arXiv subjects

Hamza Jnane

Publications and source records attributed to Hamza Jnane.

12 recordsLinked to original sources

arXiv2026

Electron shuttling as a probe for charge defects

Silicon spin qubits are a leading platform for scalable quantum computing, but their performance is limited by charge noise, widely attributed to two-level fluctuators (TLFs). The location of individual TLFs is generally unknown, and existing methods to localise them does not scale favourably with device size. Here, we show that electron shuttling turns a single mobile spin into a scanning probe of individual defects. We show that by shuttling a spin over a range of distances and tracking its coherence loss, one can localise defects along the channel and constrain their switching rate and fluctuation amplitude. Because one shuttled electron sweeps an extended region, the approach scales more favourably than previous methods. Our protocol requires no additional hardware and provides a practical route to mapping the charge-defect landscape of large silicon devices, enabling defect-aware calibration and avoidance in shuttling-based architectures.

quant-ph↗

arXiv2026

Efficient classical representation and quantum state preparation of complete active space wavefunctions

Quantum computers promise to solve the electronic structure problem for a large class of molecules. However, the performance of relevant quantum algorithms hinges on preparing initial states with substantial overlap with the target eigenvector. For classically challenging molecules with strong electron correlation, starting from multi-reference states, such as complete active space (CAS) wavefunctions is necessary. Unfortunately, the most advanced state preparation protocols applied to such states result in a gate complexity that scales exponentially with the active space size $d$. In fact, even encoding a CAS state classically is traditionally believed to be intractable for chemically relevant systems. Here, we draw insights from the recently introduced Quantum Paldus Transform (QPT) to show that there exists an efficient classical representation of CAS states and to design a new state preparation routine outperforming previous ones. The QPT represents a transformation from the Fock basis to a friendlier symmetry-adapted basis. Our main contribution consists in showing that CAS states expanded in this basis can efficiently be represented as a matrix product state (MPS) with a bond dimension scaling as $O(d^2)$. One can then efficiently load the MPS on a quantum computer and use the inverse QPT to transform the state to the Fock basis. Moreover, our method can easily be extended to the efficient preparation of CAS states in first quantisation with similar complexity. Crucially, we demonstrate that the complexity of both state preparation protocols only grows polynomially as $O(d^3)$ , which constitutes to the best of our knowledge an exponential improvement over the state of the art.

quant-ph↗

arXiv2025

Fullqubit alchemist: Quantum algorithm for alchemical free energy calculations

Accurately computing the free energies of biological processes is a cornerstone of computer-aided drug design, but it is a daunting task. The need to sample vast conformational spaces and account for entropic contributions makes the estimation of binding free energies very expensive. While classical methods, such as thermodynamic integration and alchemical free energy calculations, have significantly contributed to reducing computational costs, they still face limitations in terms of efficiency and scalability. We tackle this through a quantum algorithm for the estimation of free energy differences by adapting the existing Liouvillian approach and introducing several key algorithmic improvements. We directly implement the Liouvillian operator and provide an efficient description of electronic forces acting on both nuclear and electronic particles on the quantum ground state potential energy surface. This leads to super-polynomial runtime scaling improvements in the precision of our Liouvillian simulation approach and quadratic improvements in the scaling with the number of particles relative to prior quantum algorithms. Second, our algorithm calculates free energy differences via a fully quantum implementation of thermodynamic integration and alchemy, thereby foregoing expensive entropy estimation subroutines used in prior works. Our results open new avenues towards the application of quantum computers in drug discovery.

quant-ph↗

arXiv2025

Harnessing electron motion for global spin qubit control

Silicon spin qubits are promising candidates for building scalable quantum computers due to their nanometre scale features. However, delivering microwave control signals locally to each qubit poses a challenge and instead methods that utilise global control fields have been proposed. These require tuning the frequency of selected qubits into resonance with a global field while detuning the rest to avoid crosstalk. Common frequency tuning methods, such as electric-field-induced Stark shift, are insufficient to cover the frequency variability across large arrays of qubits. Here, we argue that electron motion, and especially the recently demonstrated high-fidelity shuttling, can be leveraged to enhance frequency tunability. Our conclusions are supported by numerical simulations proving its efficiency on concrete architectures such as a 2$\times$N array of qubits and the recently introduced looped pipeline architecture. Specifically, we show that the use of our schemes enables single-qubit fidelity improvements up to a factor of 100 compared to the state-of-the-art. Finally, we show that our scheme can naturally be extended to perform two-qubit gates globally.

quant-ph↗

arXiv2025

Snakes on a Plane: mobile, low dimensional logical qubits on a 2D surface

Recent demonstrations indicate that silicon-spin QPUs will be able to shuttle physical qubits rapidly and with high fidelity - a desirable feature for maximising logical connectivity, supporting new codes, and routing around damage. However it may seem that shuttling at the logical level is unwise: static defects in the device may 'scratch' a logical qubit as it passes, causing correlated errors to which the code is highly vulnerable. Here we explore an architecture where logical qubits are 1D strings ('snakes') which can be moved freely over a planar latticework. Possible scratch events are inferred via monitor qubits and the complimentary gap; if deemed a risk, remarkably the shuttle process can be undone in a way that negates any corruption. Interaction between logical snakes is facilitated by a semi-transversal method. We obtain encouraging estimates for the tolerable levels of shuttling-related imperfections.

quant-ph↗

arXiv2024

Low Depth Phase Oracle Using a Parallel Piecewise Circuit

We explore the important task of applying a phase $\exp(i\,f(x))$ to a computational basis state $\left| x \right>$. The closely related task of rotating a target qubit by an angle depending on $f(x)$ is also studied. Such operations are key in many quantum subroutines, and frequently $f(x)$ can be well-approximated by a piecewise function; examples range from the application of diagonal Hamiltonian terms (such as the Coulomb interaction) in grid-based many-body simulation, to derivative pricing algorithms. Here we exploit a parallelisation of the piecewise approach so that all constituent elementary rotations are performed simultaneously, that is, we achieve a total rotation depth of one. Moreover, we explore the use of recursive catalyst `towers' to implement these elementary rotations efficiently. We find that strategies prioritising execution speed can achieve circuit depth as low as $O(\log{n}{+}\log{S})$ for a register of $n$ qubits and a piecewise approximation of $S$ sections (presuming prior preparation of enabling resource states), albeit total qubit count then scales with $S$. In the limit of multiple repetitions of the oracle, we find that catalyst tower approaches have an $O(S\cdot n)$ T-count.

quant-ph↗

arXiv2024

Ab initio modelling of quantum dot qubits: Coupling, gate dynamics and robustness versus charge noise

Electron spins in semiconductor devices are highly promising building blocks for quantum processors (QPs). Commercial semiconductor foundries can create QPs using the same processes employed for conventional chips, once the QP design is suitably specified. There is a vast accessible design space; to identify the most promising options for fabrication, one requires predictive modelling of interacting electrons in real geometries and complex non-ideal environments. In this work we explore a modelling method based on real-space grids, an ab initio approach without assumptions relating to device topology and therefore with wide applicability. Given an electrode geometry, we determine the exchange coupling between quantum dot qubits, and model the full evolution of a $\sqrt{\text{SWAP}}$ gate to predict qubit loss and infidelity rates for various voltage profiles. We determine full, 3D solutions and introduce a method which can obtain near-identical predictions using far more efficient 2D computations. Moreover we explore the impact of unwanted charge defects (static and dynamic) in the environment, and test robust pulse sequences. As an example we exhibit a sequence correcting both systematic errors and (unknown) charge defects, observing an order of magnitude boost in fidelity. The technique can thus identify the most promising device designs for fabrication, as well as bespoke control sequences for each such device.

cond-mat.mes-hall↗

arXiv2024

Biased Estimator Channels for Classical Shadows

Extracting classical information from quantum systems is of fundamental importance, and classical shadows allow us to extract a large amount of information using relatively few measurements. Conventional shadow estimators are unbiased and thus approach the true mean in the infinite-sample limit. In this work, we consider a biased scheme, intentionally introducing a bias by rescaling the conventional classical shadows estimators can reduce the error in the finite-sample regime. The approach is straightforward to implement and requires no quantum resources. We analytically prove average case as well as worst- and best-case scenarios, and rigorously prove that it is, in principle, always worth biasing the estimators. We illustrate our approach in a quantum simulation task of a $12$-qubit spin-ring problem and demonstrate how estimating expected values of non-local perturbations can be significantly more efficient using our biased scheme.

quant-ph↗

arXiv2023

Quantum Error Mitigated Classical Shadows

Classical shadows enable us to learn many properties of a quantum state $\rho$ with very few measurements. However, near-term and early fault-tolerant quantum computers will only be able to prepare noisy quantum states $\rho$ and it is thus a considerable challenge to efficiently learn properties of an ideal, noise free state $\rho_{id}$. We consider error mitigation techniques, such as Probabilistic Error Cancellation (PEC), Zero Noise Extrapolation (ZNE) and Symmetry Verification (SV) which have been developed for mitigating errors in single expected value measurements and generalise them for mitigating errors in classical shadows. We find that PEC is the most natural candidate and thus develop a thorough theoretical framework for PEC shadows with the following rigorous theoretical guarantees: PEC shadows are an unbiased estimator for the ideal quantum state $\rho_{id}$; the sample complexity for simultaneously predicting many linear properties of $\rho_{id}$ is identical to that of the conventional shadows approach up to a multiplicative factor which is the sample overhead due to error mitigation. Due to efficient post-processing of shadows, this overhead does not depend directly on the number of qubits but rather grows exponentially with the number of noisy gates. The broad set of tools introduced in this work may be instrumental in exploiting near-term and early fault-tolerant quantum computers: We demonstrate in detailed numerical simulations a range of practical applications of quantum computers that will significantly benefit from our techniques.

quant-ph↗

arXiv2022

Multicore Quantum Computing

Any architecture for practical quantum computing must be scalable. An attractive approach is to create multiple cores, computing regions of fixed size that are well-spaced but interlinked with communication channels. This exploded architecture can relax the demands associated with a single monolithic device: the complexity of control, cooling and power infrastructure as well as the difficulties of cross-talk suppression and near-perfect component yield. Here we explore interlinked multicore architectures through analytic and numerical modelling. While elements of our analysis are relevant to diverse platforms, our focus is on semiconductor electron spin systems in which numerous cores may exist on a single chip. We model shuttling and microwave-based interlinks and estimate the achievable fidelities, finding values that are encouraging but markedly inferior to intra-core operations. We therefore introduce optimsed entanglement purification to enable high-fidelity communication, finding that $99.5\%$ is a very realistic goal. We then assess the prospects for quantum advantage using such devices in the NISQ-era and beyond: we simulate recently proposed exponentially-powerful error mitigation schemes in the multicore environment and conclude that these techniques impressively suppress imperfections in both the inter- and intra-core operations.

quant-ph↗

arXiv2020

Analog quantum simulation of non-Condon effects in molecular spectroscopy

In this work, we present a linear optical implementation for analog quantum simulation of molecular vibronic spectra, incorporating the non-Condon scattering operation with a quadratically small truncation error. Thus far, analog and digital quantum algorithms for achieving quantum speedup have been suggested only in the Condon regime, which refers to a transition dipole moment that is independent of nuclear coordinates. For analog quantum optical simulation beyond the Condon regime (i.e., non-Condon transitions) the resulting non-unitary scattering operations must be handled appropriately in a linear optical network. In this paper, we consider the first and second-order Herzberg-Teller expansions of the transition dipole moment operator for the non-Condon effect, for implementation on linear optical quantum hardware. We believe the method opens a new way to approximate arbitrary non-unitary operations in analog and digital quantum simulations. We report in-silico simulations of the vibronic spectra for naphthalene, phenanthrene, and benzene to support our findings.

quant-ph↗

arXiv2020

Growing Random Graphs with Quantum Rules

Random graphs are a central element of the study of complex dynamical networks such as the internet, the brain, or socioeconomic phenomena. New methods to generate random graphs can spawn new applications and give insights into more established techniques. We propose two variations of a model to grow random graphs and trees, based on continuous-time quantum walks on the graphs. After a random characteristic time, the position of the walker(s) is measured and new nodes are attached to the nodes where the walkers collapsed. Such dynamical systems are reminiscent of the class of spontaneous collapse theories in quantum mechanics. We investigate several rates of this spontaneous collapse for an individual quantum walker and for two non-interacting walkers. We conjecture (and report some numerical evidence) that the models are scale-free.

quant-ph↗