Hiranmayee Senapati | Searcharxiv

arXiv2026

Near-Room-Temperature Antiferromagnetic Ordering in the Quadruple Perovskite Sr4NaRu3O12

We report the synthesis, structure and magnetic properties of two 1:3 ordered quadruple perovskites Sr4MRu3O12 (M = Li and Na). Sr4NaRu3O12 crystallizes in the centrosymmetric space group R-3 and Sr4LiRu3O12 appears to be isostructural to the Na compound based on the PXRD data. In Sr4NaRu3O12, both Na and Ru are predominantly ordered at the B sites (here Na/Li and Ru) and the structure contains only corner-connected RuO6 and NaO6 octahedra. This atomic ordering also leads to a rather large unit cell with a = 11.25 Å and c = 27.6 Å compared to the basic 12R structure (a = 5.5 Å and c ~ 27 Å). Magnetic measurements reveal that Sr4NaRu3O12 undergoes a magnetic transition to an antiferromagnetic state below TN ~ 265 K which is confirmed by DSC and neutron diffraction. The Ru moments show a collinear antiferromagnetic spin alignment along the hexagonal c axis with a propagation vector k = (0, 0, 1.5). Interestingly, those Ru moments lying on the three-fold roto-inversion do not significantly contribute to the magnetic order, since they are located between antiferromagnetically coupled Ru atoms and are therefore probably highly frustrated. Band structure calculations on Sr4NaRu3O12 complement the observed magnetic ground state and a semiconducting behavior in the compound. Sr4LiRu3O12 shows a magnetic anomaly below 110 K, possibly associated with competing ferromagnetic and antiferromagnetic interactions.

cond-mat.str-el↗

arXiv2025

Crystal Growth, Band Structure, Magnetism and Electrochemical Properties of Hexavalent Strontium Ruthenium Oxyhydroxide

Ruthenates comprise an interesting class of materials with a wide range of extremely exciting properties, and thus the discovery of new stable ruthenates remains an active area of investigation. We report the crystal growth and comprehensive studies including crystal and electronic structure, magnetic and electrochemical properties of a hexavalent ruthenium oxyhydroxide Sr3Ru2O9H2 prepared through a low-temperature hydrothermal method. Single crystals and powder samples of this phase are isolated by optimising the Sr(OH)2 to KRuO4 ratio while maintaining a high base concentration. The new structure consists of a rare five-coordinated RuVI featuring isolated trigonal prisms and crystallising in a non-centrosymmetric tetragonal system. Isolated Ru polyhedra leading to a large spatial distance ~ 50 pm between the Ru metal centres render the compound paramagnetic despite strong antiferromagnetic correlation. Band structure calculation suggests a metal-like electronic ground state with mostly Ru d and O p orbitals contributing to the Fermi surface. The electrochemical performance of Sr3Ru2O9H2, though not as impressive as RuO2, remains relevant and is on par with other reported OER catalysts.

cond-mat.mtrl-sci↗