arXiv subjects

Haruki Sato

Publications and source records attributed to Haruki Sato.

4 recordsLinked to original sources

arXiv2025

Peak separation methods for inverse photoelectron spectra: Comparing second derivative, curve fitting, and deconvolution analyses

Inverse photoelectron spectroscopy (IPES) is a powerful technique for probing the unoccupied electronic states of materials. It can be regarded as the inversion process of photoelectron spectroscopy (PES), which examines the occupied states. Recently developed low-energy inverse photoelectron spectroscopy (LEIPS) can significantly advance the study of unoccupied states, owing to minimal sample damage and suppressed dark counts compared to conventional IPES. However, the instrumental resolution remains at 0.2 eV, which is one order of magnitude lower than that of PES. Spectral broadening caused by the low instrumental resolution often results in overlapping peaks. Peak separation is therefore crucial in the analysis of LEIPS spectra. In this study, we compared three peak separation methods-second derivative, curve fitting, and deconvolution. These methods were applied to modeled and experimental LEIPS spectra of the lowest unoccupied molecular orbital-derived band of pentacene, which consists of two splitting peaks due to the two inequivalent molecules in the unit cell. We systematically and quantitatively evaluated the performance of each method in terms of analysis parameters and discussed its robustness to noise as well as its peak separation capabilities as a function of peak energy spacing and intensity ratio. This work offers a practical framework for peak separation in LEIPS, with extensions to PES and a wide range of spectroscopies.

physics.ins-det↗

arXiv2022

Diversified Adversarial Attacks based on Conjugate Gradient Method

Deep learning models are vulnerable to adversarial examples, and adversarial attacks used to generate such examples have attracted considerable research interest. Although existing methods based on the steepest descent have achieved high attack success rates, ill-conditioned problems occasionally reduce their performance. To address this limitation, we utilize the conjugate gradient (CG) method, which is effective for this type of problem, and propose a novel attack algorithm inspired by the CG method, named the Auto Conjugate Gradient (ACG) attack. The results of large-scale evaluation experiments conducted on the latest robust models show that, for most models, ACG was able to find more adversarial examples with fewer iterations than the existing SOTA algorithm Auto-PGD (APGD). We investigated the difference in search performance between ACG and APGD in terms of diversification and intensification, and define a measure called Diversity Index (DI) to quantify the degree of diversity. From the analysis of the diversity using this index, we show that the more diverse search of the proposed method remarkably improves its attack success rate.

cs.LG↗

arXiv2022

Long-Term Optimal Delivery Planning for Replacing the Liquefied Petroleum Gas Cylinder

In the daily operation of liquefied petroleum gas service, gas providers visit customers and replace cylinders if the gas is about to run out. For a long time, frequent visits to customers were required because they could not determine the amount of remaining gas without a staff visit and observation. To solve this problem, smart meters are started to be employed to acquire gas consumption more frequently without visiting customers. In this study, we construct a system to optimize plans for cylinder replacement, and evaluate it with a large-scale field test. We propose an algorithm to create a replacement plan with three steps: estimating the replacement date, acquiring the customer list for replacement, and determining the delivery route. A more accurate estimation of the replacement date can be acquired with a smart meter, which is used for making a customer list for replacement. The formulation for making a customer list enables the gas provider to replace cylinders some days before the date when the gas would run out. It can suppress the concentration of replacements on certain days. Large-scale verification experiments were performed with more than 1,000 customers in Chiba prefecture in Japan. In the field test, the gas provider incorporated the system into its replacement operations. Moreover, the replacement plans developed by the proposed system were compared with that by the gas provider. Our system reduced the number of gas cylinders with gas shortage, the number of visits without replacement due to plenty of gas remaining, and the working duration per customer, which shows that our system benefits both gas providers and customers.

eess.SY↗

arXiv2020

Accessing the conduction band dispersion in CH3NH3PbI3 single crystals

The conduction band structure in methylammonium lead iodide (CH3NH3PbI3) was studied both by angle-resolved two-photon photoemission spectroscopy (AR-2PPE) with low-photon intensity and angle-resolved low-energy inverse photoelectron spectroscopy (AR-LEIPS). Clear energy dispersion of the conduction band along the ΓM direction was observed by these independent methods under different temperatures, and the dispersion was found to be consistent with band calculations under the cubic phase. The effective mass of the electrons at the Γ point was estimated to be (0.20+-0.05)m0 at 90 K. The observed energy position was largely different between the AR-LEIPS and AR-2PPE, demonstrating the electron correlation effects on the band structures. The present results also indicate that the surface structure in CH3NH3PbI3 provides the cubic-dominated electronic property even at lower temperatures.

cond-mat.mtrl-sci↗