arXiv subjects

H. R. Sadeghpour

Publications and source records attributed to H. R. Sadeghpour.

At least 55 records · Page 3Linked to original sources

arXiv2020

Formation of Argon Cluster with Proton Seeding

We employ force-field molecular dynamics simulations to investigate the kinetics of nucleation to new liquid or solid phases in a dense gas of particles, seeded with ions. We use precise atomic pair interactions, with physically correct long-range behavior, between argon atoms and protons. Time-dependence of molecular cluster formation is analyzed at different proton concentration, temperature and argon gas density. The modified phase transitions with proton seeding of the argon gas are identified and analyzed. The seeding of the gas enhances the formation of nano-size atomic clusters and their aggregation. The strong attraction between protons and bath gas atoms stabilizes large nano-clusters and the critical temperature for evaporation. An analytical model is proposed to describe the stability of argon-proton droplets, and is compared with the molecular dynamics simulations.

physics.chem-ph↗

arXiv2020

Ultralong-range Rydberg bi-molecules

We predict that ultralong-range Rydberg bi-molecules form in collisions between polar molecules in cold and ultracold settings. The collision of $Λ$-doublet nitric oxide (NO) with long-lived Rydberg NO($nf$, $ng$) molecules forms ultralong-range Rydberg bi-molecules with GHz energies and kilo-Debye permanent electric dipole moments. The Hamiltonian includes both the anisotropic charge-molecular dipole interaction and the electron-NO scattering. The rotational constant for the Rydberg bi-molecules is in the MHz range, allowing for microwave spectroscopy of rotational transitions in Rydberg bi-molecules. Considerable orientation of NO dipole can be achieved. The Rydberg molecules described here hold promise for studies of a special class of long-range bi-molecular interactions.

physics.atom-ph↗

arXiv2020

Rydberg spectrum of a single trapped Ca$^+$ ion: A Floquet analysis

We compute the Rydberg spectrum of a single Ca$^+$ ion in a Paul trap by incorporating various internal and external coupling terms of the ion to the trap in the Hamiltonian. The coupling terms include spin-orbit coupling in Ca$^+$, charge (electron and ionic core) coupling to the radio frequency and static fields, ion-electron coupling in the Paul trap, and ion center-of-mass coupling. The electronic Rydberg states are precisely described by a one-electron model potential for e$^-$+Ca$^{2+}$, and accurate eigenenergies, quantum defect parameters, and static and tensor polarizabilities for a number of excited Rydberg states are obtained. The time-periodic rf Hamiltonian is expanded in the Floquet basis, and the trapping-field-broadened Rydberg lines are compared with recent observations of Ca$^+(23P)$ and Ca$^+(52F)$ Rydberg lines.

physics.atom-ph↗

arXiv2019

A protocol to realize triatomic ultralong range Rydberg molecules in an ultracold KRb gas

We propose an experimentally realizable scheme to produce triatomic ultralong-range Rydberg molecules (TURM), formed in ultracold KRb traps. A near resonant coupling of the non-zero quantum defect Rydberg levels with the KRb molecule in N=0 and N=2 rotational levels, is engineered which exploits the unique Rydberg electron-molecule anisotropic dipole interaction. This near resonant coupling enhances the TURM binding and produces favorable Franck-Condon factors. Schemes for both postassium and rubidium excitations are demonstrated.

physics.atom-ph↗

arXiv2019

Efficient variational approach to dynamics of a spatially extended bosonic Kondo model

We develop an efficient variational approach to studying dynamics of a localized quantum spin coupled to a bath of mobile spinful bosons. We use parity symmetry to decouple the impurity spin from the environment via a canonical transformation and reduce the problem to a model of the interacting bosonic bath. We describe coherent time evolution of the latter using bosonic Gaussian states as a variational ansatz. We provide full analytical expressions for equations describing variational time evolution that can be applied to study in- and out-of-equilibrium phenomena in a wide class of quantum impurity problems. In the accompanying paper [Y. Ashida {\it et al.}, Phys. Rev. Lett. 123, 183001 (2019)], we present a concrete application of this general formalism to the analysis of the Rydberg Central Spin Model, in which the spin-1/2 Rydberg impurity undergoes spin-changing collisions in a dense cloud of two-component ultracold bosons. To illustrate new features arising from orbital motion of the bath atoms, we compare our results to the Monte Carlo study of the model with spatially localized bosons in the bath, in which random positions of the atoms give rise to random couplings of the standard central spin model.

cond-mat.str-el↗

arXiv2019

Quantum Rydberg Central Spin Model

We consider dynamics of a Rydberg impurity in a cloud of ultracold bosonic atoms in which the Rydberg electron can undergo spin-changing collisions with surrounding atoms. This system realizes a new type of the quantum impurity problem that compounds essential features of the Kondo model, the Bose polaron, and the central spin model. To capture the interplay of the Rydberg-electron spin dynamics and the orbital motion of atoms, we employ a new variational method that combines an impurity-decoupling transformation with a Gaussian ansatz for the bath particles. We find several unexpected features of this model that are not present in traditional impurity problems, including interaction-induced renormalization of the absorption spectrum that eludes simple explanations from molecular bound states, and long-lasting oscillations of the Rydberg-electron spin. We discuss generalizations of our analysis to other systems in atomic physics and quantum chemistry, where an electron excitation of high orbital quantum number interacts with a spinful quantum bath.

cond-mat.quant-gas↗

arXiv2019

Rydberg impurity in a Fermi gas: Quantum statistics and rotational blockade

We consider the quench of an atomic impurity via a single Rydberg excitation in a degenerate Fermi gas. The Rydberg interaction with the background gas particles induces an ultralong-range potential that binds particles to form dimers, trimers, tetramers, etc. Such oligomeric molecules were recently observed in atomic Bose-Einstein condensates. In this work, we demonstrate with a functional determinant approach that quantum statistics and fluctuations have observable spectral consequences. We show that the occupation of molecular states is predicated on the Fermi statistics, which suppresses molecular formation in an emergent molecular shell structure. At large gas densities this leads to spectral narrowing, which can serve as a probe of the quantum gas thermodynamic properties.

cond-mat.quant-gas↗

arXiv2019

Efficient computation of collisional $\ell$-mixing rate coefficients in astrophysical plasmas

We present analytical expressions for direct evaluation of $\ell$-mixing rate coefficients in proton-excited hydrogen atom collisions and describe a software package for efficient numerical evaluation of the collisional rate coefficients. Comparisons between rate coefficients calculated with various levels of approximation are discussed, highlighting their range of validity. These rate coefficients are benchmarked via radio recombination lines for hydrogen, evaluating the corresponding departure coefficients from local thermal equilibrium.

astro-ph.IM↗

arXiv2019

Observation of Multiphoton Frequency Conversion in Superconducting Circuits

Multiphoton up/down conversion in a transmon circuit, driven by a pair of microwaves tuned near and far off the qubit resonance, has been observed. The experimental realization of these high order non-linear processes is accomplished in the three-photon regime, when the transmon is coupled to weak bichromatic microwave fields with the same Rabi frequencies. A many-mode Floquet formalism, with longitudinal coupling, is used to simulate the quantum interferences in the absorption spectrum that manifest the multiphoton pumping processes in the transmon qubit. An intuitive graph theoretic approach is used to introduce effective Hamiltonians that elucidate main features of the Floquet results. The analytical solutions also illustrate how controllability is achievable for desired single- or multiphoton pumping processes in a wide frequency range.

quant-ph↗

arXiv2019

Probing Nonlocal Spatial Correlations in Quantum Gases with Ultra-long-range Rydberg Molecules

We present photo-excitation of ultra-long-range Rydberg molecules as a probe of spatial correlations in quantum gases. Rydberg molecules can be created with well-defined internuclear spacing, set by the radius of the outer lobe of the Rydberg electron wavefunction $R_n$. By varying the principal quantum number $n$ of the target Rydberg state, the molecular excitation rate can be used to map the pair-correlation function of the trapped gas $g^{(2)}(R_n)$. We demonstrate this with ultracold Sr gases and probe pair-separation length scales ranging from $R_n = 1400 - 3200$ $a_0$, which are on the order of the thermal de Broglie wavelength for temperatures around 1 $μ$K. We observe bunching for a single-component Bose gas of $^{84}$Sr and anti-bunching due to Pauli exclusion at short distances for a polarized Fermi gas of $^{87}$Sr, revealing the effects of quantum statistics.

physics.atom-ph↗

arXiv2019

Crystallographic orientation dependence of work function: Carbon adsorption on Au surfaces

We investigate the work function (WF) variation of different Au crystallographic surface orientations with carbon atom adsorption. Ab-initio calculations within density-functional theory are performed on carbon deposited (100), (110), and (111) gold surfaces. The WF behavior with carbon coverage for the different surface orientations is explained by the resultant electron charge density distributions. The dynamics of carbon adsorption at sub-to-one-monolayer (ML) coverage depends on the landscape of the potential energy surfaces. At higher ML coverage, because of adsorption saturation, the WF will have weak surface orientation dependence. This systematic study has consequential bearing on studies of electric-field noise emanating from polycrystalline gold ion-trap electrodes that have been largely employed in microfabricated electrodes.

physics.chem-ph↗

arXiv2018

Electric noise spectra of a near-surface nitrogen vacancy center diamond with a protective layer

Surface noise is a detrimental issue for sensing devices based on shallow nitrogen vacancy (NV) color center diamonds. A recent experiment indicates that electric field noise is significant compared to magnetic field noise. They also found that the electric field noise can be reduced with a protective surface layer, though the mechanism of noise reduction is not well understood. We examine the effect of a protective surface layer on the noise spectrum, which is caused by surface charge fluctuations. We use the fluctuation-dissipation theorem to calculate and analyze the noise spectrum for six different surface layer materials typically used for NV center diamond devices. We find that four parameters largely affect the noise spectrum: effective relaxation time, effective loss tangent, power law exponent of the noise spectrum, and layer thickness. Our results suggest that a surface covering layer is indeed useful for decreasing surface noise, but which material is most suitable depends on the device operational frequency range.

cond-mat.mes-hall↗

arXiv2018

Theory and simulation of spectral line broadening by exoplanetary atmospheric haze

Atmospheric haze is the leading candidate for the flattening of expolanetary spectra, as it's also an important source of opacity in the atmospheres of solar system planets, satellites, and comets. Exoplanetary transmission spectra, which carry information about how the planetary atmospheres become opaque to stellar light in transit, show broad featureless absorption in the region of wavelengths corresponding to spectral lines of sodium, potassium and water. We develop a detailed atomistic model, describing interactions of atomic or molecular radiators with dust and atmospheric haze particulates. This model incorporates a realistic structure of haze particulates from small nano-size seed particles up to sub-micron irregularly shaped aggregates, accounting for both pairwise collisions between the radiator and haze perturbers, and quasi-static mean field shift of levels in haze environments. This formalism can explain large flattening of absorption and emission spectra in haze atmospheres and shows how the radiator - haze particle interaction affects the absorption spectral shape in the wings of spectral lines and near their centers. The theory can account for nearly all realistic structure, size and chemical composition of haze particulates and predict their influence on absorption and emission spectra in hazy environments. We illustrate the utility of the method by computing shift and broadening of the emission spectra of the sodium D line in an argon haze. The simplicity, elegance and generality of the proposed model should make it amenable to a broad community of users in astrophysics and chemistry.

astro-ph.EP↗

arXiv2018

Mechanisms for carbon adsorption on Au(110)-(2*1): A work function analysis

The variation of the work function upon carbon adsorption on the reconstructed Au(110) surface is measured experimentally and compared to density functional calculations. The adsorption dynamics is simulated with ab-initio molecular dynamics techniques. The contribution of various energetically available adsorption sites on the deposition process is analyzed, and the work function behavior with carbon coverage is explained by the resultant electron charge density distributions.

physics.atom-ph↗

arXiv2018

Effective spin-spin interactions in bilayers of Rydberg atoms and polar molecules

We show that indirect spin-spin interactions between effective spin-1/2 systems can be realized in two parallel 1D optical lattices loaded with polar molecules and/or Rydberg atoms. The effective spin can be encoded into low-energy rotational states of polar molecules or long-lived states of Rydberg atoms, tightly trapped in a deep optical lattice. The spin-spin interactions can be mediated by Rydberg atoms, placed in a parallel shallow optical lattice, interacting with the effective spins by charge-dipole (for polar molecules) or dipole-dipole (for Rydberg atoms) interaction. Indirect XX, Ising and XXZ interactions with interaction coefficients $J^{\bot}$ and $J^{zz}$ sign varying with interspin distance can be realized, in particular, the $J_{1}-J_{2}$ XXZ model with frustrated ferro-(antiferro-)magnetic nearest (next-nearest) neighbor interactions.

quant-ph↗

arXiv2018

Creation of Rydberg Polarons in a Bose Gas

We report spectroscopic observation of Rydberg polarons in an atomic Bose gas. Polarons are created by excitation of Rydberg atoms as impurities in a strontium Bose-Einstein condensate. They are distinguished from previously studied polarons by macroscopic occupation of bound molecular states that arise from scattering of the weakly bound Rydberg electron from ground-state atoms. The absence of a $p$-wave resonance in the low-energy electron-atom scattering in Sr introduces a universal behavior in the Rydberg spectral lineshape and in scaling of the spectral width (narrowing) with the Rydberg principal quantum number, $n$. Spectral features are described with a functional determinant approach (FDA) that solves an extended Fröhlich Hamiltonian for a mobile impurity in a Bose gas. Excited states of polyatomic Rydberg molecules (trimers, tetrameters, and pentamers) are experimentally resolved and accurately reproduced with FDA.

quant-ph↗

arXiv2017

Electronic structure of ultralong-range Rydberg pentaatomic molecules with two polar diatomic molecules

We explore the electronic structure of ultralong-range pentaatomic Rydberg molecules from a merger of a Rydberg atom and two ground state heteronuclear diatomic molecules. Our focus is on the interaction of Rb($23s$) and Rb($n=20$, $l\ge 3$) Rydberg states with ground and rotationally excited KRb diatomic polar molecules. For symmetric and asymmetric configurations of the pentaatomic Rydberg molecule, we investigate the metamorphosis of the Born-Oppenheimer potential curves, essential for the binding of the molecule, with varying distance from the Rydberg core and analyze the alignment and orientation of the polar diatomic molecules.

quant-ph↗

arXiv2017

Editorial: Special Issue on the Atomic and Molecular Processes in the Ultracold Regime, the Chemical Regime, and Astrophysics

This editorial introduces the J. Phys. B: Atomic, Molecular and Optical Physics Special Issue "Atomic and Molecular Processes in the Ultracold Regime, the Chemical Regime and Astrophysics" dedicated to Professor Alexander Dalgarno (1928-2015). After a brief biographical review, short summaries of the contributed papers and their relations to some of Prof. Dalgarno's work are given.

physics.hist-ph↗