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Hilke E. Schlichting

Publications and source records attributed to Hilke E. Schlichting.

At least 37 records · Page 2Linked to original sources

Fleeting but not Forgotten: the Imprint of Escaping Hydrogen Atmospheres on Super-Earth Interiors

Small, close-in exoplanets are divided into two sub-populations: super-Earths and sub-Neptunes. Most super-Earths are thought to have lost their primordially accreted hydrogen-dominated atmospheres via thermally driven winds. We consider the global chemical equilibrium of super-Earths and the lasting impacts of their fleeting hydrogen atmospheres. We find that hydrogen is efficiently sequestered into the interior, oxidising iron and endogenously producing $\sim0.5-1.0\%$ water by mass. As the atmospheres of super-Earths are continuously sculpted by mass loss and chemical equilibration, they remain hydrogen-dominated by mole (number) fraction but become steam-dominated by mass, which may be observable with JWST for planets transitioning across the radius valley. One of the main effects of efficient sequestration of hydrogen into the interior is to produce an under-dense bulk interior compared to that of Earth. We predict bulk densities of super-Earths to be $\sim 5.0 \text{ g cm}^{-3}$ for a $1M_\oplus$ planet, which is consistent with high-precision mass measurements and also population-level inference analyses from atmospheric escape models.

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JWST Reveals CH$_4$, CO$_2$, and H$_2$O in a Metal-rich Miscible Atmosphere on a Two-Earth-Radius Exoplanet

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,μ\mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,μ$m (9.4$σ$), the signature of CO$_2$ at 4.3$\,μ$m (4.8$σ$), water vapor (2.5$σ$), and potential signatures of SO$_2$ at 4.0$\,μ\mathrm{m}$ and CS$_2$ at 4.6$\,μ\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes.

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Under the light of a new star: evolution of planetary atmospheres through protoplanetary disc dispersal and boil-off

The atmospheres of small, close-in exoplanets are vulnerable to rapid mass-loss during protoplanetary disc dispersal via a process referred to as `boil-off', in which confining pressure from the local gas disc reduces, inducing atmospheric loss and contraction. We construct self-consistent models of planet evolution during gaseous core accretion and boil-off. As the surrounding disc gas dissipates, we find that planets lose mass via subsonic breeze outflows which allow causal contact to exist between disc and planet. Planets initially accrete of order $\sim 10\%$ in atmospheric mass, however, boil-off can remove $\gtrsim 90\%$ of this mass during disc dispersal. We show that a planet's final atmospheric mass fraction is strongly dictated by the ratio of cooling timescale to disc dispersal timescale, as well as the planet's core mass and equilibrium temperature. With contributions from core cooling and radioactivity, we show that core luminosity eventually leads to the transition from boil-off to core-powered mass-loss. We find that smaller mass planets closest to their host star may have their atmospheres completely stripped through a combination of boil-off and core-powered mass-loss during disc dispersal, implying the existence of a population-level radius gap emerging as the disc disperses. We additionally consider the transition from boil-off/core-powered mass-loss to X-ray/EUV (XUV) photoevaporation by considering the penetration of stellar XUV photons below the planet's sonic surface. Finally, we show that planets may open gaps in their protoplanetary discs during the late stages of boil-off, which may enhance mass-loss rates.

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A Tale of Two Peas-In-A-Pod: The Kepler-323 and Kepler-104 Systems

In order to understand the relationship between planet multiplicity, mass, and composition, we present newly measured masses of five planets in two planetary systems: Kepler-323 and Kepler-104. We used the HIRES instrument at the W.M. Keck Observatory to collect 79 new radial velocity measurements (RVs) for Kepler-323, which we combined with 48 literature RVs from TNG/HARPS-N. We also conducted a reanalysis of the Kepler-104 system, using 44 previously published RV measurements. Kepler-323 b and c have masses of $2.0^{+1.2}_{-1.1}$ M$_\oplus$ and 6.5$\pm1.6$ M$_\oplus$, respectively, whereas the three Kepler-104 planets are more massive (10.0$\pm2.8$ M$_\oplus$, $7.1^{+3.8}_{-3.5}$ M$_\oplus$, and $5.5^{+4.6}_{-3.5}$ M$_\oplus$ for planets b, c, and d, respectively). The Kepler-104 planets have densities consistent with rocky cores overlaid with gaseous envelopes ($4.1^{+1.2}_{-1.1}$ g/cc, $2.9^{+1.7}_{-1.5}$ g/cc, and $1.6^{+1.5}_{-1.1}$ g/cc respectively), whereas the Kepler-323 planets are consistent with having rocky compositions ($4.5^{+2.8}_{-2.4}$ g/cc and $9.9^{+2.7}_{-2.5}$ g/cc). The Kepler-104 system has among the lowest values for gap complexity ($\mathcal{C}$ = 0.004) and mass partitioning ($\mathcal{Q}$ = 0.03); whereas, the Kepler-323 planets have a mass partitioning similar to that of the Inner Solar System ($\mathcal{Q}$ = 0.28 and $\mathcal{Q}$ = 0.24, respectively). For both exoplanet systems, the uncertainty in the mass partitioning is affected equally by (1) individual mass errors of the planets and (2) the possible existence of undetected low-mass planets, meaning that both improved mass characterization and improved sensitivity to low-mass planets in these systems would better elucidate the mass distribution among the planets.

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The Kepler Giant Planet Search. I: A Decade of Kepler Planet-host Radial Velocities from W. M. Keck Observatory

Despite the importance of Jupiter and Saturn to Earth's formation and habitability, there has not yet been a comprehensive observational study of how giant exoplanets correlate with the architectural properties of close-in, sub-Neptune-sized exoplanets. This is largely because transit surveys are particularly insensitive to planets at orbital separations >1 au, and so their census of Jupiter-like planets is incomplete, inhibiting our study of the relationship between Jupiter-like planets and the small planets that do transit. To investigate the relationship between close-in, small and distant, giant planets, we conducted the Kepler Giant Planet Survey (KGPS). Using the W. M. Keck Observatory High Resolution Echelle Spectrometer, we spent over a decade collecting 2844 radial velocities (RVs; 2167 of which are presented here for the first time) of 63 Sunlike stars that host 157 transiting planets. We had no prior knowledge of which systems would contain giant planets beyond 1 au, making this survey unbiased with respect to previously detected Jovians. We announce RV-detected companions to 20 stars from our sample. These include 13 Jovians (0.3 MJ < M sin i < 13 MJ, 1 au < a < 10 au), eight nontransiting sub-Saturns, and three stellar-mass companions. We also present updated masses and densities of 84 transiting planets. The KGPS project leverages one of the longest-running and most data-rich collections of RVs of the NASA Kepler systems yet, and it will provide a basis for addressing whether giant planets help or hinder the growth of sub-Neptune-sized and terrestrial planets. Future KGPS papers will examine the relationship between small, transiting planets and their long-period companions.

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Mapping out the parameter space for photoevaporation and core-powered mass-loss

Understanding atmospheric escape in close-in exoplanets is critical to interpreting their evolution. We map out the parameter space over which photoevaporation and core-powered mass loss dominate atmospheric escape. Generally, the transition between the two regimes is determined by the location of the Bondi radius (i.e. the sonic point of core-powered outflow) relative to the penetration depth of XUV photons. Photoevaporation dominates the loss when the XUV penetration depth lies inside the Bondi radius ($R_{XUV}<R_B$) and core-powered mass-loss when XUV radiation is absorbed higher up in the flow ($R_B<R_{XUV}$). The transition between the two regimes occurs at a roughly constant ratio of the planet's radius to its Bondi radius, with the exact value depending logarithmically on planetary and stellar properties. In general, core-powered mass-loss dominates for lower-gravity planets with higher equilibrium temperatures, and photoevaporation dominates for higher-gravity planets with lower equilibrium temperatures. However, planets can transition between these two mass-loss regimes during their evolution, and core-powered mass loss can ``enhance'' photo-evaporation over a significant region of parameter space. Interestingly, a planet that is ultimately stripped by core-powered mass-loss has likely only ever experienced core-powered mass-loss. In contrast a planet that is ultimately stripped by photoevaporation could have experienced an early phase of core-powered mass-loss. Applying our results to the observed super-Earth population suggests that it contains significant fractions of planets where each mechanism controlled the final removal of the H/He envelope, although photoevaporation appears to be responsible for the final carving of the exoplanet radius-valley.

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Investigating the Atmospheric Mass Loss of the Kepler-105 Planets Straddling the Radius Gap

An intriguing pattern among exoplanets is the lack of detected planets between approximately $1.5$ R$_\oplus$ and $2.0$ R$_\oplus$. One proposed explanation for this "radius gap" is the photoevaporation of planetary atmospheres, a theory that can be tested by studying individual planetary systems. Kepler-105 is an ideal system for such testing due to the ordering and sizes of its planets. Kepler-105 is a sun-like star that hosts two planets straddling the radius gap in a rare architecture with the larger planet closer to the host star ($R_b = 2.53\pm0.07$ R$_\oplus$, $P_b = 5.41$ days, $R_c = 1.44\pm0.04$ R$_\oplus$, $P_c = 7.13$ days). If photoevaporation sculpted the atmospheres of these planets, then Kepler-105b would need to be much more massive than Kepler-105c to retain its atmosphere, given its closer proximity to the host star. To test this hypothesis, we simultaneously analyzed radial velocities (RVs) and transit timing variations (TTVs) of the Kepler-105 system, measuring disparate masses of $M_b = 10.8\pm2.3$ M$_\oplus$ ($ ρ_b = 0.97\pm0.22$ g cm$^{-3}$) and $M_c = 5.6\pm1.2$ M$_\oplus $ ($ρ_c = 2.64\pm0.61$ g cm$^{-3}$). Based on these masses, the difference in gas envelope content of the Kepler-105 planets could be entirely due to photoevaporation (in 76\% of scenarios), although other mechanisms like core-powered mass loss could have played a role for some planet albedos.

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CHIMERA Occultation Constraints on the Abundance of Kilometer-scale Kuiper Belt Objects

Occultations provide indirect sensitivity to the number density of small Kuiper Belt objects (KBOs) too faint to directly detect telescopically. We present results from the Caltech HI-speed Multicolor camERA (CHIMERA) survey with the Palomar Hale Telescope, which monitored stars over the central 5'x5' of the M22 globular cluster along the ecliptic plane for serendipitous occultations by kilometer-scale KBOs over 63 hr across 24 nights at a 33 Hz frame rate simultaneously in i' and g'. We adapted dense-field photometry and occultation template fitting techniques to this dataset, finding a 95% confidence upper limit on the occultation rate corresponding to an ecliptic sky density of <10^7 deg^-2 of >1 km diameter classical KBOs. We discuss a few of the occultation-like light curve signatures at the edge of the sensitivity limit responsible for setting the upper bounds, and their likely nonviability as true occultations.

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The DECam Ecliptic Exploration Project (DEEP): V. The Absolute Magnitude Distribution of the Cold Classical Kuiper Belt

The DECam Ecliptic Exploration Project (DEEP) is a deep survey of the trans-Neptunian solar system being carried out on the 4-meter Blanco telescope at Cerro Tololo Inter-American Observatory in Chile using the Dark Energy Camera (DECam). By using a shift-and-stack technique to achieve a mean limiting magnitude of $r \sim 26.2$, DEEP achieves an unprecedented combination of survey area and depth, enabling quantitative leaps forward in our understanding of the Kuiper Belt populations. This work reports results from an analysis of twenty 3 sq.\ deg.\ DECam fields along the invariable plane. We characterize the efficiency and false-positive rates for our moving-object detection pipeline, and use this information to construct a Bayesian signal probability for each detected source. This procedure allows us to treat all of our Kuiper Belt Object (KBO) detections statistically, simultaneously accounting for efficiency and false positives. We detect approximately 2300 candidate sources with KBO-like motion at S/N $>6.5$. We use a subset of these objects to compute the luminosity function of the Kuiper Belt as a whole, as well as the Cold Classical (CC) population. We also investigate the absolute magnitude ($H$) distribution of the CCs, and find consistency with both an exponentially tapered power-law, which is predicted by streaming instability models of planetesimal formation, and a rolling power law. Finally, we provide an updated mass estimate for the Cold Classical Kuiper Belt of $M_{CC}(H_r < 12) = 0.0017^{+0.0010}_{-0.0004} M_{\oplus}$, assuming albedo $p = 0.15$ and density $ρ= 1$ g cm$^{-3}$.

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Atmospheres as windows into sub-Neptune interiors: coupled chemistry and structure of hydrogen-silane-water envelopes

Sub-Neptune exoplanets are commonly hypothesized to consist of a silicate-rich magma ocean topped by a hydrogen-rich atmosphere. Previous work studying the outgassing of silicate material has demonstrated that such atmosphere-interior interactions can affect the atmosphere's overall structure and extent. But these models only considered SiO in an atmosphere of hydrogen gas, without considering chemical reactions between them. Here we couple calculations of the chemical equilibrium between H, Si, and O species with an atmospheric structure model. We find that substantial amounts of silane, SiH$_4$, and water, H$_2$O, are produced by the interaction between the silicate-rich interior and hydrogen-rich atmosphere. These species extend high into the atmosphere, though their abundance is greatest at the hottest, deepest regions. For example, for a 4 $M_\oplus$ planet with an equilibrium temperature of 1000 K, a base temperature of 5000 K, and a 0.1 $M_\oplus$ hydrogen envelope, silicon species and water can comprise 30 percent of the atmosphere by number at the bottom of the atmosphere. Due to this abundance enhancement, we find that convection is inhibited at temperatures $\gtrsim 2500$ K. This temperature is lower, implying that the resultant non-convective region is thicker, than was found in previous models which did not account for atmospheric chemistry. Our findings show that significant endogenous water is produced by magma-hydrogen interactions alone, without the need to accrete ice-rich material. We discuss the observability of the signatures of atmosphere-interior interaction and directions for future work, including condensate lofting and more complex chemical networks.

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Earth shaped by primordial H$_2$ atmospheres

Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and evolution models demonstrate that rocky exoplanets commonly formed with hydrogen-rich envelopes that were lost over time. These findings suggest that Earth may also have formed from bodies with H$_2$-rich primary atmospheres. Here we use a self-consistent thermodynamic model to show that Earth's water, core density, and overall oxidation state can all be sourced to equilibrium between H$_2$-rich primary atmospheres and underlying magma oceans in its progenitor planetary embryos. Water is produced from dry starting materials resembling enstatite chondrites as oxygen from magma oceans reacts with hydrogen. Hydrogen derived from the atmosphere enters the magma ocean and eventually the metal core at equilibrium, causing metal density deficits matching that of Earth. Oxidation of the silicate rocks from solar-like to Earth-like oxygen fugacities also ensues as Si, along with H and O, alloys with Fe in the cores. Reaction with hydrogen atmospheres and metal-silicate equilibrium thus provides a simple explanation for fundamental features of Earth's geochemistry that is consistent with rocky planet formation across the galaxy.

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Conclusive evidence for a population of water-worlds around M-dwarfs remains elusive

The population of small, close-in exoplanets is bifurcated into super-Earths and sub-Neptunes. We calculate physically motivated mass-radius relations for sub-Neptunes, with rocky cores and H/He dominated atmospheres, accounting for their thermal evolution, irradiation and mass-loss. For planets $\lesssim 10~$M$_\oplus$, we find that sub-Neptunes retain atmospheric mass fractions that scale with planet mass and show that the resulting mass-radius relations are degenerate with results for `water-worlds' consisting of a 1:1 silicate-to-ice composition ratio. We further demonstrate that our derived mass-radius relation is in excellent agreement with the observed exoplanet population orbiting M-dwarfs and that planet mass and radii alone are insufficient to determine the composition of some sub-Neptunes. Finally, we highlight that current exoplanet demographics show an increase in the ratio of super-Earths to sub-Neptunes with both stellar mass (and therefore luminosity) and age, which are both indicative of thermally driven atmospheric escape processes. Therefore, such processes should not be ignored when making compositional inferences in the mass-radius diagram.

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The fundamentals of Lyman-alpha exoplanet transits

Lyman-$α$ transits have been detected from several nearby exoplanets and are one of our best insights into the atmospheric escape process. However, due to ISM absorption, we typically only observe the transit signature in the blue-wing, making them challenging to interpret. This challenge has been recently highlighted by non-detections from planets thought to be undergoing vigorous escape. Pioneering 3D simulations have shown that escaping hydrogen is shaped into a cometary tail receding from the planet. Motivated by this work, we develop a simple model to interpret Lyman-$α$ transits. Using this framework, we show that the Lyman-$α$ transit depth is primarily controlled by the properties of the stellar tidal field rather than details of the escape process. Instead, the transit duration provides a direct measurement of the velocity of the planetary outflow. This result arises because the underlying physics is the distance a neutral hydrogen atom can travel before it is photoionized in the outflow. Thus, higher irradiation levels, expected to drive more powerful outflows, produce weaker, shorter Lyman-$α$ transits because the outflowing gas is ionized more quickly. Our framework suggests that the generation of energetic neutral atoms may dominate the transit signature early, but the acceleration of planetary material produces long tails. Thus, Lyman-$α$ transits do not primarily probe the mass-loss rates. Instead, they inform us about the velocity at which the escape mechanism is ejecting material from the planet, providing a clean test of predictions from atmospheric escape models.

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The Exoplanet Radius Valley from Gas-driven Planet Migration and Breaking of Resonant Chains

The size frequency distribution of exoplanet radii between 1 and 4$R_{\oplus}$ is bimodal with peaks at $\sim$1.4 $R_{\oplus}$ and $\sim$2.4 $R_{\oplus}$, and a valley at $\sim$1.8$R_{\oplus}$. This radius valley separates two classes of planets -- usually referred to as "super-Earths" and "mini-Neptunes" -- and its origin remains debated. One model proposes that super-Earths are the outcome of photo-evaporation or core-powered mass-loss stripping the primordial atmospheres of the mini-Neptunes. A contrasting model interprets the radius valley as a dichotomy in the bulk compositions, where super-Earths are rocky planets and mini-Neptunes are water-ice rich worlds. In this work, we test whether the migration model is consistent with the radius valley and how it distinguishes these views. In the migration model, planets migrate towards the disk inner edge forming a chain of planets locked in resonant configurations. After the gas disk dispersal, orbital instabilities "break the chains" and promote late collisions. This model broadly matches the period-ratio and planet-multiplicity distributions of Kepler planets, and accounts for resonant chains such as TRAPPIST-1, Kepler-223, and TOI-178. Here, by combining the outcome of planet formation simulations with compositional mass-radius relationships, and assuming complete loss of primordial H-rich atmospheres in late giant-impacts, we show that the migration model accounts for the exoplanet radius valley and the intra-system uniformity ("peas-in-a-pod") of Kepler planets. Our results suggest that planets with sizes of $\sim$1.4 $R_{\oplus}$ are mostly rocky, whereas those with sizes of $\sim$2.4 $R_{\oplus}$ are mostly water-ice rich worlds. Our results do not support an exclusively rocky composition for the cores of mini-Neptunes.

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Properties of the radius valley around low mass stars: Predictions from the core-powered mass-loss mechanism

In recent years, analyzing the bimodality in the size distribution of small planets, i.e., the `radius valley', has given us unprecedented insight into the planet formation process. Here we explore the properties of the radius valley for low mass stars, assuming that the core-powered mass-loss is the dominant process shaping the small exoplanet population. We show that the slope of radius valley in the planet size-orbital period space, to first-order, does not vary with stellar mass and has a negative slope of $\text{d log}R_p/\text{d log}P \simeq -0.11$ even for stars as small as 0.1 $M_\odot$, as observed in latest studies. Furthermore, we find that the slope of the radius valley in the planet size-stellar mass space is $\text{d log}R_p/\text{d log}M_\ast \simeq (3 ζ- 2)/36$ where $ζ$ is given by the stellar mass-luminosity relation $L_\ast \propto M_\ast^ζ$. Because $ζ$ is $\gtrsim$ 2 and increases with stellar mass, we predict that the radius valley has a positive slope in the planet size-stellar mass space across FGKM dwarfs. This slope, however, decreases (increases) in magnitude towards lower (higher) mass stars, due to the variation of $ζ$ with stellar mass. While around 1.0 $M_\odot$ stars the slope is $\text{d log}R_p/\text{d log}M_\ast \sim 0.37$, it is as low as $\sim 0.13$ around 0.1 $M_\odot$ stars. In addition, we find that the radius valley is narrower and less empty around lower mass stars. Finally, we show that predictions for the radius valley for core-powered mass-loss and photoevaporation become increasingly distinct for lower mass stars.

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The importance of silicate vapor in determining the structure, radii, and envelope mass fractions of sub-Neptunes

Substantial silicate vapor is expected to be in chemical equilibrium at temperature conditions typical of the silicate-atmosphere interface of sub-Neptune planets, which can exceed 5000 K. Previous models of the atmospheric structure and evolution of these exoplanets, which have been used to constrain their atmospheric mass fractions, have neglected this compositional coupling. In this work, we show that silicate vapor in a hydrogen-dominated atmosphere acts as a condensable species, decreasing in abundance with altitude. The resultant mean molecular weight gradient inhibits convection at temperatures above $\sim 4000$ K, inducing a near-surface radiative layer. This radiative layer decreases the planet's total radius compared to a planet with the same base temperature and a convective, pure H/He atmosphere. Therefore, we expect silicate vapor to have major effects on the inferred envelope mass fraction and thermal evolution of sub-Neptune planets. We demonstrate that differences in radii, and hence in inferred atmospheric masses, are largest for planets which have larger masses, equilibrium temperatures, and atmospheric mass fractions. The effects are largest for younger planets, but differences can persist on gigayear time-scales for some sub-Neptunes. For a $10 M_\oplus$ planet with $T_\mathrm{eq}=1000$ K and an age of $\sim 300$ Myr, an observed radius consistent with an atmospheric mass fraction of 10% when accounting for silicate vapor would be misinterpreted as indicating an atmospheric mass fraction of 2% if a H/He-only atmosphere were assumed. The presence of silicate vapor in the atmosphere is also expected to have important implications for the accretion and loss of primordial hydrogen atmospheres.

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Chemical equilibrium between Cores, Mantles, and Atmospheres of Super-Earths and Sub-Neptunes, and Implications for their Compositions, Interiors and Evolution

We investigate equilibrium chemistry between molten metal and silicate, and a hydrogen-rich envelope using 18 independent reactions among 25 phase components for sub-Neptune-like exoplanets. Both reactive metal and unreactive metal sequestered in an isolated core are modeled. The overarching effects of equilibration are oxidation of the envelope and reduction of the mantle and core. Hydrogen and oxygen typically comprise significant fractions of metal cores at chemical equilibrium, leading to density deficits that offer a possible alternative explanation for the low densities of the Trappist-1 planets. Reactions with the magma ocean produce significant amounts of SiO and H$_2$O in the envelopes directly above the magma ocean. Molar concentrations in the envelopes of planets with reactive metal are H$_2>\rm{SiO}>CO\sim\rm{Na}\sim\rm{Mg}>\rm{H}_2\rm{O}>>\rm{CO}_2\sim\rm{CH}_4>>\rm{O}_2$ while for the unreactive metal case H$_2$O becomes the second most abundant species, after H$_2$, providing an arbiter for the two scenarios amenable to observation. The water abundances in the atmospheres exceed those in the mantles by at least an order of magnitude in both scenarios. The water concentrations in the silicate mantles are $\sim 0.01$ wt\% and $\sim 0.1$ wt\% in the reactive and unreactive metal core cases, respectively, limiting the H$_2$O that might be outgassed in a future super-Earth. Less dissolved water in the reactive core case is due to sequestration of H and O in the Fe-rich metal. The total hydrogen budget of most sub-Neptunes can be, to first order, estimated from their atmospheres alone, as the atmospheres typically contain more than 90\% of all H.

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Atmosphere Loss by Aerial Bursts

We present a simple analytic description of atmospheric mass loss by aerial bursts and demonstrate that mass loss from aerial bursts becomes significant when the maximum impactor size that leads to an aerial burst rather than a ground explosion, $r_o$, is larger than the minimum impactor size needed to achieve atmospheric loss, $r_{min}$. For vertical trajectories, which give the most stringent limit, this condition is approximately satisfied when $ρ_o/ρ_i \gtrsim 0.4 v_e/v_\infty$, which implies atmospheric densities need to be comparable to impactor densities for impactor velocities that are a few times the escape velocity of the planet. The range of impactor radii resulting in aerial burst-induced mass loss, $r_o-r_{min}$, increases with the ratio of the atmosphere to the impactor density and with the trajectory angle of the impactor. The range of impactor radii that result in aerial burst-induced mass loss and the atmospheric mass lost is larger in adiabatic atmospheres than isothermal atmospheres of equivalent total mass, scale height, and atmospheric surface density. Our results imply that aerial bursts are not expected to significantly contribute to the atmospheric mass-loss history of Earth, but are expected to play an important role for planets and exoplanets similar to Neptune with significant atmospheres. For Neptune-like atmospheres, the atmospheric mass ejected per impactor mass by aerial bursts is comparable to that lost by ground explosions, which implies that, for impactors following a Dohnanyi size distribution, overall loss by aerial busts is expected to exceed that by ground explosions by a factor of $(r_{ground}/r_{aerial})^{0.5}$.

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