arXiv subjects

Hideki Yamochi

Publications and source records attributed to Hideki Yamochi.

3 recordsLinked to original sources

arXiv2021

Magnetic field-driven transition between valence bond solid and antiferromagnetic order in distorted triangular lattice

A molecular Mott insulator $κ$-(ET)$_2$B(CN)$_4$ [ET = bis(ethylenedithio)tetrathiafulvalene] with a distorted triangular lattice exhibits a quantum disordered state with gapped spin excitation in the ground state. $^{13}$C nuclear magnetic resonance, magnetization, and magnetic torque measurements reveal that magnetic field suppresses valence bond order and induces long-range magnetic order above a critical field $\sim 8$ T. The nuclear spin-lattice relaxation rate $1/T_1$ shows persistent evolution of antiferromagnetic correlation above the transition temperature, highlighting a quantum spin liquid state with fractional excitations. The field-induced transition as observed in the spin-Peierls phase suggests that the valence bond order transition is driven through renormalized one-dimensionality and spin-lattice coupling.

cond-mat.str-el↗

arXiv2019

A molecular diamond lattice antiferromagnet as a Dirac semimetal candidate

The ground state of a molecular diamond-lattice compound (ET)Ag$_4$(CN)$_5$ is investigated by the magnetization and nuclear magnetic resonance spectroscopy. We found that the system exhibits antiferromagnetic long-range ordering with weak ferromagnetism at a high temperature of 102 K owing to the strong electron correlation. The spin susceptibility is well fitted into the diamond-lattice Heisenberg model with a nearest neighbor exchange coupling of 230 K, indicating the less frustrated interactions. The transition temperature elevates up to $\sim$195 K by applying pressure of 2 GPa, which records the highest temperature among organic molecular magnets. The first-principles band calculation suggests that the system is accessible to a three-dimensional topological semimetal with nodal Dirac lines, which has been extensively searched for a half-filling diamond lattice.

cond-mat.str-el↗

arXiv2016

Pressure-Tuned Exchange Coupling of a Quantum Spin Liquid in the Molecular Triangular Lattice $κ$-(ET)$_2$Ag$_2$(CN)$_3$

The effects of pressure on a quantum spin liquid are investigated in an organic Mott insulator $κ$-(ET)$_2$Ag$_2$(CN)$_3$ with a spin-1/2 triangular lattice. The application of negative chemical pressure to $κ$-(ET)$_2$Cu$_2$(CN)$_3$, which is a well-known sister Mott insulator, allows for extensive tuning of antiferromagnetic exchange coupling, with $J/k_{\rm B} = 175 - 310$ K, under hydrostatic pressure. Based on $^{13}$C nuclear magnetic resonance measurements under pressure, we uncover universal scaling in the static and dynamic spin susceptibilities down to low temperatures $\sim 0.1k_{\rm B}T/J$. The persistent fluctuations and residual specific heat coefficient are consistent with the presence of gapless low-lying excitations. Our results thus demonstrate fundamental finite-temperature properties of quantum spin liquid in a wide parameter range.

cond-mat.str-el↗