arXiv subjects

Hannah R. Wakeford

Publications and source records attributed to Hannah R. Wakeford.

At least 37 records · Page 2Linked to original sources

arXiv2025

Fractal Aggregate Aerosols in the Virga Cloud Code II: Exploring the Effects of Key Cloud Parameters in Warm Neptune, Hot Jupiter and Brown Dwarf Atmospheres

Aerosols and clouds are expected to be ubiquitous in exoplanet and brown dwarf atmospheres, where they can have a significant impact on transmission and emission spectra. The cloud code Virga is capable of quickly modeling cloud particle sizes as a function of altitude, and has recently been updated to include functionality for aggregates (ranging from very fluffy chains to compact fractals). We analyze the effect that these aggregates have on transmission spectra for typical warm Neptune and hot Jupiter environments, as well as their effect on emission spectra for an L-type brown dwarf, over the wavelength range 0.3 - 15 um. We find significant, measurable differences in spectra when particle shape is changed (particularly the shortest wavelengths where particle morphology strongly affects the scattering slope). We provide some intuitive rules for how non-absorbing aggregates impact spectra: when particle sizes are small compared to the wavelength of light, the most elongated and chain-like particles have the highest opacities. When particles are large, the inverse is true (the most compact shapes have the highest opacities). We present an explanation for these effects in terms of the dynamics of how the particles form and move through the atmosphere, as well as in terms of fundamental optics theory. Given the significant impact that particle shape can have on spectra, we strongly encourage the community to include shape as a free parameter in future case studies, atmospheric models, and retrievals.

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arXiv2025

Eclipse Mapping with Ariel: Future Prospects for a Population-Level Mapping Survey

Eclipse mapping is a powerful tool for measuring 3D profiles of exoplanet atmospheres. To date, only JWST has been capable of widely applying this technique, but as a general observatory, it is too time-limited to conduct population-level mapping studies. Ariel, on the other hand, is a dedicated exoplanet mission set to observe 1000 transiting exoplanets, making it a natural candidate for this. To assess Ariel's mapping potential, we quantitatively benchmark its abilities against those of JWST using a simulation-and-retrieval framework with existing JWST eclipse maps as test cases. We find that for high-ranking targets, Ariel will be able to derive qualitatively similar maps to JWST using the same amount of observations; for mid-ranking targets, Ariel will be able to compete using as few as 3x as many observations; and for lower-ranking targets, the use of phase curves overcomes the need for an impractical number of repeated eclipse observations. We find that while Ariel is unlikely to have extensive latitudinal mapping abilities, it will have wide-ranging longitudinal abilities, from which the first-order atmospheric dynamics can be constrained. Using an analytically-derived metric, we determine the best eclipse mapping targets for Ariel, finding that it will be able to map nearly 100 targets using full phase curves in only quarter of its lifetime. This would be the largest mapping survey to date, and have enormous ramifications for our demographic understanding of exoplanet atmospheric dynamics. Finally, we rank all the best mapping targets for both JWST and Ariel in order to encourage future eclipse mapping studies.

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arXiv2025

JWST-TST DREAMS: The Nightside Emission and Chemistry of WASP-17b

Theoretical studies have suggested using planetary infrared excess (PIE) to detect and characterize the thermal emission of transiting and non-transiting exoplanets, however the PIE technique requires empirical validation. Here we apply the PIE technique to a combination of JWST NIRSpec G395H transit and eclipse measurements of WASP-17b, a hot Jupiter orbiting an F-type star, obtained consecutively (0.5 phase or 1.8 days apart) as part of the JWST-TST program to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS). Using the in-eclipse measured stellar spectrum to circumvent the need for ultra-precise stellar models, we extract the first JWST nightside emission spectrum of WASP-17b using only transit and eclipse data thereby performing a controlled test of the PIE technique. From the WASP-17b nightside spectrum, we measure a nightside equilibrium temperature of $1005 \pm 256$ K and find tentative evidence for nightside SO2 absorption ($\ln B = 1.45$, $2.3σ$). In context with the dayside, the temperature of the nightside is consistent with (1) previous eclipse mapping findings that suggest relatively inefficient day-night heat transport, and (2) a non-zero bond albedo of $0.42^{+0.06}_{-0.10}$. SO2 on the nightside, if confirmed, would represent the first direct evidence for transport-induced chemistry, matching previous model predictions, and opening a new door into the 3D nature of giant exoplanets. Our results suggest that PIE is feasible with JWST/NIRSpec for two epochs separated in time by significantly less than the rotation period of the host star.

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arXiv2025

JWST-TST DREAMS: Sulfur dioxide in the atmosphere of the Neptune-mass planet HAT-P-26 b from NIRSpec G395H transmission spectroscopy

We present the James Webb Space Telescope (JWST) transmission spectrum of the exoplanet HAT-P-26 b (18.6 Earth masses, 6.33 Earth radii), based on a single transit observed with the JWST NIRSpec G395H grating. We detect water vapor (ln B = 4.1), carbon dioxide (ln B = 85.6), and sulfur dioxide (ln B = 13.5) with high confidence, along with marginal indications for hydrogen sulfide and carbon monoxide (ln B < 0.5). The detection of SO2 in a warm super-Neptune sized exoplanet (radius about 6 Earth radii) bridges the gap between previous detections in hot Jupiters and sub-Neptunes, highlighting the role of disequilibrium photochemistry across a broad range of exoplanet atmospheres, including those cooler than 1000 K. Our precise measurements of carbon, oxygen, and sulfur indicate an atmospheric metallicity of about 10 times solar and a sub-solar C/O ratio. Retrieved molecular abundances are consistent within 2 sigma with predictions from self-consistent models including photochemistry. The elevated CO2 abundance and possible H2S signal may also reflect sensitivities to the thermal structure, cloud properties, or additional disequilibrium processes such as vertical mixing. We compare the SO2 abundance in HAT-P-26 b with that of ten other JWST-observed giant exoplanets, and find a correlation with atmospheric metallicity. The trend is consistent with the prediction from Crossfield (2023), showing a steep rise in SO2 abundance at low metallicities, and a more gradual increase beyond 30 times solar. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2025

BOWIE-ALIGN: Weak spectral features in KELT-7b's JWST NIRSpec/G395H transmission spectrum imply a high cloud deck or a low-metallicity atmosphere

Hot Jupiters and their atmospheres are prime targets for transmission spectroscopy due to their extended atmospheres and the corresponding large signal-to-noise, providing the best possible constraints for the atmospheric carbon-to-oxygen (C/O) ratio and metallicity of exoplanets. Within BOWIE-ALIGN, we aim to compare JWST spectra of a sample of orbitally aligned and misaligned hot Jupiters orbiting F-type stars to probe the link between hot Jupiter atmospheres and planet formation history. Here, we present a near-infrared transmission spectrum of the aligned planet KELT-7b using one transit observed with JWST NIRSpec/G395H. We find weak features, only tentative evidence for H$_2$O and CO$_2$ in the atmosphere of KELT-7b. This poses a challenge to constrain the atmospheric properties of KELT-7b and two possible scenarios emerge from equilibrium chemistry and free chemistry retrievals: a high-altitude cloud deck muting all features or an extremely low metallicity atmosphere, respectively. The retrieved C/O ratios from our data reductions range from $0.43 - 0.74$, while the atmospheric metallicity is suggested to be solar to super-solar ($1-16 \times$ solar). Although these wide constraints prevent detailed conclusions about KELT-7b's formation history, a solar-to-super-solar metallicity would imply the accretion of solid material during its formation, which is valuable information for the survey's wider goals of understanding the relative importance of gaseous to solid accretion.

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arXiv2025

The Photochemical Plausibility of Warm Exo-Titans Orbiting M-Dwarf Stars

The James Webb Space Telescope (JWST) has begun to spectrally characterize small exoplanets orbiting M-dwarf stars, but interpretation of these spectra is ambiguous, with stellar, instrumental, or atmospheric origins possible for apparent spectral features. Consequently, interpretation of JWST small exoplanet spectra follows a Bayesian approach, with less theoretically plausible interpretations facing a higher burden of proof. Here, we use photochemical modeling to evaluate the plausibility of warm exo-Titans, exoplanets with N$_2$-CH$_4$ atmospheres analogous to Titan but orbiting closer to their host stars. Consideration of warm exo-Titans is motivated by arguments from planet formation, as well as tentative evidence from observations. Using TRAPPIST-1e as a case study, we show that the higher instellation experienced by warm exo-Titans reduces their CH$_4$ lifetime $τ_{\text{CH}_{4}}$ relative to true Titan by orders of magnitude, reducing the probability of observing them. We constrain the $τ_{\text{CH}_{4}}$ on a warm exo-Titan to be $\leq0.1\times$ (and most likely $\leq0.02\times$) true Titan, implying the absolute probability of detecting a warm exo-Titan is $<0.1$ and likely $<0.01$. This finding is consistent with recent JWST nondetections of CH$_4$-dominated atmospheres on warm terrestrial exoplanets. The low prior probability means that the standard of proof required to claim a warm exo-Titan detection is high, and we offer specific suggestions towards such a standard of proof. Observation of oxidized carbon species would corroborate a putative warm exo-Titan detection. Confirmed detection of warm exo-Titans would signal the need to fundamentally rethink our understanding of the structure, dynamics, and photochemistry of Titan-like worlds.

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arXiv2025

Fractal Aggregate Aerosols in the Virga Cloud Code I: Model Description and Application to a Benchmark Cloudy Exoplanet

We introduce new functionality to treat fractal aggregate aerosol particles within the Virga cloud modeling framework. Previously, the open source cloud modeling code Virga (Batalha et al. 2025), the Python version of EddySed (Ackerman & Marley, 2001), assumed spherical particles to compute particle mass and size distributions throughout the atmosphere. The initial release of Virga also assumed spherical particles to compute Mie scattering properties, which include the single scattering albedo, asymmetry parameter, and optical depth as a function of particle radius and composition. However, extensive evidence from Solar system aerosols, astrophysical disks and dust, and Earth climate studies suggests that non-spherical aggregate particles are common compared to idealized compact spherical particles. Following recent advances in microphysical and opacity modeling, we implement a simple parametrization for dynamical and optical (modified mean field theory) effects of fractal aggregate particles into Virga. We then use this new functionality to perform a case study using basic planetary parameters similar to the well-characterized, aerosol-laden mini-Neptune GJ 1214 b, using KCl clouds made of aggregate particles. We choose KCl to most directly explore comparisons to previous studies. We demonstrate 1) how our method compares to previous fractal aggregate particle treatments and 2) how our new fractal treatment affects theoretical spectra of cloudy atmospheres. Overall, our model is faster and more flexible for a wider range of parameter space than previous studies. We explore the limitations of our modeling set-up and offer guidance for future investigations using our framework.

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arXiv2025

JWST-TST DREAMS: NIRSpec/PRISM Transmission Spectroscopy of the Habitable Zone Planet TRAPPIST-1 e

TRAPPIST-1 e is one of the very few rocky exoplanets that is both amenable to atmospheric characterization and that resides in the habitable zone of its star -- located at a distance from its star such that it might, with the right atmosphere, sustain liquid water on its surface. Here, we present a set of 4 JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e obtained from mid to late 2023. Our transmission spectra exhibit similar levels of stellar contamination as observed in prior works for other planets in the TRAPPIST-1 system (Lim et al, 2023; Radica et al., 2024), but over a wider wavelength range, showcasing the challenge of characterizing the TRAPPIST-1 planets even at relatively long wavelengths (3-5 um). While we show that current stellar modeling frameworks are unable to explain the stellar contamination features in our spectra, we demonstrate that we can marginalize over those features instead using Gaussian Processes, which enables us to perform novel exoplanet atmospheric inferences with our transmission spectra. In particular, we are able to rule out cloudy, primary H$_2$-dominated ($\gtrsim$ 80$\%$ by volume) atmospheres at better than a 3$σ$ level. Constraints on possible secondary atmospheres on TRAPPIST-1 e are presented in a companion paper (Glidden et al., 2025). Our work showcases how JWST is breaking ground into the precisions needed to constrain the atmospheric composition of habitable-zone rocky exoplanets.

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arXiv2025

JWST-TST DREAMS: Secondary Atmosphere Constraints for the Habitable Zone Planet TRAPPIST-1 e

The TRAPPIST-1 system offers one of the best opportunities to characterize temperate terrestrial planets beyond our own solar system. Within the TRAPPIST-1 system, planet e stands out as highly likely to sustain surface liquid water if it possesses an atmosphere. Recently, we reported the first JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e, revealing significant stellar contamination, which varied between the four visits. Here, we assess the range of planetary atmospheres consistent with our transmission spectrum. We explore a wide range of atmospheric scenarios via a hierarchy of forward modeling and retrievals. We do not obtain strong evidence for or against an atmosphere. Our results weakly disfavor CO$_2$-rich atmospheres for pressures corresponding to the surface of Venus and Mars and the cloud tops of Venus at 2$σ$. We exclude H$_2$-rich atmospheres containing CO$_2$ and CH$_4$ in agreement with past work, but find that higher mean molecular weight, N$_2$-rich atmospheres with trace CO$_2$ and CH$_4$ are permitted by the data. Both a bare rock and N$_2$-rich atmospheric scenario provide adequate fits to the data, but do not fully explain all features, which may be due to either uncorrected stellar contamination or atmospheric signals. Ongoing JWST observations of TRAPPIST-1 e, exploiting consecutive transits with TRAPPIST-1 b, will offer stronger constraints via a more effective stellar contamination correction. The present work is part of the JWST Telescope Scientist Team (JWST-TST) Guaranteed Time Observations, which is performing a Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2025

Condensation Clouds in Substellar Atmospheres with Virga

Here we present an open-source cloud model for substellar atmospheres, called Virga. The Virga-v0 series has already been widely adopted in the literature. It is written in Python and has heritage from the Ackerman & Marley (2001) model (often referred to as eddysed), used to study clouds on both exoplanets and brown dwarfs. In the development of the official Virga-v1 we have retained all the original functionality of eddysed and updated/expanded several components including the back-end optical constants data, calculations of the Mie properties, available condensate species, saturation vapor pressure curves and formalism for fall speeds calculations. Here we benchmark Virga by reproducing key results in the literature, including the SiO2 cloud detection in WASP-17 b and the brown dwarf Diamondback-Sonora model series. Development of Virga is ongoing, with future versions already planned and ready for release. We encourage community feedback and collaborations within the GitHub code repository.

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arXiv2025

Modeling tails of escaping gas in exoplanet atmospheres with Harmonica

Exoplanets that reside close to their host stars, and therefore receive substantial amounts of X-ray and ultraviolet radiation, are prone to suffer from strong atmospheric escape. This can lead to the creation of an envelope of escaping gas along the planet's orbital trajectory, often referred to as a tail. When transiting in front of their host star, these tails can not only produce larger depths in the transit light curves, but also introduce significant asymmetries between ingress and egress. Using the publicly available software Harmonica, we present a method to model the light curves of transiting planets surrounded by extended envelopes of escaping gas, and subsequently infer the shape and size of the latter. We apply this method to the JWST NIRISS/SOSS observations of HAT-P-18b, which show pronounced helium tail features in its spectroscopic light curve of the metastable helium triplet at 10830 Å. Our model reveals that, in order to fit the observed light curve of HAT-P-18b, the planet must possess a trailing helium tail of $15.79^{+1.14}_{-1.05}$ planetary radii. We carry out injection-recovery tests to validate the effectiveness of the proposed methodology. We demonstrate that, with sufficient precision, we would be able to fit a multi-layer envelope to the data, which would provide insight into the relative radial variations in the opacity profile.

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arXiv2025

Additional JWST/NIRSpec Transits of the Rocky M Dwarf Exoplanet GJ 1132 b Reveal a Featureless Spectrum

As an archetypal M-dwarf rocky exoplanet, GJ 1132 b has a varied history of atmospheric measurements. At 1.13 $\rm R_{\oplus}$, 1.66 $\rm M_{\oplus}$, and 580 K, it orbits a bright, slowly rotating M dwarf in a 1.6-day period, making it a prime target for characterization. In this study, we combine two JWST NIRSpec/G395H transits previously reported by May and MacDonald et al. 2023 with two new NIRSpec/G395M transits to constrain the presence of an atmosphere. This marks the first time the G395H and G395M modes have been combined for a single target, and we report no difference in the quality of data between the two modes. For rocky M-dwarf studies, G395H may still be preferred if stacking transits to utilize the high-resolution flux-calibrated stellar spectra and assess evolving stellar heterogeneity. GJ 1132 b's co-added transmission spectrum is best-fit with a flat line. A thin steam atmosphere is also consistent with the data, but this interpretation is driven almost entirely by the first transit, which suggests an increase in cool spot coverage-fraction derived from the flux-calibrated stellar spectra. This demonstrates the importance of always considering stellar heterogeneity evolution in multi-visit transits, and also the importance of a "leave-one-transit-out" approach in modeling efforts of co-added transits. We combine these results with MIRI/LRS emission data (Xue et al. 2024) to show that together, transmission and emission are consistent with only the thinnest of atmospheres. Given GJ 1132 b's age and distance from the star, a thin atmosphere is not likely stable. Therefore, the simplest explanation is that GJ 1132 b is indeed a bare rock.

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arXiv2025

JWST COMPASS: A NIRSpec G395H Transmission Spectrum of the Super-Earth GJ 357 b

We present JWST NIRSpec/G395H transmission spectroscopy observations of GJ 357 b, a warm ($T_{\mathrm{eq}} \approx 525$ K) super-Earth ($1.2\ \mathrm{R_{\oplus}} $, $1.84\ \mathrm{M_{\oplus}} $) orbiting a nearby M3-type star, with a median precision of 18 ppm and 27 ppm in NRS1 and NRS2, respectively. These precisions are obtained by binning the spectrum into 53 spectroscopic channels with a resolution of 60 pixels (around 0.02 $μ$m) each. Our analysis of the transmission spectrum reveals no detectable atmospheric spectral features. By comparing the observed spectrum with 1D forward models, we rule out atmospheres with mean molecular weights (MMW) lower than 8 g/mol to $3 σ$, as well as atmospheres with metallicities less than 300x solar. The lack of a low MMW primary atmosphere is consistent with a primordial H$_2$ rich atmosphere having escaped, given the planet's $\gtrsim5$ Gyr age, relatively low surface gravity (log g = 3.09), and its likely history of substantial incident extreme ultraviolet radiation. We conclude that GJ 357 b most likely possesses either a high-MMW secondary atmosphere, perhaps rich in oxidized gases like CO$_2$, or is a bare rock with no atmosphere. Upcoming scheduled JWST thermal emission observations could help distinguish between these scenarios by detecting signatures indicative of atmospheric heat redistribution or molecular absorption.

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arXiv2025

Exoplanet Atmospheric Escape Observations with the Habitable Worlds Observatory

The Decadal Survey on Astronomy and Astrophysics 2020 highlights the importance of advancing research focused on discovering and characterizing habitable worlds. In line with this priority, our goal is to investigate how planetary systems evolve through atmospheric escape and to develop methods for identifying potentially Earth-like planets. By leveraging the ultraviolet (UV) capabilities of the Habitable Worlds Observatory (HWO), we can use transit spectroscopy to observe atmospheric escape in exoplanets and explore the processes that shape their evolution, assess the ability of small planets to retain their atmospheres, and search for signs of Earth-like atmospheres. To achieve this, we support the development of a UV spectrograph with moderate- to high-resolution capabilities for point-source observations, coverage of key spectral features in the 100-300 nm range, and detectors that can register high count rates reliably. This article is an adaptation of a science case document developed for the Characterizing Exoplanets Steering Committee within HWO's Solar Systems in Context Working Group.

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arXiv2025

The Effects of Cuboid Particle Scattering on Reflected Light Phase Curves: Insights from Laboratory Data and Theory

Understanding the optical properties of exoplanet cloud particles is a top priority. Many cloud condensates form as nonspherical particles and their optical properties can be very different from those of spheres. In this study, we focus on KCl particles, which likely form as cuboids in warm (T=500-1000K) exoplanet atmospheres. We compare the phase functions (at 532 nm wavelength) of KCl particles computed with Mie theory, the two-term Henyey-Greenstein (TTHG) approximation, laboratory data, and the discrete dipole approximation (DDA). Mie theory assumes scattering from spheres, while TTHG functions are used to approximate cloud scattering in two-stream radiative transfer models like PICASO. Laboratory measurements and DDA allow for a robust understanding of scattering from cuboid and deformed cuboid particle shapes. We input these phase functions into PICASO using cloud distributions from the cloud model Virga, to determine how different phase functions can impact the reflected-light intensities of the benchmark sub-Neptune, GJ 1214b. Simulated reflected light phase curves of GJ1214b produced using the TTHG, laboratory, and DDA phase curves differ by less than 3ppm. Our findings suggest that TTHG phase functions may be useful for approximating the scattering intensity of certain cuboid and irregular particle shapes. Future work should expand upon the wavelengths and particles considered to better determine when scattering approximations, like TTHG, may be useful in lieu of more accurate, but time-consuming laboratory measurements and/or nonspherical scattering theory.

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arXiv2025

Characterizing the Dynamics and Chemistry of Transiting Exoplanets with the Habitable World Observatory

The primary scientific objective of this Habitable Worlds Observatory (HWO) Science Case Development Document (SCDD) is to measure planetary rotation rates of transiting exoplanets to determine the structure, composition, circulation, and aerosol properties of their planetary atmospheres. For this analysis, HWO would obtain spectroscopic phase curves for planets with orbital periods of 5 - 20+ days, to assess tidal locking radius assumptions. Extending phase curve studies out to longer orbital periods than accessible with current and near-future telescopes will enable detailed investigation of atmospheric structure, composition, and circulation for planets that are much cooler than the more highly irradiated planets accessible with JWST phase curve observations (i.e., Teq < 500 K for HWO versus 1400 K <= Teq <= 2600 K for JWST). Broad wavelength coverage extending from the UV to the NIR would capture both reflected light and thermal emission, enabling HWO to conduct comprehensive characterization of planetary atmospheres. UV observations would probe high altitudes, thereby providing valuable insights into atmospheric (dis)equilibrium, aerosol properties, and the effects of photochemical processes on atmospheric composition. We also discuss the role of polarimetry in the classification of aerosols and the associated role they play in the atmospheric energy budget that directly ties them to the chemistry and circulation structure of the atmosphere.

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arXiv2025

The HUSTLE Program: The UV to Near-IR Transmission Spectrum of the Hot Jupiter KELT-7b

The ultraviolet and optical wavelength ranges have proven to be a key addition to infrared observations of exoplanet atmospheres, as they offer unique insights into the properties of clouds and hazes and are sensitive to signatures of disequilibrium chemistry. Here we present the 0.2-0.8 $μ$m transmission spectrum of the Teq = 2000 K Jupiter KELT-7b, acquired with HST WFC3/UVIS G280 as part of the HUSTLE Treasury program. We combined this new spectrum with the previously published HST WFC3/IR G141 (1.1-1.7 $μ$m) spectrum and Spitzer photometric points at 3.6$μ$m and 4.5$μ$m, to reveal a generally featureless transmission spectrum between 0.2 and 1.7 $μ$m, with a slight downward slope towards bluer wavelengths, and a asymmetric water feature in the 1.1-1.7 $μ$m band. Retrieval models conclude that the 0.2 - 1.7$μ$m spectrum is primarily explained by a high H- abundance ($\sim 10^{-5}$), significantly above the equilibrium chemistry prediction ($\sim 10^{-12}$), suggesting disequilibrium in KELT-7b's upper atmosphere. Our retrievals also suggest the presence of bright inhomogeneities in the stellar surface, and tentative evidence of CO2 at the Spitzer wavelengths. We demonstrate that with the UV-optical coverage provided by WFC3 UVIS/G280, we are able to confirm the presence and constrain the abundance of H-, and obtain evidence for bright stellar inhomogeneities that would have been overlooked using infrared data alone. Observations redward of 1$μ$m with JWST should be able to further constrain the abundance of H-, as well as confirm the presence of CO2 inferred by the two Spitzer datapoints.

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arXiv2025

Tracing the formation and migration history: molecular signatures in the atmosphere of misaligned hot Jupiter WASP-94Ab using JWST NIRSpec/G395H

The discovery of hot Jupiters that orbit very close to their host stars has long challenged traditional models of planetary formation and migration. Characterising their atmospheric composition - mainly in the form of the carbon-to-oxygen (C/O) ratio and metallicity - can provide insights into their formation locations and evolution pathways. With JWST we can characterise the atmospheres of these types of planets more precisely than previously possible, primarily because it allows us to determine both their atmospheric oxygen and carbon composition. Here, we present a JWST NIRSpec/G395H transmission spectrum from 2.8-5.1$μm$ of WASP-94Ab, an inflated hot Jupiter with a retrograde misaligned orbit around its F-type host star. We find a relatively cloud-free atmosphere, with absorption features of H$_2$O and CO$_2$ at detection significances of $\sim 4σ$ and $\sim 11σ$, respectively. In addition, we detect tentative evidence of CO absorption at $\sim3σ$, as well as hints of sulphur with the detection of H$_2$S at a $\sim 2.5σ$ confidence level. Our favoured equilibrium chemistry model determines a C/O ratio of $0.49^{+0.08}_{-0.13}$ for WASP-94Ab's atmosphere, which is substellar compared to the star's C/O ratio of $0.68 \pm 0.10$. The retrieved atmospheric metallicity is similar to the star's metallicity as both are $\sim 2\times$ solar. We find that this sub-stellar C/O ratio and stellar metallicity can be best explained by pebble accretion or planetesimal accretion in combination with large-distance migration of the planet.

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