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Henri Gouin

Publications and source records attributed to Henri Gouin.

At least 55 records · Page 3Linked to original sources
arXiv2009

The Hamilton principle for fluid binary mixtures with two temperatures

For binary mixtures of fluids without chemical reactions, but with components having different temperatures, the Hamilton principle of least action is able to produce the equation of motion for each component and a balance equation of the total heat exchange between components. In this nonconservative case, a Gibbs dynamical identity connecting the equations of momenta, masses, energy and heat exchange allows to deduce the balance equation of energy of the mixture. Due to the unknown exchange of heat between components, the number of obtained equations is less than the number of field variables. The second law of thermodynamics constrains the possible expression of a supplementary constitutive equation closing the system of equations. The exchange of energy between components produces an increasing rate of entropy and creates a dynamical pressure term associated with the difference of temperature between components. This new dynamical pressure term fits with the results obtained by classical thermodynamical arguments and confirms that the Hamilton principle can afford to obtain the equations of motions for multi-temperature mixtures of fluids.

math-ph↗
arXiv2009

Elastic effects of liquids on surface physics

The contact between a liquid and an elastic solid generates a stress vector depending on the curvature tensor in each point of the separating surface. For nanometer values of the mean curvature and for suitable materials, the stress vector takes significant amplitude on the surface. Although the surface average action of the liquid on the solid is the hydrostatic pressure, the local strain generates torques tending to regularize the surface undulations and asperities.

cond-mat.soft↗
arXiv2009

Liquid nanofilms. A mechanical model for the disjoining pressure

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and, in a mechanical model, the stress tensor is not any more spherical as in homogeneous bulks. The aim of this article is to show that a square-gradient functional taking into account the volume liquid free energy corrected with two surface liquid density functionals is a mean field approximation allowing to study structures of very thin liquid nanofilms near plane solid walls. The model determines analytically the concept of disjoining pressure for liquid films of thicknesses of a very few number of nanometers and yields a behavior in good agreement with the shapes of experimental curves carried out by Derjaguin and his successors.

cond-mat.soft↗
arXiv2008

A new approach for the limit to tree height using a liquid nanolayer model

Liquids in contact with solids are submitted to intermolecular forces inferring density gradients at the walls. The van der Waals forces make liquid heterogeneous, the stress tensor is not any more spherical as in homogeneous bulks and it is possible to obtain stable thin liquid films wetting vertical walls up to altitudes that incompressible fluid models are not forecasting. Application to micro tubes of xylem enables to understand why the ascent of sap is possible for very high trees like sequoias or giant eucalyptus.

physics.bio-ph↗
arXiv2008

Dynamics of liquid nanofilms

The van der Waals forces across a very thin liquid layer (nanofilm) in contact with a plane solid wall make the liquid nonhomogeneous. The dynamics of such flat liquid nanofilms is studied in isothermal case. The Navier-Stokes equations are unable to describe fluid motions in very thin films. The notion of surface free energy of a sharp interface separating gas and liquid layer is disqualified. The concept of disjoining pressure replaces the model of surface energy. In the nanofilm a supplementary free energy must be considered as a functional of the density. The equation of fluid motions along the nanofilm is obtained through the Hamilton variational principle by adding, to the conservative forces, the forces of viscosity in lubrication approximation. The evolution equation of the film thickness is deduced and takes into account the variation of the disjoining pressure along the layer.

physics.class-ph↗
arXiv2008

A mechanical model for liquid nanolayers

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and stress tensors are not any more spherical as in homogeneous bulks. The aim of this article is to show that a square-gradient functional representing liquid-vapor interface free energy corrected with a liquid density functional at solid surfaces is a well adapted model to study structures of very thin nanofilms near solid walls. This result makes it possible to study the motions of liquids in nanolayers and to generalize the approximation of lubrication in long wave hypothesis.

physics.class-ph↗
arXiv2008

Radius and surface tension of microscopic bubbles by second gradient theory

The classical theory of Laplace is not suitable for describing the behavior of microscopic bubbles. The theory of second gradient fluids (which are able to exert shear stresses in equilibrium conditions) allows us to obtain a new expression for surface tension and radius of these bubbles in terms of functionals of the chemical potential. This relationship allows us to generalize the results of Cahn-Hilliard and Tolman.

physics.class-ph↗
arXiv2008

Bubble number in a caviting flow

Cavitation is a general phenomenon of the fluid flows with obstacles. It appears in the cooling conduits of the fast nuclear engines. A model of this phenomenon using the theory of Laplace and a common non-convex energy for the liquid and vapour bulks is proposed. This model makes it possible to determine a higher limit of the density of bubbles (a number of bubbles per unit of volume in the flow). The maximum intensity of cavitation is associated with the mechanical and thermal characteristics of the fluid flow.

physics.class-ph↗
arXiv2008

Variational Theory of Mixtures in Continuum Mechanics

In continuum mechanics, the equations of motion for mixtures are derived through the use of Hamilton's extended principle which regards the mixture as a collection of distinct continua. The internal energy is assumed to be a function of densities, entropies and successive spatial gradients of each constituent. We first write the equations of motion for each constituent of an inviscid miscible mixture of fluids without chemical reactions or diffusion. Our work leads to the equations of motion in an universal thermodynamic form in which interaction terms subject to constitutive laws, difficult to interpret physically, do not occur. For an internal energy function of densities, entropies and spatial gradients, an equation describing the barycentric motion of the constituents is obtained. The result is extended for dissipative mixtures and an equation of energy is obtained. A form of Clausius-Duhem's inequality which represents the second law of thermodynamics is deduced. In the particular case of compressible mixtures, the equations reproduce the classical results. Far from critical conditions, the interfaces between different phases in a mixture of fluids are layers with strong gradients of density and entropy. The surface tension of such interfaces is interpreted.

physics.class-ph↗
arXiv2008

Variational Principle Involving the Stress Tensor in Elastodynamics

In the mechanics of inviscid conservative fluids, it is classical to generate the equations of dynamics by formulating with adequate variables, that the pressure integral calculated in the time-space domain corresponding to the motion of the continuous medium is stationary. The present study extends this principle to the dynamics of large deformations for isentropic motions in thermo-elastic bodies: we use a new way of writing the equations of motion in terms of potentials and we substitute the trace of the stress tensor for the pressure term.

physics.class-ph↗
arXiv2008

Identification of an average temperature and a dynamical pressure in a multitemperature mixture of fluids

We present a classical approach of a mixture of compressible fluids when each constituent has its own temperature. The introduction of an average temperature together with the entropy principle dictates the classical Fick law for diffusion and also novel constitutive equations associated with the difference of temperatures between the components. The constitutive equations fit with results recently obtained through Maxwellian iteration procedure in extended thermodynamics theory of multitemperature mixtures. The differences of temperatures between the constituents imply the existence of a new dynamical pressure even if the fluids have a zero bulk viscosity. The nonequilibrium dynamical pressure can be measured and may be convenient in several physical situations as for example in cosmological circumstances where - as many authors assert - a dynamical pressure played a major role in the evolution of the early universe.

physics.class-ph↗
arXiv2008

Hamiltonian Principle in Binary Mixtures of Euler Fluids with Applications to the Second Sound Phenomena

In the present paper we compare the theory of mixtures based on Rational Thermomechanics with the one obtained by Hamilton principle. We prove that the two theories coincide in the adiabatic case when the action is constructed with the intrinsic Lagrangian. In the complete thermodynamical case we show that we have also coincidence in the case of low temperature when the second sound phenomena arises for superfluid Helium and crystals.

physics.class-ph↗
arXiv2008

Dynamics effects in gradient theory for fluid mixtures

We propose a new method to study motions of mixtures in fluid interfaces. We extend the equations of equilibrium in interfaces and the results associated with travelling waves for van der Waals like fluids. Maxwell rule is extended to interfaces of fluid mixtures out of equilibrium. Formulae like Clapeyron relation are obtained for isothermal layers.

physics.flu-dyn↗
arXiv2008

Invariance Properties of Inviscid Fluids of Grade n

Fluids of grade n are continuous media in dynamic changes of phases avoiding the surfaces of discontinuity and representing the capillary layers in liquid-vapour interfaces. We recall the thermodynamic form of the equation of motion for inviscid fluids of grade n. First integrals and theorems of circulation are deduced. A general classification of flows is proposed.

physics.class-ph↗
arXiv2008

Thermocapillary fluid and adiabatic waves near the critical point

Isothermal interfacial zones are investigated starting from a local energy which can be considered as the sum of two terms: one corresponding to a medium with a uniform composition equal to the local one and a second one associated with the non-uniformity of the fluid. In an extended van der Waals theory, the volume internal energy is proposed with a gradient expansion depending not only on the gradient of density but also on the gradient of entropy. We obtain the equation of conservative motions for non-homogeneous fluids near its critical point. For such a medium, it is not possible to obtain shock waves. The waves are tangential to the interface and the wave celerity is expressed depending on thermodynamic conditions at the critical point.

math-ph↗
arXiv2008

Wetting problem for multi-component fluid mixtures

In this paper we propose an extension of the Cahn method to binary mixtures and study the problem of wetting near a two-phase critical point without any assumption on the form of intermolecular potentials. A comparison between Cahn's method and later works by Sullivan, Evans et al is made. By using an expression of the energy of interaction between solid surface and liquids proposed recently by Gouin, we obtain the equations of density profiles and the boundary conditions on a solid surface. In the case of a convex free energy, a one-dimensional solution of a linear problem is proposed for the density profiles between a bulk and on a solid wall. A non-linear model of binary mixtures extending Cahn's results for simple fluids is also studied. For the case of a purely attractive wall we have established a criterion of a first order transition in terms of the structure of the level set of the homogeneous part of the free energy. Additively, explicit expressions of density profiles near the wall are proposed. They allow one to consider the adsorption of mixture components by a solid wall.

physics.class-ph↗
arXiv2008

Vibrations of liquid drops in film boiling phenomena: the mathematical model

Flattened liquid drops poured on a very hot surface evaporate quite slowly and float on a film of their own vapour. In the cavities of a surface, an unusual type of vibrational motions occurs. Large vibrations take place and different forms of dynamic drops are possible. They form elliptic patterns with two lobes or hypotrochoid patterns with three lobes or more. The lobes are turning relatively to the hot surface. We present a model of vibrating motions of the drops. Frequencies of the vibrations are calculated regarding the number of lobes. The computations agree with experiments.

physics.class-ph↗