inside the generator. We demonstrate that depending on the source of irreversibility we obtain either the Curzon-Ahlborn efficiency for external dissipation or a universal efficiency at maximum power for internal dissipation. A continuous change between these two extremes is evidenced. Effects of dissymetry of thermal contact conductance are also investigated.

cond-mat.stat-mech↗

Efficiency at maximum power of thermally coupled heat engines

We study the efficiency at maximum power of two coupled heat engines, using thermoelectric generators (TEGs) as engines. Assuming that the heat and electric charge fluxes in the TEGs are strongly coupled, we simulate numerically the dependence of the behavior of the global system on the electrical load resistance of each generator in order to obtain the working condition that permits maximization of the output power. It turns out that this condition is not unique. We derive a simple analytic expression giving the relation between the electrical load resistance of each generator permitting output power maximization. We then focuse on the efficiency at maximum power (EMP) of the whole system to demonstrate that the Curzon-Ahlborn efficiency may not always be recovered: the EMP varies with the specific working conditions of each generator but remains in the range predicted by irreversible thermodynamics theory. We finally discuss our results in light of non-ideal Carnot engine behavior.

cond-mat.stat-mech↗

Thermoelectric internal current loops inside inhomogeneous systems

Considering a system composed of two different thermoelectric modules electrically and thermally connected in parallel, we demonstrate that the inhomogeneities of the thermoelectric properties of the materials may cause the appearance of an electrical current, which develops inside the system. We show that this current increases the effective thermal conductance of the whole system. We also discuss the significance of a recent finding concerning a reported new electrothermal effect in inhomogeneous bipolar semiconductors, in light of our results.

cond-mat.mtrl-sci↗

Optimal working conditions for thermoelectric generators with realistic thermal coupling

We study how maximum output power can be obtained from a thermoelectric generator(TEG) with nonideal heat exchangers. We demonstrate with an analytic approach based on a force-flux formalism that the sole improvement of the intrinsic characteristics of thermoelectric modules including the enhancement of the figure of merit is of limited interest: the constraints imposed by the working conditions of the TEG must be considered on the same footing. Introducing an effective thermal conductance we derive the conditions which permit maximization of both efficiency and power production of the TEG dissipatively coupled to heat reservoirs. Thermal impedance matching must be accounted for as well as electrical impedance matching in order to maximize the output power. Our calculations also show that the thermal impedance does not only depend on the thermal conductivity at zero electrical current: it also depends on the TEG figure of merit. Our analysis thus yields both electrical and thermal conditions permitting optimal use of a thermoelectric generator.

physics.class-ph↗

Polariton-polariton scattering in microcavities: A microscopic theory

We apply the fermion commutation technique for composite bosons to polariton-polariton scattering in semiconductor planar microcavities. Derivations are presented in a simple and physically transparent fashion. A procedure of orthogonolization of the initial and final two-exciton state wavefunctions is used to calculate the effective scattering matrix elements and the scattering rates. We show how the bosonic stimulation of the scattering appears in this full fermionic approach whose equivalence to the bosonization method is thus demonstrated in the regime of low exciton density. We find an additional contribution to polariton-polariton scattering due to the exciton oscillator strength saturation, which we analyze as well. We present a theory of the polariton-polariton scattering with opposite spin orientations and show that this scattering process takes place mainly via dark excitonic states. Analytical estimations of the effective scattering amplitudes are given.

cond-mat.mes-hall↗

Photon emission induced by elastic exciton--carrier scattering in semiconductor quantum wells

We present a study of the elastic exciton--electron ($X-e^-$) and exciton--hole ($X-h$) scattering processes in semiconductor quantum wells, including fermion exchange effects. The balance between the exciton and the free carrier populations within the electron-hole plasma is discussed in terms of ionization degree in the nondegenerate regime. Assuming a two-dimensional Coulomb potential statically screened by the free carrier gas, we apply the variable phase method to obtain the excitonic wavefunctions, which we use to calculate the 1$s$ exciton--free carrier matrix elements that describe the scattering of excitons into the light cone where they can radiatively recombine. The photon emission rates due to the carrier-assisted exciton recombination in semiconductor quantum-wells (QWs) at room temperature and in a low density regime are obtained from Fermi's golden rule, and studied for mid-gap and wide-gap materials. The quantitative comparison of the direct and exchange terms of the scattering matrix elements shows that fermion exchange is the dominant mechanism of the exciton--carrier scattering process. This is confirmed by our analysis of the rates of photon emission induced by electron-assisted and hole-assisted exciton recombinations.

cond-mat.other↗

Bose glass and superfuid phases of cavity polaritons

We report the calculation of cavity exciton-polariton phase diagram which takes into account the presence of realistic structural disorder. Polaritons are modelled as weakly interacting two-dimensional bosons. We show that with increasing density polaritons first undergo a quasi-phase transition towards a Bose glass: the condensate is localized in at least one minimum of the disorder potential, depending on the value of the chemical potential of the polariton system. A further increase of the density leads to a percolation process of the polariton fluid which gives rise to a Kosterlitz-Thouless phase transition towards superfluidity. The spatial representation of the condensate wavefunction as well as the spectrum of elementary excitations are obtained from the solution of the Gross-Pitaevskii equation for all the phases.

cond-mat.mtrl-sci↗