arXiv subjects

Heiner Linke

Publications and source records attributed to Heiner Linke.

34 records · Page 2Linked to original sources

arXiv2017

Single-nanowire, low-bandgap hot carrier solar cells with tunable open-circuit voltage

Compared to traditional pn-junction photovoltaics, hot carrier solar cells offer potentially higher efficiency by extracting work from the kinetic energy of photogenerated "hot carriers" before they cool to the lattice temperature. Hot carrier solar cells have been demonstrated in high-bandgap ferroelectric insulators and GaAs/AlGaAs heterostructures, but so far not in low-bandgap materials, where the potential efficiency gain is highest. Recently, a high open-circuit voltage was demonstrated in an illuminated wurtzite InAs nanowire with a low bandgap of 0.39 eV, and was interpreted in terms of a photothermoelectric effect. Here, we point out that this device is a hot carrier solar cell and discuss its performance in those terms. In the demonstrated devices, InP heterostructures are used as energy filters in order to thermoelectrically harvest the energy of hot electrons photogenerated in InAs absorber segments. The obtained photovoltage depends on the heterostructure design of the energy filter and is therefore tunable. By using a high-resistance, thermionic barrier an open-circuit voltage is obtained that is in excess of the Shockley-Queisser limit. These results provide generalizable insight into how to realize high voltage hot carrier solar cells in low-bandgap materials, and therefore are a step towards the demonstration of higher efficiency hot carrier solar cells.

physics.app-ph↗

arXiv2017

Supremacy of the quantum many-body Szilard engine with attractive bosons

In a classic thought experiment, Szilard suggested a heat engine where a single particle, for example an atom or a molecule, is confined in a container coupled to a single heat bath. The container can be separated into two parts by a moveable wall acting as a piston. In a single cycle of the engine, work can be extracted from the information on which side of the piston the particle resides. The work output is consistent with Landauers principle that the erasure of one bit of information costs the entropy kB ln 2, exemplifying the fundamental relation between work, heat and information. Here we apply the concept of the Szilard engine to a fully interacting quantum many-body system. We find that a working medium of a number of bosons (larger or equal two) with attractive interactions is clearly superior to other previously discussed setups. In sharp contrast to the classical case, we find that the average work output increases with the particle number. The highest overshoot occurs for a small but finite temperature, showing an intricate interplay between thermal and quantum effects. We anticipate that our finding will shed new light on the role of information in controlling thermodynamic fluctuations in the deep quantum regime, which are strongly influenced by quantum correlations in interacting systems.

quant-ph↗

arXiv2016

Experiments on thermoelectric properties of quantum dots

Quantum dots (QDs) are good model systems for fundamental studies of mesoscopic transport phenomena using thermoelectric effects because of their small size, electrostatically tunable properties and thermoelectric response characteristics that are very sensitive to small thermal biases. Here we provide a review of experimental studies on thermoelectric properties of single QDs realized in two-dimensional electron gases, single-walled carbon nanotubes and semiconductor nanowires. A key requirement for such experiments is methods for nanoscale thermal biasing. We briefly review the main techniques used in the field, namely, heating of the QD contacts, side heating and top heating, and touch upon their relative advantages. The thermoelectric response of a QD as a function of gate potential has a characteristic oscillatory behavior with the same period as is observed for conductance peaks. Much of the existing literature focuses on the agreement between experiments and theory, particularly for amplitude and line-shape of the thermovoltage $V_{th}$. A general observation is that the widely used single-electron tunneling approximation for QDs has limited success in reproducing measured $V_{th}$. Landauer-type calculations are often found to describe measurement results better despite the large electron-electron interactions in QDs. More recently, nonlinear thermoelectric effects have moved into the focus of attention and we offer a brief overview of experiments done so far. We conclude by discussing open questions and avenues for future work, including the role of asymmetries in tunnel- and capacitive couplings in thermoelectric behavior of QDs.

cond-mat.mes-hall↗

arXiv2015

Nonlinear thermoelectric response due to energy-dependent transport properties of a quantum dot

Quantum dots are useful model systems for studying quantum thermoelectric behavior because of their highly energy-dependent electron transport properties, which are tunable by electrostatic gating. As a result of this strong energy dependence, the thermoelectric response of quantum dots is expected to be nonlinear with respect to an applied thermal bias. However, until now this effect has been challenging to observe because, first, it is experimentally difficult to apply a sufficiently large thermal bias at the nanoscale and, second, it is difficult to distinguish thermal bias effects from purely temperature-dependent effects due to overall heating of a device. Here we take advantage of a novel thermal biasing technique and demonstrate a nonlinear thermoelectric response in a quantum dot which is defined in a heterostructured semiconductor nanowire. We also show that a theoretical model based on the Master equations fully explains the observed nonlinear thermoelectric response given the energy-dependent transport properties of the quantum dot.

cond-mat.mes-hall↗

arXiv2015

Reversible electron-hole separation in a hot carrier solar cell

Hot-carrier solar cells are envisioned to utilize energy filtering to extract power from photogenerated electron-hole pairs before they thermalize with the lattice, and thus potentially offer higher power conversion efficiency compared to conventional, single absorber solar cells. The efficiency of hot-carrier solar cells can be expected to strongly depend on the details of the energy filtering process, a relationship which to date has not been satisfactorily explored. Here, we establish the conditions under which electron-hole separation in hot-carrier solar cells can occur reversibly, that is, at maximum energy conversion efficiency. We thus focus our analysis on the internal operation of the hot-carrier solar cell itself, and in this work do not consider the photon-mediated coupling to the sun. After deriving an expression for the voltage of a hot-carrier solar cell valid under conditions of both reversible and irreversible electrical operation, we identify separate contributions to the voltage from the thermoelectric effect and the photovoltaic effect. We find that, under specific conditions, the energy conversion efficiency of a hot-carrier solar cell can exceed the Carnot limit set by the intra-device temperature gradient alone, due to the additional contribution of the quasi-Fermi level splitting in the absorber. We also establish that the open-circuit voltage of a hot-carrier solar cell is not limited by the band gap of the absorber, due to the additional thermoelectric contribution to the voltage. Additionally, we find that a hot-carrier solar cell can be operated in reverse as a thermally driven solid-state light emitter. Our results help explore the fundamental limitations of hot-carrier solar cells, and provide a first step towards providing experimentalists with a guide to the optimal configuration of devices.

cond-mat.mes-hall↗

arXiv2015

Thermoelectric performance of classical topological insulator nanowires

There is currently substantial effort being invested into creating efficient thermoelectric nanowires based on topological insulator chalcogenide-type materials. A key premise of these efforts is the assumption that the generally good thermoelectric properties that these materials exhibit in bulk form will translate into similarly good or even better thermoelectric performance of the same materials in nanowire form. Here, we calculate thermoelectric performance of topological insulator nanowires based on Bi2Te3, Sb2Te3 and Bi2Se3 as a function of diameter and Fermi level. We show that the thermoelectric performance of topological insulator nanowires does not derive from the properties of the bulk material in a straightforward way. For all investigated systems the competition between surface states and bulk channel causes a significant modification of the thermoelectric transport coefficients if the diameter is reduced into the sub-10 um range. Key aspects are that the surface and bulk states are optimized at different Fermi levels or have different polarity as well as the high surface to volume ratio of the nanowires. This limits the maximum thermoelectric performance of topological insulator nanowires and thus their application in efficient thermoelectric devices.

cond-mat.mtrl-sci↗

arXiv2014

Using polymer electrolyte gates to set-and-freeze threshold voltage and local potential in nanowire-based devices and thermoelectrics

We use the strongly temperature-dependent ionic mobility in polymer electrolytes to 'freeze in' specific ionic charge environments around a nanowire using a local wrap-gate geometry. This enables us to set both the threshold voltage for a conventional doped substrate gate and the local disorder potential at temperatures below 200 Kelvin, which we characterize in detail by combining conductance and thermovoltage measurements with modeling. Our results demonstrate that local polymer electrolyte gates are compatible with nanowire thermoelectrics, where they offer the advantage of a very low thermal conductivity, and hold great potential towards setting the optimal operating point for solid-state cooling applications.

cond-mat.mes-hall↗

arXiv2013

Nonlinear thermovoltage and thermocurrent in quantum dots

Quantum dots are model systems for quantum thermoelectric behavior because of the ability to control and measure the effects of electron-energy filtering and quantum confinement on thermoelectric properties. Interestingly, nonlinear thermoelectric properties of such small systems can modify the efficiency of thermoelectric power conversion. Using quantum dots embedded in semiconductor nanowires, we measure thermovoltage and thermocurrent that are strongly nonlinear in the applied thermal bias. We show that most of the observed nonlinear effects can be understood in terms of a renormalization of the quantum-dot energy levels as a function of applied thermal bias and provide a theoretical model of the nonlinear thermovoltage taking renormalization into account. Furthermore, we propose a theory that explains a possible source of the observed, pronounced renormalization effect by the melting of Kondo correlations in the mixed-valence regime. The ability to control nonlinear thermoelectric behavior expands the range in which quantum thermoelectric effects may be used for efficient energy conversion.

cond-mat.mes-hall↗

arXiv2012

Heat flow in InAs/InP heterostructure nanowires

The transfer of heat between electrons and phonons plays a key role for thermal management in future nanowire-based devices, but only a few experimental measurements of electron-phonon (e-ph) coupling in nanowires are available. Here, we combine experimental temperature measurements on an InAs/InP heterostructure nanowire system with finite element modeling (FEM) to extract information on heat flow mediated by e-ph coupling. We find that the electron and phonon temperatures in our system are highly coupled even at temperatures as low as 2 K. Additionally, we find evidence that the usual power-law temperature dependence of electron-phonon coupling may not correctly describe the coupling in nanowires and show that this result is consistent with previous research on similar one-dimensional electron systems. We also compare the strength of the observed e-ph coupling to a theoretical analysis of e-ph interaction in InAs nanowires, which predicts a significantly weaker coupling strength than observed experimentally.

cond-mat.mes-hall↗

arXiv2012

Thermally driven ballistic rectifer

The response of electric devices to an applied thermal gradient has, so far, been studied almost exclusively in two-terminal devices. Here we present measurements of the response to a thermal bias of a four-terminal, quasi-ballistic junction with a central scattering site. We find a novel transverse thermovoltage measured across isothermal contacts. Using a multi-terminal scattering model extended to the weakly non-linear voltage regime, we show that the device's response to a thermal bias can be predicted from its nonlinear response to an electric bias. Our approach forms a foundation for the discovery and understanding of advanced, nonlocal, thermoelectric phenomena that in the future may lead to novel thermoelectric device concepts.

cond-mat.mes-hall↗

arXiv2011

Increasing thermoelectric performance using coherent transport

We show that coherent electron transport through zero-dimensional systems can be used to tailor the shape of the system's transmission function. This quantum-engineering approach can be used to enhance the performance of quantum dots or molecules in thermal-to-electric power conversion. Specifically, we show that electron interference in a two-level system can substantially improve the maximum thermoelectric power and the efficiency at maximum power by suppressing parasitic charge flow near the Fermi energy, and by reducing electronic heat conduction. We discuss possible realizations of this approach in molecular junctions or quantum dots.

cond-mat.mes-hall↗

arXiv2010

Thermoelectric efficiency at maximum power in low-dimensional systems

Low-dimensional electronic systems in thermoelectrics have the potential to achieve high thermal-to-electric energy conversion efficiency. A key measure of performance is the efficiency when the device is operated under maximum power conditions. Here we study the efficiency at maximum power of three low-dimensional, thermoelectric systems: a zero-dimensional quantum dot (QD) with a Lorentzian transmission resonance of finite width, a one-dimensional (1D) ballistic conductor, and a thermionic (TI) power generator formed by a two-dimensional energy barrier. In all three systems, the efficiency at maximum power is independent of temperature, and in each case a careful tuning of relevant energies is required to achieve maximal performance. We find that quantum dots perform relatively poorly under maximum power conditions, with relatively low efficiency and small power throughput. Ideal one-dimensional conductors offer the highest efficiency at maximum power (36% of the Carnot efficiency). Whether 1D or TI systems achieve the larger maximum power output depends on temperature and area filling factor. These results are also discussed in the context of the traditional figure of merit $ZT$.

cond-mat.mes-hall↗

arXiv2010

A Master equation approach to modeling an artificial protein motor

Linear bio-molecular motors move unidirectionally along a track by coordinating several different processes, such as fuel (ATP) capture, hydrolysis, conformational changes, binding and unbinding from a track, and center-of-mass diffusion. A better understanding of the interdependencies between these processes, which take place over a wide range of different time scales, would help elucidate the general operational principles of molecular motors. Artificial molecular motors present a unique opportunity for such a study because motor structure and function are a priori known. Here we describe use of a Master equation approach, integrated with input from Langevin and molecular dynamics modeling, to stochastically model a molecular motor across many time scales. We apply this approach to a specific concept for an artificial protein motor, the Tumbleweed.

cond-mat.stat-mech↗

arXiv2008

Realization of a feedback controlled flashing ratchet

A flashing ratchet transports diffusive particles using a time-dependent, asymmetric potential. Particle speed is predicted to increase when a feedback algorithm based on particle positions is used. We have experimentally realized such a feedback ratchet using an optical line trap, and observed that use of feedback increases velocity by up to an order of magnitude. We compare two different feedback algorithms for small particle numbers, and find good agreement with simulations. We also find that existing algorithms can be improved to be more tolerant to feedback delay times.

cond-mat.stat-mech↗

arXiv2008

Multi-directional sorting modes in deterministic lateral displacement devices

Deterministic lateral displacement (DLD) devices separate micrometer-scale particles in solution based on their size using a laminar microfluidic flow in an array of obstacles. We investigate array geometries with rational row-shift fractions in DLD devices by use of a simple model including both advection and diffusion. Our model predicts novel multi-directional sorting modes that could be experimentally tested in high-throughput DLD devices containing obstacles that are much smaller than the separation between obstacles.

physics.flu-dyn↗

arXiv2006

Mechanical coupling in flashing ratchets

We consider the transport of rigid objects with internal structure in a flashing ratchet potential by investigating the overdamped behavior of a rod-like chain of evenly spaced point particles. In 1D, analytical arguments show that the velocity can reverse direction multiple times in response to changing the size of the chain or the temperature of the heat bath. The physical reason is that the effective potential experienced by the mechanically coupled objects can have a different symmetry than that of individual objects. All analytical predictions are confirmed by Brownian dynamics simulations. These results may provide a route to simple, coarse-grained models of molecular motor transport that incorporate an object's size and rotational degrees of freedom into the mechanism of transport.

cond-mat.stat-mech↗