arXiv subjects

H. Sakata

Publications and source records attributed to H. Sakata.

13 recordsLinked to original sources

arXiv2023

Bulk superconductivity in Pb-substituted BiS$_{\bf 2}$-based compounds studied by hard-x-ray spectroscopy

In this study, we investigate the bulk electronic structure of Pb-substituted LaO$_{0.5}$F$_{0.5}$BiS$_2$ single crystals, using two types of hard-x-ray spectroscopy. High-energy-resolution fluorescence-detected x-ray absorption spectroscopy revealed a spectral change at low temperatures. Using density functional theory (DFT) simulations, we find that the temperature-induced change originates from a structural phase transition, similar to the pressure-induced transition in LaO$_{0.5}$F$_{0.5}$BiS$_2$. This finding suggests that the mechanism of bulk superconductivity induced by Pb substitution is the same as that under high pressure. Furthermore, a novel low-valence state with a mixture of divalent and trivalent Bi ions is discovered using hard x-ray photoemission spectroscopy with the aid of DFT calculations.

cond-mat.supr-con↗

arXiv2017

Effect of Lead Substitution on LaO0.5F0.5BiS2

We examined Lead (Pb) Substitution effect on a single crystal of a layered superconductor LaO0.5F0.5BiS2. Pb concentration dependence of the lattice constant showed slight anomaly at about 8% and 9% substitution of Pb for Bi. These samples showed the enhancement of the superconducting transition temperature and the superconducting volume fraction. Furthermore, these samples showed the anomaly in the temperature dependence of the resistivity at about 150K. These results were not observed in Pb substituted NdO0.7F0.3BiS2. Therefore, the enhancement of the superconducting properties by Pb substitution is related to the structural instability for the pale perturbation in LaO0.5F0.5BiS2.

cond-mat.supr-con↗

arXiv2015

Enhancement of Tc in BiS2 based superconductors NdO0.7F0.3BiS2 by substitution of Pb for Bi

We succeed in enhancement of a superconducting transition temperature (Tc) for NdO0.7F0.3BiS2 single crystal by partial substitution of Pb for Bi. The Tc increases with increasing Pb concentration until 6%. The maximum Tczero is 5.6 K, which is the highest value among BiS2 based superconductors synthesized under an ambient pressure. Pb substitution for Bi induces lattice shrinkage along the c axis. These results reflect that superconductivity in this system is responsive to the lattice strain.

cond-mat.supr-con↗

arXiv2015

Visualizing the Pt doping effect on surface and electronic structure in Ir_{1-x}Pt_{x}Te_{2} by scanning tunneling microscopy and spectroscopy

We report on the Pt doping effect on surface and electronic structure in Ir$_{\mathrm{1-x}}$Pt$_{\mathrm{x}}$Te$_ {\mathrm{2}}$ by scanning tunneling microscopy (STM) and spectroscopy (STS). The surface prepared by cleavage at 4.2 K shows a triangular lattice of topmost Te atoms. The compounds that undergo structural transition have supermodulation with a fixed wave vector $q = \frac{2π}{5a_m}$ (where $a_m$ is the lattice constant in the monoclinic phase) despite the different Pt concentrations. The superconducting compounds show patch structures. The surface of the compound that exhibits neither the superconductivity nor the structural transition shows no superstructure. In all doped samples, the dopant is observed as a dark spot in STM images. The tunneling spectra near the dopant show the change in the local density of state at approximately -200 mV. Such microscopic effects of the dopant give us the keys for establishing a microscopic model of this material.

cond-mat.supr-con↗

arXiv2014

Checkerboard stripe electronic state on cleaved surface of NdO$_{0.7}$F$_{0.3}$BiS$_{2}$ probed by scanning tunneling microscope

We present scanning tunneling microscopy measurements on a cleaved surface of the recently discovered superconductor NdO$_{0.7}$F$_{0.3}$BiS$_{2}$ with a transition temperature ($T_{\mathrm{c}}$) of 5.1 K.Tunneling spectra at 4.2 K (below $T_{\mathrm{c}}$) and 22 K (above $T_{\mathrm{c}}$) show a large spectroscopic gap ($\sim$40 mV), which is inconsistent with the metallic nature demonstrated in bulk measurements. Moreover, we find two interesting real-space electronic features. The first feature is a `checkerboard stripe' electronic state characterized by an alternating arrangement of two types of nanocluster. In one cluster, one-dimensional electronic stripes run along one Bi-Bi direction, whereas, in the other cluster, the stripes run along the other Bi-Bi direction. The second feature is a nanoscale electronic inhomogeneity whose microscopic source seems to be atomic defects on the cleaved surface or dopant F atoms.

cond-mat.supr-con↗

arXiv2013

Visualization of the effect of structural supermodulation on electronic structure in IrTe$_{2}$ by scanning tunneling spectroscopy

We report on the scanning tunneling spectroscopy experiments on single crystals of IrTe$_{2}$. A structural supermodulation and a local density-of-states (LDOS) modulation with a wave vector of $q$ = 1/5$\times$$2π/a_{0}$ ($a_{0}$ is the lattice constant in the $ab$-plane) have been observed at 4.2K where the sample is in the monoclinic phase. %We cannot find an energy gap emerging reproducibly.% on the region where the supermodulation resides. As synchronized with the supermodulation, the LDOS spatially modulates within two energy ranges (below -200 meV and around -100 meV). We further investigated the effect of the local perturbations including the antiphase boundaries and the twin boundaries on the LDOS. These perturbations also modify the LDOS below -200 meV and around -100 meV, even though the lattice distortions induced by these perturbations appear to be different from those by the supermodulation. Our results indicating several microscopic structural effects on the LDOS seem to offer crucial keys for the establishment of the microscopic model describing the parent state.

cond-mat.str-el↗

arXiv2013

Observation of isosceles triangular electronic structure around excess iron atoms in Fe$_{1+δ}$Te

We present scanning tunneling microscopy and spectroscopy studies around an individual excess Fe atom, working as a local perturbation, in the parent material of the iron-chalcogenide superconductor Fe$_{1+δ}$Te. Spectroscopic imaging reveals a novel isosceles triangular electronic structure around the excess Fe atoms. Its spatial symmetry reects the underlying bicollinear antiferromagnetic spin state and the structural monoclinic symmetry. These findings provide important clues to understand the role of the excess Fe atoms, which complicate the understanding of the phenomena occurring in iron-chalcogenide materials.

cond-mat.str-el↗

arXiv2012

Electromagnon and phonon excitations in multiferroic TbMnO3

We have performed Raman measurements on TbMnO3 single crystal under magnetic field along the three crystallographic directions. The flip of the spin spiral plane creates an electromagnon excitation. In addition to the electromagnons induced by the Heisenberg coupling, we have detected the electromagnon created by the Dzyaloshinskii-Moriya interaction along the c axis. We have identified all the vibrational modes of TbMnO3. Their temperature dependences show that only one phonon observed along the polarization axis is sensitive to the ferroelectric transition. This mode is tied to the Tb3+ ion displacements that contribute to the ferroelectric polarization.

cond-mat.str-el↗

arXiv2011

Magnetic field induced dehybridization of the electromagnons in multiferroic TbMnO3

We have studied the impact of the magnetic field on the electromagnon excitations in TbMnO3 crystal. Applying magnetic field along the c axis, we show that the electromagnons transform into pure antiferromagnetic modes, losing their polar character. Entering in the paraelectric phase, we are able to track the spectral weight transfer from the electromagnons to the magnon excitations and we discuss the magnetic excitations underlying the electromagnons. We also point out the phonons involved in the phase transition process. This reveals that the Mn-O distance plays a key role in understanding the ferroelectricity and the polar character of the electromagnons. Magnetic field measurements along the b axis allow us to detect a new electromagnon resonance in agreement with a Heisenberg model.

cond-mat.mtrl-sci↗

arXiv2010

Infrared reflectivity of the phonon spectra in multiferroic TbMnO3

We measured the temperature dependent infrared reflectivity spectra of TbMnO3 with the electric field of light polarized along each of the three crystallographic axes. We analyzed the effect, on the phonon spectra, of the different phase transitions occurring in this material. We show that the antiferromagnetic transition at TN renormalizes the phonon parameters along the three directions. Our data indicate that the electromagnon, observed along the a direction, has an important contribution to the building of the dielectric constant. Only one phonon, observed along the c-axis, has anomalies at the ferroelectric transition. This phonon is built mostly from Mn vibrations, suggesting that Mn displacements are closely related to the formation of the ferroelectric order.

cond-mat.mtrl-sci↗

arXiv2009

Magneto-electric excitations in multiferroic TbMnO3 by Raman scattering

Low energy excitations in the multiferroic material TbMnO3 have been investigated by Raman spectroscopy. Our observations reveal the existence of two peaks at 30 cm-1 and 60 cm-1. They are observed in the cycloidal phase below the Curie temperature but not in the sinusoidal phase, suggesting their magnetoelectric origin. While the peak energies coincide with the frequencies of electromagnons measured previously by transmission spectroscopy, they show surprisingly different selection rules, with the 30 cm-1 excitation enhanced by the electric field of light along the spontaneous polarization. The origins of the modes are discussed under Raman and infrared selection rules considerations.

cond-mat.str-el↗

arXiv2008

Doping Dependence of Two Energy Scales in the Tunneling Spectra of Superconducting La$_{2-x}$Sr$_{x}$CuO$_{4}$

Scanning tunneling microscopy and spectroscopy have been performed on superconducting La$_{2-x}$Sr$_{x}$CuO$_{4}$ ($x=0.06, 0.12, 0.16$, and 0.21) at 4.2 K. Atomically resolved surface topography has been observed on the $ab$ surface, which exhibits a one-dimensional structure corresponding to the buckling pattern of the orthorhombic phase. The tunneling spectra of all samples exhibit kinks at about $\pm 5$ meV in addition to the energy gap, indicating the existence of two energy scales. While the gap magnitude varies on the length scale of a few nm and steadily increases upon underdoping, the kink energy is spatially uniform on the surface and almost independent of the doping level.

cond-mat.supr-con↗

arXiv2006

Appearance of New Energy Gap and Periodic Local Density-of-States Modulation in $Bi_2 Sr_{1.6} La_{0.4} CuO_{6+δ}$

The spatial variation of the local density of states in optimally doped Bi$_{2}$Sr$_{1.6}$La$_{0.4}$CuO$_{6+δ}$ (superconducting transition temperature is 34 K) is studied by scanning tunneling spectroscopy at 4.2 K in zero magnetic field. Two-dimensional density-of-states modulation aligned with the Cu-O-Cu bond with a periodicity of about five lattice constants is observed. It is found that this modulation accompanies the appearance of a new energy gap of approximately 10 meV, whose gap edge peak is spatially modulated in intensity. This gap coexists with the superconducting gap, the value of which ranges from 10 meV to 60 meV.

cond-mat.supr-con↗