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Hannah R. Wakeford

Publications and source records attributed to Hannah R. Wakeford.

At least 73 records · Page 4Linked to original sources

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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JWST-TST High Contrast: Achieving direct spectroscopy of faint substellar companions next to bright stars with the NIRSpec IFU

The JWST NIRSpec integral field unit (IFU) presents a unique opportunity to observe directly imaged exoplanets from 3-5 um at moderate spectral resolution (R~2,700) and thereby better constrain the composition, disequilibrium chemistry, and cloud properties of their atmospheres. In this work, we present the first NIRSpec IFU high-contrast observations of a substellar companion that requires starlight suppression techniques. We develop specific data reduction strategies to study faint companions around bright stars, and assess the performance of NIRSpec at high contrast. First, we demonstrate an approach to forward model the companion signal and the starlight directly in the detector images, which mitigates the effects of NIRSpec's spatial undersampling. We demonstrate a sensitivity to planets that are 3e-6 fainter than their stars at 1'', or 3e-5 at 0.3''. Then, we implement a reference star point spread function (PSF) subtraction and a spectral extraction that does not require spatially and spectrally regularly sampled spectral cubes. This allows us to extract a moderate resolution (R~2,700) spectrum of the faint T-dwarf companion HD 19467 B from 2.9-5.2 um with signal-to-noise ratio (S/N)~10 per resolution element. Across this wavelength range, HD~19467~B has a flux ratio varying between 1e-5-1e-4 and a separation relative to its star of 1.6''. A companion paper by Hoch et al. more deeply analyzes the atmospheric properties of this companion based on the extracted spectrum. Using the methods developed here, NIRSpec's sensitivity may enable direct detection and spectral characterization of relatively old (~1 Gyr), cool (~250 K), and closely separated (~3-5 au) exoplanets that are less massive than Jupiter.

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HST SHEL: Enabling Comparative Exoplanetology with HST/STIS

The Hubble Space Telescope (HST) has been our most prolific tool to study exoplanet atmospheres. As the age of JWST begins, there is a wealth of HST archival data that is useful to strengthen our inferences from JWST. Notably, HST/STIS and its 0.3-1 $μ$m wavelength coverage extends past JWST's 0.6 $μ$m wavelength cutoff and holds an abundance of potential information: alkali (Na, K) and molecular (TiO, VO) species opacities, aerosol information, and the presence of stellar contamination. However, time series observations with HST suffer from significant instrumental systematics and can be highly dependent on choices made during the transit fitting process. This makes comparing transmission spectra of planets with different data reduction methodologies challenging, as it is difficult to discern if an observed trend is caused by differences in data reduction or underlying physical processes. Here, we present the Sculpting Hubble's Exoplanet Legacy (SHEL) program, which aims to build a consistent data reduction and light curve analysis methodology and associated database of transmission spectra from archival HST observations. In this paper, we present the SHEL analysis framework for HST/STIS and its low-resolution spectroscopy modes, G430L and G750L. We apply our methodology to four notable hot Jupiters: WASP-39 b, WASP-121 b, WASP-69 b, and WASP-17 b, and use these examples to discuss nuances behind analysis with HST/STIS. Our results for WASP-39 b, WASP-121 b, and WASP-17 b are consistent with past publications, but our analysis of WASP-69 b differs and shows evidence of either a strong scattering slope or stellar contamination. The data reduction pipeline and tutorials are available on Github.

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JWST COMPASS: A NIRSpec/G395H Transmission Spectrum of the Sub-Neptune TOI-836c

Planets between the sizes of Earth and Neptune are the most common in the Galaxy, bridging the gap between the terrestrial and giant planets in our Solar System. Now that we are firmly in the era of JWST, we can begin to measure, in more detail, the atmospheres of these ubiquitous planets to better understand their evolutionary trajectories. The two planets in the TOI-836 system are ideal candidates for such a study, as they fall on either side of the radius valley, allowing for direct comparisons of the present-day atmospheres of planets that formed in the same environment but had different ultimate end states. We present results from the JWST NIRSpec G395H transit observation of the larger and outer of the planets in this system, TOI-836c (2.587 R$_{\oplus}$, 9.6 M$_{\oplus}$, T$_{\rm eq}$$\sim$665 K). While we measure average 30-pixel binned precisions of $\sim$24ppm for NRS1 and $\sim$43ppm for NRS2 per spectral bin, we do find residual correlated noise in the data, which we attempt to correct using the JWST Engineering Database. We find a featureless transmission spectrum for this sub-Neptune planet, and are able to rule out atmospheric metallicities $<$175$\times$ Solar in the absence of aerosols at $\lesssim$1 millibar. We leverage microphysical models to determine that aerosols at such low pressures are physically plausible. The results presented herein represent the first observation from the COMPASS (Compositions of Mini-Planet Atmospheres for Statistical Study) JWST program, which also includes TOI-836b and will ultimately compare the presence and compositions of atmospheres for 12 super-Earths/sub-Neptunes.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of the Super-Earth TOI-836b

We present two transit observations of the ~870K, 1.7R$_E$ super-Earth TOI-836b with JWST NIRSpec/G395H, resulting in a 2.8-5.2$μ$m transmission spectrum. Using two different reduction pipelines, we obtain a median transit depth precision of 34ppm for Visit 1 and 36ppm for Visit 2, leading to a combined precision of 25ppm in spectroscopic channels 30 pixels wide (~0.02$μ$m). We find that the transmission spectrum from both visits is well fit by a zero-sloped line by fitting zero-sloped and sloped lines, as well as step functions to our data. Combining both visits, we are able to rule out atmospheres with metallicities <250xSolar for an opaque pressure level of 0.1 bar, corresponding to mean molecular weights to <6gmol$^{-1}$. We therefore conclude that TOI-836b does not have an H$_2$-dominated atmosphere, in possible contrast with its larger, exterior sibling planet, TOI-836c. We recommend that future proposals to observe small planets exercise caution when requiring specific numbers of transits to rule out physical scenarios, particularly for high metallicities and planets around bright host stars, as PandExo predictions appear to be more optimistic than that suggested by the gains from additional transits implied by our data.

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The Importance of Optical Wavelength Data on Atmospheric Retrievals of Exoplanet Transmission Spectra

Exoplanet transmission spectra provide rich information about the chemical composition, clouds and temperature structure of exoplanet atmospheres. Most exoplanet transmission spectra only span infrared wavelengths ($\gtrsim$ 1 $\rm{μm}$), which can preclude crucial atmospheric information from shorter wavelengths. Here, we explore how retrieved atmospheric parameters from exoplanet transmission spectra change with the addition of optical data. From a sample of 14 giant planets with transit spectra from 0.3-4.5 $\rm{μm}$, primarily from the Hubble and Spitzer space telescopes, we apply a free chemistry retrieval to planetary spectra for wavelength ranges of 0.3-4.5 $\rm{μm}$, 0.6-4.5 $\rm{μm}$, and 1.1-4.5 $\rm{μm}$. We analyse the posterior distributions of these retrievals and perform an information content analysis, finding wavelengths below 0.6 $\rm{μm}$ are necessary to constrain cloud scattering slope parameters ($\log{a}$ and $γ$) and alkali species Na and K. There is limited improvement in the constraints on the remaining atmospheric parameters. Across the population, we find limb temperatures are retrieved colder than planetary equilibrium temperatures but have an overall good agreement with Global Circulation Models. As JWST extends to a minimum wavelength of 0.6 $\rm{μm}$, we demonstrate that exploration into complementing JWST observations with optical HST data is important to further our understanding of aerosol properties and alkali abundances in exoplanet atmospheres.

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Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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JWST/NIRCam Transmission Spectroscopy of the Nearby Sub-Earth GJ 341b

We present a JWST/NIRCam transmission spectrum from $3.9-5.0$ $μ$m of the recently-validated sub-Earth GJ 341b ($\mathrm{R_P} = 0.92$ $\mathrm{R_{\oplus}}$, $\mathrm{T_{eq}} = 540$ K) orbiting a nearby bright M1 star ($\mathrm{d} = 10.4$ pc, $\mathrm{K_{mag}}=5.6$). We use three independent pipelines to reduce the data from the three JWST visits and perform several tests to check for the significance of an atmosphere. Overall, our analysis does not uncover evidence of an atmosphere. Our null hypothesis tests find that none of our pipelines' transmission spectra can rule out a flat line, although there is weak evidence for a Gaussian feature in two spectra from different pipelines (at 2.3 and $2.9σ$). However, the candidate features are seen at different wavelengths (4.3 $μ$m vs 4.7 $μ$m), and our retrieval analysis finds that different gas species can explain these features in the two reductions (CO$_2$ at $3.1σ$ compared to O$_3$ at $2.9σ$), suggesting that they are not real astrophysical signals. Our forward model analysis rules out a low mean molecular weight atmosphere ($< 350\times$ solar metallicity) to at least $3σ$, and disfavors CH$_4$-dominated atmospheres at $1-3σ$, depending on the reduction. Instead, the forward models find our transmission spectra are consistent with no atmosphere, a hazy atmosphere, or an atmosphere containing a species that does not have prominent molecular bands across the NIRCam/F444W bandpass, such as a water-dominated atmosphere. Our results demonstrate the unequivocal need for two or more transit observations analyzed with multiple reduction pipelines, alongside rigorous statistical tests, to determine the robustness of molecular detections for small exoplanet atmospheres.

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Aerosols are not Spherical Cows: Using Discrete Dipole Approximation to Model the Properties of Fractal Particles

The optical properties of particulate-matter aerosols, within the context of exoplanet and brown dwarf atmospheres, are compared using three different models: Mie theory, Modified Mean Field (MMF) Theory, and Discrete Dipole Approximation (DDA). Previous results have demonstrated that fractal haze particles (MMF and DDA) absorb much less long-wavelength radiation than their spherical counterparts (Mie), however it is shown here that the opposite can also be true if a more varying refractive index profile is used. Additionally, it is demonstrated that absorption and scattering cross-sections, as well as the asymmetry parameter, are underestimated if Mie theory is used. Although DDA can be used to obtain more accurate results, it is known to be much more computationally intensive; to avoid this, the use of low-resolution aerosol models is explored, which could dramatically speed up the process of obtaining accurate computations of optical cross-sections within a certain parameter space. The validity of DDA is probed for wavelengths of interest for observations of aerosols within exoplanet and brown dwarf atmospheres (0.2 to 15 micrometres). Finally, novel code is presented to compare the results of Mie, MMF and DDA theories (CORAL: Comparison Of Radiative AnaLyses), as well as to increase and decrease the resolution of DDA shape files accordingly (SPHERIFY). Both codes can be applied to a range of other interesting astrophysical environments in addition to exoplanet atmospheres, for example dust grains within protoplanetary disks.

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Double Trouble: Two Transits of the Super-Earth GJ 1132 b Observed with JWST NIRSpec G395H

The search for rocky planet atmospheres with JWST has focused on planets transiting M dwarfs. Such planets have favorable planet-to-star size ratios, enhancing the amplitude of atmospheric features. Since the expected signal strength of atmospheric features is similar to the single-transit performance of JWST, multiple observations are required to confirm any detection. Here, we present two transit observations of the rocky planet GJ 1132 b with JWST NIRSpec G395H, covering 2.8-5.2 $μ$m. Previous HST WFC3 observations of GJ 1132 b were inconclusive, with evidence reported for either an atmosphere or a featureless spectrum based on analyses of the same dataset. Our JWST data exhibit substantial differences between the two visits. One transit is consistent with either a H$_2$O-dominated atmosphere containing ~1% CH$_4$ and trace N$_2$O ($χ^{2}_ν$ = 1.13) or stellar contamination from unocculted starspots ($χ^{2}_ν$ = 1.36). However, the second transit is consistent with a featureless spectrum. Neither visit is consistent with a previous report of HCN. Atmospheric variability is unlikely to explain the scale of the observed differences between the visits. Similarly, our out-of-transit stellar spectra show no evidence of changing stellar inhomogeneity between the two visits - observed 8 days apart, only 6.5% of the stellar rotation rate. We further find no evidence of differing instrumental systematic effects between visits. The most plausible explanation is an unlucky random noise draw leading to two significantly discrepant transmission spectra. Our results highlight the importance of multi-visit repeatability with JWST prior to claiming atmospheric detections for these small, enigmatic planets.

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Detection of Carbon Monoxide in the Atmosphere of WASP-39b Applying Standard Cross-Correlation Techniques to JWST NIRSpec G395H Data

Carbon monoxide was recently reported in the atmosphere of the hot Jupiter WASP-39b using the NIRSpec PRISM transit observation of this planet, collected as part of the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) Program. This detection, however, could not be confidently confirmed in the initial analysis of the higher resolution observations with NIRSpec G395H disperser. Here we confirm the detection of CO in the atmosphere of WASP-39b using the NIRSpec G395H data and cross-correlation techniques. We do this by searching for the CO signal in the unbinned transmission spectrum of the planet between 4.6 and 5.0 $μ$m, where the contribution of CO is expected to be higher than that of other anticipated molecules in the planet's atmosphere. Our search results in a detection of CO with a cross-correlation function (CCF) significance of $6.6 σ$ when using a template with only ${\rm ^{12}C^{16}O}$ lines. The CCF significance of the CO signal increases to $7.5 σ$ when including in the template lines from additional CO isotopologues, with the largest contribution being from ${\rm ^{13}C^{16}O}$. Our results highlight how cross-correlation techniques can be a powerful tool for unveiling the chemical composition of exoplanetary atmospheres from medium-resolution transmission spectra, including the detection of isotopologues.

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Hydrodynamic atmospheric escape in HD 189733 b: Signatures of carbon and hydrogen measured with the Hubble Space Telescope

One of the most well-studied exoplanets to date, HD 189733 b, stands out as an archetypal hot Jupiter with many observations and theoretical models aimed at characterizing its atmosphere, interior, host star, and environment. We report here on the results of an extensive campaign to observe atmospheric escape signatures in HD 189733 b using the Hubble Space Telescope and its unique ultraviolet capabilities. We have found a tentative, but repeatable in-transit absorption of singly-ionized carbon (C II, $5.2\% \pm 1.4\%$) in the epoch of June-July/2017, as well as a neutral hydrogen (H I) absorption consistent with previous observations. We model the hydrodynamic outflow of HD 189733 b using an isothermal Parker wind formulation to interpret the observations of escaping C and O nuclei at the altitudes probed by our observations. Our forward models indicate that the outflow of HD 189733 b is mostly neutral within an altitude of $\sim 2$ R$_\mathrm{p}$ and singly ionized beyond that point. The measured in-transit absorption of C II at 133.57 nm is consistent with an escape rate of $\sim 1.1 \times 10^{11}$ g$\,$s$^{-1}$, assuming solar C abundance and outflow temperature of $12\,100$ K. Although we find a marginal neutral oxygen (O I) in-transit absorption, our models predict an in-transit depth that is only comparable to the size of measurement uncertainties. A comparison between the observed Lyman-$α$ transit depths and hydrodynamics models suggests that the exosphere of this planet interacts with a stellar wind at least one order of magnitude stronger than solar.

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Detection of carbon monoxide's 4.6 micron fundamental band structure in WASP-39b's atmosphere with JWST NIRSpec G395H

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrmμ$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b.

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A JWST NIRSpec Phase Curve for WASP-121b: Dayside Emission Strongest Eastward of the Substellar Point and Nightside Conditions Conducive to Cloud Formation

We present the first exoplanet phase curve measurement made with the JWST NIRSpec instrument, highlighting the exceptional stability of this newly-commissioned observatory for exoplanet climate studies. The target, WASP-121b, is an ultrahot Jupiter with an orbital period of 30.6 hr. We analyze two broadband light curves generated for the NRS1 and NRS2 detectors, covering wavelength ranges of 2.70-3.72 micron and 3.82-5.15 micron, respectively. Both light curves exhibit minimal systematics, with approximately linear drifts in the baseline flux level of 30 ppm/hr (NRS1) and 10 ppm/hr (NRS2). Assuming a simple brightness map for the planet described by a low-order spherical harmonic dipole, our light curve fits suggest that the phase curve peaks coincide with orbital phases $3.36 \pm 0.11$ deg (NRS1) and $2.66 \pm 0.12$ deg (NRS2) prior to mid-eclipse. This is consistent with the strongest dayside emission emanating from eastward of the substellar point. We measure planet-to-star emission ratios of $3,924 \pm 7$ ppm (NRS1) and $4,924 \pm 9$ ppm (NRS2) for the dayside hemisphere, and $136 \pm 8$ ppm (NRS1) and $630 \pm 10$ ppm (NRS2) for the nightside hemisphere. The latter nightside emission ratios translate to planetary brightness temperatures of $926 \pm 12$ K (NRS1) and $1,122 \pm 10$ K (NRS2), which are low enough for a wide range of refractory condensates to form, including enstatite and forsterite. A nightside cloud deck may be blocking emission from deeper, hotter layers of the atmosphere, potentially helping to explain why cloud-free 3D general circulation model simulations systematically over-predict the nightside emission for WASP-121b.

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A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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Transmission strings: a technique for spatially mapping exoplanet atmospheres around their terminators

Exoplanet transmission spectra, which measure the absorption of light passing through a planet's atmosphere during transit, are most often assessed globally, resulting in a single spectrum per planetary atmosphere. However, the inherent three-dimensional nature of planetary atmospheres, via thermal, chemical, and dynamical processes, can imprint inhomogeneous structure and properties in the observables. In this work, we devise a technique for spatially mapping the atmospheres of exoplanets in transmission. Our approach relaxes the assumption that transit light curves are created from circular stars occulted by circular planets, and instead we allow for flexibility in the planet's sky-projected shape. We define the planet's radius to be a single-valued function of angle around its limb, and we refer to this mathematical object as a transmission string. These transmission strings are parameterised in terms of Fourier series, a choice motivated by these series having adjustable complexity, generating physically practical shapes, while being reducible to the classical circular case. The utility of our technique is primarily intended for high-precision multi-wavelength light curves, from which inferences of transmission spectra can be made as a function of angle around a planet's terminator, enabling analysis of the multidimensional physics at play in exoplanet atmospheres. More generally, the technique can be applied to any transit light curve to derive the shape of the transiting body. The algorithm we develop is available as an open-source package, called harmonica.

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Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $μ$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$σ$) and H$_2$O (21.5$σ$), and identify SO$_2$ as the source of absorption at 4.1 $μ$m (4.8$σ$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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Early Release Science of the exoplanet WASP-39b with JWST NIRISS

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 μ$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator.

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