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Hajime Tanaka

Publications and source records attributed to Hajime Tanaka.

At least 55 records · Page 3Linked to original sources

Asymptotic joint spectra of Cartesian powers of strongly regular graphs and bivariate Charlier-Hermite polynomials

Generalizing previous work of Hora (1998) on the asymptotic spectral analysis for the Hamming graph $H(n,q)$ which is the $n^{\mathrm{th}}$ Cartesian power $K_q^{\square n}$ of the complete graph $K_q$ on $q$ vertices, we describe the possible limits of the joint spectral distribution of the pair $(G^{\square n},\overline{G}\vphantom{G}^{\square n})$ of the $n^{\mathrm{th}}$ Cartesian powers of a strongly regular graph $G$ and its complement $\overline{G}$, where we let $n\rightarrow\infty$, and $G$ may vary with $n$. This result is an analogue of the bivariate central limit theorem, and we obtain in this way the bivariate Poisson distributions and the standard bivariate Gaussian distribution, together with the product measures of univariate Poisson and Gaussian distributions. We also report a family of bivariate hypergeometric orthogonal polynomials with respect to the last distributions, which we call the bivariate Charlier-Hermite polynomials, and prove basic formulas for them. This family of orthogonal polynomials seems previously unnoticed, possibly because of its peculiarity.

math.CO↗

Water-like anomalies as a function of tetrahedrality

Tetrahedral interactions describe the behaviour of the most abundant and technologically important materials on Earth, such as water, silicon, carbon, germanium, and countless others. Despite their differences, these materials share unique common physical behaviours, such as liquid anomalies, open crystalline structures, and extremely poor glass-forming ability at ambient pressure. To reveal the physical origin of these anomalies and their link to the shape of the phase diagram, we systematically study the properties of the Stillinger-Weber potential as a function of the strength of the tetrahedral interaction $λ$. We uncover a new transition to a re-entrant spinodal line at low values of $λ$, accompanied with a change in the dynamical behaviour, from Non-Arrhenius to Arrhenius. We then show that a two-state model can provide a comprehensive understanding on how the thermodynamic and dynamic anomalies of this important class of materials depend on the strength of the tetrahedral interaction. Our work establishes a deep link between the shape of phase diagram and the thermodynamic and dynamic properties through local structural ordering in liquids, and hints at why water is so special among all substances.

cond-mat.soft↗

Gelation as condensation frustrated by hydrodynamics and mechanical isostaticity

Colloidal gels have unique mechanical and transport properties that stem from their bicontinous nature, in which a colloidal network is intertwined with a viscous solvent, and have found numerous applications in foods, cosmetics, construction materials, and for medical applications, such as cartilage replacements. So far, our understanding of the process of colloidal gelation is limited to long-time dynamical effects, where gelation is viewed as a phase separation process interrupted by the glass transition. However, this picture neglects two important effects: the influence of hydrodynamic interactions, and the emergence of mechanical stability. With confocal microscopy experiments, here we successfully follow the entire process of gelation with a single-particle resolution, yielding time-resolved measures of internal stress and viscoelasticity from the very beginning of the aggregation process. First, we demonstrate that the incompressible nature of a liquid component constrains the initial stage of phase separation, assisting the formation of a percolated network. Then we show that this network is not mechanically stable and undergoes rearrangements driven by self-generated internal stress. Finally, we show that mechanical metastability is reached only after percolation of locally isostatic environments, proving isostaticity a necessary condition for the stability and load bearing ability of gels rather than the glass transition. Our work reveals the crucial roles of momentum conservation in gelation in addition to the conventional purely out-of-equilibrium thermodynamic picture.

cond-mat.soft↗

Dual Polar Graphs, a nil-DAHA of Rank One, and Non-Symmetric Dual q-Krawtchouk Polynomials

Let $Γ$ be a dual polar graph with diameter $D \geqslant 3$, having as vertices the maximal isotropic subspaces of a finite-dimensional vector space over the finite field $\mathbb{F}_q$ equipped with a non-degenerate form (alternating, quadratic, or Hermitian) with Witt index $D$. From a pair of a vertex $x$ of $Γ$ and a maximal clique $C$ containing $x$, we construct a $2D$-dimensional irreducible module for a nil-DAHA of type $(C^{\vee}_1, C_1)$, and establish its connection to the generalized Terwilliger algebra with respect to $x$, $C$. Using this module, we then define the non-symmetric dual $q$-Krawtchouk polynomials and derive their recurrence and orthogonality relations from the combinatorial points of view. We note that our results do not depend essentially on the particular choice of the pair $x$, $C$, and that all the formulas are described in terms of $q$, $D$, and one other scalar which we assign to $Γ$ based on the type of the form.

math.CO↗

Formation of porous crystals via viscoelastic phase separation

Viscoelastic phase separation of colloidal suspensions can be interrupted to form gels either by glass transition or by crystallization. With a new confocal microscopy protocol, we follow the entire kinetics of phase separation, from homogeneous phase to different arrested states. For the first time in experiments, our results unveil a novel crystallization pathway to sponge-like porous crystal structures. In the early stages, we show that nucleation requires a structural reorganization of the liquid phase, called stress-driven ageing. Once nucleation starts, we observe that crystallization follows three different routes: direct crystallization of the liquid phase, Bergeron process, and Ostwald ripening. Nucleation starts inside the reorganised network, but crystals grow past it by direct condensation of the gas phase on their surface, driving liquid evaporation, and producing a network structure different from the original phase separation pattern. We argue that similar crystal-gel states can be formed in monoatomic and molecular systems if the liquid phase is slow enough to induce viscoelastic phase separation, but fast enough to prevent immediate vitrification. This provides a novel pathway to form nano-porous crystals of metals and semiconductors without dealloying, which may be important for catalytic, optical, sensing, and filtration applications.

cond-mat.soft↗

Impact of Spatial Dimension on Structural Ordering in Metallic Glass

Metallic glasses have so far attracted considerable attention for their applications as bulk materials. However, new physics and applications often emerge by dimensional reduction from three dimension (3D) to two dimension (2D). Here, we study, by molecular dynamics simulations, how the liquid-to-glass transition of a binary Cu50Zr50 MG is affected by spatial dimensionality. We find clear evidence that crystal-like structural ordering controls both dynamic heterogeneity and slow dynamics, and thus plays a crucial role in the formation of the 2DMG. Although the 2DMG reproduces the dynamical behaviors of its 3D counterpart by considering Mermin-Wagner-type fluctuations specific to 2D, this atomic-scale structural mechanism is essentially different from that for the 3DMG in which icosahedral clusters incompatible with crystallographic symmetry play a key role in glassy behaviors. Our finding provides a new structural mechanism for the formation of 2DMGs, which cannot be inferred from the knowledge of 3DMGs. The results suggest a structural basis for the glass transition in 2DMG and provide possible explanations for some previous experimental observations in ultrathin film MGs.

cond-mat.mtrl-sci↗

Common mechanism of thermodynamic and mechanical origin for ageing and crystallisation of glasses

The glassy state is known to undergo slow structural relaxation, where the system progressively explores lower free-energy minima which are either amorphous (ageing) or crystalline (devitrification). Recently, there is growing interest in the unusual intermittent collective displacements of a large number of particles known as "avalanches". However, their structural origin and dynamics are yet to be fully addressed. Here, we study hard-sphere glasses which either crystallise or age depending on the degree of size polydispersity, and show that a small number of particles are thermodynamically driven to rearrange in regions of low density and bond orientational order. This causes a transient loss of mechanical equilibrium which facilitates a large cascade of motion. Combined with previously identified phenomenology, we have a complete kinetic pathway for structural change which is common to both ageing and crystallisation. Furthermore, this suggests that transient force balance is what distinguishes glasses from supercooled liquids.

cond-mat.soft↗

An Assmus-Mattson theorem for codes over commutative association schemes

We prove an Assmus-Mattson-type theorem for block codes where the alphabet is the vertex set of a commutative association scheme (say, with $s$ classes). This in particular generalizes the Assmus-Mattson-type theorems for $\mathbb{Z}_4$-linear codes due to Tanabe (2003) and Shin, Kumar, and Helleseth (2004), as well as the original theorem by Assmus and Mattson (1969). The weights of a code are $s$-tuples of non-negative integers in this case, and the conditions in our theorem for obtaining $t$-designs from the code involve concepts from polynomial interpolation in $s$ variables. The Terwilliger algebra is the main tool to establish our results.

math.CO↗

Impact of surface roughness on liquid-liquid transition

Liquid-liquid transition (LLT) in single-component liquids is one of the most mysterious phenomena in condensed matter. So far this problem has attracted attention mainly from the purely scientific viewpoint. Here we report the first experimental study on an impact of surface nano-structuring on LLT by using a surface treatment called rubbing, which is the key technology for the production of liquid crystal displays. We find that such a rubbing treatment has a significant impact on the kinetics of liquid-liquid transition (LLT) of an isotropic molecular liquid, triphenyl phosphite. For a liquid confined between rubbed surfaces, surface-induced barrier-less formation of the liquid II phase is observed even in a metastable state, where there should be a barrier for nucleation of the liquid II phase in bulk. Thus, surface rubbing of substrates not only changes the ordering behavior, but also accelerates the kinetics significantly. This spatio-temporal pattern modulation of LLT can be explained by a wedge filling transition and the resulting drastic reduction of the nucleation barrier. However, this effect completely disappears in the unstable (spinodal) regime, indicating the absence of the activation barrier even for bulk LLT. This confirms the presence of nucleation-growth-type and spinodal-decomposition-type LLT, supporting that LLT is truly a first-order transition with criticality. Our finding also opens up a new way to control the kinetics of LLT of a liquid confined in a solid cell by structuring its surface on a mesoscopic lengthscale, which may contribute to making LLT useful for micro-fluidics and other industrial applications.

cond-mat.soft↗

Crystal nucleation as the ordering of multiple order parameters

Nucleation is an activated process in which the system has to overcome a free energy barrier in order for a first-order phase transition between the metastable and the stable phases to take place. In the liquid-to-solid transition the process occurs between phases of different symmetry, and it is thus inherently a multi-dimensional process, in which all symmetries are broken at the transition. In this Focus Article, we consider some recent studies which highlight the multi-dimensional nature of the nucleation process. Even for a single-component system, the formation of solid crystals from the metastable melt involves fluctuations of two (or more) order parameters, often associated with the decoupling of positional and orientational symmetry breaking. In other words, we need at least two order parameters to describe the free-energy of a system including its liquid and crystalline states. This decoupling occurs naturally for asymmetric particles or directional interactions, focusing here on the case of water, but we will show that it also affects spherically symmetric interacting particles, such as the hard-sphere system. We will show how the treatment of nucleation as a multi-dimensional process has shed new light on the process of polymorph selection, on the effect of external fields on the nucleation process, and on glass-forming ability.

cond-mat.soft↗

A possible four-phase coexistence in a single-component system

For different phases to coexist in equilibrium at constant temperature $T$ and pressure $P$, the condition of equal chemical potential $μ$ must be satisfied. This condition dictates that, for a single-component system, the maximum number of phases that can coexist is three. Historically this is known as the Gibbs phase rule, and is one of the oldest and venerable rules of thermodynamics. Here we makes use of the fact that, by varying model parameters, the Gibbs phase rule can be generalized so that four phases can coexist even in single-component systems. To systematically search for the quadruple point, we use a monoatomic system interacting with a Stillinger-Weber potential with variable tetrahedrality. Our study indicates that the quadruple point provides novel flexibility in controlling multiple equilibrium phases and may be realized in systems with tunable interactions, which are nowadays feasible in several soft matter systems (e.g., patchy colloids).

cond-mat.soft↗

The reversibility and first-order nature of liquid-liquid transition in a molecular liquid

Liquid-liquid transition is an intriguing phenomenon in which a liquid transforms into another liquid via the first-order transition. For molecular liquids, however, it always takes place in a supercooled liquid state metastable against crystallization, which has led to a number of serious debates concerning its origin: liquid-liquid transition vs. unusual nano-crystal formation. Thus, there have so far been no single example free from such debates. Here we show the first firm experimental evidence that the transition is truly liquid-liquid transition and not nano-crystallization for a molecular liquid, triphenyl phosphite. We kinetically isolate the reverse liquid-liquid transition from glass transition and crystallization with an extremely high heating rate of flash differential scanning calorimetry, and prove the reversibility and first-order nature of liquid-liquid transition. Our finding not only deepens our physical understanding of liquid-liquid transition but also will initiate a new phase of its research from both fundamental and applications viewpoints.

cond-mat.soft↗

Non-classical pathways of crystallization in colloidal systems

Colloidal systems offer the ideal conditions to study the nucleation process, both from an experimental viewpoint, due to their relative large size and long time-scales, and from a modeling point of view, due to the tunability of their interactions. Here we review some recent works that study the process of colloidal crystallization from a microscopic perspective. We focus in particular on non-classical pathways to nucleation where the appearance of the solid crystals involves fluctuations of two (or more) order parameters. We interpret the non-classical behavior as a decoupling of positional and orientational symmetry breaking. We then consider how the nucleation pathway determines which polymorph is selected upon nucleation from the melt. Moreover we show how the study of nucleation pathways not only sheds new light on the microscopic mechanism of nucleation, but also provides important information regarding its avoidance, thus suggesting a deep link between crystallization and vitrification.

cond-mat.soft↗

A semidefinite programming approach to a cross-intersection problem with measures

We present a semidefinite programming approach to bound the measures of cross-independent pairs in a bipartite graph. This can be viewed as a far-reaching extension of Hoffman's ratio bound on the independence number of a graph. As an application, we solve a problem on the maximum measures of cross-intersecting families of subsets with two different product measures, which is a generalized measure version of the Erdős-Ko-Rado theorem for cross-intersecting families with different uniformities.

math.CO↗

Effect of Energy Polydispersity on the Nature of Lennard-Jones Liquids

In the companion paper [T. S. Ingebrigtsen and H. Tanaka, J. Phys. Chem. B 119, 11052 (2015)] the effect of size polydispersity on the nature of Lennard-Jones (LJ) liquids, which represent most molecular liquids without hydrogen bonds, was studied. More specifically, it was shown that even highly size polydisperse LJ liquids are Roskilde-simple (RS) liquids. RS liquids are liquids with strong correlation between constant volume equilibrium fluctuations of virial and potential energy and are simpler than other types of liquids. Moreover, it was shown that size polydisperse LJ liquids have isomorphs to a good approximation. Isomorphs are curves in the phase diagram of RS liquids along which structure, dynamics, and some thermodynamic quantities are invariant in dimensionless (reduced) units. In this paper, we study the effect of energy polydispersity on the nature of LJ liquids. We show that energy polydisperse LJ liquids are RS liquids. However, a tendency of particle segregation which increases with the degree of polydispersity leads to a loss of strong virial-potential energy correlation, but is mitigated with increasing temperature and/or density. Isomorphs are a good approximation also for energy polydisperse LJ liquids, although particle-resolved quantities display a somewhat poorer scaling compared to the mean quantities along the isomorph.

cond-mat.soft↗

Distance-regular graphs

This is a survey of distance-regular graphs. We present an introduction to distance-regular graphs for the reader who is unfamiliar with the subject, and then give an overview of some developments in the area of distance-regular graphs since the monograph 'BCN' [Brouwer, A.E., Cohen, A.M., Neumaier, A., Distance-Regular Graphs, Springer-Verlag, Berlin, 1989] was written.

math.CO↗

On relative $t$-designs in polynomial association schemes

Motivated by the similarities between the theory of spherical $t$-designs and that of $t$-designs in $Q$-polynomial association schemes, we study two versions of relative $t$-designs, the counterparts of Euclidean $t$-designs for $P$- and/or $Q$-polynomial association schemes. We develop the theory based on the Terwilliger algebra, which is a noncommutative associative semisimple $\mathbb{C}$-algebra associated with each vertex of an association scheme. We compute explicitly the Fisher type lower bounds on the sizes of relative $t$-designs, assuming that certain irreducible modules behave nicely. The two versions of relative $t$-designs turn out to be equivalent in the case of the Hamming schemes. From this point of view, we establish a new algebraic characterization of the Hamming schemes.

math.CO↗

Probing colloidal gels at multiple lengthscales: the role of hydrodynamics

Colloidal gels are out-of-equilibrium structures, made up of a rarefied network of colloidal particles. Comparing experiments to numerical simulations, with hydrodynamic interactions switched off, we demonstrate the crucial role of the solvent for gelation. Hydrodynamic interactions suppress the formation of larger local equilibrium structures of closed geometry, and instead lead to the formation of highly anisotropic threads, which promote an open gel network. We confirm these results with simulations which include hydrodynamics. Based on three-point correlations, we propose a scale-resolved quantitative measure for the anisotropy of the gel structure. We find a strong discrepancy for interparticle distances just under twice the particle diameter between systems with and without hydrodynamics, quantifying the role of hydrodynamics from a structural point of view.

cond-mat.soft↗