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H. T. Quan

Publications and source records attributed to H. T. Quan.

At least 19 recordsLinked to original sources

Fluctuation theorems for autonomous work in the quantum regime

Fluctuation theorems for work provide universal constraints on nonequilibrium fluctuations, yet their quantum generalizations often rely on externally prescribed classical driving protocols. While for classical systems, fluctuation theorems have been extended to autonomous work, where the dynamics of the work source is subject to the backaction of the system, their generalization to the quantum regime is constrained by the uncertainty principle. Here, we extend fluctuation theorems for autonomous work from the classical regime to the quantum regime. By performing successive projective measurements over the work source and the system, we derive Jarzynski-type and Crooks-type fluctuation theorems for autonomous inclusive work from initial mixed thermal states. These relations are analogous to fluctuation theorems for autonomous work in the classical regime and explicitly incorporate the fluctuations of the work source. However, quantum noncommutativity prevents a consistent reduction to the nonautonomous counterparts, even in the limit of a large work source and correspondingly negligible backaction. By contrast, under the exclusive work definition, the nonautonomous limit is recovered when the measured observable of the work source commutes with its bare Hamiltonian and the backaction of the system on the work source is negligible. Our results are illustrated with the Dicke model, where a single-mode radiation field and an ensemble of two-level atoms act as the system of interest and the work source, respectively.

cond-mat.stat-mech

A Field-Theoretic Framework for Work Statistics and Universal Scaling in Non-equilibrium Phase Transitions

We develop a field-theoretic framework for work statistics in $O(N)$ models driven through criticality. By analyzing the dynamic renormalization group flow of composite power operators, we find the Kibble-Zurek scaling laws as a natural consequence of the flow, and we derive the scaling of work cumulants relevant to Kibble-Zurek scaling of topological defects from first principles, bypassing heuristic freeze-out argument. This yields the universal scaling $c_n \sim τ_Q^{-α_n}$ for the $n$-th work cumulant density: isolated quantum systems exhibit a scaling of $α_n = p(d+nz)ν/(1+pzν)$, whereas open quantum and classical systems undergo a dimensional collapse to $α_n = pdν/(1+pzν)$. Validated by exact Gaussian solutions and numerical simulations, our theory establishes a foundation for general work statistics far from equilibrium, thereby bridging stochastic thermodynamics and the renormalization group theory.

cond-mat.stat-mech

Stochastic Thermodynamics of Score Matching in Diffusion Models

Score-based diffusion models are a powerful class of generative AI systems capable of sampling from complex, high-dimensional probability distributions. Their dynamics consist of a forward diffusion process that transforms data into noise and a learned reverse process that reconstructs data by reversing the probability flow. Here, we develop a stochastic thermodynamic framework for diffusion models and their score-matching objective. We introduce a trajectory-dependent quantity, time-asymmetry entropy production (TAEP), defined from the forward and reverse diffusion dynamics, and show that it obeys exact fluctuation theorems. Remarkably, Hyvärinen's implicit score-matching kernel emerges naturally as a fluctuating component of TAEP, while the average TAEP is exactly proportional to the score-matching objective. We further show that fluctuations of TAEP quantify sampling unevenness and provide a thermodynamic measure of data-manifold coverage. These results yield a quantitative explanation for the superior sampling diversity of diffusion models and reveal a thermodynamic mechanism by which stochastic gradient descent favors flatter, more generalizable solutions. By uncovering the entropic nature of score matching, our work establishes fundamental statistical-mechanical principles underlying diffusion-based generative AI.

cond-mat.dis-nn

Extending Covariant Fluctuation Theorems into Quantum Regime through Quasiprobability Approach

The covariant formulation of stochastic thermodynamics requires treating the stochastic work as a 4-vector, posing significant challenges for quantum systems due to the non-commutativity. We introduce a new quasiprobability distribution for the work 4-vector, which combines the Wigner and Margenau-Hill quasiprobabilities. This extends the covariant fluctuation theorems from classical to quantum regime. We illustrate our findings with a scalar field driven by classical particles with a generalized version of trace formula. Our work establishes a quasiprobability approach to studying relativistic quantum thermodynamics in a covariant way.

cond-mat.stat-mech

Scaling Behaviors of Work Cumulants in Slow Isothermal Processes

We study the cumulants of work in a slow isothermal process for gapped systems. Using the Martin-Siggia-Rose-De Dominicis-Janssen (MSRDJ) formalism and the properties of connected correlation functions, we show that in this process, the $n$-th cumulant of work scales as $1/T^{n-1}$ , where $T$ is the time duration. This result holds generally for arbitrary smooth protocols. Furthermore, we derive the coefficients of the cumulants from equilibrium properties. These coefficients are found to be relevant to thermodynamic geometric tensors.

cond-mat.stat-mech

Criticality around the Spinodal Point of First-Order Quantum Phase Transitions

Universality and scaling are hallmarks of second-order phase transitions but are generally unexpected in first-order quantum phase transitions (FOQPTs). We present a microscopic theory showing that quantum criticality can emerge around the quantum spinodal point of FOQPTs where metastability disappears. We demonstrate that, at this instability, resonant local excitations dynamically decouple a Hilbert subspace characterized by an emergent discrete translational symmetry. Projecting the original Hamiltonian onto this subspace yields an effective Hamiltonian that exhibits a genuine second-order quantum phase transition (SOQPT) and the Kibble-Zurek scaling. We validate this framework in the tilted Ising chain which breaks $\mathbb{Z}_2$ symmetry, and predict the absence of criticality in the staggered-field PXP model. This work indicates that the dynamics of FOQPTs is usually governed by an emergent critical point around the quantum spinodal point. Our results uncover a hidden criticality in FOQPTs, reshaping the conventional understanding of FOQPTs beyond the mean-field theory.

cond-mat.stat-mech

Exact four-vector work distribution and covariant fluctuation theorems of work for a relativistic particle in an expanding piston

We investigate the non-equilibrium four-vector work in an expanding relativistic piston. We derive the exact work distribution in this pedagogical model and find that the joint distribution of four-vector work $(W^0, W^1)$ concentrates on the origin and some curves in the $(W^0, W^1)$ space, rather than being smoothly distributed. In the non-relativistic limit, our model consistently recovers the non-relativistic dynamics. We further demonstrate that the momentum component of four-vector work remains significant in both the Lorentz-relativistic and Galilean-relativistic frameworks. On top of the work distribution, we verify a family of covariant fluctuation theorems of work. In addition, we introduce a novel geometrical technique for analyzing the dynamics of relativistic collision processes, which can be straightforwardly extended to multi-dimensional piston models.

cond-mat.stat-mech

Exact Work Distribution and Jarzynski's Equality of a Relativistic Particle in an Expanding Piston

We study the non-equilibrium work in a pedagogical model of relativistic ideal gas. We obtain the exact work distribution and verify the Jarzynski's equality. In the non-relativistic limit, our results recover the non-relativistic results [arXiv:cond-mat/0502434]. We also find that, unlike the non-relativistic case, the work distribution no longer has zeros and the number of collisions in this relativistic gas model is finite. In addition, based on an analysis of the experimental parameters, we conclude that it is difficult to detect the relativistic effects of the work distribution of the ideal gas in a piston system with the current experimental techniques.

cond-mat.stat-mech

Promoting Fluctuation Theorems into Covariant Forms

The principle of covariance, a cornerstone of modern physics, asserts the equivalence of all inertial frames of reference. Fluctuation theorems, as extensions of the second law of thermodynamics, establish universal connections between irreversibility and fluctuation in terms of stochastic thermodynamic quantities. However, these relations typically assume that both the thermodynamic system and the heat bath are at rest with respect to the observer, thereby failing to satisfy the principle of covariance. In this study, by introducing covariant work and heat that incorporate both energy-related and momentum-related components, we promote fluctuation theorems into covariant forms applicable to moving thermodynamic systems and moving heat baths. We illustrate this framework with two examples: the work statistics of a relativistic stochastic field and the heat statistics of a relativistic Brownian motion. Although our study is carried out in the context of special relativity, the results can be extended to the nonrelativistic limit. Our work combines the principle of covariance and fluctuation theorems into a coherent framework and may have applications in the study of thermodynamics relevant to cosmic microwave background as well as the radiative heat transfer and noncontact friction between relatively moving bodies.

cond-mat.stat-mech

Ergodicity Breaking and Scaling Relations for Finite-Time First-Order Phase Transition

Hysteresis and metastable states are typical features associated with ergodicity breaking in the first-order phase transition. We explore the scaling relations of nonequilibrium thermodynamics in finite-time first-order phase transitions. Using the Curie-Weiss model as an example, for large systems we find the excess work scales as $v^{2/3}$ when the magnetic field is quenched at a finite rate $v$ across the phase transition. We further reveal a crossover in the scaling of the excess work from $v^{2/3}$ to $v$ when downsizing the system. Our study elucidates the interplay between the finite-time dynamics and the finite-size effect, which leads to different scaling behaviors of the excess work with or without ergodicity breaking.

cond-mat.stat-mech

Lorentz Transformation of the Energy Spectrum of the Equilibrium State of Massive Free Fields

In previous studies of relativistic thermodynamics, the temperature of a static system, as perceived by a moving observer, has traditionally been treated as a scalar. This assumption has also been extended to the research on the cosmic microwave background. However, the validity of this assumption is a consequence of the massless nature of photons. More generally, when an observer is in relative motion to a system, the thermal equilibrium state is characterized by a four-vector temperature. In this paper, we study the non-interacting massive Bosonic and Fermionic field systems. We derive the Lorentz transformation of the energy spectral density in the equilibrium state of these fields. In the massless limit for bosonic field, our results recover the transformation of black body radiation [G. W. Ford and R. F. O' Connell., Phys. Rev. E, 88, 044101(2013)], which corresponds to a scalar temperature with dipole anisotropy. For the massive fields, the moving equilibrium state cannot be characterized by a corresponding scalar temperature. This result shows the necessity of introducing four-vector temperature in relativistic thermodynamics.

cond-mat.stat-mech

Optimal control theory for maximum power of Brownian heat engines

The pursuit of achieving the maximum power in microscopic thermal engines has gained increasing attention in recent studies of stochastic thermodynamics. We employ the optimal control theory to study the performance of Brownian heat engines and determine the optimal heat-engine cycles in generic damped situation, which were previously known only in the overdamped and the underdamped limits. These optimal cycles include two isothermal processes, two adiabatic processes, and an extra isochoric relaxation process at the upper stiffness constraint. Our results not only interpolate the optimal cycles between the overdamped and the underdamped limits, but also determine the appropriate friction coefficient of the Brownian heat engine to achieve the maximum power. These findings offer valuable insights for the development of high-performance Brownian heat engines in experimental setups.

cond-mat.stat-mech

Exploring quasiprobability approach to quantum work in the presence of initial coherence: Advantages of the Margenau-Hill distribution

In quantum thermodynamics, the two-projective-measurement (TPM) scheme provides a successful description of stochastic work only in the absence of initial quantum coherence. Extending the quantum work distribution to quasiprobability is a general approach to characterize work fluctuation in the presence of initial coherence. However, among a large number of different definitions, there is no consensus on the most appropriate work quasiprobability. In this article, we list several physically reasonable requirements including the first law of thermodynamics, time-reversal symmetry, positivity of second-order moment, and a support condition for the work distribution. We prove that the only definition that satisfies all these requirements is the Margenau-Hill (MH) quasiprobability of work. In this sense, the MH quasiprobability of work shows its advantages over other definitions. As an illustration, we calculate the MH work distribution of a breathing harmonic oscillator with initial squeezed states and show the convergence to classical work distribution in the classical limit.

cond-mat.stat-mech

Heat statistics in the relaxation process of the Edwards-Wilkinson elastic manifold

The stochastic thermodynamics of systems with a few degrees of freedom has been studied extensively so far. We would like to extend the study to systems with more degrees of freedom and even further-continuous fields with infinite degrees of freedom. The simplest case for a continuous stochastic field is the Edwards-Wilkinson elastic manifold. It is an exactly solvable model of which the heat statistics in the relaxation process can be calculated analytically. The cumulants require a cutoff spacing to avoid ultra-violet divergence. The scaling behavior of the heat cumulants with time and the system size as well as the large deviation rate function of the heat statistics in the large size limit is obtained.

cond-mat.stat-mech

Hierarchical structure of fluctuation theorems for a driven system in contact with multiple heat reservoirs

For driven open systems in contact with multiple heat reservoirs, we find the marginal distributions of work or heat do not satisfy any fluctuation theorem, but only the joint distribution of work and heat satisfies a family of fluctuation theorems. A hierarchical structure of these fluctuation theorems is discovered from microreversibility of the dynamics by adopting a step-by-step coarse-graining procedure in both classical and quantum regimes. Thus, we put all fluctuation theorems concerning work and heat into a unified framework. We also propose a general method to calculate the joint statistics of work and heat in the situation of multiple heat reservoirs via the Feynman-Kac equation. For a classical Brownian particle in contact with multiple heat reservoirs, we verify the validity of the fluctuation theorems for the joint distribution of work and heat.

cond-mat.stat-mech

Microreversibility, fluctuation relations, and response properties in 1D Kitaev Chain

We analytically calculate the cumulant generating function of energy and particle transport in an open 1D Kitaev chain by utilizing the Keldysh technique. The joint distribution of particle and energy currents obeys different fluctuation relations in different regions of the parameter space as a result of $U$(1) symmetry breaking and energy conservation. We discuss the thermoelectricity of the Kitaev chain as a three terminal system and derive an analytical expression of the maximum work power. The response theory up to the second order is explicitly checked, and the result is consistent with the relations derived from the fluctuation relation.

cond-mat.stat-mech

Full Counting Statistics and Fluctuation Theorem for the Currents in the Discrete Model of Feynman's Ratchet

We provide a detailed investigation on the fluctuations of the currents in the discrete model of Feynman's ratchet proposed by Jarzynski and Mazonka in 1999. Two macroscopic currents are identified, with the corresponding affinities determined using Schnakenberg's graph analysis. We also investigate full counting statistics of the two currents and show that fluctuation theorem holds for their joint probability distribution. Moreover, fluctuation-dissipation relation, Onsager reciprocal relation and their nonlinear generalizations are numerically shown to be satisfied in this model.

cond-mat.stat-mech

Work statistics across a quantum critical surface

We study the universality of work statistics of a system quenched through a quantum critical surface. By using the adiabatic perturbation theory, we obtain the general scaling behavior for all cumulants of work. These results extend the studies of Kibble-Zurek mechanism scaling of work statistics from an isolated quantum critical point to a critical surface. As an example, we study the scaling behavior of work statistics in the two-dimensional (2D) Kitaev honeycomb model featured with a critical line. By utilizing the trace formula for quadratic fermionic Hamiltonian, we obtain the exact characteristic function of work of the 2D Kitaev model at zero temperature. The results confirm our prediction.

cond-mat.stat-mech