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H. Yoshizawa

Publications and source records attributed to H. Yoshizawa.

At least 19 recordsLinked to original sources

Pauli-limited superconductivity and antiferromagnetism in the heavy-fermion compound CeCo(In1-xZnx)5

We report on the anisotropic properties of Pauli-limited superconductivity (SC) and antiferromagnetism (AFM) in the solid solutions CeCo(In_{1-x}Zn_x)_5 (x<=0.07). In CeCo(In_{1-x}Zn_x)_5, the SC transition temperature T_c is continuously reduced from 2.3 K (x=0) to ~1.4 K (x=0.07) by doping Zn, and then the AFM order with the transition temperature of T_N~2.2 K develops for x larger than ~0.05. The present thermal, transport and magnetic measurements under magnetic field B reveal that the substitution of Zn for In yields little change of low-temperature upper critical field μ_0H_{c2} for both the tetragonal a and c axes, while it monotonically reduces the SC transition temperature T_c. In particular, the magnitudes of μ_0H_{c2} at the nominal Zn concentration of x = 0.05 (measured Zn amount of ~0.019) are 11.8 T for B||a and 4.8 T for B||c, which are as large as those of pure compound though T_c is reduced to 80% of that for x=0. We consider that this feature originates from a combination of both an enhanced AFM correlation and a reduced SC condensation energy in these alloys. It is also clarified that the AFM order differently responds to the magnetic field, depending on the field directions. For B||c, the clear anomaly due to the AFM transition is observed up to the AFM critical field of ~5 T in the thermodynamic quantities, whereas it is rapidly damped with increasing B for B||a. We discuss this anisotropic response on the basis of a rich variety of the AFM modulations involved in the Ce115 compounds.

cond-mat.str-el

Long-range order and spin-liquid states of polycrystalline Tb$_{2+x}$Ti$_{2-x}$O$_{7+y}$

Low-temperature states of polycrystalline samples of a frustrated pyrochlore oxide Tb$_{2+x}$Ti$_{2-x}$O$_{7+y}$ have been investigated by specific heat, magnetic susceptibility, and neutron scattering experiments. We have found that this system can be tuned by a minute change of $x$ from a spin-liquid state ($x < x_{\text{c}}$) to a partly ordered state with a small antiferromagnetic ordering of the order of $0.1 μ_{\text{B}}$. Specific heat shows a sharp peak at a phase transition at $T_{\text{c}}= 0.5$ K for $x=0.005$. Magnetic excitation spectra for this sample change from a quasielastic to a gapped type through $T_{\text{c}}$. The possibility of a Jahn-Teller transition is discussed.

cond-mat.str-el

Structural and magnetic properties in the quantum S=1/2 dimer systems Ba3(Cr1-xVx)2O8 with site disorder

We report a comprehensive study of dc susceptibility, specific heat, neutron diffraction, and inelastic neutron scattering measurements on polycrystalline Ba3(Cr1-xVx)2O8 samples, where x=0, 0.06, 0.15, and 0.53. A Jahn-Teller structure transition occurs for x=0, 0.06, and 0.15 samples and the transition temperature is reduced upon vanadium substitution from 70(2) K at x=0 to 60(2) K at x=0.06 and 0.15. The structure becomes less distorted as x increases and such transition disappears at x=0.53. The observed magnetic excitation spectrum indicates that the singlet ground state remains unaltered and spin gap energy Δ=1.3(1) meV is identical within the instrument resolution for all x. In addition, the dispersion bandwidth W decreases with increase of x. At x=0.53, W is reduced to 1.4(1) meV from 2.0(1) meV at x=0.

cond-mat.mtrl-sci

Short-range Charge and Spin Superstructures in Doped Layered Co Perovskites

We have investigated cobaltite relatives of the layered perovskite cuprates and nickelates, Pr$_{2-x}$Ca$_x$CoO$_4$ ($0.39 \leq x \leq 0.73$) and La$_{2-x}$Sr$_x$CoO$_4$ ($x = 0.61$), using elastic neutron scattering. We have discovered doping-dependent incommensurate short-range ordering of charges and magnetic moments, which in cobaltites occur in the range of heavy doping, $ 0.5 \lesssim x \lesssim 0.75$. The charge order exists already at room temperature and shows no change on cooling. The incommensurability of its propagation vector, ${\bf Q}_c = (ε_c,0,l)$, roughly scales with the concentration of Co$^{2+}$ ions, $ε_c \sim (1-x)$. Magnetic order is only established at low T$\lesssim 40$ K and has twice larger periodicity, indicating a dominant antiferromagnetic correlation between the nearest Co$^{2+}$ spins.

cond-mat.str-el

Low-lying optical phonon modes in the filled skutterudite CeRu4Sb12

The phonon dynamics of filled skutterudite CeRu4Sb12 have been studied at room temperature by inelastic neutron scattering. Optical phonons associated with a large vibration of Ce atoms are observed at a relatively low energy of E = 6 meV, and show anticrossing behavior with acoustic phonons. We propose that the origin of the low lattice thermal conductivity in filled skutterudites can be attributed to intensive Umklapp scattering originating from low-lying optical phonons. By an analysis based on a Born-von Karman force model, the longitudinal force constants of the nearest Ce-Sb and Ce-Ru pairs are estimated to be 0.025 mdyn/A, while that of the nearest Ru-Sb pair is estimated to be 1.4 mdyn/A, indicating that the Ce atoms are bound very weakly to the surrounding rigid RuSb6-octahedron cages.

cond-mat.str-el

Pressure-temperature phase diagram of the heavy-electron superconductor URu2Si2

The pressure-temperature phase diagram of the heavy-electron superconductor URu2Si2 has been reinvestigated by ac-susceptibility and elastic neutron-scattering (NS) measurements performed on a small single-crystalline rod (2 mm in diameter, 6 mm in length) in a Cu-Be clamp-type high-pressure cell (P < 1.1 GPa). At ambient pressure, this sample shows the weakest antiferromagnetic (AF) Bragg reflections reported so far, corresponding to the volume-averaged staggered moment of mord ~ 0.011 mB/U. Under applied pressure, the AF scattering intensity exhibits a sharp increase at P ~ 0.7 GPa at low temperatures. The saturation value of the AF scattering intensity above 0.7 GPa corresponds to mord ~ 0.41 mB/U, which is in good agreement with that (~ 0.39 mB/U) observed above 1.5 GPa in our previous NS measurements. The superconductivity is dramatically suppressed by the evolution of AF phase, indicating that the superconducting state coexists only with the hidden order phase. The presence of parasitic ferro- and/or antiferromagnetic phases with transition temperatures T1star =120(5) K, T2star = 36(3) K and T3star = 16.5(5) K and their relationship to the low-T ordered phases are also discussed.

cond-mat.str-el

New Magnetic State in Incommensurate Magnetic Phase of Heavy-Fermion Superconductor CeRh0.6Co0.4In5

We performed elastic neutron scattering experiments on solid solution CeRh1-xCoxIn5 with x=0.4 to clarify the nature of the antiferromagnetic (AF) phase in the vicinity of the quantum critical point. We observed the incommensurate AF order below T_Nh=3.5 K. The structure of the incommensurate AF order is basically unchanged from that for pure CeRhIn5. We further found the evolution of a new commensurate AF order with the modulation of q_c=(1/2,1/2,1/2) below T_Nc=2.9 K. The volume-averaged moments for the incommensurate and commensurate AF phases are 0.38 mu_B/Ce and 0.21 mu_B/Ce, respectively, which are reduced from the incommensurate AF moment (0.75 mu_B/Ce) for pure CeRhIn5. We suggest from these results that the commensurate magnetic correlation may be tightly coupled with the superconductivity observed below T_c=1.4 K.

cond-mat.str-el

Competition between hidden order and antiferromagnetism in URu_2Si_2 under uniaxial stress studied by neutron scattering

We have performed elastic neutron scattering experiments under uniaxial stress sigma applied along the tetragonal [100], [110] and [001] directions for the heavy electron compound URu2Si2. We found that antiferromagnetic (AF) order with large moment is developed with sigma along the [100] and [110] directions. If the order is assumed to be homogeneous, the staggered ordered moment mu_o continuously increases from 0.02 mu_B (sigma=0) to 0.22 mu_B (0.25 GPa). The rate of increase partial mu_o/partial sigma is ~ 1.0 mu_B/GPa, which is four times larger than that for the hydrostatic pressure (partial mu_o/partial P sim 0.25 mu_B/GPa). Above 0.25 GPa, mu_o shows a tendency to saturate, similar to the hydrostatic pressure behavior. For sigma||[001], mu_o shows only a slight increase to 0.028 mu_B (sigma = 0.46 GPa) with a rate of ~ 0.02 mu_B/GPa, indicating that the development of the AF state highly depends on the direction of sigma. We have also found a clear hysteresis loop in the isothermal mu_o(sigma) curve obtained for sigma||[110] under the zero-stress-cooled condition at 1.4 K. This strongly suggests that the sigma-induced AF phase is metastable, and separated from the "hidden order" phase by a first-order phase transition. We discuss these experimental results on the basis of crystalline strain effects and elastic energy calculations, and show that the c/a ratio plays a key role in the competition between these two phases.

cond-mat.str-el

Electronically smectic-like phase in a nearly half-doped manganite

We use neutron scattering to study the spin and charge/orbital ordering (CO-OO) in the nearly half-doped perovskite manganite $Pr_{0.55}(Ca_{0.8}Sr_{0.2})_{0.45}MnO_3$ (PCSMO). On cooling from room temperature, PCSMO first enters into a CO-OO state below $T_{CO}$ and then becomes a CE-type long-range ordered antiferromagnet below $T_N$. At temperatures above $T_N$ but below $T_{CO}$ ($T_N<T<T_{CO}$), the spins in PCSMO form highly anisotropic smectic liquid-crystal-like texture with ferromagnetic (FM) quasi-long-range ordered one-dimensional zigzag chains weakly coupled antiferromagnetically. Such a magnetic smectic-like phase results directly from the spin-orbit interaction and demonstrates the presence of textured `electronic soft' phases in doped Mott insulators.

cond-mat.str-el

Observation of Modulated Quadrupolar Structures in PrPb3

Neutron diffraction measurements have been performed on the cubic compound PrPb3 in a [001] magnetic field to examine the quadrupolar ordering. Antiferromagnetic components with q=(1/2+-d 1/2 0), (1/2 1/2+-d 0) (d~1/8) are observed below the transition temperature TQ (0.4 K at H=0) whose amplitudes vary linear with H and vanish at zero field, providing the first evidence for a modulated quadrupolar phase. For H<1 T, a non-square modulated state persists even below 100 mK suggesting quadrupole moments associated with a Gamma3 doublet ground state to be partially quenched by hybridization with conduction electrons.

cond-mat.str-el

Magnetic Excitations in U(Ru_{1-x}Rh_x)_2Si_2 (x<=0.03)

We have investigated magnetic excitations for a mixed phase of hidden order (HO) and the antiferromagnetic (AF) order in U(Ru_{1-x}Rh_x)_2Si_2 (x <= 0.03) by means of inelastic neutron scattering. The inelastic peaks observed at Q=(1,0,0) and (1,0.4,0) in the HO phase for x=0 and 0.015 at 1.4 K are found to be strongly reduced in the AF dominant compositions of x=0.02 and 0.03. Similar behavior is observed as the HO is replaced by the AF order upon cooling for x=0.02. The x-T region in which the strong reduction of inelastic peaks is observed corresponds to the AF-rich region, indicating that the magnetic excitations typical for the HO-phase vanish in the AF phase.

cond-mat.str-el

A-site Randomness Effect on Structural and Physical Properties of Ba-based Perovskite Manganites

The discovery of novel structural and physical properties in the $A$-site ordered manganite $R$BaMn$_{2}$O$_{6}$ ($R$ = Y and rare earth elements) has demanded new comprehension about perovskite manganese oxides. In the present study, the $A$-site disordered form, $R_{0.5}$Ba$_{0.5}$MnO$_{3}$, has been investigated and compared with both $R$BaMn$_{2}$O$_{6}$ and $R_{0.5}A_{0.5}$MnO$_{3}$ ($A$: Sr, Ca) in the structures and electromagnetic properties. $R_{0.5}$Ba$_{0.5}$MnO$_{3}$ has a primitive cubic perovskite cell in the structure and magnetic glassy states are dominant as its ground state, in contrast to the ordinary disordered $R_{0.5}A_{0.5}$MnO$_{3}$ ($A$: Sr, Ca). In Pr-compounds with various degrees of Pr/Ba randomness at the $A$-sites, the $A$-site disorder gradually suppresses both ferromagnetic and A-type antiferromagnetic transitions and finally leads to a magnetic glassy state in Pr$_{0.5}$Ba$_{0.5}$MnO$_{3}$. A peculiar behavior, multi-step magnetization and resistivity change, has been observed in Pr$_{0.5}$Ba$_{0.5}$MnO$_{3}$. These properties could be closely related to any spatial heterogeneity caused by the random distribution of Ba$^{2 +}$ and $R^{3 +}$ with much different ionic radius.

cond-mat.str-el

Anisotropy in the Antiferromagnetic Spin Fluctuations of Sr2RuO4

It has been proposed that Sr_2RuO_4 exhibits spin triplet superconductivity mediated by ferromagnetic fluctuations. So far neutron scattering experiments have failed to detect any clear evidence of ferromagnetic spin fluctuations but, instead, this type of experiments has been successful in confirming the existence of incommensurate spin fluctuations near q=(1/3 1/3 0). For this reason there have been many efforts to associate the contributions of such incommensurate fluctuations to the mechanism of its superconductivity. Our unpolarized inelastic neutron scattering measurements revealed that these incommensurate spin fluctuations possess c-axis anisotropy with an anisotropic factor χ''_{c}/χ''_{a,b} of \sim 2.8. This result is consistent with some theoretical ideas that the incommensurate spin fluctuations with a c-axis anisotropy can be a origin of p-wave superconductivity of this material.

cond-mat.str-el

Neutron diffraction study of TbMnO3: Magnetic structure revisited

Magnetic ordering in TbMnO3 was revisited by a neutron diffraction study. In addition to the previously reported A-type and G-type modulated structures with a propagation vector (0,q_Mn,0), we found C-type and F-type orderings of the Mn moments. All the components appear below T_N^Mn = 46 K, and the G, C,and F-type components are enhanced below T_lock = 28 K, where q_Mn ordering locks at its low temperature value. The locking of the propagation vector also yields the squaring up of the spin arrangement. The magnetic moments of Tb ions show a quasi long-range ordering below T_N^Tb = 7 K. It drastically promotes the development of the G, C, and F-type components while suppressing the A-type components.

cond-mat.str-el

Neutron Scattering Study on Competition between Hidden Order and Antiferromagnetism in U(Ru_{1-x}Rh_x)_2Si_2 (x <= 0.05)

We have performed elastic and inelastic neutron scattering experiments on the solid solutions U(Ru_{1-x}Rh_x)_2Si_2 for the Ru rich concentrations: x=0, 0.01, 0.02, 0.025, 0.03, 0.04 and 0.05. Hidden order is suppressed with increasing x, and correspondingly the onset temperature T_m (~ 17.5 K at x=0) of weak antiferromagnetic (AF) Bragg reflection decreases. For x=0.04 and 0.05, no magnetic order is detected in the investigated temperature range down to 1.4 K. In the middle range, 0.02 <= x <= 0.03, we found that the AF Bragg reflection is strongly enhanced. At x=0.02, this takes place at ~ 7.7 K (=T_M), which is significantly lower than T_m (~ 13.7 K). T_M increases with increasing x, and seems to merge with T_m at x=0.03. If the AF state is assumed to be homogeneous, the staggered moment μ_o estimated at 1.4 K increases from 0.02(2) μ_B/U (x=0) to 0.24(1) μ_B/U (x=0.02). The behavior is similar to that observed under hydrostatic pressure (μ_o increases to ~ 0.25 μ_B/U at 1.0 GPa), suggesting that the AF evolution induced by Rh doping is due to an increase in the AF volume fraction. We also found that the magnetic excitation observed at Q=(1,0,0) below T_m disappears as T is lowered below T_M.

cond-mat.str-el

Ferromagnetic insulating phase in Pr{1-x}Ca{x}MnO3

A ferromagnetic insulating (FM-I) state in Pr0.75Ca0.25MnO3 has been studied by neutron scattering experiment and theoretical calculation. The insulating behavior is robust against an external magnetic field, and is ascribed to neither the phase separation between a ferromagnetic metallic (FM-M) phase and a non-ferromagnetic insulating one, nor the charge ordering. We found that the Jahn-Teller type lattice distortion is much weaker than PrMnO3 and the magnetic interaction is almost isotropic. These features resembles the ferromagnetic metallic state of manganites, but the spin exchange interaction J is much reduced compared to the FM-M state. The theoretical calculation based on the staggered type orbital order well reproduces several features of the spin and orbital state in the FM-I phase.

cond-mat.str-el

Spontaneous rearrangement of the checkerboard charge order to stripe order in La1.5Sr0.5NiO4

The charge ordering in La1.5Sr0.5NiO4 has been studied with neutron diffraction technique. An interesting rearrangement of the charge ordering was observed as a function of temperature. With decreasing temperature, a checkerboard-type charge order is formed below T{CO-C} ~ 480 K. It is, however, taken over by the stripe-type charge order with an incommensurability twice as large as that of the spin order below T{CO-IC} ~ 180 K. Surprisingly, the stripe phase persists up to x = 0.7 for highly hole-doped samples of Nd{2-x}Sr{x}NiO{4} with 0.45 < x < 0.7.

cond-mat.str-el

New Stacking Variations of the CE-type Structure in the Metal-Ordered Manganite YBaMn2O6

For the paramagnetic insulating phase in the metal-ordered manganite YBaMn2O6, the so-called CE-type of charge/orbital ordered state was observed within the monoclinic ab-plane, which is most commonly observed for the ordinary half doped manganites. However, TEM revealed a 4-fold periodicity along the c-axis, suggesting a new stacking pattern, where planes of the CE-type are built up according to the sequence [aabb...]. Interestingly, when th system enters into the antiferromagnetic state, this stacking pattern changes into [aaaa...] or [abab], suggesting close interplay between spins and orbitals. These features are discusses in terms of inherent structural alternation, i.e., the Y/Ba order along the c-axis.

cond-mat.str-el