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H. Takeya

Publications and source records attributed to H. Takeya.

At least 19 recordsLinked to original sources
arXiv2020

Intermittent dynamics of antiferromagnetic phase in inhomogeneous iron-based chalcogenide superconductor

Coexistence of phases, characterized by different electronic degrees of freedom, commonly occurs in layered superconductors. Among them, alkaline intercalated chalcogenides are model systems showing microscale coexistence of paramagnetic (PAR) and antiferromagnetic (AFM) phases, however, temporal behavior of different phases is still unknown. Here, we report the first visualization of the atomic motion in the granular phase of K$_{x}$Fe$_{2-y}$Se$_2$ using X-ray photon correlation spectroscopy. Unlike the PAR phase, the AFM texture reveals an intermittent dynamics with avalanches as in martensites. When cooled down across the superconducting transition temperature T$_c$, the AFM phase goes through an anomalous slowing behavior suggesting a direct relationship between the atomic motions in the AFM phase and the superconductivity. In addition of providing a compelling evidence of avalanche-like dynamics in a layered superconductor, the results provide a basis for new theoretical models to describe quantum states in inhomogeneous solids.

cond-mat.supr-con↗
arXiv2016

Novel Diamond Anvil Cell for Electrical Measurements using Boron-doped Metallic Diamond Electrodes

A novel diamond anvil cell suitable for electrical transport measurements under high pressure has been developed. A boron-doped metallic diamond film was deposited as an electrode onto a nano-polycrystalline diamond anvil using a microwave plasma-assisted chemical vapor deposition technique combined with electron beam lithography. The electrical transport measurements of Pb were performed up to 8 GPa, and the maximum pressure reached was above 30 GPa. The boron-doped metallic diamond electrodes showed no signs of degradation after repeated compression measurements.

cond-mat.supr-con↗
arXiv2015

Direct observation of nanoscale interface phase in the superconducting chalcogenide K$_{x}$Fe$_{2-y}$Se$_2$ with intrinsic phase separation

We have used scanning micro x-ray diffraction to characterize different phases in superconducting K$_{x}$Fe$_{2-y}$Se$_2$ as a function of temperature, unveiling the thermal evolution across the superconducting transition temperature (T$_c\sim$32 K), phase separation temperature (T$_{ps}\sim$520 K) and iron-vacancy order temperature (T$_{vo}\sim$580 K). In addition to the iron-vacancy ordered tetragonal magnetic phase and orthorhombic metallic minority filamentary phase, we have found a clear evidence of the interface phase with tetragonal symmetry. The metallic phase is surrounded by this interface phase below $\sim$300 K, and is embedded in the insulating texture. The spatial distribution of coexisting phases as a function of temperature provides a clear evidence of the formation of protected metallic percolative paths in the majority texture with large magnetic moment, required for the electronic coherence for the superconductivity. Furthermore, a clear reorganization of iron-vacancy order around the T$_{ps}$ and T$_c$ is found with the interface phase being mostly associated with a different iron-vacancy configuration, that may be important for protecting the percolative superconductivity in K$_{x}$Fe$_{2-y}$Se$_2$.

cond-mat.supr-con↗
arXiv2015

Temperature dependence of iron local magnetic moment in phase-separated superconducting chalcogenide

We have studied local magnetic moment and electronic phase separation in superconducting K$_{x}$Fe$_{2-y}$Se$_2$ by x-ray emission and absorption spectroscopy. Detailed temperature dependent measurements at the Fe K-edge have revealed coexisting electronic phases and their correlation with the transport properties. By cooling down, the local magnetic moment of Fe shows a sharp drop across the superconducting transition temperature (T$_c$) and the coexisting phases exchange spectral weights with the low spin state gaining intensity at the expense of the higher spin state. After annealing the sample across the iron-vacancy order temperature, the system does not recover the initial state and the spectral weight anomaly at T$_c$ as well as superconductivity disappear. The results clearly underline that the coexistence of the low spin and high spin phases and the transitions between them provide unusual magnetic fluctuations and have a fundamental role in the superconducting mechanism of electronically inhomogeneous K$_{x}$Fe$_{2-y}$Se$_2$ system.

cond-mat.supr-con↗
arXiv2014

On the superconductivity of the Li$_{x}$RhB$_{y}$ compositions

We observed superconductivity ($T_{c}$ $\simeq$2-3 K) in Li$_{x}$RhB$_{y}$ intermetallics wherein $x$ and $y$ vary over a wide compositional range. The crystal structure consists of cubic unit-cell ($a$ $\simeq$ 12.1 Å) with centro-symmetric space group $Pn\bar{3}n$. A weak but positive pressure-induced increase of $T_{c}$ was observed. The correlations between the composition and each of the followings were followed over a wide range of $x$ and $y$: the unit-cell dimensions, $T_{c}$ , Sommerfeld coefficient $γ$, Debye temperature $θ_{D}$, and critical fields $H$$_{c1}$ and $H$$_{c2}$. The thermal evolution of the electronic specific heat within the superconducting phase was observed to follow a quadratic-in-$T$ behavior. In addition, a paramagnetic Meissner Effect (PME) is manifested during a low-field-cooled magnetization cycle. This manifestation of quadratic-in-$T$ behavior and PME feature will be discussed.

cond-mat.supr-con↗
arXiv2014

Pressure-dependent magnetization and magnetoresistivity studies on the tetragonal FeS (mackinawite): revealing its intrinsic metallic character

The transport and magnetic properties of the tetragonal Fe$_{1+δ}$S were investigated using magnetoresistivity and magnetization within 2$\leq T\leq $300 K, $H\leq$70 kOe and $P\leq$ 3.0 GPa. In addition, room-temperature X-ray diffraction and photoelectron spectroscopy were also applied. In contrast to previously reported nonmetallic character, Fe$_{1+δ}$S is intrinsically metallic but due to a presence of a weak localization such metallic character is not exhibited below room temperature. An applied pressure reduces strongly this additional resistive contribution and as such enhances the temperature range of the metallic character which, for $\sim$3 GPa, is evident down to 75 K. The absence of superconductivity as well as the mechanism behind the weak localization will be discussed.

cond-mat.str-el↗
arXiv2014

On the bad metallicity and phase diagrams of Fe$_{1+δ}X$ ($X$ =Te, Se, S, solid solutions): an electrical resistivity study

Based on a systematic analysis of the thermal evolution of the resistivities of Fe-based chalcogenides Fe$_{1+δ}$Te$_{1-x}X_{x}$ ($X$= Se, S), it is inferred that their often observed nonmetallic resistivities are related to a presence of two resistive channels: one is a high-temperature thermally-activated process while the other is a low-temperature log-in-$T$ process. On lowering temperature, there are often two metal-to-nonmetall crossover events: one from the high-$T$ thermally-activated nonmetallic regime into a metal-like phase and the other from the log-in-$T$ regime into a second metal-like phase. Based on these events, together with the magnetic and superconducting transitions, a phase diagram is constructed for each series. We discuss the origin of both processes as well as the associated crossover events. We also discuss how these resistive processes are being influenced by pressure, intercalation, disorder, doping, or sample condition and, in turn, how these modifications are shaping the associated phase diagrams.

cond-mat.supr-con↗
arXiv2014

Spectromicroscopy of electronic phase separation in K$_x$Fe$_{2-y}$Se$_2$ superconductor

Structural phase separation in A$_x$Fe$_{2-y}$Se$_2$ system has been studied by different experimental techniques, however, it should be important to know how the electronic uniformity is influenced, on which length scale the electronic phases coexist, and what is their spatial distribution. Here, we have used novel scanning photoelectron microscopy (SPEM) to study the electronic phase separation in K$_x$Fe$_{2-y}$Se$_2$, providing a direct measurement of the topological spatial distribution of the different electronic phases. The SPEM results reveal a peculiar interconnected conducting filamentary phase that is embedded in the insulating texture. The filamentary structure with a particular topological geometry could be important for the high T$_c$ superconductivity in the presence of a phase with a large magnetic moment in A$_x$Fe$_{2-y}$Se$_2$ materials.

cond-mat.supr-con↗
arXiv2014

Anamalous positive magnetization signal at the onset of normal to superconductor transition in single crystal Nb sphere

We report the observation of positive magnetization signal at the onset of superconducting transition in isothemral and isomagnetic measurements in single crystal Niobium sphere. The PME displays two regimes, viz., low applied magnetic fields H < 4 Oe) and higher fields H > 120 Oe, and the PME signal is absent at the intermediate magnetic fields. Subsequently, the isothermal magnetization data shows the presence of positive signal at the superconductor to normal transition. Using this data we are able to plot the H(c3)-T(c3) line, at which the positive magnetization signal nucleates, in the phase diagram of single crystal Nb.

cond-mat.supr-con↗
arXiv2013

Observation of isosceles triangular electronic structure around excess iron atoms in Fe$_{1+δ}$Te

We present scanning tunneling microscopy and spectroscopy studies around an individual excess Fe atom, working as a local perturbation, in the parent material of the iron-chalcogenide superconductor Fe$_{1+δ}$Te. Spectroscopic imaging reveals a novel isosceles triangular electronic structure around the excess Fe atoms. Its spatial symmetry reects the underlying bicollinear antiferromagnetic spin state and the structural monoclinic symmetry. These findings provide important clues to understand the role of the excess Fe atoms, which complicate the understanding of the phenomena occurring in iron-chalcogenide materials.

cond-mat.str-el↗
arXiv2012

Superconductivity in Fe1+dTe0.9Se0.1 induced by deintercalation of excess Fe using alcoholic beverage treatment

Superconductivity in polycrystalline Fe1+dTe0.9Se0.1 was enhanced by heating in alcoholic beverages. We found that part of the excess Fe was deintercalated from the interlayer sites by the treatment and the shielding volume fractions were increased with the reduction of excess Fe content in sample. This behavior is similar to the case of Fe1+dTe1-xSx. Thus the technique of alcoholic beverage treatment can be applied generally to the Fe-chalcogenide superconductors.

cond-mat.supr-con↗
arXiv2012

Evolution of superconductivity in LaO1-xFxBiS2 prepared by high pressure technique

Novel BiS2-based superconductors LaO1-xFxBiS2 prepared by the high pressure synthesis technique were systematically studied. It was found that the high pressure annealing strongly the lattice as compared to the LaO1-xFxBiS2 samples prepared by conventional solid state reaction at ambient pressure. Bulk superconductivity was observed within a wide F-concentration range of x = 0.2 ~ 0.7. On the basis of those results, we have established a phase diagram of LaO1-xFxBiS2.

cond-mat.supr-con↗
arXiv2012

Fermiological Interpretation of Superconductivity/Non-superconductivity of FeTe_{1-x}Se_{x} Thin Crystal Determined by Quantum Oscillation Measurement

We have successfully observed quantum oscillation (QO) for FeTe_{1-x}Se_{x}. QO measurements were performed using non-superconducting and superconducting thin crystals of FeTe_{0.65}Se_{0.35} fabricated by the scotch-tape method. We show that the Fermi surfaces (FS) of the non-superconducting crystal are in good agreement with the rigid band shift model based on electron doping by excess Fe while that of the superconducting crystal is in good agreement with the calculated FS with no shift. From the FS comparison of both crystals, we demonstrate the change of the cross-sectional area of the FS, suggesting that the suppression of the FS nesting with the vector Q_{s} = (π, π) due to excess Fe results in the disappearance of the superconductivity.

cond-mat.supr-con↗
arXiv2012

Evolution of the magnetism of Tb(Co_{x}Ni_{1-x})_{2}B_{2}C

The magnetic properties of polycrystalline Tb(Co_{x}Ni_{1-x})_{2}B_{2}C (x=0.2,0.4,0.6,0.8) samples were probed by magnetization, specific heat, ac susceptibility, and resistivity techniques. For x{\neq}0.4, the obtained curves are consistent with the features expected for the corresponding magnetic modes, namely k_{1}=(0.55,0,0) at x=0; k_{2}=([nicefrac]\nicefrac{1}{2} ,0,[nicefrac] \nicefrac{1}{2}) at x= 0.2; k_{3}=(0,0,[nicefrac]\nicefrac{1}{3}) at x= 0.6, and k_{4}=(0,0,0) at x= 0.8 and 1. For x=0.4, even though the neutron diffraction indicates a k_{2} mode, but with a reduced magnetic moment, the magnetization, the ac susceptibility, and resistivity indicate two magnetic events; furthermore, deviation from Curie-Weiss behavior is observed below 150 K for this sample. These features, together with the evolution of both magnetic moment and critical temperature, are attributed to an interplay between competing magnetic couplings; for the particular x=0.4 case, additional factors such as crystalline electric field effects may be in operation.

cond-mat.str-el↗
arXiv2012

Coexistence of different electronic phases in the K0.8Fe1.6Se2 superconductor: a bulk-sensitive hard x-rays spectroscopy study

We have studied electronic and magnetic properties of the K0.8Fe1.6Se2 superconductor by x-ray absorption and emission spectroscopy. Detailed temperature dependent measurements alongwith a direct comparison with the binary FeSe system have revealed coexisting electronic phases: a majority phase with high spin 3+Fe state and a minority phase with intermediate spin 2+Fe state. The effect of high temperature annealing suggests that the compressed phase with lower spin 2+Fe state is directly related with the high Tc superconductivity in the title system. The results clearly underline glassy nature of superconductivity in the electronically inhomogeneous K0.8Fe1.6Se2, similar to the superconductivity in granular phases.

cond-mat.supr-con↗
arXiv2012

Quantum limiting behaviors of a vortex core in an anisotropic gap superconductor

Quantized bound states at a vortex core are discretized in YNi$_2$B$_2$C. By using scanning tunneling spectroscopy with an unprecedented 0.1 nm spatial resolution, we find and identify the localized spectral structure, where in addition to the first main peak with a positive low energy, a second subpeak coming from the fourfold symmetric gap structure is seen inside the energy gap. Those spectral features are understood by solving the Bogoliubov-de Gennes equation for a fully three-dimensional gap structure. A particle-hole asymmetric spectrum at the core site and quantum oscillation in the spectra are clearly observed.

cond-mat.supr-con↗
arXiv2012

Phase diagram and oxygen annealing effect of FeTe1-xSex iron-based superconductor

Phase diagrams of as-grown and O2-annealed FeTe1-xSex determined from magnetic susceptibility measurement were obtained. For as-grown samples, the antiferromagnetic order was fully suppressed in the range region x \geq 0.15, and weak superconductivity appeared when x \geq 0.1. Beginning at x = 0.5, weak superconductivity was found to evolve into bulk superconductivity. Interestingly, for O2-annealed samples, complete suppression of magnetic order and the occurrence of bulk superconductivity were observed when x \geq 0.1. We found that O2-annealing induces bulk superconductivity for FeTe1-xSex. Oxygen probably plays a key role in the suppression of the magnetic order and the appearance of bulk superconductivity.

cond-mat.supr-con↗