Searcharxiv⌕ Search

arXiv subjects

Higor V. M. Ferreira

Publications and source records attributed to Higor V. M. Ferreira.

3 recordsLinked to original sources

An overview of the fractional-order gradient descent method and its applications

Recent studies have shown that fractional calculus is an effective alternative mathematical tool in various scientific fields. However, some investigations indicate that results established in differential and integral calculus do not necessarily hold true in fractional calculus. In this work we will compare various methods presented in the literature to improve the Gradient Descent Method, in terms of convergence of the method, convergence to the extreme point, and convergence rate. In general, these methods that generalize the gradient descent algorithm by replacing the gradient with a fractional-order operator are inefficient in achieving convergence to the extremum point of the objective function. To avoid these difficulties, we proposed to choose the Fractional Continuous Time algorithm to generalize the gradient method. In this approach, the convergence of the method to the extreme point of the function is guaranteed by introducing the fractional order in the time derivative, rather than in of the gradient. In this case, the issue of finding the extreme point is resolved, while the issue of stability at the equilibrium point remains. Fractional Continuous Time method converges to extreme point of cost function when fractional-order is between 0 and 1. The simulations shown in this work suggests that a similar result can be found when $1 \leq α\leq 2$. { This paper highlights the main advantages and disadvantages of generalizations of the gradient method using fractional derivatives, aiming to optimize convergence in complex problems. Some chemical problems, with n=11 and 24 optimization parameters, are employed as means of evaluating the efficacy of the propose algorithms. In general, previous studies are restricted to mathematical questions and simple illustrative examples.

math.OC↗

A Fractional Variational Approach to Spectral Filtering Using the Fourier Transform

The interference of fluorescence signals and noise remains a significant challenge in Raman spectrum analysis, often obscuring subtle spectral features that are critical for accurate analysis. Inspired by variational methods similar to those used in image denoising, our approach minimizes a functional involving fractional derivatives to balance noise suppression with the preservation of essential chemical features of the signal, such as peak position, intensity, and area. The original problem is reformulated in the frequency domain through the Fourier transform, making the implementation simple and fast. In this work, we discuss the theoretical framework, practical implementation, and the advantages and limitations of this method in the context of {simulated} Raman data, as well as in image processing. The main contribution of this article is the combination of a variational approach in the frequency domain, the use of fractional derivatives, and the optimization of the {regularization parameter and} derivative order through the concept of Shannon entropy. This work explores how the fractional order, combined with the regularization parameter, affects noise removal and preserves the essential features of the spectrum {and image}. Finally, the study shows that the combination of the proposed strategies produces an efficient, robust, and easily implementable filter.

eess.IV↗

Fractional kinetic modelling of the adsorption and desorption process from experimental SPR curves

The application of surface plasmon resonance (SPR) has transformed the field of study of interactions between a ligand immobilized on the surface of a sensor chip, designated as $L_S$, and an analyte in solution, referred to as $A$. This technique enables the real-time measurement of interactions with high sensitivity. The dynamics of adsorption-desorption process, $A+L_S \rightarrow AL_S$, can be expressed mathematically as a set of coupled integer-order differential equations. However, this approach has limited ability to acoount for temperature distribution, diffusion and transport effects involved in the reaction process. The fractional kinetic model provides a methodology for incorporating non-local effects into the problem. In this study, the proposed model was applied to analyze data to the interaction between Immobilized Baru Protein (IBP) and Congo Red dye (CR) at concentrations ranging from $7.5$ to $97.5$ $μM$, at pH $7.4$ and $16^o$ C. The variation in the kinetic constants was studied, and it was demonstrated that the integer-order model is unable to adequately represent the experimental data. This work has shown that the fractional-order model is capable of capturing the complexity of the adsorption-desorption process involved in the SPR data.

physics.bio-ph↗